IL33891A - A process for the production of fibers, textiles and designed products consisting of inorganic material - Google Patents

A process for the production of fibers, textiles and designed products consisting of inorganic material

Info

Publication number: IL33891A
Authority: IL; Israel
Prior art keywords: carbon; metal; carbon dioxide; precursor; composition
Prior art date: 1969-02-17

Application number

IL33891A

Other languages

English (en)

Hebrew (he)

Other versions

IL33891A0 (en

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1969-02-17

Filing date

1970-02-12

Publication date

1973-05-31

1970-02-12 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1970-04-20 Publication of IL33891A0 publication Critical patent/IL33891A0/xx

1973-05-31 Publication of IL33891A publication Critical patent/IL33891A/en

Links

238000000034 method Methods 0.000 title claims description 40
230000008569 process Effects 0.000 title claims description 36
239000000835 fiber Substances 0.000 title claims description 13
238000004519 manufacturing process Methods 0.000 title claims description 8
239000004753 textile Substances 0.000 title claims description 8
229910010272 inorganic material Inorganic materials 0.000 title claims description 3
239000011147 inorganic material Substances 0.000 title claims description 3
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 62
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 41
229910052799 carbon Inorganic materials 0.000 claims description 39
229910052751 metal Inorganic materials 0.000 claims description 33
239000002184 metal Substances 0.000 claims description 33
229910002092 carbon dioxide Inorganic materials 0.000 claims description 32
239000001569 carbon dioxide Substances 0.000 claims description 30
239000000203 mixture Substances 0.000 claims description 26
150000002736 metal compounds Chemical class 0.000 claims description 20
238000005245 sintering Methods 0.000 claims description 18
229910044991 metal oxide Inorganic materials 0.000 claims description 16
150000004706 metal oxides Chemical class 0.000 claims description 16
238000010438 heat treatment Methods 0.000 claims description 14
239000000463 material Substances 0.000 claims description 9
239000011261 inert gas Substances 0.000 claims description 6
239000011368 organic material Substances 0.000 claims description 5
239000002243 precursor Substances 0.000 description 34
229960004424 carbon dioxide Drugs 0.000 description 27
238000006243 chemical reaction Methods 0.000 description 19
150000001875 compounds Chemical class 0.000 description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
229920000297 Rayon Polymers 0.000 description 13
239000000047 product Substances 0.000 description 13
238000000354 decomposition reaction Methods 0.000 description 12
239000002964 rayon Substances 0.000 description 12
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 6
150000002739 metals Chemical class 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
150000004767 nitrides Chemical class 0.000 description 4
239000007800 oxidant agent Substances 0.000 description 4
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
239000000908 ammonium hydroxide Substances 0.000 description 3
229910052786 argon Inorganic materials 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
239000002657 fibrous material Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000000314 lubricant Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
239000004627 regenerated cellulose Substances 0.000 description 3
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
229910002090 carbon oxide Inorganic materials 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
230000008859 change Effects 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
238000007596 consolidation process Methods 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical class ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 2
239000004744 fabric Substances 0.000 description 2
239000011872 intimate mixture Substances 0.000 description 2
238000011068 loading method Methods 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
230000009467 reduction Effects 0.000 description 2
238000005406 washing Methods 0.000 description 2
IPCAPQRVQMIMAN-UHFFFAOYSA-L zirconyl chloride Chemical compound Cl[Zr](Cl)=O IPCAPQRVQMIMAN-UHFFFAOYSA-L 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229920000298 Cellophane Polymers 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
229910004664 Cerium(III) chloride Inorganic materials 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Chemical class 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical class [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
206010042135 Stomatitis necrotising Diseases 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
229910006213 ZrOCl2 Inorganic materials 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000009413 insulation Methods 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
-1 linen Substances 0.000 description 1
239000002932 luster Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
150000001247 metal acetylides Chemical class 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
239000010955 niobium Substances 0.000 description 1
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
201000008585 noma Diseases 0.000 description 1
239000000123 paper Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
239000011269 tar Substances 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
VGBPIHVLVSGJGR-UHFFFAOYSA-N thorium(4+);tetranitrate Chemical compound [Th+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VGBPIHVLVSGJGR-UHFFFAOYSA-N 0.000 description 1
238000005303 weighing Methods 0.000 description 1
239000002023 wood Substances 0.000 description 1
PCMOZDDGXKIOLL-UHFFFAOYSA-K yttrium chloride Chemical compound [Cl-].[Cl-].[Cl-].[Y+3] PCMOZDDGXKIOLL-UHFFFAOYSA-K 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/06—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
- C01B13/145—After-treatment of oxides or hydroxides, e.g. pulverising, drying, decreasing the acidity
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/218—Yttrium oxides or hydroxides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/229—Lanthanum oxides or hydroxides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/235—Cerium oxides or hydroxides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/16—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from products of vegetable origin or derivatives thereof, e.g. from cellulose acetate
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
- C01P2006/33—Phase transition temperatures
- C01P2006/34—Melting temperatures
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Geology (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Fibers (AREA)
Chemical Or Physical Treatment Of Fibers (AREA)
Ceramic Products (AREA)
Carbon And Carbon Compounds (AREA)

