IL28446A - Hydrocarbon oxidation process - Google Patents

Hydrocarbon oxidation process

Info

Publication number: IL28446A
Authority: IL; Israel
Prior art keywords: oxidation; hydrocarbon; zone; fraction; process according
Prior art date: 1966-08-04

Application number

IL28446A

Other languages

English (en)

Hebrew (he)

Original Assignee

Halcon International Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1966-08-04

Filing date

1967-08-03

Publication date

1970-12-24

1967-08-03 Application filed by Halcon International Inc filed Critical Halcon International Inc

1970-12-24 Publication of IL28446A publication Critical patent/IL28446A/en

Links

238000007254 oxidation reaction Methods 0.000 title claims description 82
230000003647 oxidation Effects 0.000 title claims description 80
229930195733 hydrocarbon Natural products 0.000 title claims description 42
150000002430 hydrocarbons Chemical class 0.000 title claims description 42
238000000034 method Methods 0.000 title claims description 23
239000004215 Carbon black (E152) Substances 0.000 claims description 37
239000000203 mixture Substances 0.000 claims description 20
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 19
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
239000007788 liquid Substances 0.000 claims description 13
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 11
229910052796 boron Inorganic materials 0.000 claims description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
239000007789 gas Substances 0.000 claims description 7
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 5
229910001882 dioxygen Inorganic materials 0.000 claims description 5
239000007791 liquid phase Substances 0.000 claims description 5
239000000463 material Substances 0.000 claims description 4
150000001639 boron compounds Chemical class 0.000 claims description 2
239000007787 solid Substances 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
OPFTUNCRGUEPRZ-QLFBSQMISA-N Cyclohexane Natural products CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 claims 1
125000004432 carbon atom Chemical group C* 0.000 claims 1
229930195734 saturated hydrocarbon Natural products 0.000 claims 1
238000005201 scrubbing Methods 0.000 claims 1
150000002576 ketones Chemical class 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 11
238000005984 hydrogenation reaction Methods 0.000 description 11
238000004821 distillation Methods 0.000 description 9
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 6
239000004327 boric acid Substances 0.000 description 6
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
238000000926 separation method Methods 0.000 description 5
239000000243 solution Substances 0.000 description 4
239000002671 adjuvant Substances 0.000 description 3
-1 cyclohexyl borate ester Chemical class 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000012074 organic phase Substances 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
239000006200 vaporizer Substances 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
150000001642 boronic acid derivatives Chemical class 0.000 description 2
238000010908 decantation Methods 0.000 description 2
238000004508 fractional distillation Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000012071 phase Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
241001292396 Cirrhitidae Species 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
PHLBKPHSAVXXEF-UHFFFAOYSA-N trazodone Chemical compound ClC1=CC=CC(N2CCN(CCCN3C(N4C=CC=CC4=N3)=O)CC2)=C1 PHLBKPHSAVXXEF-UHFFFAOYSA-N 0.000 description 1
238000011282 treatment Methods 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

IL28446A 1966-08-04 1967-08-03 Hydrocarbon oxidation process IL28446A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US57033966A	1966-08-04	1966-08-04

Publications (1)

Publication Number	Publication Date
IL28446A true IL28446A (en)	1970-12-24

Family

ID=24279264

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL28446A IL28446A (en)	1966-08-04	1967-08-03	Hydrocarbon oxidation process

Country Status (10)

Country	Link
US (1)	US3558687A (fr)
BE (1)	BE702094A (fr)
CH (1)	CH476654A (fr)
DE (1)	DE1668202A1 (fr)
ES (1)	ES343836A1 (fr)
FR (1)	FR1548378A (fr)
GB (1)	GB1138420A (fr)
IL (1)	IL28446A (fr)
LU (1)	LU54217A1 (fr)
NL (1)	NL6710454A (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3932513A (en) *	1971-02-05	1976-01-13	Halcon International, Inc.	Cyclohexane oxidation
US3959389A (en) *	1972-07-14	1976-05-25	Nippon Shokubai Kagaku Kogyo Co., Ltd.	Method of manufacturing alkylene oxide adducts of an aliphatic alcohol
US3932531A (en) *	1972-07-14	1976-01-13	Nippon Shokubai Kaguku Kogyo Co., Ltd.	Method of manufacturing alkylene oxide adducts of an aliphatic alcohol
US3914295A (en) *	1972-12-18	1975-10-21	Atlantic Richfield Co	Catalytic oxidation of hydrocarbons with organic hydroperoxides
US4599322A (en) *	1984-01-12	1986-07-08	Phillips Petroleum Company	Method for producing ketones and phenols
US4532360A (en) *	1984-01-12	1985-07-30	Phillips Petroleum Company	Method for producing ketones and phenols
AU2376001A (en) *	1999-12-14	2001-06-25	Fortum Oil And Gas Oy	Method for the manufacture of olefins

