IL28237A - Vitamin-enriched cereals - Google Patents
Vitamin-enriched cerealsInfo
- Publication number
- IL28237A IL28237A IL28237A IL2823767A IL28237A IL 28237 A IL28237 A IL 28237A IL 28237 A IL28237 A IL 28237A IL 2823767 A IL2823767 A IL 2823767A IL 28237 A IL28237 A IL 28237A
- Authority
- IL
- Israel
- Prior art keywords
- vitamin
- supplement
- weight
- cereals
- rice
- Prior art date
Links
- 229940088594 vitamin Drugs 0.000 title claims description 45
- 229930003231 vitamin Natural products 0.000 title claims description 45
- 235000013343 vitamin Nutrition 0.000 title claims description 45
- 239000011782 vitamin Substances 0.000 title claims description 45
- 235000013339 cereals Nutrition 0.000 title claims description 36
- 150000003722 vitamin derivatives Chemical class 0.000 title claims description 34
- 241000209094 Oryza Species 0.000 claims description 32
- 235000007164 Oryza sativa Nutrition 0.000 claims description 32
- 235000009566 rice Nutrition 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 19
- 235000019195 vitamin supplement Nutrition 0.000 claims description 19
- 239000013589 supplement Substances 0.000 claims description 16
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 claims description 10
- 229960003966 nicotinamide Drugs 0.000 claims description 10
- 235000005152 nicotinamide Nutrition 0.000 claims description 10
- 239000011570 nicotinamide Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000004464 cereal grain Substances 0.000 claims description 8
- 241000209140 Triticum Species 0.000 claims description 6
- 235000021307 Triticum Nutrition 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 150000001413 amino acids Chemical class 0.000 claims description 3
- 239000011149 active material Substances 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical compound COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- AUNGANRZJHBGPY-UHFFFAOYSA-N D-Lyxoflavin Natural products OCC(O)C(O)C(O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-UHFFFAOYSA-N 0.000 description 8
- 229960002477 riboflavin Drugs 0.000 description 8
- 229930003471 Vitamin B2 Natural products 0.000 description 6
- 235000019164 vitamin B2 Nutrition 0.000 description 6
- 239000011716 vitamin B2 Substances 0.000 description 6
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 5
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 5
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 235000015927 pasta Nutrition 0.000 description 5
- 235000019155 vitamin A Nutrition 0.000 description 5
- 239000011719 vitamin A Substances 0.000 description 5
- 229940045997 vitamin a Drugs 0.000 description 5
- 229960000344 thiamine hydrochloride Drugs 0.000 description 4
- 235000019190 thiamine hydrochloride Nutrition 0.000 description 4
- 239000011747 thiamine hydrochloride Substances 0.000 description 4
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 4
- 244000098345 Triticum durum Species 0.000 description 3
- 235000007264 Triticum durum Nutrition 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229930182817 methionine Natural products 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000019612 pigmentation Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000019192 riboflavin Nutrition 0.000 description 2
- 239000002151 riboflavin Substances 0.000 description 2
- 230000000153 supplemental effect Effects 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OHSHFZJLPYLRIP-BMZHGHOISA-M Riboflavin sodium phosphate Chemical compound [Na+].OP(=O)([O-])OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O OHSHFZJLPYLRIP-BMZHGHOISA-M 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- YXJHJCDOUFKMBG-BMZHGHOISA-M riboflavin sodium Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)[N-]C2=O YXJHJCDOUFKMBG-BMZHGHOISA-M 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/101—Addition of antibiotics, vitamins, amino-acids, or minerals
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
Landscapes
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Cereal-Derived Products (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Grain Derivatives (AREA)
- Noodles (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
RAN 6001/10 Various processes for the vitamin supplementatio of cereal foodstuffs, particularly rice, are known in the art. ' , For the most part, however, certain disadvantages have been found to inhere in the known processes. For example, while a number of the prior art processes are relatively simple to carr out, their usefulness is diminished greatly by the fact that the ' supplemental vitamins are washed out'- of the final product ' when it is placed in water. Certain prior art ' processes obviated, or at least minimized, this undesirable feature.
A majority of such processes utilized some form of coating · technique to protect the product against vitamin losses.
To a large extent, however, coating techniques have proved to be commercially impractical since they are time-consuming and require the use of expensive apparatus. Often times the cost of coating the vitamins exceeded the value of the vitamins themselves.
The present invention aims at an amelioration of this situation. It provides in its broadest aspect. Vitamin-enriched . cereals containing a vitamin supplement comprising (l) a vitamin or a mixture of vitamins and (2) a farinaceous material as a carrier for said vitamins, said supplement' being in a form resembling a cereal grain in size, shape and appearance.
