IL28919A - Manufacture of polyamides and filaments obtained therefron - Google Patents

Manufacture of polyamides and filaments obtained therefron

Info

Publication number: IL28919A
Authority: IL; Israel
Prior art keywords: polyamide; nucleating agent; calcium fluoride; yarn; filaments
Prior art date: 1966-11-10

Application number

IL28919A

Other languages

English (en)

Original Assignee

Ici Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1966-11-10

Filing date

1967-11-10

Publication date

1971-02-25

1967-11-10 Application filed by Ici Ltd filed Critical Ici Ltd

1971-02-25 Publication of IL28919A publication Critical patent/IL28919A/en

Links

229920002647 polyamide Polymers 0.000 title claims description 63
239000004952 Polyamide Substances 0.000 title claims description 61
238000004519 manufacturing process Methods 0.000 title claims description 8
229920000642 polymer Polymers 0.000 claims description 67
WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical group [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 52
229910001634 calcium fluoride Inorganic materials 0.000 claims description 51
239000002245 particle Substances 0.000 claims description 46
239000002667 nucleating agent Substances 0.000 claims description 39
238000009987 spinning Methods 0.000 claims description 37
238000000034 method Methods 0.000 claims description 35
238000000926 separation method Methods 0.000 claims description 26
238000002425 crystallisation Methods 0.000 claims description 13
150000003839 salts Chemical class 0.000 claims description 12
238000007711 solidification Methods 0.000 claims description 12
230000008023 solidification Effects 0.000 claims description 12
239000002002 slurry Substances 0.000 claims description 11
-1 polyoctamethylene Polymers 0.000 claims description 9
229920002302 Nylon 6,6 Polymers 0.000 claims description 8
GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 claims description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
238000002074 melt spinning Methods 0.000 claims description 5
KNXVOGGZOFOROK-UHFFFAOYSA-N trimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane Chemical compound [Mg+2].[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O KNXVOGGZOFOROK-UHFFFAOYSA-N 0.000 claims description 5
239000000454 talc Substances 0.000 claims description 4
229910052623 talc Inorganic materials 0.000 claims description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
239000011248 coating agent Substances 0.000 claims description 3
238000000576 coating method Methods 0.000 claims description 3
NKTZYSOLHFIEMF-UHFFFAOYSA-N dioxido(dioxo)tungsten;lead(2+) Chemical compound [Pb+2].[O-][W]([O-])(=O)=O NKTZYSOLHFIEMF-UHFFFAOYSA-N 0.000 claims description 3
239000010439 graphite Substances 0.000 claims description 3
229910002804 graphite Inorganic materials 0.000 claims description 3
238000011065 in-situ storage Methods 0.000 claims description 3
238000002347 injection Methods 0.000 claims description 3
239000007924 injection Substances 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 2
239000000920 calcium hydroxide Substances 0.000 claims description 2
229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
KTAAUBVMSAZOLC-UHFFFAOYSA-L calcium;hexanedioate Chemical compound [Ca+2].[O-]C(=O)CCCCC([O-])=O KTAAUBVMSAZOLC-UHFFFAOYSA-L 0.000 claims description 2
230000001747 exhibiting effect Effects 0.000 claims description 2
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 2
229910052903 pyrophyllite Inorganic materials 0.000 claims description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 2
230000003993 interaction Effects 0.000 claims 2
DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims 1
230000008020 evaporation Effects 0.000 claims 1
238000001704 evaporation Methods 0.000 claims 1
239000004677 Nylon Substances 0.000 description 41
229920001778 nylon Polymers 0.000 description 41
NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
239000000243 solution Substances 0.000 description 16
239000000725 suspension Substances 0.000 description 14
239000000654 additive Substances 0.000 description 11
239000011698 potassium fluoride Substances 0.000 description 11
235000003270 potassium fluoride Nutrition 0.000 description 11
239000000047 product Substances 0.000 description 8
230000000996 additive effect Effects 0.000 description 7
239000011575 calcium Substances 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
238000012360 testing method Methods 0.000 description 7
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 6