1966
- 1966-08-04 US US570339A patent/US3558687A/en not_active Expired - Lifetime
1967
- 1967-07-28 NL NL6710454A patent/NL6710454A/xx unknown
- 1967-07-31 GB GB35024/67A patent/GB1138420A/en not_active Expired
- 1967-07-31 BE BE702094D patent/BE702094A/xx unknown
- 1967-08-01 LU LU54217D patent/LU54217A1/xx unknown
- 1967-08-03 IL IL28446A patent/IL28446A/en unknown
- 1967-08-03 CH CH1093767A patent/CH476654A/fr not_active IP Right Cessation
- 1967-08-03 FR FR1548378D patent/FR1548378A/fr not_active Expired
- 1967-08-04 DE DE19671668202 patent/DE1668202A1/de active Pending
- 1967-08-04 ES ES343836A patent/ES343836A1/es not_active Expired

Also Published As

Publication number	Publication date
LU54217A1 (fr)	1969-06-16
BE702094A (fr)	1968-01-31
ES343836A1 (es)	1968-10-01
GB1138420A (en)	1969-01-01
NL6710454A (fr)	1968-02-05
DE1668202A1 (de)	1971-06-09
FR1548378A (fr)	1968-12-06
US3558687A (en)	1971-01-26
CH476654A (fr)	1969-08-15

Publication	Publication Date	Title
US2757209A (en)	1956-07-31	Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures
US2565087A (en)	1951-08-21	Process for oxidation of cycloaliphatic compounds
US3964980A (en)	1976-06-22	Process for the recovery of ethylene oxide
US3932513A (en)	1976-01-13	Cyclohexane oxidation
US2587753A (en)	1952-03-04	Method for purifying alcohols
US2938924A (en)	1960-05-31	Production of alcohols and ketones by the oxidation of cycloaliphatic or araliphatic hydrocarbons
EP0008869A1 (fr)	1980-03-19	Procédé pour la préparation de phénol et d'un composé carbonylé par décomposition catalysée d'un hydroperoxyde aromatique
US2557281A (en)	1951-06-19	Oxidation op petroleum cyclohexane
US4476333A (en)	1984-10-09	Process for the continuous production of secondary butyl alcohol
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CN109134217B (zh)	2023-10-17	一种环己烷氧化法生产环己酮过程中氧化装置及氧化工艺改进方法
IL28446A (en)	1970-12-24	Hydrocarbon oxidation process
US2757203A (en)	1956-07-31	Synthesis of alcoiiol and aldehyde from olefins, carbon monoxide and hydrogen
US3654094A (en)	1972-04-04	Process for purifying propylene oxide by plural stage distillation
US2606933A (en)	1952-08-12	Production of unsaturateb
US2403741A (en)	1946-07-09	Process for making butadiene
US2514968A (en)	1950-07-11	Purification of crude acrolein by rectified absorption
US4003952A (en)	1977-01-18	Direct hydration of olefins to alcohols
US3277179A (en)	1966-10-04	Manufacture of aqueous formaldehyde solution and paraformaldehyde
US2688635A (en)	1954-09-07	Process for the production of ketene or acetic anhydride from a mixture of acetic acid and formic acid
US3449219A (en)	1969-06-10	Process for fractionating propylene from propylene oxide in the presence of hydrocarbon flux
US3254962A (en)	1966-06-07	Apparatus for oxidizing hydrocarbons