IL142827A - Method for protecting and consolidating calcareous materials - Google Patents

Method for protecting and consolidating calcareous materials

Info

Publication number: IL142827A
Authority: IL; Israel
Prior art keywords: rinsing; approximately; aqueous solution; solution; applying
Prior art date: 1998-10-29

Application number

IL14282799A

Other languages

English (en)

Other versions

IL142827A0 (en

Original Assignee

Mcc Materials Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-10-29

Filing date

1999-10-28

Publication date

2004-09-27

1999-10-28 Application filed by Mcc Materials Inc filed Critical Mcc Materials Inc

2002-03-10 Publication of IL142827A0 publication Critical patent/IL142827A0/xx

2004-09-27 Publication of IL142827A publication Critical patent/IL142827A/en

Links

238000000034 method Methods 0.000 title claims abstract description 76
239000000463 material Substances 0.000 title claims description 46
238000006243 chemical reaction Methods 0.000 claims abstract description 76
229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 37
239000011707 mineral Substances 0.000 claims abstract description 37
239000007864 aqueous solution Substances 0.000 claims abstract description 36
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 10
239000003795 chemical substances by application Substances 0.000 claims abstract description 10
239000000243 solution Substances 0.000 claims description 65
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 34
229940095064 tartrate Drugs 0.000 claims description 19
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 16
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 16
239000000920 calcium hydroxide Substances 0.000 claims description 16
229910001861 calcium hydroxide Inorganic materials 0.000 claims description 14
239000001358 L(+)-tartaric acid Substances 0.000 claims description 10
235000011002 L(+)-tartaric acid Nutrition 0.000 claims description 10
FEWJPZIEWOKRBE-LWMBPPNESA-N L-(+)-Tartaric acid Natural products OC(=O)[C@@H](O)[C@H](O)C(O)=O FEWJPZIEWOKRBE-LWMBPPNESA-N 0.000 claims description 10
VLBFTBWEFJRAHI-UHFFFAOYSA-L calcium;2,3-dihydroxybutanedioate;tetrahydrate Chemical compound O.O.O.O.[Ca+2].[O-]C(=O)C(O)C(O)C([O-])=O VLBFTBWEFJRAHI-UHFFFAOYSA-L 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 8
238000009472 formulation Methods 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 6
239000000126 substance Substances 0.000 claims description 6
239000011575 calcium Substances 0.000 claims description 5
235000002906 tartaric acid Nutrition 0.000 claims description 5
239000011975 tartaric acid Substances 0.000 claims description 5
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
230000002378 acidificating effect Effects 0.000 claims description 4
239000000908 ammonium hydroxide Substances 0.000 claims description 4
230000002708 enhancing effect Effects 0.000 claims description 3
-1 hydroxycarboxyl Chemical group 0.000 claims description 3
239000005871 repellent Substances 0.000 claims description 3
238000005728 strengthening Methods 0.000 claims description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 2
SGPGESCZOCHFCL-UHFFFAOYSA-N Tilisolol hydrochloride Chemical compound [Cl-].C1=CC=C2C(=O)N(C)C=C(OCC(O)C[NH2+]C(C)(C)C)C2=C1 SGPGESCZOCHFCL-UHFFFAOYSA-N 0.000 claims 1
230000002940 repellent Effects 0.000 claims 1
238000011282 treatment Methods 0.000 description 26
235000010755 mineral Nutrition 0.000 description 21
229910021532 Calcite Inorganic materials 0.000 description 19
239000013078 crystal Substances 0.000 description 18
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 14
239000010459 dolomite Substances 0.000 description 13
229910000514 dolomite Inorganic materials 0.000 description 13
238000007654 immersion Methods 0.000 description 12
239000004579 marble Substances 0.000 description 12
239000004568 cement Substances 0.000 description 11
235000011116 calcium hydroxide Nutrition 0.000 description 10
230000015572 biosynthetic process Effects 0.000 description 9
238000012360 testing method Methods 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
FEWJPZIEWOKRBE-JCYAYHJZSA-L L-tartrate(2-) Chemical compound [O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O FEWJPZIEWOKRBE-JCYAYHJZSA-L 0.000 description 6
229910000019 calcium carbonate Inorganic materials 0.000 description 6
235000010216 calcium carbonate Nutrition 0.000 description 6
235000019738 Limestone Nutrition 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
238000003916 acid precipitation Methods 0.000 description 5
239000000945 filler Substances 0.000 description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
