IL30654A - Hollow synthetic fibers and method for preparing them - Google Patents

Hollow synthetic fibers and method for preparing them

Info

Publication number: IL30654A
Authority: IL; Israel
Prior art keywords: fiber; polymer; solvent; bath; dissolved
Prior art date: 1967-09-05

Application number

IL30654A

Other languages

English (en)

Other versions

IL30654A0 (en

Original Assignee

Monsanto Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1967-09-05

Filing date

1968-09-02

Publication date

1972-03-28

1968-09-02 Application filed by Monsanto Co filed Critical Monsanto Co

1968-11-27 Publication of IL30654A0 publication Critical patent/IL30654A0/xx

1972-03-28 Publication of IL30654A publication Critical patent/IL30654A/en

Links

238000000034 method Methods 0.000 title claims description 22
229920002994 synthetic fiber Polymers 0.000 title claims description 5
239000012209 synthetic fiber Substances 0.000 title claims description 5
229920000642 polymer Polymers 0.000 claims description 37
239000000835 fiber Substances 0.000 claims description 30
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 29
230000015271 coagulation Effects 0.000 claims description 16
238000005345 coagulation Methods 0.000 claims description 16
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 15
239000007788 liquid Substances 0.000 claims description 15
229910002092 carbon dioxide Inorganic materials 0.000 claims description 13
239000001569 carbon dioxide Substances 0.000 claims description 13
239000002904 solvent Substances 0.000 claims description 13
239000000701 coagulant Substances 0.000 claims description 12
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 9
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
239000012510 hollow fiber Substances 0.000 claims description 4
235000011089 carbon dioxide Nutrition 0.000 claims description 3
238000002360 preparation method Methods 0.000 claims description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 2
239000003960 organic solvent Substances 0.000 claims 2
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims 1
229940113088 dimethylacetamide Drugs 0.000 claims 1
238000001035 drying Methods 0.000 description 7
238000002166 wet spinning Methods 0.000 description 7
229920001577 copolymer Polymers 0.000 description 6
239000000203 mixture Substances 0.000 description 6
238000010438 heat treatment Methods 0.000 description 5
239000000178 monomer Substances 0.000 description 5
238000009987 spinning Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 4
239000004604 Blowing Agent Substances 0.000 description 4
RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
229920002239 polyacrylonitrile Polymers 0.000 description 4
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical class C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 3
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 3
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000000463 material Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
229920001059 synthetic polymer Polymers 0.000 description 3
239000011800 void material Substances 0.000 description 3
238000005406 washing Methods 0.000 description 3
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
-1 etyrene Chemical compound 0.000 description 2
UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
239000011148 porous material Substances 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
239000004753 textile Substances 0.000 description 2
DQIRHMDFDOXWHX-UHFFFAOYSA-N 1-bromo-1-chloroethene Chemical group ClC(Br)=C DQIRHMDFDOXWHX-UHFFFAOYSA-N 0.000 description 1
VOCDJQSAMZARGX-UHFFFAOYSA-N 1-ethenylpyrrolidine-2,5-dione Chemical compound C=CN1C(=O)CCC1=O VOCDJQSAMZARGX-UHFFFAOYSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical class OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 description 1
GPOGMJLHWQHEGF-UHFFFAOYSA-N 2-chloroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCl GPOGMJLHWQHEGF-UHFFFAOYSA-N 0.000 description 1
YBXYCBGDIALKAK-UHFFFAOYSA-N 2-chloroprop-2-enamide Chemical compound NC(=O)C(Cl)=C YBXYCBGDIALKAK-UHFFFAOYSA-N 0.000 description 1
QQBUHYQVKJQAOB-UHFFFAOYSA-N 2-ethenylfuran Chemical compound C=CC1=CC=CO1 QQBUHYQVKJQAOB-UHFFFAOYSA-N 0.000 description 1
IGDLZDCWMRPMGL-UHFFFAOYSA-N 2-ethenylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(C=C)C(=O)C2=C1 IGDLZDCWMRPMGL-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
229940117913 acrylamide Drugs 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
YPTLFOZCUOHVFO-VOTSOKGWSA-N diethyl (e)-2-methylbut-2-enedioate Chemical compound CCOC(=O)\C=C(/C)C(=O)OCC YPTLFOZCUOHVFO-VOTSOKGWSA-N 0.000 description 1
YPTLFOZCUOHVFO-SREVYHEPSA-N diethyl (z)-2-methylbut-2-enedioate Chemical compound CCOC(=O)\C=C(\C)C(=O)OCC YPTLFOZCUOHVFO-SREVYHEPSA-N 0.000 description 1
238000000578 dry spinning Methods 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
239000000975 dye Substances 0.000 description 1
XJELOQYISYPGDX-UHFFFAOYSA-N ethenyl 2-chloroacetate Chemical compound ClCC(=O)OC=C XJELOQYISYPGDX-UHFFFAOYSA-N 0.000 description 1
AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
238000001802 infusion Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
125000005395 methacrylic acid group Chemical class 0.000 description 1
125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
238000001000 micrograph Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
230000035515 penetration Effects 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
- D01D5/247—Discontinuous hollow structure or microporous structure
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/16—Stretch-spinning methods using rollers, or like mechanical devices, e.g. snubbing pins
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Mechanical Engineering (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Toxicology (AREA)
Artificial Filaments (AREA)

