IL24118A - Process for reactivating a solid phthalocyanine catalyst - Google Patents

Process for reactivating a solid phthalocyanine catalyst

Info

Publication number: IL24118A
Authority: IL; Israel
Prior art keywords: catalyst; composite; process according; phthalocyanine; solution
Prior art date: 1964-08-12

Application number

IL24118A

Other languages

English (en)

Original Assignee

Universal Oil Prod Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1964-08-12

Filing date

1965-08-03

Publication date

1969-02-27

1965-08-03 Application filed by Universal Oil Prod Co filed Critical Universal Oil Prod Co

1969-02-27 Publication of IL24118A publication Critical patent/IL24118A/en

Links

239000003054 catalyst Substances 0.000 title claims description 102
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 title claims description 39
238000000034 method Methods 0.000 title claims description 29
230000008569 process Effects 0.000 title claims description 18
239000007787 solid Substances 0.000 title description 14
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 71
239000000243 solution Substances 0.000 claims description 50
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
239000002131 composite material Substances 0.000 claims description 23
230000001476 alcoholic effect Effects 0.000 claims description 19
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 13
MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical group [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 claims description 12
238000005406 washing Methods 0.000 claims description 12
230000002378 acidificating effect Effects 0.000 claims description 8
229910052751 metal Inorganic materials 0.000 claims description 8
239000002184 metal Substances 0.000 claims description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
-1 anadium Chemical compound 0.000 claims description 5
239000010941 cobalt Substances 0.000 claims description 5
229910017052 cobalt Inorganic materials 0.000 claims description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
230000000274 adsorptive effect Effects 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 4
239000003929 acidic solution Substances 0.000 claims description 3
230000003197 catalytic effect Effects 0.000 claims description 3
239000000463 material Substances 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
239000000377 silicon dioxide Substances 0.000 claims description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
229910052802 copper Inorganic materials 0.000 claims 1
239000010949 copper Substances 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
229910052742 iron Inorganic materials 0.000 claims 1
239000003350 kerosene Substances 0.000 description 14
238000007254 oxidation reaction Methods 0.000 description 14
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
230000003647 oxidation Effects 0.000 description 12
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 11
239000012670 alkaline solution Substances 0.000 description 11
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 10
239000002245 particle Substances 0.000 description 9
230000007420 reactivation Effects 0.000 description 9
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
239000000047 product Substances 0.000 description 8
229910052717 sulfur Inorganic materials 0.000 description 8
239000011593 sulfur Substances 0.000 description 8
239000004215 Carbon black (E152) Substances 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 6
230000009849 deactivation Effects 0.000 description 6
239000007789 gas Substances 0.000 description 6
229930195733 hydrocarbon Natural products 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
239000000203 mixture Substances 0.000 description 6
239000007800 oxidant agent Substances 0.000 description 6
239000002253 acid Substances 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000003502 gasoline Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
229960000583 acetic acid Drugs 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
239000003518 caustics Substances 0.000 description 3
239000003610 charcoal Substances 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
238000011065 in-situ storage Methods 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000009471 action Effects 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
239000000908 ammonium hydroxide Substances 0.000 description 2
238000007664 blowing Methods 0.000 description 2
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
239000000969 carrier Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
150000002019 disulfides Chemical class 0.000 description 2
239000008187 granular material Substances 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000010742 number 1 fuel oil Substances 0.000 description 2
239000003921 oil Substances 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
235000019260 propionic acid Nutrition 0.000 description 2
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
KMHSUNDEGHRBNV-UHFFFAOYSA-N 2,4-dichloropyrimidine-5-carbonitrile Chemical compound ClC1=NC=C(C#N)C(Cl)=N1 KMHSUNDEGHRBNV-UHFFFAOYSA-N 0.000 description 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
IXWIAFSBWGYQOE-UHFFFAOYSA-M aluminum;magnesium;oxygen(2-);silicon(4+);hydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] IXWIAFSBWGYQOE-UHFFFAOYSA-M 0.000 description 1
HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
239000011324 bead Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
150000001721 carbon Chemical class 0.000 description 1
238000010000 carbonizing Methods 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000000571 coke Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000010431 corundum Substances 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
238000001035 drying Methods 0.000 description 1
235000013399 edible fruits Nutrition 0.000 description 1
229910001651 emery Inorganic materials 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000010433 feldspar Substances 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910052621 halloysite Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
230000001788 irregular Effects 0.000 description 1
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000008188 pellet Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000006187 pill Substances 0.000 description 1
239000008262 pumice Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
238000010025 steaming Methods 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
239000001648 tannin Substances 0.000 description 1
235000018553 tannin Nutrition 0.000 description 1
229920001864 tannin Polymers 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
235000020681 well water Nutrition 0.000 description 1
239000002349 well water Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1
150000003755 zirconium compounds Chemical class 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
- B01J2531/56—Vanadium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

IL24118A 1964-08-12 1965-08-03 Process for reactivating a solid phthalocyanine catalyst IL24118A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US389179A US3326816A (en)	1964-08-12	1964-08-12	Reactivating solid phthalocyanine catalyst

Publications (1)

Publication Number	Publication Date
IL24118A true IL24118A (en)	1969-02-27

Family

ID=23537178

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL24118A IL24118A (en)	1964-08-12	1965-08-03	Process for reactivating a solid phthalocyanine catalyst

Country Status (12)