The vitamin supplement-1used in the practice of this' invention resembles in appearance, shape and size, cereal grains. The vitamin supplement Is produced by distributing a vitamin, or a • vitamin mixture, throughout a paste produced by mixing water and . a farinaceous product derived, for example, from wheat or rice.
Using conventional equipment and apparatus, for example, a pasta press, the paste-like mass is transformed, for example, i j into tubular-like strings of desired diameter or elongated I strips of desired width and thickness, following which such ■ strings or strips are cut to the desired length and dried. j The form in which the paste is extruded,' i.e. as strings, j into .the cereal foodstuff is variable. In general, the j ! j ' I amount of supplement which is used in any particular instance ; will be governed by the level of vitamin, or vitamin mixture, to be achieved in the final product. The quantity of supplement ; 1 ] needed to achieve such level of vitamin supplementation will ■ , depend upon the vitamin content of the supplement. Under . | ordinary circumstances, however, a ratio of about 1 part of the j grain-like vitamin supplement will be used for each 50 to „500 parts by weight of cereal foodstuff to be supplemented. In the preferred embodiment of th© AnvQtttion, Uttiere will fcfc l©y<≥d a ratio of about 1 part by weight of the vitamin supplement fo each 100 to 200 parts by weight of the cereal foodstuff to be supplemented. Where, however,a supplement of this invention contains active ingredients other than vitamin components, for example, where it contains amino acids, calcium salts, etc., there can be used a ratio of about 1 part by weight of the supplement for up to about each 20 parts by weight ,of the cereal foodstuff to be supplemented.
The vitamin supplements of this invention are manufactured in. a physical form which resembles the cereal feedstuff to be fortified. In the preferred practice of the invention, the supplements- are so manufactured as to resemble rice grains and they are used to supplement rice with added vitamins.
The manner in which the vitamin compositions of this invention are incorporated into the cereal foodstuff will be readily apparent to persons skilled in the art. They are simply added to, and mixed with, the grain-like cereal foodstuff. Special manufacturing equipment is not required. The latter feature is a distinct advantage over the presently known processes for the vitaminization of cereal foodstuffs, such as, rice.
In addition to ease of manufacture, both of the supplements and the supplemental foodstuff, the present invention provides other distinct advantages. For example, in certain of the known processes, vitaminization of rice is carried out by- adding rlo© grain© which are highly vitaminized to rice grains which are not vitamin supplemented. When vitamin B2 is present in the vitaminized rice, the rice grains have a distinctive , yellow discoloration. This is attributable to the fact that the vitamin is concentrated in the outer layers of the rice.
When the vitaminized rice grains and the non-vitaminized rice grains are mixed, the two types of grains are clearly distinguishable. This creates the distinct possibility that the consumer will reject the product in the belief that ■ the discolored grains are impure or at least inferior in quality. The practice of the present invention eliminates or at least minimizes the discoloration problem. In the present ' products, the vitamins are especially uniformly distributed throughout the farinaceous carrier with the result that little 1 or no discoloration, due to the vitamin B2 content, can be observed. The prior art recognized and sought to solve the problem by coating the grains with a pigment. The products of the present invention can be colored, if desired. However, unlike the known processes, where pigmentation is accomplished by coating the grains necessitating the use of costly apparatus, pigmentation of the products of the present I invention is readily carried out simply by adding the pigment to the paste from which the grain-like supplements are produced.
For a fuller understanding of the nature and objects .of the present ■ invention, reference can be had to the following examples, which are given as illustrations of the invention. ' Example 1 In this example 2.0 grams of thiamine hydrochloride, 3.5 grams of sodium riboflavin * -phosphate and .25.0 grams of niacinamide were dissolved in 50.0 grams of distilled water. After dilution with an additional 725 grams of water the ' solution was added to, and mixed with, 2.5 kg. of hard wheat ' grits In a band mixer. A paste-like mass was thus obtained. The paste-like mass was thereafter charged into a pasta press and elongated tubular strings, resembling spaghetti, having a diameter of 2.5 mm. were obtained. The strings were then cut to a length of about 6 mm. The product was allowed to dry.
The grain-like product which was thus obtained, resembled rice grains in appearance, size and shape. The grain-like product was added torice, a ratio of 1 part by weight of the ' vitamin supplement for each 200 parts by weight of rice . being provided. There was thus obtained a Vitamin-supplemented ; rice, each 100 grams of which contained 0.^ mg.. of vitamin i Bi, 0.6 mg. of vitamin B2, 5.0 mg. of niacinamide.
