IL24837A - Thermoplastic polymers containing polyols;and polyurethanes produced therefrom - Google Patents

Thermoplastic polymers containing polyols;and polyurethanes produced therefrom

Info

Publication number: IL24837A
Authority: IL; Israel
Prior art keywords: anhydride; starter; ether; polymer; reaction
Prior art date: 1965-02-18

Application number

IL24837A

Other languages

English (en)

Original Assignee

Columbian Carbon

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1965-02-18

Filing date

1965-12-21

Publication date

1969-03-27

1965-12-21 Application filed by Columbian Carbon filed Critical Columbian Carbon

1969-03-27 Publication of IL24837A publication Critical patent/IL24837A/en

Links

229920001169 thermoplastic Polymers 0.000 title claims description 14
229920002635 polyurethane Polymers 0.000 title claims description 3
239000004814 polyurethane Substances 0.000 title claims description 3
229920005862 polyol Polymers 0.000 title description 33
150000003077 polyols Chemical class 0.000 title description 31
150000008064 anhydrides Chemical class 0.000 claims description 41
239000007858 starting material Substances 0.000 claims description 35
150000004292 cyclic ethers Chemical class 0.000 claims description 24
238000006243 chemical reaction Methods 0.000 claims description 23
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 23
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
229920000642 polymer Polymers 0.000 claims description 18
229920005830 Polyurethane Foam Polymers 0.000 claims description 16
239000011496 polyurethane foam Substances 0.000 claims description 16
150000001875 compounds Chemical class 0.000 claims description 15
125000004432 carbon atom Chemical group C* 0.000 claims description 13
238000006116 polymerization reaction Methods 0.000 claims description 13
239000007795 chemical reaction product Substances 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 11
238000000034 method Methods 0.000 claims description 10
229920001228 polyisocyanate Polymers 0.000 claims description 10
239000005056 polyisocyanate Substances 0.000 claims description 10
125000001033 ether group Chemical group 0.000 claims description 7
239000004416 thermosoftening plastic Substances 0.000 claims description 7
125000000623 heterocyclic group Chemical group 0.000 claims description 6
125000004122 cyclic group Chemical group 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
125000004430 oxygen atom Chemical group O* 0.000 claims description 5
230000001476 alcoholic effect Effects 0.000 claims description 4
150000007524 organic acids Chemical class 0.000 claims description 4
150000007519 polyprotic acids Polymers 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 39
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 22
229920005906 polyester polyol Polymers 0.000 description 19
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 15
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 15
239000004721 Polyphenylene oxide Substances 0.000 description 11
229920000570 polyether Polymers 0.000 description 11
239000000203 mixture Substances 0.000 description 10
238000002360 preparation method Methods 0.000 description 9
-1 tripentek Chemical compound 0.000 description 9
239000002253 acid Substances 0.000 description 7
239000006260 foam Substances 0.000 description 7
239000000376 reactant Substances 0.000 description 7
239000011541 reaction mixture Substances 0.000 description 7
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 6
239000000460 chlorine Substances 0.000 description 6
229910052801 chlorine Inorganic materials 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 4
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 4
229930006000 Sucrose Natural products 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000000047 product Substances 0.000 description 4
229940014800 succinic anhydride Drugs 0.000 description 4
239000005720 sucrose Substances 0.000 description 4
SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 4
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
125000002843 carboxylic acid group Chemical group 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
239000004604 Blowing Agent Substances 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000003776 cleavage reaction Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000009472 formulation Methods 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
239000008240 homogeneous mixture Substances 0.000 description 2
235000005985 organic acids Nutrition 0.000 description 2
150000003141 primary amines Chemical class 0.000 description 2
YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
230000007017 scission Effects 0.000 description 2
AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 2
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
OTJFQRMIRKXXRS-UHFFFAOYSA-N (hydroxymethylamino)methanol Chemical compound OCNCO OTJFQRMIRKXXRS-UHFFFAOYSA-N 0.000 description 1
FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
RXYVNNWGXQRJAC-UHFFFAOYSA-N 1-chloro-1-[3-(trifluoromethyl)phenyl]propan-2-one Chemical compound CC(=O)C(Cl)C1=CC=CC(C(F)(F)F)=C1 RXYVNNWGXQRJAC-UHFFFAOYSA-N 0.000 description 1
DKJBREHOVWISMR-UHFFFAOYSA-N 1-chloro-2,3-diisocyanatobenzene Chemical compound ClC1=CC=CC(N=C=O)=C1N=C=O DKJBREHOVWISMR-UHFFFAOYSA-N 0.000 description 1
VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
PVRZMTHMPKVOBP-UHFFFAOYSA-N 1-n,4-n-dimethylbenzene-1,4-diamine Chemical compound CNC1=CC=C(NC)C=C1 PVRZMTHMPKVOBP-UHFFFAOYSA-N 0.000 description 1
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
JPSKCQCQZUGWNM-UHFFFAOYSA-N 2,7-Oxepanedione Chemical compound O=C1CCCCC(=O)O1 JPSKCQCQZUGWNM-UHFFFAOYSA-N 0.000 description 1
NWPCFCBFUXXJIE-UHFFFAOYSA-N 2-(hydroxymethylamino)ethanol Chemical compound OCCNCO NWPCFCBFUXXJIE-UHFFFAOYSA-N 0.000 description 1
LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
MWGATWIBSKHFMR-UHFFFAOYSA-N 2-anilinoethanol Chemical compound OCCNC1=CC=CC=C1 MWGATWIBSKHFMR-UHFFFAOYSA-N 0.000 description 1
WHNBDXQTMPYBAT-UHFFFAOYSA-N 2-butyloxirane Chemical compound CCCCC1CO1 WHNBDXQTMPYBAT-UHFFFAOYSA-N 0.000 description 1
229910000619 316 stainless steel Inorganic materials 0.000 description 1
UHMARZNHEMRXQH-UHFFFAOYSA-N 3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical class C1=CCCC2C(=O)OC(=O)C21 UHMARZNHEMRXQH-UHFFFAOYSA-N 0.000 description 1
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
DMOSWVCKHJJLLN-UHFFFAOYSA-N 4-(4-amino-2-methylphenyl)-2-methylaniline Chemical group C1=C(N)C(C)=CC(C=2C(=CC(N)=CC=2)C)=C1 DMOSWVCKHJJLLN-UHFFFAOYSA-N 0.000 description 1
KNDQHSIWLOJIGP-UHFFFAOYSA-N 826-62-0 Chemical compound C1C2C3C(=O)OC(=O)C3C1C=C2 KNDQHSIWLOJIGP-UHFFFAOYSA-N 0.000 description 1
239000004135 Bone phosphate Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
ZFIVKAOQEXOYFY-UHFFFAOYSA-N Diepoxybutane Chemical compound C1OC1C1OC1 ZFIVKAOQEXOYFY-UHFFFAOYSA-N 0.000 description 1
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
208000000474 Poliomyelitis Diseases 0.000 description 1
208000036366 Sensation of pressure Diseases 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
XMUZQOKACOLCSS-UHFFFAOYSA-N [2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CO XMUZQOKACOLCSS-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000007824 aliphatic compounds Chemical class 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
RPHKINMPYFJSCF-UHFFFAOYSA-N benzene-1,3,5-triamine Chemical compound NC1=CC(N)=CC(N)=C1 RPHKINMPYFJSCF-UHFFFAOYSA-N 0.000 description 1
HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
IDVDAZFXGGNIDQ-UHFFFAOYSA-N benzo[e][2]benzofuran-1,3-dione Chemical class C1=CC2=CC=CC=C2C2=C1C(=O)OC2=O IDVDAZFXGGNIDQ-UHFFFAOYSA-N 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
238000005266 casting Methods 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000006482 condensation reaction Methods 0.000 description 1
239000006071 cream Substances 0.000 description 1
YMHQVDAATAEZLO-UHFFFAOYSA-N cyclohexane-1,1-diamine Chemical compound NC1(N)CCCCC1 YMHQVDAATAEZLO-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
BQQUFAMSJAKLNB-UHFFFAOYSA-N dicyclopentadiene diepoxide Chemical compound C12C(C3OC33)CC3C2CC2C1O2 BQQUFAMSJAKLNB-UHFFFAOYSA-N 0.000 description 1
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
FLISWPFVWWWNNP-BQYQJAHWSA-N dihydro-3-(1-octenyl)-2,5-furandione Chemical compound CCCCCC\C=C\C1CC(=O)OC1=O FLISWPFVWWWNNP-BQYQJAHWSA-N 0.000 description 1
125000005442 diisocyanate group Chemical group 0.000 description 1
239000000539 dimer Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
229940031098 ethanolamine Drugs 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
229930182478 glucoside Natural products 0.000 description 1
150000008131 glucosides Chemical class 0.000 description 1
VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
NNYHMCFMPHPHOQ-UHFFFAOYSA-N mellitic anhydride Chemical compound O=C1OC(=O)C2=C1C(C(OC1=O)=O)=C1C1=C2C(=O)OC1=O NNYHMCFMPHPHOQ-UHFFFAOYSA-N 0.000 description 1
AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
150000002924 oxiranes Chemical class 0.000 description 1
ZJHUBLNWMCWUOV-UHFFFAOYSA-N oxocane-2,8-dione Chemical compound O=C1CCCCCC(=O)O1 ZJHUBLNWMCWUOV-UHFFFAOYSA-N 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 1
150000004986 phenylenediamines Chemical class 0.000 description 1
MEGDIQXLXPPWGL-UHFFFAOYSA-N phenylmethanetriamine Chemical compound NC(N)(N)C1=CC=CC=C1 MEGDIQXLXPPWGL-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000768 polyamine Chemical class 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000011369 resultant mixture Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
150000000000 tetracarboxylic acids Chemical class 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
229940029284 trichlorofluoromethane Drugs 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
239000013638 trimer Substances 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
- C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4261—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups prepared by oxyalkylation of polyesterpolyols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4291—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from polyester forming components containing monoepoxy compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/68—Unsaturated polyesters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyurethanes Or Polyureas (AREA)
Polyethers (AREA)
Polyesters Or Polycarbonates (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

