IE44643B1 - Stabilised metal salts of ethylene bis dithiocarbamic acid, compositions containing them and processes for preparing them - Google Patents

Stabilised metal salts of ethylene bis dithiocarbamic acid, compositions containing them and processes for preparing them

Info

Publication number: IE44643B1
Authority: IE; Ireland
Prior art keywords: cinnamic aldehyde; stabilised; composition; metal salt; ethylene bis
Prior art date: 1976-03-10

Application number

IE52977A

Other languages

English (en)

Other versions

IE44643L (en

Original Assignee

Procida

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-03-10

Filing date

1977-03-10

Publication date

1982-02-10

1977-03-10 Application filed by Procida filed Critical Procida

1977-09-10 Publication of IE44643L publication Critical patent/IE44643L/xx

1982-02-10 Publication of IE44643B1 publication Critical patent/IE44643B1/en

Links

150000003839 salts Chemical class 0.000 title claims abstract description 78
229910052751 metal Inorganic materials 0.000 title claims abstract description 54
239000002184 metal Substances 0.000 title claims abstract description 54
AWYFNIZYMPNGAI-UHFFFAOYSA-N ethylenebis(dithiocarbamic acid) Chemical class SC(=S)NCCNC(S)=S AWYFNIZYMPNGAI-UHFFFAOYSA-N 0.000 title claims abstract description 36
238000000034 method Methods 0.000 title claims abstract description 16
230000008569 process Effects 0.000 title claims abstract description 16
239000000203 mixture Chemical class 0.000 title claims description 77
AXMVYSVVTMKQSL-UHFFFAOYSA-N UNPD142122 Natural products OC1=CC=C(C=CC=O)C=C1O AXMVYSVVTMKQSL-UHFFFAOYSA-N 0.000 claims abstract description 81
229940117916 cinnamic aldehyde Drugs 0.000 claims abstract description 81
KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 claims abstract description 81
KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 claims abstract description 80
YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims description 51
229920000940 maneb Polymers 0.000 claims description 51
FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 48
230000000855 fungicidal effect Effects 0.000 claims description 25
239000011717 all-trans-retinol Substances 0.000 claims description 24
235000019169 all-trans-retinol Nutrition 0.000 claims description 24
238000009472 formulation Methods 0.000 claims description 17
239000000843 powder Substances 0.000 claims description 15
239000004563 wettable powder Substances 0.000 claims description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
239000003381 stabilizer Substances 0.000 claims description 12
239000007900 aqueous suspension Substances 0.000 claims description 11
238000001035 drying Methods 0.000 claims description 11
238000006731 degradation reaction Methods 0.000 claims description 10
230000015556 catabolic process Effects 0.000 claims description 9
230000003019 stabilising effect Effects 0.000 claims description 9
239000012084 conversion product Substances 0.000 claims description 8
238000002360 preparation method Methods 0.000 claims description 8
239000000725 suspension Substances 0.000 claims description 8
230000015572 biosynthetic process Effects 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 6
239000011149 active material Substances 0.000 claims description 5
238000009826 distribution Methods 0.000 claims description 4
238000003786 synthesis reaction Methods 0.000 claims description 4
239000004480 active ingredient Substances 0.000 claims description 3
239000006194 liquid suspension Substances 0.000 claims description 3
238000005507 spraying Methods 0.000 claims description 3
239000000126 substance Substances 0.000 claims description 3
238000002156 mixing Methods 0.000 abstract description 6
YAUCKEPYKXHCFF-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate;manganese Chemical compound [Mn].NC(=S)SCCSC(N)=S YAUCKEPYKXHCFF-UHFFFAOYSA-N 0.000 abstract description 4
FROZIYRKKUFAOC-UHFFFAOYSA-N amobam Chemical compound N.N.SC(=S)NCCNC(S)=S FROZIYRKKUFAOC-UHFFFAOYSA-N 0.000 abstract description 3
239000000417 fungicide Substances 0.000 abstract description 3
230000006641 stabilisation Effects 0.000 abstract description 3
238000011105 stabilization Methods 0.000 abstract 1
WWJZWCUNLNYYAU-UHFFFAOYSA-N temephos Chemical compound C1=CC(OP(=S)(OC)OC)=CC=C1SC1=CC=C(OP(=S)(OC)OC)C=C1 WWJZWCUNLNYYAU-UHFFFAOYSA-N 0.000 abstract 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
239000007864 aqueous solution Substances 0.000 description 10
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 9
229910052791 calcium Inorganic materials 0.000 description 9
239000011575 calcium Substances 0.000 description 9
238000003860 storage Methods 0.000 description 9
239000000377 silicon dioxide Substances 0.000 description 8
239000002244 precipitate Substances 0.000 description 6
239000000047 product Substances 0.000 description 6
PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 5
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
238000000354 decomposition reaction Methods 0.000 description 5
229910052748 manganese Inorganic materials 0.000 description 5
239000011572 manganese Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
238000002485 combustion reaction Methods 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
238000003828 vacuum filtration Methods 0.000 description 4
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
239000002671 adjuvant Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
230000006866 deterioration Effects 0.000 description 3
235000007079 manganese sulphate Nutrition 0.000 description 3
239000011702 manganese sulphate Substances 0.000 description 3
SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
150000003751 zinc Chemical class 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
238000013019 agitation Methods 0.000 description 2
RHOJHZRROLYFKX-UHFFFAOYSA-N azane 2-carbamothioylsulfanylethyl carbamodithioate Chemical compound N.NC(=S)SCCSC(N)=S RHOJHZRROLYFKX-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
230000008859 change Effects 0.000 description 2
239000000470 constituent Substances 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
QGDIJZMKEQCRBX-UHFFFAOYSA-N zinc;ethene Chemical group [Zn+2].[CH-]=C.[CH-]=C QGDIJZMKEQCRBX-UHFFFAOYSA-N 0.000 description 2
WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
QRNATDQRFAUDKF-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate Chemical class NC(=S)SCCSC(N)=S QRNATDQRFAUDKF-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
229930040373 Paraformaldehyde Natural products 0.000 description 1
231100000674 Phytotoxicity Toxicity 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
239000010775 animal oil Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
125000002871 cinnamic aldehydes group Chemical group 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000012505 colouration Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000007857 degradation product Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000012990 dithiocarbamate Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000011872 intimate mixture Substances 0.000 description 1
229940018564 m-phenylenediamine Drugs 0.000 description 1
150000002696 manganese Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229940096717 pamine Drugs 0.000 description 1
229920002866 paraformaldehyde Polymers 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
235000009529 zinc sulphate Nutrition 0.000 description 1
239000011686 zinc sulphate Substances 0.000 description 1