IL33891A 1969-02-17 1970-02-12 A process for the production of fibers, textiles and designed products consisting of inorganic material IL33891A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US79998869A	1969-02-17	1969-02-17

Publications (2)

Publication Number	Publication Date
IL33891A0 IL33891A0 (en)	1970-04-20
IL33891A true IL33891A (en)	1973-05-31

Family

ID=25177231

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL33891A IL33891A (en)	1969-02-17	1970-02-12	A process for the production of fibers, textiles and designed products consisting of inorganic material

Country Status (8)

Country	Link
JP (1)	JPS5127686B1 (fr)
BE (1)	BE746112A (fr)
CH (1)	CH510136A (fr)
DE (1)	DE2007209C3 (fr)
FR (1)	FR2035490A5 (fr)
GB (1)	GB1292908A (fr)
IL (1)	IL33891A (fr)
NL (1)	NL7002145A (fr)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3385915A (en) *	1966-09-02	1968-05-28	Union Carbide Corp	Process for producing metal oxide fibers, textiles and shapes

1970
- 1970-02-12 IL IL33891A patent/IL33891A/en unknown
- 1970-02-16 FR FR7005471A patent/FR2035490A5/fr not_active Expired
- 1970-02-16 NL NL7002145A patent/NL7002145A/xx unknown
- 1970-02-17 CH CH227370A patent/CH510136A/fr not_active IP Right Cessation
- 1970-02-17 GB GB7558/70A patent/GB1292908A/en not_active Expired
- 1970-02-17 BE BE746112D patent/BE746112A/fr unknown
- 1970-02-17 JP JP45013160A patent/JPS5127686B1/ja active Pending
- 1970-02-17 DE DE2007209A patent/DE2007209C3/de not_active Expired

Also Published As

Publication number	Publication date
IL33891A0 (en)	1970-04-20
DE2007209C3 (de)	1975-05-15
DE2007209A1 (de)	1970-09-03
FR2035490A5 (fr)	1970-12-18
NL7002145A (fr)	1970-08-19
DE2007209B2 (fr)	1974-08-29
BE746112A (fr)	1970-08-17
CH510136A (fr)	1971-07-15
JPS5127686B1 (fr)	1976-08-14
GB1292908A (en)	1972-10-18

Publication	Publication Date	Title
US3385915A (en)	1968-05-28	Process for producing metal oxide fibers, textiles and shapes
US3403008A (en)	1968-09-24	Process for producing metal carbide fibers, textiles and shapes
US3529044A (en)	1970-09-15	Production of inorganic fibrous materials
GB2059407A (en)	1981-04-23	Process for producing carbon tows
IL27279A (en)	1972-04-27	Metal fibers,textiles and shapes and process for producing them
US3556729A (en)	1971-01-19	Process for oxidizing and carbonizing acrylic fibers
US3723607A (en)	1973-03-27	Surface modification of carbon fibers
GB2168966A (en)	1986-07-02	High-strength carbonaceous fiber
US4073869A (en)	1978-02-14	Internal chemical modification of carbon fibers to yield a product of reduced electrical conductivity
US4460650A (en)	1984-07-17	Acrylonitrile fibers, a process for producing acrylonitrile fibers, as well as producing peroxidized fibers, fibrous active carbon or carbon fibers therefrom
US3406025A (en)	1968-10-15	Process for producing metal fibers, textiles and shapes
US4162301A (en)	1979-07-24	Flexible microcrystalline zirconium carbide fabric
US3723150A (en)	1973-03-27	Surface modification of carbon fibers
US3661616A (en)	1972-05-09	Process for carbonizing cellulose fiber or the products thereof
US3803056A (en)	1974-04-09	Heat resistant black fibers and fabrics derived from regenerated cellulose,containing certain heavy metals
US3754957A (en)	1973-08-28	Enhancement of the surface characteristics of carbon fibers
EP0057492A2 (fr)	1982-08-11	Procédé pour la modification superficielle de fibres de carbone
US4250131A (en)	1981-02-10	Refractory inorganic oxide fibers
US3639140A (en)	1972-02-01	Process for carbonized cellulose fiber or the products thereof
US3859187A (en)	1975-01-07	Electrolytic process for the surface modification of high modulus carbon fibers
EP0378381A2 (fr)	1990-07-18	Fibres de carbone chargées de métaux
GB1589178A (en)	1981-05-07	Dry spinning of cellulose
GB2130188A (en)	1984-05-31	Process for producing carbon fiber or graphite fiber
US4883619A (en)	1989-11-28	Refractory metal oxide processes
US3900285A (en)	1975-08-19	Process for producing fireproof fibers