IE921161A1 - Agglomeration of high active pastes to form surfactant¹granules useful in detergent compositions - Google Patents

Agglomeration of high active pastes to form surfactant¹granules useful in detergent compositions

Info

Publication number: IE921161A1
Authority: IE; Ireland
Prior art keywords: surfactant; paste; powder; builder; detergent
Prior art date: 1991-04-12

Application number

IE921161A

Other languages

English (en)

Inventor

Lucas Goovaerts

Jose Luis Vega

Original Assignee

Procter & Gamble

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-04-12

Filing date

1992-04-10

Publication date

1992-10-21

1992-04-10 Application filed by Procter & Gamble filed Critical Procter & Gamble

1992-10-21 Publication of IE921161A1 publication Critical patent/IE921161A1/en

Links

239000003599 detergent Substances 0.000 title claims abstract description 79
239000000203 mixture Substances 0.000 title claims abstract description 78
238000005054 agglomeration Methods 0.000 title description 14
230000002776 aggregation Effects 0.000 title description 14
239000004094 surface-active agent Substances 0.000 claims abstract description 114
239000000843 powder Substances 0.000 claims abstract description 91
238000000034 method Methods 0.000 claims abstract description 60
230000008569 process Effects 0.000 claims abstract description 55
239000003945 anionic surfactant Substances 0.000 claims abstract description 31
238000005469 granulation Methods 0.000 claims abstract description 28
230000003179 granulation Effects 0.000 claims abstract description 28
238000002156 mixing Methods 0.000 claims abstract description 28
230000000694 effects Effects 0.000 claims abstract description 26
239000008187 granular material Substances 0.000 claims abstract description 25
239000003093 cationic surfactant Substances 0.000 claims abstract description 7
125000000129 anionic group Chemical group 0.000 claims abstract description 6
239000002563 ionic surfactant Substances 0.000 claims abstract description 5
239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 5
239000002002 slurry Substances 0.000 claims description 40
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 35
239000002245 particle Substances 0.000 claims description 29
238000001694 spray drying Methods 0.000 claims description 19
229910021536 Zeolite Inorganic materials 0.000 claims description 18
238000001035 drying Methods 0.000 claims description 18
239000002736 nonionic surfactant Substances 0.000 claims description 18
239000010457 zeolite Substances 0.000 claims description 18
239000012530 fluid Substances 0.000 claims description 10
238000005086 pumping Methods 0.000 claims description 6
238000001125 extrusion Methods 0.000 claims description 3
238000001704 evaporation Methods 0.000 claims 1
238000010438 heat treatment Methods 0.000 claims 1
239000004615 ingredient Substances 0.000 abstract description 8
238000004090 dissolution Methods 0.000 abstract description 3
238000007580 dry-mixing Methods 0.000 abstract description 2
125000004432 carbon atom Chemical group C* 0.000 description 38
-1 alkyl sulfate acids Chemical class 0.000 description 31
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
125000000217 alkyl group Chemical group 0.000 description 25
239000011734 sodium Substances 0.000 description 25
229910052708 sodium Inorganic materials 0.000 description 25
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 24
239000000463 material Substances 0.000 description 22
239000002253 acid Substances 0.000 description 21
150000003839 salts Chemical class 0.000 description 21
229910000323 aluminium silicate Inorganic materials 0.000 description 19
238000005342 ion exchange Methods 0.000 description 17
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 15
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 13
238000004519 manufacturing process Methods 0.000 description 11
239000003760 tallow Substances 0.000 description 10
239000007859 condensation product Substances 0.000 description 9
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 8
235000014113 dietary fatty acids Nutrition 0.000 description 8
239000006185 dispersion Substances 0.000 description 8
239000000194 fatty acid Substances 0.000 description 8
229930195729 fatty acid Natural products 0.000 description 8
239000000047 product Substances 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
239000007844 bleaching agent Substances 0.000 description 7
238000001816 cooling Methods 0.000 description 7
150000004665 fatty acids Chemical class 0.000 description 7
239000007788 liquid Substances 0.000 description 7
238000006386 neutralization reaction Methods 0.000 description 7
159000000001 potassium salts Chemical class 0.000 description 7
238000012545 processing Methods 0.000 description 7
229910000029 sodium carbonate Inorganic materials 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
150000001340 alkali metals Chemical class 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
235000013305 food Nutrition 0.000 description 6
229920000642 polymer Polymers 0.000 description 6
239000011591 potassium Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
235000017550 sodium carbonate Nutrition 0.000 description 6
238000003860 storage Methods 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
235000013162 Cocos nucifera Nutrition 0.000 description 5
244000060011 Cocos nucifera Species 0.000 description 5
102000004190 Enzymes Human genes 0.000 description 5
108090000790 Enzymes Proteins 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
239000000344 soap Substances 0.000 description 5
159000000000 sodium salts Chemical class 0.000 description 5
239000000126 substance Substances 0.000 description 5
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical group [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