IL24837A 1965-02-18 1965-12-21 Thermoplastic polymers containing polyols;and polyurethanes produced therefrom IL24837A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US43366065A	1965-02-18	1965-02-18

Publications (1)

Publication Number	Publication Date
IL24837A true IL24837A (en)	1969-03-27

Family

ID=23721045

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL24837A IL24837A (en)	1965-02-18	1965-12-21	Thermoplastic polymers containing polyols;and polyurethanes produced therefrom

Country Status (9)

Country	Link
US (1)	US3455886A (fr)
JP (1)	JPS4833040B1 (fr)
BE (1)	BE676742A (fr)
DE (1)	DE1568249A1 (fr)
ES (1)	ES322299A1 (fr)
FR (1)	FR1463547A (fr)
GB (1)	GB1141417A (fr)
IL (1)	IL24837A (fr)
NL (1)	NL6601190A (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3761434A (en) *	1971-04-30	1973-09-25	Cities Service Oil Co	Petroleum hydrocarbon compositions
US3755212A (en) *	1971-05-13	1973-08-28	Dow Chemical Co	Air blown polyurethane foams
US3965073A (en) *	1973-06-04	1976-06-22	The Dow Chemical Company	Preparation of rapid setting non-elastomeric polyurethane compositions in the presence of ester-modified polyoxyalkylene compounds
US4028309A (en) *	1975-03-12	1977-06-07	E. I. Du Pont De Nemours And Company	Coating compositions containing esters of dibasic acids, glycols and glycidyl esters, and polyisocyanates
JPS53149342U (fr) *	1977-04-30	1978-11-24
US4264745A (en) *	1979-09-14	1981-04-28	Owens-Corning Fiberglas Corporation	Fire-retardant polyurethane foam based on a bromine-containing polyester
JPS5681332A (en) *	1979-12-04	1981-07-03	Dai Ichi Kogyo Seiyaku Co Ltd	Production of modified polyisocyanurate foam
US4543369A (en) *	1982-09-07	1985-09-24	Henkel Corporation	Alkoxylated polyester polyols and polyurethanes made therefrom
US4487853A (en) *	1983-12-27	1984-12-11	Basf Wyandotte Corporation	Low ethylene oxide/high primary hydroxyl content polyether-ester polyols and polyurethane foams based thereon
US4481309A (en) *	1984-04-09	1984-11-06	Basf Aktiengesellschaft	Process for the preparation of cellular and non-cellular polyurethanes
US4564697A (en) *	1984-11-29	1986-01-14	Ethyl Corporation	Halogenated polyol-ester neutralization agent
DE3621039A1 (de) *	1986-06-24	1988-01-07	Bayer Ag	Verfahren zur herstellung von hydroxylgruppen aufweisenden oligoestern und deren verwendung
US5332859A (en) *	1992-11-03	1994-07-26	Great Lakes Chemical Europe, Ltd.	Process for producing tetrabromophthalic diesters
US7045564B2 (en) *	2003-08-29	2006-05-16	Albemarle Corporation	Flame retardants with high halogen content and low viscosity
JP4597129B2 (ja) *	2003-08-29	2010-12-15	アルベマール・コーポレーシヨン	高ハロゲン含量低粘度難燃剤
KR20110117139A (ko)	2009-01-06	2011-10-26	존슨 컨트롤스 테크놀러지 컴퍼니	일체형 와이어 하니스를 구비한 헤드라이너
US9227908B2 (en)	2010-01-07	2016-01-05	Chemtura Corporation	Tetrabromophthalic diester flame retardants and their production
BR112014008018A2 (pt) *	2011-10-14	2017-04-11	Dow Global Technologies Llc	poliol poliéster-poliéter, mistura de poliol, sistema de reação para produção de uma espuma rígida e processo para preparar uma espuma de poliuretano rígida
CN108026247B (zh)	2015-09-29	2022-03-25	陶氏环球技术有限责任公司	基于甲苯二异氰酸酯缩二脲的聚氨酯泡沫预聚物
CN114369236B (zh) *	2021-11-30	2024-04-12	山东一诺威新材料有限公司	高性能聚酯醚多元醇及其制备方法和应用