IL30654A 1967-09-05 1968-09-02 Hollow synthetic fibers and method for preparing them IL30654A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US66550667A	1967-09-05	1967-09-05

Publications (2)

Publication Number	Publication Date
IL30654A0 IL30654A0 (en)	1968-11-27
IL30654A true IL30654A (en)	1972-03-28

Family

ID=24670380

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL30654A IL30654A (en)	1967-09-05	1968-09-02	Hollow synthetic fibers and method for preparing them

Country Status (7)

Country	Link
BE (1)	BE720449A (fr)
CH (1)	CH491209A (fr)
FR (1)	FR1584637A (fr)
GB (1)	GB1212786A (fr)
IL (1)	IL30654A (fr)
LU (1)	LU56808A1 (fr)
NL (1)	NL6812533A (fr)

1968
- 1968-08-29 GB GB41314/68A patent/GB1212786A/en not_active Expired
- 1968-09-02 IL IL30654A patent/IL30654A/en unknown
- 1968-09-03 LU LU56808D patent/LU56808A1/xx unknown
- 1968-09-03 NL NL6812533A patent/NL6812533A/xx unknown
- 1968-09-04 CH CH1325668A patent/CH491209A/fr not_active IP Right Cessation
- 1968-09-05 BE BE720449D patent/BE720449A/xx unknown
- 1968-09-05 FR FR1584637D patent/FR1584637A/fr not_active Expired

Also Published As

Publication number	Publication date
LU56808A1 (fr)	1969-06-18
CH491209A (fr)	1970-05-31
IL30654A0 (en)	1968-11-27
BE720449A (fr)	1969-03-05
FR1584637A (fr)	1969-12-26
NL6812533A (fr)	1969-03-07
GB1212786A (en)	1970-11-18

Publication	Publication Date	Title
US2558735A (en)	1951-07-03	Method of forming dyed shaped articles from acrylonitrile polymerization products
US2948581A (en)	1960-08-09	Method of producing a synthetic fiber
US2697023A (en)	1954-12-14	Spinning acrylonitrile
GB584548A (en)	1947-01-17	Improvements in or relating to the spinning of filaments of acrylonitrile polymers
US3963790A (en)	1976-06-15	Non-inflammable filaments comprising acrylonitrile/vinylidene chloride copolymers
USRE25831E (en)	1965-08-03	Method for dyeing acrylonitrile polymer fibers
US4383086A (en)	1983-05-10	Filaments and fibers of acrylonitrile copolymer mixtures
US3932577A (en)	1976-01-13	Method for making void-free acrylic fibers
US3941860A (en)	1976-03-02	Polyvinylidene fluoride containing threads, fibers and films of good dye affinity, and process for obtaining them
US2880056A (en)	1959-03-31	Synthetic fibers having a natural crimp and method for preparing the same
US3851036A (en)	1974-11-26	Method of making hollow fibers
GB663500A (en)	1951-12-19	Method of making shaped articles of an acrylonitrile polymer
US4663232A (en)	1987-05-05	Acrylic fiber having excellent durability and dyeability and process for preparation thereof
US3706828A (en)	1972-12-19	Wet spinning non-circular polyacrylonitrile fibers by utilizing circular orifices and sequential coagulation
US3180845A (en)	1965-04-27	Method of preparing void free fibers from acrylonitrile polymers
US4056517A (en)	1977-11-01	Modacryl filaments and fibers and process for their manufacture
US2743994A (en)	1956-05-01	Method of producing shaped articles from polymeric materials
US2984912A (en)	1961-05-23	Art of producing filamentary polyacrylonitrile
US3577499A (en)	1971-05-04	Method for preparing permanently opaque fibers
IL30654A (en)	1972-03-28	Hollow synthetic fibers and method for preparing them
US3551547A (en)	1970-12-29	Method for preparing permanently opaque fibers
US3402234A (en)	1968-09-17	Novel coagulation process
US3101245A (en)	1963-08-20	Production of polyacrylonitrile fibers
US3505445A (en)	1970-04-07	Solvent removal process for wet spun fibers
US3451140A (en)	1969-06-24	Production of acrylic synthetic fibers