239000001639 calcium acetate Substances 0.000 description 6
235000011092 calcium acetate Nutrition 0.000 description 6
229960005147 calcium acetate Drugs 0.000 description 6
230000008014 freezing Effects 0.000 description 6
238000007710 freezing Methods 0.000 description 6
239000006228 supernatant Substances 0.000 description 6
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
238000001816 cooling Methods 0.000 description 5
230000006911 nucleation Effects 0.000 description 5
238000010899 nucleation Methods 0.000 description 5
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
229910052791 calcium Inorganic materials 0.000 description 4
239000000835 fiber Substances 0.000 description 4
229920002292 Nylon 6 Polymers 0.000 description 3
239000007900 aqueous suspension Substances 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000004744 fabric Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
238000010791 quenching Methods 0.000 description 3
101100326791 Caenorhabditis elegans cap-2 gene Proteins 0.000 description 2
101150107838 Capg gene Proteins 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
238000005162 X-ray Laue diffraction Methods 0.000 description 2
101100440252 Xenopus laevis ncapg gene Proteins 0.000 description 2
230000008901 benefit Effects 0.000 description 2
ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000010622 cold drawing Methods 0.000 description 2
238000002788 crimping Methods 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
239000000975 dye Substances 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
230000000171 quenching effect Effects 0.000 description 2
238000012216 screening Methods 0.000 description 2
229920002545 silicone oil Polymers 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
HVBZWQXBWZXQAW-UHFFFAOYSA-N 6-azaniumylhexylazanium;difluoride Chemical compound [F-].[F-].[NH3+]CCCCCC[NH3+] HVBZWQXBWZXQAW-UHFFFAOYSA-N 0.000 description 1
UFFRSDWQMJYQNE-UHFFFAOYSA-N 6-azaniumylhexylazanium;hexanedioate Chemical compound [NH3+]CCCCCC[NH3+].[O-]C(=O)CCCCC([O-])=O UFFRSDWQMJYQNE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910000669 Chrome steel Inorganic materials 0.000 description 1
PTIWCWYYGIRDIZ-UHFFFAOYSA-K Durazol blue 4R Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(cc3cc(cc(O)c23)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O PTIWCWYYGIRDIZ-UHFFFAOYSA-K 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241000489861 Maximus Species 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
MTDMHAKNYZTKQR-UHFFFAOYSA-N [Ba][Ba] Chemical compound [Ba][Ba] MTDMHAKNYZTKQR-UHFFFAOYSA-N 0.000 description 1
VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
235000015895 biscuits Nutrition 0.000 description 1
238000009529 body temperature measurement Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
XOHOZPWASOGZRZ-UHFFFAOYSA-L calcium difluoride dihydrate Chemical compound O.O.[F-].[F-].[Ca++] XOHOZPWASOGZRZ-UHFFFAOYSA-L 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
LPLMZAJYUPAYQZ-UHFFFAOYSA-N diazanium;difluoride Chemical compound [NH4+].[NH4+].[F-].[F-] LPLMZAJYUPAYQZ-UHFFFAOYSA-N 0.000 description 1
UKRAWUDNDRUQDW-UHFFFAOYSA-J dicalcium tetrafluoride Chemical compound F[Ca]F.F[Ca]F UKRAWUDNDRUQDW-UHFFFAOYSA-J 0.000 description 1
238000004455 differential thermal analysis Methods 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
150000004673 fluoride salts Chemical class 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
230000010354 integration Effects 0.000 description 1
238000009940 knitting Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
235000011056 potassium acetate Nutrition 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
239000011369 resultant mixture Substances 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000004781 supercooling Methods 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Artificial Filaments (AREA)
Chemical Or Physical Treatment Of Fibers (AREA)

IL28919A 1966-11-10 1967-11-10 Manufacture of polyamides and filaments obtained therefron IL28919A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB50471/66A GB1211685A (en)	1966-11-10	1966-11-10	Improvements in or relating to the manufacture of polyamides and to filaments obtained therefrom

Publications (1)

Publication Number	Publication Date
IL28919A true IL28919A (en)	1971-02-25

Family

ID=10456008

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL28919A IL28919A (en)	1966-11-10	1967-11-10	Manufacture of polyamides and filaments obtained therefron

Country Status (10)