150000008051 alkyl sulfates Chemical class 0.000 description 4
229910000019 calcium carbonate Inorganic materials 0.000 description 4
235000010216 calcium carbonate Nutrition 0.000 description 4
229910001424 calcium ion Inorganic materials 0.000 description 4
235000019864 coconut oil Nutrition 0.000 description 4
239000003240 coconut oil Substances 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000002191 fatty alcohols Chemical class 0.000 description 4
230000003472 neutralizing effect Effects 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
239000006057 Non-nutritive feed additive Substances 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
229920013820 alkyl cellulose Polymers 0.000 description 3
230000008901 benefit Effects 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000015556 catabolic process Effects 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
125000002768 hydroxyalkyl group Chemical group 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 3
235000019832 sodium triphosphate Nutrition 0.000 description 3
239000007921 spray Substances 0.000 description 3
LRZSAGKIMYFLHY-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;dihydrate Chemical compound O.O.OC(=O)CC(O)(C(O)=O)CC(O)=O LRZSAGKIMYFLHY-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
239000012190 activator Substances 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
230000002411 adverse Effects 0.000 description 2
150000001335 aliphatic alkanes Chemical group 0.000 description 2
235000019270 ammonium chloride Nutrition 0.000 description 2
235000011089 carbon dioxide Nutrition 0.000 description 2
239000003518 caustics Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000010168 coupling process Methods 0.000 description 2
238000005859 coupling reaction Methods 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
238000006073 displacement reaction Methods 0.000 description 2
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
239000003752 hydrotrope Substances 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
239000004973 liquid crystal related substance Substances 0.000 description 2
229910052943 magnesium sulfate Inorganic materials 0.000 description 2
235000019341 magnesium sulphate Nutrition 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
235000014366 other mixer Nutrition 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
HSFQBFMEWSTNOW-UHFFFAOYSA-N sodium;carbanide Chemical group [CH3-].[Na+] HSFQBFMEWSTNOW-UHFFFAOYSA-N 0.000 description 2
239000002689 soil Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical class CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
239000004034 viscosity adjusting agent Substances 0.000 description 2
239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
XYJLPCAKKYOLGU-UHFFFAOYSA-N 2-phosphonoethylphosphonic acid Chemical class OP(O)(=O)CCP(O)(O)=O XYJLPCAKKYOLGU-UHFFFAOYSA-N 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
SXKQTYJLWWQUKA-UHFFFAOYSA-N O.O.O.O.O.O.O.O.O.O.OB(O)O.OB(O)O.OB(O)O.OB(O)O Chemical compound O.O.O.O.O.O.O.O.O.O.OB(O)O.OB(O)O.OB(O)O.OB(O)O SXKQTYJLWWQUKA-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
229920000388 Polyphosphate Chemical class 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
235000010724 Wisteria floribunda Nutrition 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
229940091181 aconitic acid Drugs 0.000 description 1
150000001253 acrylic acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
229910000272 alkali metal oxide Inorganic materials 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000005192 alkyl ethylene group Chemical class 0.000 description 1
125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
125000005233 alkylalcohol group Chemical group 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
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239000011362 coarse particle Substances 0.000 description 1
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XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
239000000428 dust Substances 0.000 description 1
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238000004900 laundering Methods 0.000 description 1
238000011068 loading method Methods 0.000 description 1
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VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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238000002844 melting Methods 0.000 description 1
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HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
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LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
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MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
239000003002 pH adjusting agent Substances 0.000 description 1
238000012856 packing Methods 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
239000002304 perfume Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000001205 polyphosphate Chemical class 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
235000019422 polyvinyl alcohol Nutrition 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical class CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
LUIGSJYSMIUMPK-UHFFFAOYSA-N propane-1-sulfonoperoxoic acid Chemical class CCCS(=O)(=O)OO LUIGSJYSMIUMPK-UHFFFAOYSA-N 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
229940071207 sesquicarbonate Drugs 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
241000894007 species Species 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
239000000271 synthetic detergent Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
238000005406 washing Methods 0.000 description 1
229910009112 xH2O Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

