IL23759A - Preparation of high impact copolymers - Google Patents

Preparation of high impact copolymers

Info

Publication number: IL23759A
Authority: IL; Israel
Prior art keywords: weight; parts; monomers; mixture; polymerization
Prior art date: 1964-06-26

Application number

IL2375965A

Other languages

English (en)

Original Assignee

Montedison Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1964-06-26

Filing date

1965-06-20

Publication date

1968-12-26

1965-06-20 Application filed by Montedison Spa filed Critical Montedison Spa

1968-12-26 Publication of IL23759A publication Critical patent/IL23759A/en

Links

229920001577 copolymer Polymers 0.000 title claims description 54
238000002360 preparation method Methods 0.000 title claims description 10
239000000203 mixture Substances 0.000 claims description 56
239000000178 monomer Substances 0.000 claims description 51
238000000034 method Methods 0.000 claims description 48
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 39
238000006116 polymerization reaction Methods 0.000 claims description 31
229920001971 elastomer Polymers 0.000 claims description 23
239000005060 rubber Substances 0.000 claims description 23
229920000642 polymer Polymers 0.000 claims description 22
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 18
238000006243 chemical reaction Methods 0.000 claims description 16
229920003051 synthetic elastomer Polymers 0.000 claims description 13
239000000725 suspension Substances 0.000 claims description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
244000043261 Hevea brasiliensis Species 0.000 claims description 9
229920003052 natural elastomer Polymers 0.000 claims description 9
229920001194 natural rubber Polymers 0.000 claims description 9
239000003795 chemical substances by application Substances 0.000 claims description 7
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 5
150000002978 peroxides Chemical class 0.000 claims description 5
239000000126 substance Substances 0.000 claims description 5
229920001169 thermoplastic Polymers 0.000 claims description 5
-1 Inorganic acid salt Chemical class 0.000 claims description 4
239000000463 material Substances 0.000 claims description 4
239000004416 thermosoftening plastic Substances 0.000 claims description 4
239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 3
229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
239000002685 polymerization catalyst Substances 0.000 claims description 3
230000000379 polymerizing effect Effects 0.000 claims description 3
239000004926 polymethyl methacrylate Substances 0.000 claims description 3
229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
238000005904 alkaline hydrolysis reaction Methods 0.000 claims description 2
239000007900 aqueous suspension Substances 0.000 claims description 2
230000007062 hydrolysis Effects 0.000 claims description 2
238000006460 hydrolysis reaction Methods 0.000 claims description 2
239000002861 polymer material Substances 0.000 claims 2
238000007334 copolymerization reaction Methods 0.000 claims 1
150000002148 esters Chemical class 0.000 claims 1
239000000047 product Substances 0.000 description 45
238000002156 mixing Methods 0.000 description 11
238000001125 extrusion Methods 0.000 description 9
229920002857 polybutadiene Polymers 0.000 description 9
239000005062 Polybutadiene Substances 0.000 description 7
239000003054 catalyst Substances 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
239000000243 solution Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
229920002554 vinyl polymer Polymers 0.000 description 4
PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical compound CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 3
241001508691 Martes zibellina Species 0.000 description 3
238000000465 moulding Methods 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
229920001897 terpolymer Polymers 0.000 description 3
FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 description 2
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000011324 bead Substances 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000012535 impurity Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
239000005061 synthetic rubber Substances 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 description 1
229920013645 Europrene Polymers 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
229920013619 Plioflex Polymers 0.000 description 1
229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
230000003064 anti-oxidating effect Effects 0.000 description 1
VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
UPIWXMRIPODGLE-UHFFFAOYSA-N butyl benzenecarboperoxoate Chemical compound CCCCOOC(=O)C1=CC=CC=C1 UPIWXMRIPODGLE-UHFFFAOYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
238000010559 graft polymerization reaction Methods 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000012258 stirred mixture Substances 0.000 description 1
239000004575 stone Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
239000012815 thermoplastic material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

IL2375965A 1964-06-26 1965-06-20 Preparation of high impact copolymers IL23759A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT1415164		1964-06-26

Publications (1)

Publication Number	Publication Date
IL23759A true IL23759A (en)	1968-12-26

Family

ID=11144867

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL2375965A IL23759A (en)	1964-06-26	1965-06-20	Preparation of high impact copolymers

Country Status (9)