Example 2 In this example, 2.0 grams of thiamine hydrochloride, 2.7 grams of pyrldoxlne hydrochloride, .55 grams of sodium riboflavin 5' -phosphate and 25.0 grams of niacinamide were dissolved in 50.0 grams of distilled water. The solution was further diluted with 510 grams of water. The solution, thus obtained, was added to, and mixed with, 1.65 kg. of hard wheat grits in a band mixer. A paste-like mass was thus produced. The paste-like mass was compressed in a pasta press to form elongated tubular strings resembling spaghetti.
These strings, which had a diameter of about 2.5 mm., were cut to lengths of 6 mm. and dried. · The grain-like product, thus obtained, resembled rice grains in appearance, size and shape. Thereafter, 1 kg. of the vitamin supplement was added to, and mixed with, 300 kg. of rice to obtain a vitamin-supplemented rice, each 100 grams of which contained 0.4 mg. of vitamin Bij 0.6 mg. of vitamin B2; 0.52 mg. of vitamin Be; and 5.0 mg. of niacinamide.
Example 5 In this example, 2.0 grams of thiamine hydrochloride, 3.0 grams of riboflavin, 25.0 grams of niacinamide and 50.0 grams of dry vitamin A powder containing 500,000 I.U. of vitamin per gram were added to, and mixed with, 2420 kg. of wheat flour in a band mixer. A wheat flour derived from Durum wheat, a type of flour conventionally used in the production of spaghetti, was employed. Thereafter, 775.0 grams of water was added to the mixture and a paste-like mass was thus obtained. i The paste-like mass was added to, and extruded from, a pasta press in the form of tubular strings, diameter of about 2.5 mm., resembling spaghetti. The strings were then cut to a length of about 6 mm. and dried.
After drying, the vitamin supplement, which resembled rice grains in appearance, size and shape, was mixed with rice in a ratio of 1 part by weight of vitamin supplement for each i 200 parts by weight of rice. The vitamin-supplemented rice contained, per 100 grams, 0.4 mg. of vitamin Bi, 0.6 mg. of vitamin B2, 5.0 mg. of niacinamide, 5,000 I.U. of vitamin A.
Example In this example, 2.0 grams of thiamine hydrochloride, 3.0 grams of riboflavin, 25.0 grams of niacinamide, 50.0 grams of dry vitamin A powder containing 500, 000 I.U. of vitamin A per gram and 250 grams of methionine were added to, and mixed with, 2170 kg. of wheat meal. The mixture was mixed with 68o grams of water to form a paste-like mass.
The paste-like mass thus obtained was charged into, and extruded from) a pasta press in the form of tubular strings, diameter . about 2.5 rn . , resembling spaghetti. The strings were cut into lengths of about 6 mm. and dried.
After drying, the vitamin supplement, which in appearance, shape and size resembled rice grains, were mixed with rice, there being provided a ratio of one part by weight of vitamin supplement for each 200 parts by weight of rice. There was obtained ' a vitaminized rice product containing in each 100 grams, OA mg. j Ί of vitamin Bi, 0.6 mg. of vitamin B2, 5.0 mg. of niacinamide, j 5,000 I.U. of vitamin A and 10 grams of methionine. 1 ;
Claims (15)
1. Vitamin-enriched cereals containing a vitamin supplement comprising (l) a vitamin or a mixture of vitamins, and (2) a farinaceous material as a carrier for said vitamins •said .supplement being in a form resembling a cereal grain in size, shape and appearance.
2. Cereals as claimed in Claim 1, wherein the vitamin' supplement contains about -0.2$ to about 20$ by weight of active material..
3. · Cereals as claimed in Claim 1 or 2 wherein the supplement contains vitamin Β^·, vitamin B^, vitamin Bg and/or niacinamide. '
4. Cereals as claimed in Claim 1,2 or 3, wherein the supplement contains additionally amino acids. -
5. · Cereals as claimed in any one of Claims- 1 to wherein the farinaceous material used as carrier is derived from wheat or rice.
6. Cereals as claimed in any one of Claims 1 to 5 comprising a vitamin supplement in the form of rice grains in admixture with rice grains.
7. :7. Cereals- as claimed in any one of Claims 1 to 6 comprising from about 50 to 500 parts by weight of cereal grains for each part by weight of the vitamin supplement present therein.
8. A process for the manufacture of vitamin enriched cereal which comprises preparing a paste containing (l) a vitamin or a mixture of vitamins, (2) a farinaceous material as a carrier for said vitamin and (3) water, shaping the paste into a form resembling cereal grains in size, shape and appearance, drying the vitamin supplement thus obtained and adding same to cereal grains to be vitamin enriched.
9. A process as claimed in Claim 8, wherein a vitamin supplement is added containing about 0.2$ to about 20$ by weight of active material.