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3089863A (en) *	1956-06-29	1963-05-14	Devoe & Raynolds Co Inc	Process for preparation of a polyester resin of pentaerythritol, a dicarboxylic acid anhydride, and a monoepoxide

1965
- 1965-02-18 US US433660A patent/US3455886A/en not_active Expired - Lifetime
- 1965-12-21 IL IL24837A patent/IL24837A/en unknown
1966
- 1966-01-13 FR FR45776A patent/FR1463547A/fr not_active Expired
- 1966-01-27 ES ES0322299A patent/ES322299A1/es not_active Expired
- 1966-01-31 NL NL6601190A patent/NL6601190A/xx unknown
- 1966-02-10 GB GB5983/66A patent/GB1141417A/en not_active Expired
- 1966-02-11 DE DE19661568249 patent/DE1568249A1/de active Pending
- 1966-02-18 BE BE676742D patent/BE676742A/xx unknown
- 1966-02-18 JP JP41009868A patent/JPS4833040B1/ja active Pending

Also Published As

Publication number	Publication date
GB1141417A (en)	1969-01-29
BE676742A (fr)	1966-08-18
NL6601190A (fr)	1966-08-19
JPS4833040B1 (fr)	1973-10-11
ES322299A1 (es)	1967-03-16
US3455886A (en)	1969-07-15
DE1568249A1 (de)	1970-02-05
FR1463547A (fr)	1966-12-23

Publication	Publication Date	Title
US3455886A (en)	1969-07-15	Thermoplastic polyols containing polyester-ether blocks
US3454530A (en)	1969-07-08	Novel polyols which are reaction products of a monoepoxide and a cyclic monoanhydride
US3637540A (en)	1972-01-25	Polyurethanes from fatty acids and their production
US3755212A (en)	1973-08-28	Air blown polyurethane foams
US3645925A (en)	1972-02-29	4 4'-dimorpholinodiethyl ether catalyst for polyurethane preparation
WO2021004993A1 (fr)	2021-01-14	Mousses de polyuréthane sans isocyanate autogonflantes
WO2007132463A1 (fr)	2007-11-22	Composition retardatrice de flammes
AU592649B2 (en)	1990-01-18	A process for the production of oligoesters containing hydroxy groups and their use
US3644234A (en)	1972-02-22	Method of preparing cellular polymers from organic polyisocyanates and polycarboxylic acid compounds
US3639534A (en)	1972-02-01	Hydroxy terminated phosphorus-containing half esters of benzophenone tetracarboxylic acid
Chan et al.	1988	Polyurethane ionomers: effects of emulsification on properties of hexamethylene diisocyanate-based polyether polyurethane cationomers
US4632970A (en)	1986-12-30	Epoxy resin composition
US3400085A (en)	1968-09-03	High density polyurethane foams
US3037947A (en)	1962-06-05	Foamed polyurethane polymer and method of making same
US5118721A (en)	1992-06-02	Dispersion polymer polyols
US3275606A (en)	1966-09-27	Compositions containing adducts of hexahalocyclopentadiene
US3579471A (en)	1971-05-18	Cell modifying agents for polyurethane foams
WO2021092100A1 (fr)	2021-05-14	Polyols de polyester contenant un imide et mousses rigides intumescentes
US4468481A (en)	1984-08-28	Flame retardant polyurethane modified polyisocyanurate
US3703484A (en)	1972-11-21	Polyurethane foam process using distannoxane/aminoalcohol catalyst combination
US3655588A (en)	1972-04-11	Urethane-containing aminic polyols and foams derived therefrom
EP0361937A2 (fr)	1990-04-04	Procédé de préparation de mousse de polyurée ou polyuréthane/urée
US3823176A (en)	1974-07-09	Ester-containing amine-based liquid polyols and use in preparation of urethane compositions
US3574167A (en)	1971-04-06	Nitrogenous polyester-ether polyols and polyurethanes prepared therefrom
KR19990007838A (ko)	1999-01-25	중합체 재료