IE41743B1 - Process for the manufacture of shaped articles - Google Patents

Process for the manufacture of shaped articles

Info

Publication number: IE41743B1
Authority: IE; Ireland
Prior art keywords: weight; compound; protein; solution; saturated
Prior art date: 1974-10-07

Application number

IE2165/75A

Other languages

English (en)

Other versions

IE41743L (en

Original Assignee

Hoechst Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-10-07

Filing date

1975-10-03

Publication date

1980-03-12

1975-10-03 Application filed by Hoechst Ag filed Critical Hoechst Ag

1976-04-07 Publication of IE41743L publication Critical patent/IE41743L/xx

1980-03-12 Publication of IE41743B1 publication Critical patent/IE41743B1/en

Links

238000000034 method Methods 0.000 title claims description 53
238000004519 manufacturing process Methods 0.000 title claims description 7
239000007788 liquid Substances 0.000 claims abstract description 35
150000001875 compounds Chemical class 0.000 claims abstract description 29
239000007864 aqueous solution Substances 0.000 claims abstract description 27
235000018102 proteins Nutrition 0.000 claims abstract description 25
102000004169 proteins and genes Human genes 0.000 claims abstract description 25
108090000623 proteins and genes Proteins 0.000 claims abstract description 25
238000009987 spinning Methods 0.000 claims abstract description 22
239000005018 casein Substances 0.000 claims abstract description 18
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims abstract description 18
235000021240 caseins Nutrition 0.000 claims abstract description 18
230000001588 bifunctional effect Effects 0.000 claims abstract description 15
229920006395 saturated elastomer Polymers 0.000 claims abstract description 14
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
125000000217 alkyl group Chemical group 0.000 claims abstract description 9
239000007795 chemical reaction product Substances 0.000 claims abstract description 5
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 5
239000001257 hydrogen Substances 0.000 claims abstract description 5
239000002202 Polyethylene glycol Substances 0.000 claims abstract description 3
229920001223 polyethylene glycol Polymers 0.000 claims abstract description 3
238000001556 precipitation Methods 0.000 claims abstract description 3
150000002894 organic compounds Chemical class 0.000 claims abstract 12
239000000243 solution Substances 0.000 claims description 54
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 39
239000004014 plasticizer Substances 0.000 claims description 23
239000012460 protein solution Substances 0.000 claims description 17
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 16
230000001376 precipitating effect Effects 0.000 claims description 14
238000004132 cross linking Methods 0.000 claims description 11
230000000694 effects Effects 0.000 claims description 7
238000010438 heat treatment Methods 0.000 claims description 6
238000002156 mixing Methods 0.000 claims description 5
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
239000003054 catalyst Substances 0.000 claims description 3
235000013580 sausages Nutrition 0.000 claims description 3
150000007824 aliphatic compounds Chemical class 0.000 claims 2
150000001408 amides Chemical class 0.000 claims 1
125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
229920001451 polypropylene glycol Polymers 0.000 claims 1
102000008186 Collagen Human genes 0.000 abstract description 5
108010035532 Collagen Proteins 0.000 abstract description 5
229920001436 collagen Polymers 0.000 abstract description 5
108010010803 Gelatin Proteins 0.000 abstract description 4
-1 diamine compound Chemical class 0.000 abstract description 4
229920000159 gelatin Polymers 0.000 abstract description 4
239000008273 gelatin Substances 0.000 abstract description 4
235000019322 gelatine Nutrition 0.000 abstract description 4
235000011852 gelatine desserts Nutrition 0.000 abstract description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 3
235000017060 Arachis glabrata Nutrition 0.000 abstract description 2
241001553178 Arachis glabrata Species 0.000 abstract description 2
235000010777 Arachis hypogaea Nutrition 0.000 abstract description 2
235000018262 Arachis monticola Nutrition 0.000 abstract description 2
229920002494 Zein Polymers 0.000 abstract description 2
108010055615 Zein Proteins 0.000 abstract description 2
235000020232 peanut Nutrition 0.000 abstract description 2
239000005019 zein Substances 0.000 abstract description 2
229940093612 zein Drugs 0.000 abstract description 2
101100188552 Arabidopsis thaliana OCT3 gene Proteins 0.000 abstract 1
239000000463 material Substances 0.000 description 25
239000003431 cross linking reagent Substances 0.000 description 22
229920003023 plastic Polymers 0.000 description 18