IE921161A 1991-04-12 1992-04-10 Agglomeration of high active pastes to form surfactant¹granules useful in detergent compositions IE921161A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP91870061		1991-04-12
EP92870038		1992-03-10

Publications (1)

Publication Number	Publication Date
IE921161A1 true IE921161A1 (en)	1992-10-21

Family

ID=26130357

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IE921161A IE921161A1 (en)	1991-04-12	1992-04-10	Agglomeration of high active pastes to form surfactant¹granules useful in detergent compositions

Country Status (4)

Country	Link
EP (1)	EP0510746A3 (fr)
IE (1)	IE921161A1 (fr)
MA (1)	MA22502A1 (fr)
PT (1)	PT100359A (fr)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5663136A (en) *	1992-06-15	1997-09-02	The Procter & Gamble Company	Process for making compact detergent compositions
EP0578872B1 (fr) *	1992-07-15	1998-10-14	The Procter & Gamble Company	Compositions de détergents
EP0618289B1 (fr) *	1993-03-30	1998-08-19	The Procter & Gamble Company	Détergents granulaires à haute activité comprenant des agents de chelation et polymères et leur procédés de préparation
EP0639638A1 (fr) *	1993-08-18	1995-02-22	The Procter & Gamble Company	Procédé de préparation de compositions détergentes
US5486303A (en) *	1993-08-27	1996-01-23	The Procter & Gamble Company	Process for making high density detergent agglomerates using an anhydrous powder additive
US5733862A (en) *	1993-08-27	1998-03-31	The Procter & Gamble Company	Process for making a high density detergent composition from a sufactant paste containing a non-aqueous binder
SK280571B6 (sk) *	1993-11-24	2000-03-13	Unilever Nv	Časticová detergentná zmes
DE69425550T2 (de) *	1994-01-17	2001-04-26	The Procter & Gamble Company, Cincinnati	Verfahren zur Herstellung von Reinigungsmittelgranulaten
US5478503A (en) *	1994-02-28	1995-12-26	The Procter & Gamble Company	Process for making a granular detergent composition containing succinate hydrotrope and having improved solubility in cold temperature laundering solutions
US5565137A (en) *	1994-05-20	1996-10-15	The Proctor & Gamble Co.	Process for making a high density detergent composition from starting detergent ingredients
US5496487A (en) *	1994-08-26	1996-03-05	The Procter & Gamble Company	Agglomeration process for making a detergent composition utilizing existing spray drying towers for conditioning detergent agglomerates
US5516448A (en) *	1994-09-20	1996-05-14	The Procter & Gamble Company	Process for making a high density detergent composition which includes selected recycle streams for improved agglomerate
US5489392A (en) *	1994-09-20	1996-02-06	The Procter & Gamble Company	Process for making a high density detergent composition in a single mixer/densifier with selected recycle streams for improved agglomerate properties
US5691297A (en) *	1994-09-20	1997-11-25	The Procter & Gamble Company	Process for making a high density detergent composition by controlling agglomeration within a dispersion index
US5574005A (en) *	1995-03-07	1996-11-12	The Procter & Gamble Company	Process for producing detergent agglomerates from high active surfactant pastes having non-linear viscoelastic properties
US5569645A (en) *	1995-04-24	1996-10-29	The Procter & Gamble Company	Low dosage detergent composition containing optimum proportions of agglomerates and spray dried granules for improved flow properties
US5707959A (en) *	1995-05-31	1998-01-13	The Procter & Gamble Company	Processes for making a granular detergent composition containing a crystalline builder
GB9513327D0 (en) *	1995-06-30	1995-09-06	Uniliver Plc	Process for the production of a detergent composition
US5554587A (en) *	1995-08-15	1996-09-10	The Procter & Gamble Company	Process for making high density detergent composition using conditioned air
US5665691A (en) *	1995-10-04	1997-09-09	The Procter & Gamble Company	Process for making a low density detergent composition by agglomeration with a hydrated salt
DE69722627T2 (de) *	1996-07-26	2004-04-29	The Procter & Gamble Company, Cincinnati	Herstellung von kieselsäure enthaltende waschmittelagglomerate mit niedriger dichte
BR9710559A (pt) *	1996-07-26	1999-08-17	Procter & Gamble	Prepara-Æo de aglomerados detergentes de baixa densidade contendo silica
US6610645B2 (en)	1998-03-06	2003-08-26	Eugene Joseph Pancheri	Selected crystalline calcium carbonate builder for use in detergent compositions
TW201024034A (en) *	2008-12-30	2010-07-01	Saint Gobain Abrasives Inc	Bonded abrasive tool and method of forming
US20150252294A1 (en) *	2014-03-10	2015-09-10	Board Of Regents, The University Of Texas System	High active flowable surfactant blends for detergent and other cleaning applications

