IL287465B2 - Systems and methods for recovering lithium from brines - Google Patents

Systems and methods for recovering lithium from brines

Info

Publication number
IL287465B2
IL287465B2 IL287465A IL28746521A IL287465B2 IL 287465 B2 IL287465 B2 IL 287465B2 IL 287465 A IL287465 A IL 287465A IL 28746521 A IL28746521 A IL 28746521A IL 287465 B2 IL287465 B2 IL 287465B2
Authority
IL
Israel
Prior art keywords
lithium
brine
pond
precipitation
stream
Prior art date
Application number
IL287465A
Other languages
English (en)
Hebrew (he)
Other versions
IL287465B1 (en
IL287465A (en
Original Assignee
Energy Exploration Tech Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Exploration Tech Inc filed Critical Energy Exploration Tech Inc
Publication of IL287465A publication Critical patent/IL287465A/en
Publication of IL287465B1 publication Critical patent/IL287465B1/en
Publication of IL287465B2 publication Critical patent/IL287465B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10Obtaining alkali metals
    • C22B26/12Obtaining lithium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00Lithium compounds
    • C01D15/04Halides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00Lithium compounds
    • C01D15/06Sulfates; Sulfites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00Halides of sodium, potassium or alkali metals in general
    • C01D3/04Chlorides
    • C01D3/06Preparation by working up brines; seawater or spent lyes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00Sulfates or sulfites of sodium, potassium or alkali metals in general
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00Compounds of magnesium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00Compounds of magnesium
    • C01F5/26Magnesium halides
    • C01F5/30Chlorides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00Compounds of magnesium
    • C01F5/38Magnesium nitrates
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00Compounds of magnesium
    • C01F5/40Magnesium sulfates
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
IL287465A 2020-05-12 2021-05-12 Systems and methods for recovering lithium from brines IL287465B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US202063023528P 2020-05-12 2020-05-12
PCT/US2021/032027 WO2021231597A1 (fr) 2020-05-12 2021-05-12 Systèmes et procédés de récupération de lithium à partir de saumures

Publications (3)

Publication Number Publication Date
IL287465A IL287465A (en) 2021-12-01
IL287465B1 IL287465B1 (en) 2023-11-01
IL287465B2 true IL287465B2 (en) 2024-03-01

Family

ID=78511805

Family Applications (1)

Application Number Title Priority Date Filing Date
IL287465A IL287465B2 (en) 2020-05-12 2021-05-12 Systems and methods for recovering lithium from brines

Country Status (9)

Country Link
EP (1) EP3947756A4 (fr)
CN (1) CN113924375B (fr)
AU (1) AU2021254665B2 (fr)
CA (1) CA3136247C (fr)
IL (1) IL287465B2 (fr)
JO (1) JOP20210311A1 (fr)
MX (1) MX2021013733A (fr)
PE (1) PE20220205A1 (fr)
WO (1) WO2021231597A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12391566B2 (en) 2020-08-21 2025-08-19 Schlumberger Technology Corporation Lithium extraction improvements
US20240226813A9 (en) * 2021-02-16 2024-07-11 Energy Exploration Technologies, Inc. Polymeric materials and methods for selective ion separation or transport
WO2023215353A1 (fr) * 2022-05-03 2023-11-09 Schlumberger Technology Corporation Contrôle d'impuretés dans la récupération de lithium
AR129373A1 (es) * 2022-05-20 2024-08-21 Schlumberger Technology Bv Recuperación de litio a partir de sólidos precipitados
CN115650476B (zh) * 2022-09-30 2025-07-29 广东邦普循环科技有限公司 一种膜法盐湖卤水提锂用便于自动更换滤膜的过滤装置
US12421137B2 (en) 2022-12-07 2025-09-23 Schlumberger Technology Corporation Hydrocarbon and sulfide removal in direct aqueous extraction
WO2024123398A1 (fr) 2022-12-07 2024-06-13 Schlumberger Technology Corporation Élimination d'hydrocarbures et de sulfure dans une extraction aqueuse directe
WO2024249270A1 (fr) * 2023-05-26 2024-12-05 Energy Exploration Technologies, Inc. Compositions de réactif, appareil et procédés d'extraction de lithium à partir de sels mixtes
CN120230923A (zh) * 2025-05-29 2025-07-01 河南中鑫新材料有限公司 一种从磷锂铝石中提取锂的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130101484A1 (en) * 2011-10-24 2013-04-25 Minera Exar S.A. Method for the production of battery grade lithium carbonate from natural and industrial brines
CN109748298A (zh) * 2019-02-23 2019-05-14 温州大学新材料与产业技术研究院 一种从含锂卤水中自发选择性分离镁富集锂的方法及其装置