Country	Link
US (1)	US3326816A (de)
AT (1)	AT263179B (de)
BE (1)	BE668037A (de)
CH (1)	CH472235A (de)
DE (1)	DE1275519B (de)
DK (1)	DK123077B (de)
ES (1)	ES316364A1 (de)
FI (1)	FI42529B (de)
GB (1)	GB1108973A (de)
IL (1)	IL24118A (de)
NL (1)	NL151642B (de)
SE (1)	SE329597B (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3460913A (en) *	1966-12-27	1969-08-12	Universal Oil Prod Co	Regeneration of sulfur contaminated catalysts
US4003827A (en) *	1975-06-12	1977-01-18	Universal Oil Products Company	Mercaptan conversion process for a petroleum distillate charge stock
US4009120A (en) *	1975-08-18	1977-02-22	Uop Inc.	Process for the regeneration of a solid bed metal phthalocyanine catalyst system
US4308169A (en) *	1978-12-26	1981-12-29	Uop Inc.	Method of reactivating a catalytic composite of a carrier material and a mercaptan oxidation catalyst
US4299729A (en) *	1978-12-26	1981-11-10	Uop Inc.	Method of reactivating a catalytic composite of an adsorptive carrier material and a mercaptan oxidation catalyst
FR2594136B2 (fr) *	1985-08-13	1988-11-04	Inst Francais Du Petrole	Procede ameliore d'adoucissement de coupes petrolieres
FR2640636B1 (fr) *	1988-12-21	1991-04-05	Total France	Procede d'adoucissement en lit fixe de coupes petrolieres
CN107043656B (zh) *	2017-04-24	2019-08-02	中国天辰工程有限公司	一种用于洗涤硅铝磷分子筛的分散剂及洗涤装置

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE232166C (de) *	1910-08-30	1911-03-13
US2949421A (en) *	1955-12-29	1960-08-16	Sun Oil Co	Preparation and use of acid activated clay
US3053774A (en) *	1960-05-16	1962-09-11	California Research Corp	Aqueous regeneration of silica gel

1964
- 1964-08-12 US US389179A patent/US3326816A/en not_active Expired - Lifetime
1965
- 1965-08-03 IL IL24118A patent/IL24118A/en unknown
- 1965-08-09 AT AT734965A patent/AT263179B/de active
- 1965-08-09 BE BE668037D patent/BE668037A/xx unknown
- 1965-08-10 DE DEU11955A patent/DE1275519B/de active Pending
- 1965-08-11 GB GB34306/65A patent/GB1108973A/en not_active Expired
- 1965-08-11 DK DK412465AA patent/DK123077B/da unknown
- 1965-08-11 ES ES0316364A patent/ES316364A1/es not_active Expired
- 1965-08-11 SE SE10485/65A patent/SE329597B/xx unknown
- 1965-08-11 FI FI1940/65A patent/FI42529B/fi active
- 1965-08-12 NL NL656510511A patent/NL151642B/xx unknown
- 1965-08-12 CH CH1132865A patent/CH472235A/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
DE1275519B (de)	1968-08-22
CH472235A (de)	1969-05-15
BE668037A (de)	1965-12-01
GB1108973A (en)	1968-04-10
SE329597B (de)	1970-10-19
FI42529B (de)	1970-06-01
DK123077B (da)	1972-05-15
AT263179B (de)	1968-07-10
ES316364A1 (es)	1966-03-01
NL151642B (nl)	1976-12-15
NL6510511A (de)	1966-02-14
US3326816A (en)	1967-06-20

Publication	Publication Date	Title
US2988500A (en)	1961-06-13	Treatment of hydrocarbon distillates
US3108081A (en)	1963-10-22	Catalyst and manufacture thereof
US4156641A (en)	1979-05-29	Catalytic oxidation of mercaptan in petroleum distillate including quaternary ammonium hydroxide
US4159964A (en)	1979-07-03	Metal chelate catalyst and alkanolamine hydroxide on adsorptive support
US3252892A (en)	1966-05-24	Oxidation of mercapto compounds using corrinoid catalyst
US4121998A (en)	1978-10-24	Treating a petroleum distillate with a supported metal phthalocyanine and a polynuclear aromatic sulfonic acid
US4908122A (en)	1990-03-13	Process for sweetening a sour hydrocarbon fraction
EP0394571B1 (de)	1993-09-01	Verwendung einer katalytischen Zusammensetzung für das Süssen von sauren Erdöldestillaten
US4206079A (en)	1980-06-03	Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
US4098681A (en)	1978-07-04	Oxidation of mercaptans in a petroleum distillate with a supported metal phthalocyanine catalyst
NO159295B (no)	1988-09-05	Katode for elektrolytisk fremstilling av hydrogen.
US3148156A (en)	1964-09-08	Phthalocyanine catalyst regeneration
US3371031A (en)	1968-02-27	Oxidation of mercapto compounds
US4498978A (en)	1985-02-12	Catalytic oxidation of mercaptan in petroleum distillate
CA1241614A (en)	1988-09-06	Catalytic oxidation of mercaptans in petroleum distillate
US3326816A (en)	1967-06-20	Reactivating solid phthalocyanine catalyst
US4003827A (en)	1977-01-18	Mercaptan conversion process for a petroleum distillate charge stock
CA1072526A (en)	1980-02-26	Process for the regeneration of a solid bed metal phthalocyanine catalyst system
US4107078A (en)	1978-08-15	Preparation of a supported metal phthalocyanine catalyst
RU1826987C (ru)	1993-07-07	Способ очистки высокосернистой углеводородной фракции, содержащей меркаптаны
EP0145408B1 (de)	1988-03-30	Katalytische Oxidation von Merkaptanen in sauren Kohlenwasserstofffraktionen
US4141819A (en)	1979-02-27	Process for treating a sour petroleum distillate
US4203827A (en)	1980-05-20	Process for treating sour petroleum distillates
US4142964A (en)	1979-03-06	Process for treating a sour petroleum distillate
US4072630A (en)	1978-02-07	Metal phthalocyanine catalyst preparation