239000004033 plastic Substances 0.000 description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
102000035118 modified proteins Human genes 0.000 description 12
108091005573 modified proteins Proteins 0.000 description 12
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 11
239000000203 mixture Substances 0.000 description 10
102000014171 Milk Proteins Human genes 0.000 description 8
108010011756 Milk Proteins Proteins 0.000 description 8
235000021239 milk protein Nutrition 0.000 description 8
238000003756 stirring Methods 0.000 description 8
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
239000000126 substance Substances 0.000 description 7
235000011149 sulphuric acid Nutrition 0.000 description 7
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
229910052938 sodium sulfate Inorganic materials 0.000 description 6
235000011152 sodium sulphate Nutrition 0.000 description 6
239000001117 sulphuric acid Substances 0.000 description 6
239000000047 product Substances 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
229920000877 Melamine resin Polymers 0.000 description 4
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
239000004202 carbamide Substances 0.000 description 3
239000001913 cellulose Substances 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
238000010382 chemical cross-linking Methods 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
238000005406 washing Methods 0.000 description 3
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
108090000317 Chymotrypsin Proteins 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
229960002376 chymotrypsin Drugs 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
239000013067 intermediate product Substances 0.000 description 2
229910001629 magnesium chloride Inorganic materials 0.000 description 2
229920005615 natural polymer Polymers 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
229940113115 polyethylene glycol 200 Drugs 0.000 description 2
229920005862 polyol Polymers 0.000 description 2
150000003077 polyols Chemical class 0.000 description 2
238000007493 shaping process Methods 0.000 description 2
229920001059 synthetic polymer Polymers 0.000 description 2
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
PACBIGNRUWABMA-UHFFFAOYSA-N 2-(2,3-dihydro-1,3-benzothiazol-2-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(C2SC3=CC=CC=C3N2)=C1O PACBIGNRUWABMA-UHFFFAOYSA-N 0.000 description 1
229920000856 Amylose Polymers 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
WBKCJAUWRNQBAS-UHFFFAOYSA-N NCS(O)(=O)=O.CC1=CC=CC=C1 Chemical compound NCS(O)(=O)=O.CC1=CC=CC=C1 WBKCJAUWRNQBAS-UHFFFAOYSA-N 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
102100033227 Teneurin-2 Human genes 0.000 description 1
101710122316 Teneurin-2 Proteins 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
229920000615 alginic acid Polymers 0.000 description 1
235000010443 alginic acid Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
239000007809 chemical reaction catalyst Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229940100539 dibutyl adipate Drugs 0.000 description 1
MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
235000013773 glyceryl triacetate Nutrition 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000005445 natural material Substances 0.000 description 1
229930014626 natural product Natural products 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
229920001289 polyvinyl ether Polymers 0.000 description 1
ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
230000008961 swelling Effects 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
YZWRNSARCRTXDS-UHFFFAOYSA-N tripropionin Chemical compound CCC(=O)OCC(OC(=O)CC)COC(=O)CC YZWRNSARCRTXDS-UHFFFAOYSA-N 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
210000002268 wool Anatomy 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
- A—HUMAN NECESSITIES
- A22—BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
- A22C—PROCESSING MEAT, POULTRY, OR FISH
- A22C13/00—Sausage casings
- A22C13/0013—Chemical composition of synthetic sausage casings
- A22C13/0016—Chemical composition of synthetic sausage casings based on proteins, e.g. collagen
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Food Science & Technology (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Compositions Of Macromolecular Compounds (AREA)
Artificial Filaments (AREA)
Treatments Of Macromolecular Shaped Articles (AREA)
Peptides Or Proteins (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

IE2165/75A 1974-10-07 1975-10-03 Process for the manufacture of shaped articles IE41743B1 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2447680A DE2447680C3 (de)	1974-10-07	1974-10-07	Verfahren zur Herstellung eines Formkörpers, der aus chemisch modifiziertem Eiweiß besteht, und seine Verwendung