Country	Link
BE (1)	BE665901A (de)
CH (1)	CH472447A (de)
DE (1)	DE1569418A1 (de)
DK (1)	DK116096B (de)
ES (1)	ES315115A1 (de)
GB (1)	GB1116256A (de)
IL (1)	IL23759A (de)
NL (1)	NL6508223A (de)
SE (1)	SE332070B (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1193356B (it) *	1980-01-16	1988-06-15	Montedison Spa	Polimeri vinil-aromatici modificati aventi migliorata resistenza alla fessurazione sotto sollecitazione
DE102010028952A1 (de)	2010-05-12	2011-11-17	Wacker Chemie Ag	Low-Profile-Additive auf Basis nachwachsender Rohstoffe

1965
- 1965-06-20 IL IL2375965A patent/IL23759A/en unknown
- 1965-06-22 GB GB2640965A patent/GB1116256A/en not_active Expired
- 1965-06-23 CH CH878365A patent/CH472447A/de not_active IP Right Cessation
- 1965-06-23 DE DE19651569418 patent/DE1569418A1/de active Pending
- 1965-06-24 BE BE665901D patent/BE665901A/xx unknown
- 1965-06-24 SE SE840365A patent/SE332070B/xx unknown
- 1965-06-25 NL NL6508223A patent/NL6508223A/xx unknown
- 1965-06-26 ES ES0315115A patent/ES315115A1/es not_active Expired
1966
- 1966-10-25 DK DK554166A patent/DK116096B/da unknown

Also Published As

Publication number	Publication date
DE1569418A1 (de)	1970-04-16
NL6508223A (de)	1965-12-27
ES315115A1 (es)	1965-11-16
CH472447A (de)	1969-05-15
DK116096B (da)	1969-12-08
GB1116256A (en)	1968-06-06
SE332070B (de)	1971-01-25
BE665901A (de)	1965-10-18

Publication	Publication Date	Title
AU733887B2 (en)	2001-05-31	High gloss high impact monovinylidene aromatic polymers
US3265765A (en)	1966-08-09	Block polymers of monovinyl aromatic hydrocarbons and conjugated dienes
US2958673A (en)	1960-11-01	Graft polymer and method of making
US3449471A (en)	1969-06-10	Process for the production of thermoplastic moulding compositions
US3703566A (en)	1972-11-21	Graft copolymerisation process
CN1064975C (zh)	2001-04-25	制备用橡胶增强的乙烯基芳族共聚物的方法
US3676527A (en)	1972-07-11	Process for preparation of high impact polystyrene
CA1049189A (en)	1979-02-20	Method for producing polystyrene composition
US3178489A (en)	1965-04-13	Multi-stage polymerization process for preparing transparent compositions
US3594451A (en)	1971-07-20	Chlorosulfonated polyethylene graft polymers
US3066115A (en)	1962-11-27	Process for the polymerization of ethylenically unsaturated monomers with a diphenylethane accelerator
US4732924A (en)	1988-03-22	Method for producing vinyl aromatic resin composition
US3622653A (en)	1971-11-23	Grafts of vinyl or vinylidene monomers onto polymerized cyclopentene
US4082820A (en)	1978-04-04	High softening maleic anhydride copolymers
JPH075789B2 (ja)	1995-01-25	ポリブタジエンゴム組成物
US3763123A (en)	1973-10-02	Vinyl halide interpolymers
US3557254A (en)	1971-01-19	Polymerization process
CA2372178A1 (en)	2000-11-23	Method for producing thermoplastic molding materials using rubber solutions
US4306043A (en)	1981-12-15	Process for producing thermoplastic resins
US4137281A (en)	1979-01-30	Impact-resistant, high softening maleic anhydride copolymers
EP0054148A3 (de)	1983-04-06	Verfahren zur kontinuierlichen Herstellung alterungsbeständiger AES-Polymerisate
US3665057A (en)	1972-05-23	Method of preparing high impact resistance resins by a bulk-suspension two stage process
JPH10218953A (ja)	1998-08-18	ゴム状重合体及びその製造方法、及び新規なアニオン重合開始剤及び樹脂組成物
DE2164022C3 (de)	1978-11-23	Verfahren zur Herstellung thermoplastischer Kunststoffe
US3591658A (en)	1971-07-06	Production of butadiene-styrene graft copolymers with a nickel carboxylic acid salt-boron trifluoride etherate-trialkylaluminum catalyst