229910001748 carbonate mineral Inorganic materials 0.000 description 4
239000002131 composite material Substances 0.000 description 4
230000006872 improvement Effects 0.000 description 4
230000001965 increasing effect Effects 0.000 description 4
238000011160 research Methods 0.000 description 4
230000000717 retained effect Effects 0.000 description 4
229920006395 saturated elastomer Polymers 0.000 description 4
238000003756 stirring Methods 0.000 description 4
239000012085 test solution Substances 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
239000004567 concrete Substances 0.000 description 3
238000007596 consolidation process Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
239000006028 limestone Substances 0.000 description 3
239000004570 mortar (masonry) Substances 0.000 description 3
230000003287 optical effect Effects 0.000 description 3
230000008569 process Effects 0.000 description 3
239000000047 product Substances 0.000 description 3
239000004575 stone Substances 0.000 description 3
238000012935 Averaging Methods 0.000 description 2
235000008733 Citrus aurantifolia Nutrition 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
235000011941 Tilia x europaea Nutrition 0.000 description 2
230000009102 absorption Effects 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
238000007605 air drying Methods 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
NGPGDYLVALNKEG-OLXYHTOASA-N diammonium L-tartrate Chemical compound [NH4+].[NH4+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O NGPGDYLVALNKEG-OLXYHTOASA-N 0.000 description 2
238000006253 efflorescence Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000004571 lime Substances 0.000 description 2
MIJOQRIGYYXRNY-UHFFFAOYSA-L magnesium 2,3-dihydroxybutanedioate hydrate Chemical class O.C(=O)([O-])C(O)C(O)C(=O)[O-].[Mg+2] MIJOQRIGYYXRNY-UHFFFAOYSA-L 0.000 description 2
238000005259 measurement Methods 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000003973 paint Substances 0.000 description 2
230000035515 penetration Effects 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
238000004321 preservation Methods 0.000 description 2
239000011435 rock Substances 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
238000009736 wetting Methods 0.000 description 2
UUDLQDCYDSATCH-UHFFFAOYSA-N 2,3-dihydroxybutanedioic acid;hydrate Chemical compound O.OC(=O)C(O)C(O)C(O)=O UUDLQDCYDSATCH-UHFFFAOYSA-N 0.000 description 1
BJGIDOPGWGEGSI-UHFFFAOYSA-N 8-ethoxyoctan-1-ol;methane Chemical compound C.C.CCOCCCCCCCCO BJGIDOPGWGEGSI-UHFFFAOYSA-N 0.000 description 1
235000008314 Echinocereus dasyacanthus Nutrition 0.000 description 1
240000005595 Echinocereus dasyacanthus Species 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
239000011398 Portland cement Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000013466 adhesive and sealant Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000009739 binding Methods 0.000 description 1
230000027455 binding Effects 0.000 description 1
HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
125000005586 carbonic acid group Chemical group 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
230000004069 differentiation Effects 0.000 description 1
230000029087 digestion Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000005530 etching Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000012634 fragment Substances 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
238000005286 illumination Methods 0.000 description 1
238000011221 initial treatment Methods 0.000 description 1
YWXYYJSYQOXTPL-SLPGGIOYSA-N isosorbide mononitrate Chemical compound [O-][N+](=O)O[C@@H]1CO[C@@H]2[C@@H](O)CO[C@@H]21 YWXYYJSYQOXTPL-SLPGGIOYSA-N 0.000 description 1
239000011499 joint compound Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000000386 microscopy Methods 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
238000000465 moulding Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011505 plaster Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
206010037844 rash Diseases 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000000523 sample Substances 0.000 description 1
239000000565 sealant Substances 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
230000019635 sulfation Effects 0.000 description 1
238000005670 sulfation reaction Methods 0.000 description 1
150000003892 tartrate salts Chemical class 0.000 description 1
238000012795 verification Methods 0.000 description 1
230000003442 weekly effect Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4584—Coating or impregnating of particulate or fibrous ceramic material
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/23—Acid resistance, e.g. against acid air or rain