10. A process as claimed in Claim 8 or 9, wherein a supplement is used containing vitamin B^, vitamin B^, vitamin Bg and/or niacinamide.
11. A process as claimed in Claim 8, 9 or 10, wherein a supplement is used containing additionally amino acids.
12. A process as claimed in any one of Claims 8 to 11, wherein a supplement is used the farinaceous material thereof used as carrier is derived from wheat or rice.
13. A process as claimed in any one of Claims 8 to 12, wherein the vitamin supplement in the form of rice grains is added to rice grains.
14. A process as claimed in any one of Claims 8 to 13 which comprises the steps of (a) mixing (l) a vitamin or a mixture of vitamins, (2) a farinaceous material and (3) a quantity of water sufficient to form a paste therewith, (b) extruding said paste through an orifice of desired shape and size to form an elongated pastelike mass, (c) cutting said mass to desired length, (d) drying the cut particles thus obtained, and (e) addin said dried particles to cereal grains, there being used in said process a quantity. of ingredient (l) to provide a dry vitamin supplement containing from about 0.2 to about 20 by weight of said ingredient (l),
15. * A process as, claimed in any one of Claims 8 to 13 which comprises adding to about 50 to 500 parts by weight of cereal grains to be vitamin enriched, one part by weight of the vitamin supplement. - Dated this 2nd day of July, 1967
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1012966A CH484630A (en) | 1966-07-12 | 1966-07-12 | Process for the production of vitamin-enriched cereals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL28237A true IL28237A (en) | 1971-01-28 |
Family
ID=4359676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL28237A IL28237A (en) | 1966-07-12 | 1967-07-03 | Vitamin-enriched cereals |
Country Status (13)
| Country | Link |
|---|---|
| AT (1) | AT279327B (en) |
| BE (1) | BE701179A (en) |
| BR (1) | BR6791146D0 (en) |
| CH (1) | CH484630A (en) |
| DE (1) | DE1692673A1 (en) |
| ES (1) | ES342909A1 (en) |
| FI (1) | FI43942B (en) |
| GB (1) | GB1120775A (en) |
| IL (1) | IL28237A (en) |
| MY (1) | MY6900174A (en) |
| NL (1) | NL6709683A (en) |
| OA (1) | OA02460A (en) |
| SE (1) | SE325470B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1229930B (en) * | 1988-10-14 | 1991-09-16 | Dox Al Italia Spa | PROCEDURE FOR THE PREPARATION OF MIXTURES FOR FOOD AND FOOD USE INCLUDING ACTIVE SUBSTANCES UNIFORMLY DISTRIBUTED |
| FR2802059B1 (en) * | 1999-12-09 | 2003-02-28 | Bionovation | FOOD COMPOSITION COMPRISING AT LEAST ONE NATURAL VITAMIN, LIKELY TO BE SUBJECTED TO HEAT TREATMENT |
-
1966
- 1966-07-12 CH CH1012966A patent/CH484630A/en not_active IP Right Cessation
-
1967
- 1967-06-13 DE DE19671692673 patent/DE1692673A1/en active Pending
- 1967-06-13 AT AT547467A patent/AT279327B/en not_active IP Right Cessation
- 1967-06-21 SE SE08826/67A patent/SE325470B/xx unknown
- 1967-06-27 FI FI1796/67A patent/FI43942B/fi active
- 1967-06-28 OA OA52990A patent/OA02460A/en unknown
- 1967-07-03 IL IL28237A patent/IL28237A/en unknown
- 1967-07-10 BR BR191146/67A patent/BR6791146D0/en unknown
- 1967-07-10 GB GB31597/67A patent/GB1120775A/en not_active Expired
- 1967-07-11 ES ES342909A patent/ES342909A1/en not_active Expired
- 1967-07-11 BE BE701179D patent/BE701179A/xx unknown
- 1967-07-12 NL NL6709683A patent/NL6709683A/xx unknown
-
1969
- 1969-12-30 MY MY174/69A patent/MY6900174A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE701179A (en) | 1968-01-11 |
| AT279327B (en) | 1970-03-10 |
| ES342909A1 (en) | 1968-08-16 |
| OA02460A (en) | 1970-05-05 |
| GB1120775A (en) | 1968-07-24 |
| NL6709683A (en) | 1968-01-15 |
| BR6791146D0 (en) | 1973-12-26 |
| FI43942B (en) | 1971-03-31 |
| DE1692673A1 (en) | 1971-08-12 |
| CH484630A (en) | 1970-01-31 |
| SE325470B (en) | 1970-06-29 |
| MY6900174A (en) | 1969-12-31 |
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