Landscapes

Agricultural Chemicals And Associated Chemicals (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

IE52977A 1976-03-10 1977-03-10 Stabilised metal salts of ethylene bis dithiocarbamic acid, compositions containing them and processes for preparing them IE44643B1 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR7606814A FR2343726A1 (fr)	1976-03-10	1976-03-10	Sels metalliques stabilises de l'acide ethylene bis dithiocarbamique, procede de preparation et compositions les contenant

Publications (2)

Publication Number	Publication Date
IE44643L IE44643L (en)	1977-09-10
IE44643B1 true IE44643B1 (en)	1982-02-10

Family

ID=9170211

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IE52977A IE44643B1 (en)	1976-03-10	1977-03-10	Stabilised metal salts of ethylene bis dithiocarbamic acid, compositions containing them and processes for preparing them

Country Status (14)

Country	Link
JP (1)	JPS52116421A (fr)
AR (1)	AR219703A1 (fr)
BE (1)	BE852247A (fr)
BR (1)	BR7701452A (fr)
CA (1)	CA1091863A (fr)
CH (1)	CH597173A5 (fr)
DE (1)	DE2710469A1 (fr)
DK (1)	DK102677A (fr)
FR (1)	FR2343726A1 (fr)
GB (1)	GB1530744A (fr)
IE (1)	IE44643B1 (fr)
IT (1)	IT1086779B (fr)
LU (1)	LU76922A1 (fr)
NL (1)	NL7702528A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2009146079A2 (fr) *	2008-04-01	2009-12-03	Dow Agrosciences Llc	Compositions et procédés pour lutter contre les pathogènes fongiques oomycètes
WO2015140002A1 (fr) *	2014-03-20	2015-09-24	Nestec S.A.	Procédés et compositions utilisant du cinnamaldéhyde et du zinc pour la gestion du poids

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1476610A (fr) *	1965-12-01	1967-04-14	Soc D Etudes Prod Chimique	Procédé de stabilisation de dithiocarbamates et produits résultant de ce procédé
FR2096963A6 (en) *	1970-07-21	1972-03-03	Aries Robert	Long-acting organophosphorus pesticidal compsns - contg a cinnamic acid deriv

1976
- 1976-03-10 FR FR7606814A patent/FR2343726A1/fr active Granted
1977
- 1977-03-09 CA CA273,545A patent/CA1091863A/fr not_active Expired
- 1977-03-09 LU LU76922A patent/LU76922A1/xx unknown
- 1977-03-09 BE BE175609A patent/BE852247A/fr not_active IP Right Cessation
- 1977-03-09 NL NL7702528A patent/NL7702528A/xx not_active Application Discontinuation
- 1977-03-09 CH CH297177A patent/CH597173A5/xx not_active IP Right Cessation
- 1977-03-09 IT IT4840077A patent/IT1086779B/it active
- 1977-03-09 DK DK102677A patent/DK102677A/da not_active Application Discontinuation
- 1977-03-09 AR AR26679377A patent/AR219703A1/es active
- 1977-03-10 IE IE52977A patent/IE44643B1/en unknown
- 1977-03-10 BR BR7701452A patent/BR7701452A/pt unknown
- 1977-03-10 DE DE19772710469 patent/DE2710469A1/de not_active Withdrawn
- 1977-03-10 GB GB1013477A patent/GB1530744A/en not_active Expired
- 1977-03-10 JP JP2550777A patent/JPS52116421A/ja active Pending

Also Published As

Publication number	Publication date
DK102677A (da)	1977-09-11
CH597173A5 (fr)	1978-03-31
LU76922A1 (fr)	1978-10-18
BE852247A (fr)	1977-09-09
NL7702528A (nl)	1977-09-13
DE2710469A1 (de)	1977-09-22
CA1091863A (fr)	1980-12-23
JPS52116421A (en)	1977-09-29
AR219703A1 (es)	1980-09-15
FR2343726B1 (fr)	1979-06-29
BR7701452A (pt)	1977-11-08
GB1530744A (en)	1978-11-01
FR2343726A1 (fr)	1977-10-07
IE44643L (en)	1977-09-10
IT1086779B (it)	1985-05-31

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