IL27043A - Process for the low-temperature polymerization of vinyl chloride - Google Patents

Process for the low-temperature polymerization of vinyl chloride

Info

Publication number: IL27043A
Authority: IL; Israel
Prior art keywords: reactor; compound; polymerisation; boron; vinyl chloride
Prior art date: 1965-12-17

Application number

IL2704366A

Other languages

English (en)

Original Assignee

Montedison Spa

Chatillon Italiana Fibre

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1965-12-17

Filing date

1966-12-12

Publication date

1970-10-30

1966-12-12 Application filed by Montedison Spa, Chatillon Italiana Fibre filed Critical Montedison Spa

1970-10-30 Publication of IL27043A publication Critical patent/IL27043A/en

Links

238000000034 method Methods 0.000 title claims description 30
230000008569 process Effects 0.000 title claims description 30
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 18
238000006116 polymerization reaction Methods 0.000 title claims description 3
229920000642 polymer Polymers 0.000 claims description 40
239000000178 monomer Substances 0.000 claims description 32
150000001875 compounds Chemical class 0.000 claims description 17
239000000203 mixture Substances 0.000 claims description 17
239000011541 reaction mixture Substances 0.000 claims description 12
-1 organometallic boron compound Chemical class 0.000 claims description 11
239000012670 alkaline solution Substances 0.000 claims description 7
150000001639 boron compounds Chemical class 0.000 claims description 7
238000002360 preparation method Methods 0.000 claims description 7
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
239000000126 substance Substances 0.000 claims description 6
229910052796 boron Inorganic materials 0.000 claims description 5
229920001577 copolymer Polymers 0.000 claims description 5
238000001704 evaporation Methods 0.000 claims description 5
230000008020 evaporation Effects 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
239000003513 alkali Substances 0.000 claims description 4
239000003054 catalyst Substances 0.000 claims description 4
150000002894 organic compounds Chemical class 0.000 claims description 4
239000000243 solution Substances 0.000 claims description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 3
150000001342 alkaline earth metals Chemical class 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
238000011282 treatment Methods 0.000 claims description 3
LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 claims description 3
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 2
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims description 2
229960003750 ethyl chloride Drugs 0.000 claims description 2
239000012530 fluid Substances 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
239000004094 surface-active agent Substances 0.000 claims description 2
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims 1
XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 1
150000007824 aliphatic compounds Chemical class 0.000 claims 1
125000000217 alkyl group Chemical group 0.000 claims 1
125000003710 aryl alkyl group Chemical group 0.000 claims 1
125000003118 aryl group Chemical group 0.000 claims 1
UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims 1
229910010277 boron hydride Inorganic materials 0.000 claims 1
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 claims 1
239000000463 material Substances 0.000 claims 1
229910000029 sodium carbonate Inorganic materials 0.000 claims 1
BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims 1
229940082004 sodium laurate Drugs 0.000 claims 1
239000001488 sodium phosphate Substances 0.000 claims 1
229910000162 sodium phosphate Inorganic materials 0.000 claims 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims 1
CMHHITPYCHHOGT-UHFFFAOYSA-N tributylborane Chemical compound CCCCB(CCCC)CCCC CMHHITPYCHHOGT-UHFFFAOYSA-N 0.000 claims 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 32
229920002554 vinyl polymer Polymers 0.000 description 9
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 8
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
230000008859 change Effects 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
238000009835 boiling Methods 0.000 description 3
230000009471 action Effects 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000002904 solvent Substances 0.000 description 2
241001174990 Boros Species 0.000 description 1
241001292274 Eumenes Species 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WZHMZRUDNLHCKN-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Na+].[C+4].[Na+].[Na+] Chemical compound P(=O)([O-])([O-])[O-].[Na+].[C+4].[Na+].[Na+] WZHMZRUDNLHCKN-UHFFFAOYSA-K 0.000 description 1
UQEJHZBXKJRUBO-UHFFFAOYSA-N [B].C1(=CC=CC=C1)C(C)C Chemical compound [B].C1(=CC=CC=C1)C(C)C UQEJHZBXKJRUBO-UHFFFAOYSA-N 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000001638 boron Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000001010 compromised effect Effects 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
MRIZMKJLUDDMHF-UHFFFAOYSA-N cumene;hydrogen peroxide Chemical compound OO.CC(C)C1=CC=CC=C1 MRIZMKJLUDDMHF-UHFFFAOYSA-N 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000015541 sensory perception of touch Effects 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
238000005406 washing Methods 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

IL2704366A 1965-12-17 1966-12-12 Process for the low-temperature polymerization of vinyl chloride IL27043A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT1237965		1965-12-17

Publications (1)

Publication Number	Publication Date
IL27043A true IL27043A (en)	1970-10-30

Family

ID=11139707

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL2704366A IL27043A (en)	1965-12-17	1966-12-12	Process for the low-temperature polymerization of vinyl chloride

Country Status (2)

Country	Link
ES (1)	ES335369A1 (es)
IL (1)	IL27043A (es)

1966
- 1966-12-12 IL IL2704366A patent/IL27043A/en unknown
- 1966-12-17 ES ES0335369A patent/ES335369A1/es not_active Expired

Also Published As

Publication number	Publication date
ES335369A1 (es)	1967-12-16

Publication	Publication Date	Title
US3689460A (en)	1972-09-05	Interpolymers of carbon monoxide and process for preparing same
US2870099A (en)	1959-01-20	Production of polymers of epoxide compounds
US3169949A (en)	1965-02-16	Process for the polymerization of vinyl chloride with a catalyst mixture of trialkyl aluminum and boric acid trialkyl ester and a cocatalyst
US2929808A (en)	1960-03-22	Removal of metal contaminants in polymerization processes
US3476727A (en)	1969-11-04	Process for the low-temperature homopolymerization and copolymerization of vinyl chloride
US2746944A (en)	1956-05-22	Process for preparing vinyl halide copolymers and copolymers produced thereby
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US5047490A (en)	1991-09-10	High molecular weight copolymers of maleic anhydride and methyl vinyl ether
US3956257A (en)	1976-05-11	Hydrocarbylaluminum hydrocarbyloxide antifouling agent in olefin polymerization process
US5115055A (en)	1992-05-19	Hydroperoxide catalyzed free radical polymerization of vinyl aromatic monomers
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US3062797A (en)	1962-11-06	Polymerization process of polar vinyl monomers with vanadyl diketones as catalysts
US3228923A (en)	1966-01-11	Preparation of polymers
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US2371499A (en)	1945-03-13	Modified polymerization of vinyl aromatic compounds
US3067186A (en)	1962-12-04	Vinyl chloride polymerisation process
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US3707530A (en)	1972-12-26	Method for producing polymers of ethylene
CA1306990C (en)	1992-09-01	CATALYST COMPONENTS FOR POLYMERIZATION CATALYSTS OF .alpha.-OLEFINES AND A METHOD FOR THEIR PRODUCTION