Publications (2)

Publication Number	Publication Date
IE41743L IE41743L (en)	1976-04-07
IE41743B1 true IE41743B1 (en)	1980-03-12

Family

ID=5927696

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IE2165/75A IE41743B1 (en)	1974-10-07	1975-10-03	Process for the manufacture of shaped articles

Country Status (15)

Country	Link
US (1)	US4002710A (2)
JP (1)	JPS5230884A (2)
AT (1)	AT348318B (2)
BE (1)	BE834241A (2)
CA (1)	CA1090074A (2)
CH (1)	CH618201A5 (2)
DE (1)	DE2447680C3 (2)
DK (1)	DK449675A (2)
FR (1)	FR2287321A1 (2)
GB (1)	GB1520757A (2)
IE (1)	IE41743B1 (2)
IT (1)	IT1047709B (2)
LU (1)	LU73517A1 (2)
NL (1)	NL7511730A (2)
SE (1)	SE405978B (2)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2447690C2 (de) *	1974-10-07	1982-02-25	Hoechst Ag, 6000 Frankfurt	Verfahren zur Herstellung eines Kunststoffs auf Basis von chemisch modifiziertem Casein und seine Verwendung
US4142013A (en) *	1974-10-07	1979-02-27	Hoechst Aktiengesellschaft	Shaped article of cellulose hydrate with a coating of plastic material of chemically modified protein and process for the production thereof
DE2539302C2 (de) *	1975-09-04	1982-04-15	Hoechst Ag, 6000 Frankfurt	Verfahren zur Herstellung von Wursthüllen aus Kunststoff aus chemisch modifiziertem Casein
GB1542462A (en) *	1976-02-04	1979-03-21	Ciba Geigy Ag	N-vinyl sulphonyl-or sulphinylalkyl amides ureas and sulphoxylureas and their use as cross-linking agents for hydrophilic colloids
US5596080A (en) *	1994-10-03	1997-01-21	E. I. Du Pont De Nemours And Company	Crosslinking processes/agents for zein
DE19704737A1 (de) *	1997-02-07	1998-08-13	Kalle Nalo Gmbh	Eßbare Formkörper, insbesondere Flach- und Schlauchfolien
DE102005032241A1 (de) *	2005-07-09	2007-01-11	Kalle Gmbh	Nahrungsmittelhülle auf Basis von Cellulosehydrat mit einer Kollagen-Fibrillen und Gelatine enthaltenden Beschichtung
WO2008062840A1 (fr) *	2006-11-21	2008-05-29	Fujifilm Corporation	Procédé d'élimination d'un solvant organique
WO2009044820A1 (ja)	2007-10-02	2009-04-09	Aichi Steel Corporation	マグネトインピーダンス素子およびマグネトインピーダンスセンサ
ES2962943T3 (es) *	2018-01-16	2024-03-21	Viscofan Sa	Tripa alimentaria con propiedades antifúngicas y procedimiento para su producción

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2375103A (en) *	1943-05-22	1945-05-01	Goodrich Co B F	Protein plastic composition
CH555388A (de) *	1970-08-11	1974-10-31	Ciba Geigy Ag	Vernetzung hydrophiler kolloide.
US3885054A (en) *	1973-04-26	1975-05-20	Tee Pak Inc	Edible collagen casing cross-linked by bisulfite addition

1974
- 1974-10-07 DE DE2447680A patent/DE2447680C3/de not_active Expired
1975
- 1975-10-03 CA CA237,014A patent/CA1090074A/en not_active Expired
- 1975-10-03 US US05/619,223 patent/US4002710A/en not_active Expired - Lifetime
- 1975-10-03 IE IE2165/75A patent/IE41743B1/en unknown
- 1975-10-03 GB GB40563/75A patent/GB1520757A/en not_active Expired
- 1975-10-03 CH CH1286075A patent/CH618201A5/de not_active IP Right Cessation
- 1975-10-06 IT IT51660/75A patent/IT1047709B/it active
- 1975-10-06 NL NL7511730A patent/NL7511730A/xx not_active Application Discontinuation
- 1975-10-06 SE SE7511164A patent/SE405978B/xx unknown
- 1975-10-06 BE BE160733A patent/BE834241A/xx unknown
- 1975-10-06 FR FR7530505A patent/FR2287321A1/fr active Granted
- 1975-10-06 AT AT763275A patent/AT348318B/de not_active IP Right Cessation
- 1975-10-06 DK DK449675A patent/DK449675A/da unknown
- 1975-10-06 LU LU73517A patent/LU73517A1/xx unknown
- 1975-10-07 JP JP50121208A patent/JPS5230884A/ja active Pending