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Ceramic Engineering (AREA)
Materials Engineering (AREA)
Structural Engineering (AREA)
Organic Chemistry (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Aftertreatments Of Artificial And Natural Stones (AREA)
Curing Cements, Concrete, And Artificial Stone (AREA)
Chemical Or Physical Treatment Of Fibers (AREA)
Jib Cranes (AREA)
Processing Of Solid Wastes (AREA)
Investigation Of Foundation Soil And Reinforcement Of Foundation Soil By Compacting Or Drainage (AREA)
Superconductors And Manufacturing Methods Therefor (AREA)
Detergent Compositions (AREA)
Saccharide Compounds (AREA)

IL14282799A 1998-10-29 1999-10-28 Method for protecting and consolidating calcareous materials IL142827A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US10614498P	1998-10-29	1998-10-29
PCT/US1999/025447 WO2000026158A1 (en)	1998-10-29	1999-10-28	Method for protecting and consolidating calcareous materials

Publications (2)

Publication Number	Publication Date
IL142827A0 IL142827A0 (en)	2002-03-10
IL142827A true IL142827A (en)	2004-09-27

Family

ID=22309730

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL14282799A IL142827A (en)	1998-10-29	1999-10-28	Method for protecting and consolidating calcareous materials

Country Status (13)

Country	Link
US (2)	US6296905B1 (de)
EP (1)	EP1124773B1 (de)
AT (1)	ATE312802T1 (de)
AU (1)	AU770262B2 (de)
CA (1)	CA2349551C (de)
DE (1)	DE69928958T2 (de)
EG (1)	EG22354A (de)
HU (1)	HUP0104179A3 (de)
IL (1)	IL142827A (de)
MX (1)	MXPA01004299A (de)
PL (1)	PL348111A1 (de)
WO (1)	WO2000026158A1 (de)
ZA (1)	ZA200103412B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2848207A1 (fr) *	2002-12-06	2004-06-11	Lafarge Platres	Procede de reduction du fluage d'un element a base de platre, composition a base de platre et procede de fabrication d'un element a base de platre a fluage reduit
US7255842B1 (en) *	2003-09-22	2007-08-14	United States Of America Department Of Energy	Multi-component removal in flue gas by aqua ammonia
US20060047032A1 (en) *	2004-09-01	2006-03-02	Miller Chandra T	Anionic/cationic masonry sealing systems
ES2265298B1 (es)	2005-07-30	2007-12-16	Universidad De Cadiz	Procedimiento para consolidar rocas y otros materiales de construccion.
WO2017184231A1 (en)	2016-04-20	2017-10-26	Dow Corning Corporation	Lithium alkylsiliconate composition, coating, and method of making same

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3577244A (en)	1968-12-19	1971-05-04	Univ New York	Preservation of limestone structures
US3998878A (en)	1975-11-05	1976-12-21	Boise Cascade Corporation	Selectively separating oxalic, tartaric, glyoxylic and erythronic acids from aqueous solutions containing the same
GB1588963A (en)	1976-07-28	1981-05-07	Nat Res Dev	Stone treatment
FR2511670B1 (fr) *	1981-08-21	1985-12-06	Dev Rech Indle	Procede d'hydrofugation de materiaux de construction et produits destines a la mise en oeuvre de ce procede
DE3141946A1 (de)	1981-10-22	1983-05-05	Siemens AG, 1000 Berlin und 8000 München	Verfahren zur herstellung von reaktionsharzsystemen
CA1165506A (en)	1981-12-07	1984-04-17	Ervin I. Szabo	Method of manufacturing a foundry mould mix containing binder components and mould binder components therefor
IT1212870B (it)	1983-06-01	1989-11-30	Pouchain Maurizio	Porcedimento di riformazione del carbonato di calcio per il restauro di monumenti litici e simili
YU43948B (en) *	1984-11-08	1989-12-31	Centoedei Formzo Es Segedanyag	Protection method against water, for structure materials especially concrete and bricks
IT1207493B (it)	1985-02-22	1989-05-25	Montefuols S P A E Franco Piac	Procedimento per la protezione ed il consolidamento di materiali lapidei
ZA863770B (en) *	1985-06-05	1987-09-30	Johnson & Son Inc S C	Stone surface treating methods and compositions
US4738876A (en)	1985-06-05	1988-04-19	S. C. Johnson & Son, Inc.	Stone surface treating methods and compositions
US4756766A (en)	1987-05-07	1988-07-12	Hertron International, Inc.	Method of cleaning and conditioning surfaces
JPH01320284A (ja) *	1988-06-22	1989-12-26	Toru Shimizu	コンクリートおよびモルタルの結晶増殖剤
IT1227692B (it)	1988-12-19	1991-04-23	Ausimont Srl	Procedimento per la protezione di materiali lapidei, marmo, laterizi e cemento dagli agenti e dagli inquinanti atmosferici
IT1243431B (it)	1990-10-01	1994-06-10	Ausimont Spa	Procedimento per la protezione ed il consolidamento di materiali lapidei
IT1244357B (it)	1991-01-03	1994-07-08	Ausimont Spa	Procedimento per la protezione ed il consolidamento di materiali lapidei
US5459197A (en) *	1992-02-07	1995-10-17	Bayer Aktiengesellschaft	Coating compositions, a process for their production and their use for coating water-resistant substrates
US5282900A (en)	1992-03-19	1994-02-01	Minnesota Mining And Manufacturing Company	Nonwoven surface treating articles, system including same, and method of treating calcium carbonate-containing surfaces with said system
US5490883A (en)	1994-06-16	1996-02-13	The Servicemaster Company, L.P.	Solution and method for cleaning marble surfaces
JP2693741B2 (ja) *	1995-05-22	1997-12-24	菊水化学工業株式会社	床面塗装用組成物
JPH09110558A (ja) *	1995-10-16	1997-04-28	P & Ii Internatl:Kk	カルシウム系無機質材の処理方法およびその処理剤
JPH10218687A (ja) *	1997-02-03	1998-08-18	Taki Chem Co Ltd	コンクリートまたはモルタル用炭酸化抑制剤
FR2767817B1 (fr) *	1997-09-04	1999-11-12	Francais Ciments	Melanges cimentaires a base de clinkers sulfoalumineux et ferroalumineux et leur utilisation dans la construction d'ouvrages cimentaires au contact de solutions agressives