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES8607378A1 (es) *	1984-08-06	1986-05-16	Kao Corp	Una composicion detergente en polvo de gran densidad
US4925585A (en) *	1988-06-29	1990-05-15	The Procter & Gamble Company	Detergent granules from cold dough using fine dispersion granulation
CA2017921C (fr) *	1989-06-09	1995-05-16	John Michael Jolicoeur	Preparation de granules detergentes par voie de separation d'une pate detergente

1992
- 1992-04-07 EP EP19920200993 patent/EP0510746A3/en not_active Withdrawn
- 1992-04-08 PT PT10035992A patent/PT100359A/pt not_active Application Discontinuation
- 1992-04-10 IE IE921161A patent/IE921161A1/en not_active Application Discontinuation
- 1992-04-10 MA MA22784A patent/MA22502A1/fr unknown

Also Published As

Publication number	Publication date
EP0510746A3 (en)	1993-09-08
PT100359A (pt)	1993-06-30
MA22502A1 (fr)	1992-12-31
EP0510746A2 (fr)	1992-10-28

Legal Events

Date	Code	Title	Description
1995-11-29	FA9A	Application withdrawn section 33(1)

Publication	Publication Date	Title
CA2108166C (fr)	1998-08-04	Structuration chimique de pates de surfactant pour former des granules de surfactant hautement actifs
EP0510746A2 (fr)	1992-10-28	Procédé pour la préparation de granules de détergent condensés
US4925585A (en)	1990-05-15	Detergent granules from cold dough using fine dispersion granulation
EP0715652B1 (fr)	1998-12-16	Procede de fabrication d'agglomerats detersifs de masse volumique elevee
EP0656825B1 (fr)	2002-09-04	Procede de preparation de compositions detersives compactes
US5494599A (en)	1996-02-27	Agglomeration of high active pastes to form surfactant granules useful in detergent compositions
US5663136A (en)	1997-09-02	Process for making compact detergent compositions
EP0578871B1 (fr)	1998-05-27	Procédé et compositions pour détergents sous forme compacte
CA2242420C (fr)	2005-08-30	Procede pour la production d'une composition detergente
US5529710A (en)	1996-06-25	Production of detergent granules with excellent white appearance
CA2140285C (fr)	1999-01-26	Compositions detergentes
US6596683B1 (en)	2003-07-22	Process for preparing a granular detergent composition
US5451354A (en)	1995-09-19	Chemical structuring of surfactant pastes to form high active surfactant granules
EP0560001A1 (fr)	1993-09-15	Pâtes détergentes à haute activité
WO1992018603A1 (fr)	1992-10-29	Agglomeration de pates fortement actives pour former des granules tensioactifs pouvant etre utilises dans des compositions detersives
EP0816486B1 (fr)	2004-04-14	Procédé pour conditionner des pâtes tensio-actives pour obtenir des agglomérats tensio-actifs à haute activité
US6172033B1 (en)	2001-01-09	Process for conditioning of surfactant pastes to form high active surfactant agglomerates
PL191480B1 (pl)	2006-05-31	Sposób wytwarzania granulowanego detergentowego produktu
JP2002533531A (ja)	2002-10-08	顆粒状洗剤組成物の製造方法