Country	Link
BE (1)	BE706378A (de)
CH (1)	CH487211A (de)
DE (1)	DE1694476A1 (de)
ES (1)	ES346987A1 (de)
FR (1)	FR1557047A (de)
GB (1)	GB1211685A (de)
IL (1)	IL28919A (de)
LU (1)	LU54845A1 (de)
NL (1)	NL6715270A (de)
SE (1)	SE329688B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4370375A (en)	1981-04-20	1983-01-25	E. I. Du Pont De Nemours And Company	Abrasion-resistant monofilament with molybdenum disulfide useful in the formation of papermaking belts
US4397979A (en)	1981-08-03	1983-08-09	Allied Corporation	Polymer composition containing lithium, manganese or zirconium nucleating agent
US4501844A (en) *	1983-12-05	1985-02-26	The Upjohn Company	Polyamides with talc as crystallization promoter
US5496918A (en) *	1991-09-23	1996-03-05	Alliedsignal Inc.	Process for improving the properties of polymers
WO2008140476A2 (en)	2006-10-31	2008-11-20	Oroscience, Inc.	Process to form nano-sized materials, the compositions and uses thereof

1966
- 1966-11-10 GB GB50471/66A patent/GB1211685A/en not_active Expired
1967
- 1967-09-09 SE SE15386/67*A patent/SE329688B/xx unknown
- 1967-11-09 CH CH1564867A patent/CH487211A/de not_active IP Right Cessation
- 1967-11-10 NL NL6715270A patent/NL6715270A/xx unknown
- 1967-11-10 LU LU54845D patent/LU54845A1/xx unknown
- 1967-11-10 ES ES346987A patent/ES346987A1/es not_active Expired
- 1967-11-10 FR FR1557047D patent/FR1557047A/fr not_active Expired
- 1967-11-10 DE DE19671694476 patent/DE1694476A1/de active Pending
- 1967-11-10 IL IL28919A patent/IL28919A/en unknown
- 1967-11-10 BE BE706378D patent/BE706378A/xx unknown

Also Published As

Publication number	Publication date
DE1694476A1 (de)	1970-10-22
CH487211A (de)	1970-03-15
LU54845A1 (de)	1968-02-02
NL6715270A (de)	1968-05-13
ES346987A1 (es)	1969-01-16
BE706378A (de)	1968-05-10
FR1557047A (de)	1969-02-14
GB1211685A (en)	1970-11-11
SE329688B (de)	1970-10-19

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US3671542A (en)	1972-06-20	Optically anisotropic aromatic polyamide dopes
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DE1929694B2 (de)	1976-04-22	Optisch anisotrope massen von aromatischen polyamiden
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US3585264A (en)	1971-06-15	Process for spinning polyamide filaments containing nucleating agents
US3011904A (en)	1961-12-05	Method of coating a flake of nylon with a pigment
JP2646349B2 (ja)	1997-08-27	衣料用糸
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US4542063A (en)	1985-09-17	Uniformly dyeable nylon 66 fiber and process for the production thereof
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JPH0241414A (ja)	1990-02-09	着色されたアラミド繊維
US3591565A (en)	1971-07-06	Polyamides containing alkali metal halide additives as void formation inhibitors
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US3707522A (en)	1972-12-26	Polyamide composition and process
JP5388448B2 (ja)	2014-01-15	無機固体を含有するポリマー材料およびその製造法
US4835053A (en)	1989-05-30	Dark dyeing yarn containing polyester fibers and method of preparation
DE69400617T2 (de)	1997-02-27	Textilfasern aus sulfoniertem poly(p-phenylen-terephtalamide)
US5238637A (en)	1993-08-24	Process for obtaining polyamide yarns with better output efficiency
US3061576A (en)	1962-10-30	Filament comprising polypropylene and a caprolactam-coated pigment and method of making same
US4919874A (en)	1990-04-24	Process for preparing a nylon fiber with reduced spherulites
KR930003221B1 (ko)	1993-04-23	고밀도 폴리에스테르 섬유의 제조방법.
US4128989A (en)	1978-12-12	Deep-dyeing polyester spinning process
DE1694476B (de)		Polyamidfaden
DE69114134T2 (de)	1996-03-28	Verbesserte nylon-flachgarne.