IE812127L - Methanol/higher-alcohol mixture. - Google Patents

Methanol/higher-alcohol mixture.

Info

Publication number
IE812127L
IE812127L IE812127A IE212781A IE812127L IE 812127 L IE812127 L IE 812127L IE 812127 A IE812127 A IE 812127A IE 212781 A IE212781 A IE 212781A IE 812127 L IE812127 L IE 812127L
Authority
IE
Ireland
Prior art keywords
methanol
oxides
alcohol mixture
alkali metals
considered
Prior art date
Application number
IE812127A
Other versions
IE51556B1 (en
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam Progetti filed Critical Snam Progetti
Publication of IE812127L publication Critical patent/IE812127L/en
Publication of IE51556B1 publication Critical patent/IE51556B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/26Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Mixtures of methanol and higher alcohols to be used in particular as fuels, either alone or in admixture with petrol, are produced by reacting H2 and CO, possibly in the presence of CO2, in a molar ratio H2:CO of from 0.1:1 to 20:1, preferably from 0.5:1 to 5:1, at a temperature of from 300 to 500 DEG C, preferably from 350 to 450 DEG C, and at a pressure of from 2000 to 16000 KPa, in the presence of a catalyst based on chromium, zinc and at least one alkali metal. The Zn:Cr weight ratio of the catalyst, considered as oxides thereof, is from 5:1 to 1:1 and the alkali metals or the alkali metals as oxides are present in an amount of 0.5 to 5% by weight relative to the total of the elements considered as oxides. [GB2083469A]
IE2127/81A 1980-09-15 1981-09-14 Methanol/higher alcohol mixtures IE51556B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT24659/80A IT1193555B (en) 1980-09-15 1980-09-15 PROCEDURE FOR THE PRODUCTION OF METHANOL MIXTURES AND HIGHER ALCOHOLS AND MIXTURES OBTAINED BY THAT PROCEDURE

Publications (2)

Publication Number Publication Date
IE812127L true IE812127L (en) 1982-03-05
IE51556B1 IE51556B1 (en) 1987-01-07

Family

ID=11214288

Family Applications (1)

Application Number Title Priority Date Filing Date
IE2127/81A IE51556B1 (en) 1980-09-15 1981-09-14 Methanol/higher alcohol mixtures

Country Status (32)

Country Link
JP (1) JPS5780486A (en)
KR (1) KR860000422B1 (en)
AT (1) AT375062B (en)
AU (1) AU546859B2 (en)
BE (1) BE890341A (en)
BR (1) BR8105777A (en)
CA (1) CA1187109A (en)
CH (1) CH651852A5 (en)
CS (1) CS221987B2 (en)
CU (1) CU35516A (en)
DD (1) DD201671A5 (en)
DE (1) DE3136088C2 (en)
DK (1) DK396981A (en)
ES (1) ES8206410A1 (en)
FI (1) FI812866L (en)
FR (1) FR2490215B1 (en)
GB (1) GB2083469B (en)
GR (1) GR74675B (en)
IE (1) IE51556B1 (en)
IN (1) IN154478B (en)
IT (1) IT1193555B (en)
LU (1) LU83631A1 (en)
NL (1) NL8104257A (en)
NO (1) NO156007C (en)
NZ (1) NZ198082A (en)
PH (1) PH17030A (en)
PL (1) PL136284B1 (en)
RO (1) RO83096B (en)
SE (1) SE8105470L (en)
TR (1) TR22083A (en)
YU (1) YU202481A (en)
ZA (1) ZA816258B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3524317A1 (en) * 1985-07-08 1987-01-15 Union Rheinische Braunkohlen METHOD FOR THE CATALYTIC PRODUCTION OF AN ALCOHOL MIXTURE WITH INCREASED ISOBUTANOL CONTENT
US4705532A (en) * 1985-07-15 1987-11-10 The Standard Oil Company Alcohol compositions for blending with gasoline
IT1276931B1 (en) * 1995-10-13 1997-11-03 Snam Progetti PROCEDURE FOR PRODUCING MIXTURES OF METHANOL AND HIGHER ALCOHOLS
CN101918518A (en) * 2008-01-04 2010-12-15 南加州大学 Environmentally friendly ternary transportation flex fuel of gasoline, methanol and bioethanol
CN106390978B (en) * 2016-09-14 2019-04-09 中国科学院大连化学物理研究所 A kind of high temperature carbon dioxide hydrogenation synthesis methanol catalyst and its preparation and application

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB275345A (en) * 1926-05-12 1927-08-11 Synthetic Ammonia & Nitrates Improvements in or relating to the production of methanol and other oxygenated organic compounds
GB323240A (en) * 1928-06-22 1929-12-23 Du Pont Improvements in and relating to the catalytic synthesis of aliphatic alcohols
DE868146C (en) * 1944-01-04 1953-02-23 Basf Ag Process for the production of catalysts from chromium oxide and excess zinc oxide for the synthesis of alcohols from carbon oxide-hydrogen mixtures

Also Published As

Publication number Publication date
DE3136088C2 (en) 1987-03-26
KR830007800A (en) 1983-11-07
YU202481A (en) 1983-06-30
NO156007C (en) 1987-07-08
NL8104257A (en) 1982-04-01
NO813093L (en) 1982-03-16
FI812866A7 (en) 1982-03-16
DD201671A5 (en) 1983-08-03
IE51556B1 (en) 1987-01-07
CH651852A5 (en) 1985-10-15
PH17030A (en) 1984-05-17
RO83096A (en) 1984-02-21
PL233029A1 (en) 1982-04-13
FR2490215B1 (en) 1985-06-14
NO156007B (en) 1987-03-30
ZA816258B (en) 1982-11-24
DK396981A (en) 1982-03-16
AU7439181A (en) 1982-03-25
RO83096B (en) 1984-02-28
ATA396981A (en) 1983-11-15
IT1193555B (en) 1988-07-08
CU35516A (en) 1982-12-22
AU546859B2 (en) 1985-09-26
IT8024659A0 (en) 1980-09-15
NZ198082A (en) 1984-11-09
LU83631A1 (en) 1982-04-14
TR22083A (en) 1986-03-21
PL136284B1 (en) 1986-02-28
IN154478B (en) 1984-11-03
BR8105777A (en) 1982-05-25
BE890341A (en) 1982-03-15
DE3136088A1 (en) 1982-04-15
AT375062B (en) 1984-06-25
SE8105470L (en) 1982-03-16
ES506040A0 (en) 1982-08-16
GR74675B (en) 1984-07-02
FI812866L (en) 1982-03-16
GB2083469A (en) 1982-03-24
ES8206410A1 (en) 1982-08-16
GB2083469B (en) 1984-05-31
JPS5780486A (en) 1982-05-20
CS221987B2 (en) 1983-04-29
CA1187109A (en) 1985-05-14
FR2490215A1 (en) 1982-03-19
KR860000422B1 (en) 1986-04-19

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