1999
- 1999-10-28 CA CA002349551A patent/CA2349551C/en not_active Expired - Fee Related
- 1999-10-28 US US09/428,713 patent/US6296905B1/en not_active Expired - Fee Related
- 1999-10-28 WO PCT/US1999/025447 patent/WO2000026158A1/en not_active Ceased
- 1999-10-28 HU HU0104179A patent/HUP0104179A3/hu unknown
- 1999-10-28 AT AT99971406T patent/ATE312802T1/de not_active IP Right Cessation
- 1999-10-28 EP EP99971406A patent/EP1124773B1/de not_active Expired - Lifetime
- 1999-10-28 AU AU14575/00A patent/AU770262B2/en not_active Ceased
- 1999-10-28 IL IL14282799A patent/IL142827A/en not_active IP Right Cessation
- 1999-10-28 DE DE69928958T patent/DE69928958T2/de not_active Expired - Fee Related
- 1999-10-28 MX MXPA01004299A patent/MXPA01004299A/es not_active IP Right Cessation
- 1999-10-28 PL PL99348111A patent/PL348111A1/xx unknown
- 1999-10-30 EG EG135999A patent/EG22354A/xx active
2001
- 2001-04-26 ZA ZA200103412A patent/ZA200103412B/en unknown
- 2001-05-10 US US09/852,975 patent/US20020058164A1/en not_active Abandoned

Also Published As

Publication number	Publication date
ATE312802T1 (de)	2005-12-15
EG22354A (en)	2002-12-31
IL142827A0 (en)	2002-03-10
AU770262B2 (en)	2004-02-19
ZA200103412B (en)	2001-12-03
PL348111A1 (en)	2002-05-06
EP1124773B1 (de)	2005-12-14
HUP0104179A3 (en)	2003-05-28
MXPA01004299A (es)	2003-06-06
US6296905B1 (en)	2001-10-02
CA2349551A1 (en)	2000-05-11
EP1124773A1 (de)	2001-08-22
DE69928958T2 (de)	2006-08-24
CA2349551C (en)	2007-09-25
US20020058164A1 (en)	2002-05-16
HUP0104179A2 (hu)	2002-02-28
AU1457500A (en)	2000-05-22
DE69928958D1 (de)	2006-01-19
WO2000026158A1 (en)	2000-05-11

Legal Events

Date	Code	Title
2005-02-20	FF	Patent granted
2005-06-19	KB	Patent renewed
2006-02-05	KB	Patent renewed
2010-11-30	MM9K	Patent not in force due to non-payment of renewal fees

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