Also Published As

Publication number	Publication date
DE2447680A1 (de)	1976-04-15
FR2287321B1 (2)	1980-01-25
JPS5230884A (en)	1977-03-08
FR2287321A1 (fr)	1976-05-07
DE2447680B2 (de)	1980-10-30
IT1047709B (it)	1980-10-20
DK449675A (da)	1976-04-08
BE834241A (fr)	1976-04-06
CA1090074A (en)	1980-11-25
LU73517A1 (2)	1977-05-24
ATA763275A (de)	1978-06-15
NL7511730A (nl)	1976-04-09
SE405978B (sv)	1979-01-15
AT348318B (de)	1979-02-12
GB1520757A (en)	1978-08-09
SE7511164L (sv)	1976-04-08
US4002710A (en)	1977-01-11
DE2447680C3 (de)	1981-10-29
IE41743L (en)	1976-04-07
CH618201A5 (2)	1980-07-15

Publication	Publication Date	Title
US2137235A (en)	1938-11-22	Shaped articles from polymeric materials
US2430860A (en)	1947-11-18	Polyamide-formaldehyde reactions and products thereof
US2214405A (en)	1940-09-10	Plasticized synthetic linear polyamide composition
IE41743B1 (en)	1980-03-12	Process for the manufacture of shaped articles
US4198325A (en)	1980-04-15	Shaped article comprising a permanently plasticized cellulose composition and preparation thereof
KR880001261B1 (ko)	1988-07-16	폴리비닐 알콜 물건의 제조방법
US4002485A (en)	1977-01-11	Process for the production of thermoplastic synthetic materials of chemically modified protein and plastic shaping materials of chemically modified protein and a chemical plasticizer
US4097963A (en)	1978-07-04	Shaped article comprising cellulose hydrate which is chemically modified by polyalkylene oxide containing synthetic polymers, and preparation thereof
US4045239A (en)	1977-08-30	Process for the production of thermoplastic synthetic materials and plastic shaping materials of chemically modified protein and a chemical plasticizer and including a bisacrylamide or bismethacrylamide
JPS63235599A (ja)	1988-09-30	強化セルロースアミノメタネート
US4226264A (en)	1980-10-07	Elastic amylose polymers
JP2566786B2 (ja)	1996-12-25	乳酸とεーカプロラクトンとの共重合体からなる医療用成形物の製造方法
US2404719A (en)	1946-07-23	Acrylonitrile polymer solutions
US3919385A (en)	1975-11-11	Process for producing high fluid-holding fiber mass
US3937672A (en)	1976-02-10	Process for the manufacture of consolidated shaped structures of cellulose hydrate
US4221821A (en)	1980-09-09	Shaped article comprising a permanently plasticized cellulose composition of high mechanical strength and preparation thereof
US2214397A (en)	1940-09-10	Plasticized synthetic linear polyamide composition
US2244183A (en)	1941-06-03	Polymeric materials
US4104444A (en)	1978-08-01	Fiber reinforced chemically modified protein articles
US4777249A (en)	1988-10-11	Crosslinked cellulose aminomethanate
US3084992A (en)	1963-04-09	Process for the manufacture of shaped structures from acrolein polymers
US2487864A (en)	1949-11-15	Linear polyvinyl acetals
US2404725A (en)	1946-07-23	Polymer solutions
US3093446A (en)	1963-06-11	Modified spinning solutions, methods for producing fibers and films, and filmy products produced therefrom
US4076932A (en)	1978-02-28	Process for producing regenerated cellulosic articles