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL118655A0 (en) * 1995-07-18 1996-10-16 Tarim Associates For Scient Mi Process for recovery of lithium and other metals and salts from brines
US6921522B2 (en) * 1998-07-16 2005-07-26 Chemetall Foote Corporation Production of lithium compounds directly from lithium containing brines
US8641992B2 (en) * 2008-07-18 2014-02-04 Ady Resources Limited Process for recovering lithium from a brine
JP5556450B2 (ja) * 2010-07-02 2014-07-23 パナソニック株式会社 回転式圧縮機
AU2011236094B2 (en) * 2011-01-20 2012-11-29 Rockwood Lithium Inc. Production of high purity lithium compounds directly from lithium containing brines
JP5791917B2 (ja) * 2011-02-23 2015-10-07 Jx日鉱日石金属株式会社 リチウム回収方法
CN103958412A (zh) * 2011-09-15 2014-07-30 奥若可博有限公司 用于从浓锂卤水制备碳酸锂的方法
WO2014098357A1 (fr) * 2012-12-21 2014-06-26 재단법인 포항산업과학연구원 Procédé d'extraction de lithium présent dans une solution contenant du lithium
AU2015408086A1 (en) * 2015-08-28 2018-03-15 Albemarle Corporation Processes for recovering lithium values from lithium-containing brines
WO2019002653A1 (fr) * 2017-06-26 2019-01-03 GRANDE VILLARINO, Alejandro María Procédé à impact environnemental minimum et à récupération maximum de lithium pour obtenir des saumures concentrées avec une teneur minimale en impuretés à partir de saumures qui imprègnent des salines et des mines de sel naturelles
MX2020006277A (es) 2017-12-15 2020-12-03 Univ Monash Membranas de armazones metalorganicos.
CN110606499A (zh) * 2018-06-15 2019-12-24 上海东硕环保科技股份有限公司 一种含锂盐湖卤水提锂组合装置

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130101484A1 (en) * 2011-10-24 2013-04-25 Minera Exar S.A. Method for the production of battery grade lithium carbonate from natural and industrial brines
CN109748298A (zh) * 2019-02-23 2019-05-14 温州大学新材料与产业技术研究院 一种从含锂卤水中自发选择性分离镁富集锂的方法及其装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
FLEXER, VICTORIA, CELSO FERNANDO BASPINEIRO, AND CLAUDIA IN?S GALLI., LITHIUM RECOVERY FROM BRINES: A VITAL RAW MATERIAL FOR GREEN ENERGIES WITH A POTENTIAL ENVIRONMENTAL IMPACT IN ITS MINING AND PROCESSING., 31 December 2018 (2018-12-31) *

Also Published As

Publication number Publication date
WO2021231597A1 (fr) 2021-11-18
MX2021013733A (es) 2021-12-10
CN113924375A (zh) 2022-01-11
PE20220205A1 (es) 2022-02-01
EP3947756A4 (fr) 2022-07-06
IL287465B1 (en) 2023-11-01
IL287465A (en) 2021-12-01
CA3136247A1 (fr) 2021-11-12
JOP20210311A1 (ar) 2023-01-30
AU2021254665B2 (en) 2022-04-21
WO2021231597A9 (fr) 2022-01-20
EP3947756A1 (fr) 2022-02-09
CN113924375B (zh) 2023-04-04
CA3136247C (fr) 2022-12-20
AU2021254665A1 (en) 2021-12-02

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