IL40860A - Smokable products and their production - Google Patents
Smokable products and their productionInfo
- Publication number
- IL40860A IL40860A IL40860A IL4086072A IL40860A IL 40860 A IL40860 A IL 40860A IL 40860 A IL40860 A IL 40860A IL 4086072 A IL4086072 A IL 4086072A IL 40860 A IL40860 A IL 40860A
- Authority
- IL
- Israel
- Prior art keywords
- aluminium
- iron
- ammonium
- process according
- magnesium
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 claims 46
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 41
- 238000000034 method Methods 0.000 claims 40
- 239000013522 chelant Substances 0.000 claims 26
- 229910021529 ammonia Inorganic materials 0.000 claims 20
- 239000000463 material Substances 0.000 claims 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 16
- 150000001735 carboxylic acids Chemical class 0.000 claims 14
- DSLZVSRJTYRBFB-DUHBMQHGSA-N galactaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(O)=O DSLZVSRJTYRBFB-DUHBMQHGSA-N 0.000 claims 14
- -1 magnesium-aluminium-saccharat manganese-iron(III) Chemical compound 0.000 claims 13
- 229910052742 iron Inorganic materials 0.000 claims 12
- DSLZVSRJTYRBFB-LLEIAEIESA-N D-glucaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O DSLZVSRJTYRBFB-LLEIAEIESA-N 0.000 claims 11
- 150000003863 ammonium salts Chemical class 0.000 claims 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 10
- 239000001913 cellulose Substances 0.000 claims 10
- 229920002678 cellulose Polymers 0.000 claims 10
- 241000208125 Nicotiana Species 0.000 claims 9
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 9
- 150000001450 anions Chemical class 0.000 claims 9
- 239000007800 oxidant agent Substances 0.000 claims 8
- 239000002253 acid Substances 0.000 claims 7
- 239000000945 filler Substances 0.000 claims 7
- 230000000391 smoking effect Effects 0.000 claims 7
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 6
- 239000005864 Sulphur Substances 0.000 claims 6
- 239000004411 aluminium Substances 0.000 claims 6
- 229910052782 aluminium Inorganic materials 0.000 claims 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 6
- FOJJCOHOLNJIHE-UHFFFAOYSA-N aluminum;azane Chemical compound N.[Al+3] FOJJCOHOLNJIHE-UHFFFAOYSA-N 0.000 claims 6
- UMEAURNTRYCPNR-UHFFFAOYSA-N azane;iron(2+) Chemical compound N.[Fe+2] UMEAURNTRYCPNR-UHFFFAOYSA-N 0.000 claims 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 6
- 235000018102 proteins Nutrition 0.000 claims 6
- 108090000623 proteins and genes Proteins 0.000 claims 6
- 102000004169 proteins and genes Human genes 0.000 claims 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 5
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 claims 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 5
- MHKWSJBPFXBFMX-UHFFFAOYSA-N iron magnesium Chemical compound [Mg].[Fe] MHKWSJBPFXBFMX-UHFFFAOYSA-N 0.000 claims 5
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims 5
- 150000003839 salts Chemical class 0.000 claims 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 4
- 229920002230 Pectic acid Polymers 0.000 claims 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 4
- 235000001014 amino acid Nutrition 0.000 claims 4
- 150000001413 amino acids Chemical class 0.000 claims 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- 229940095064 tartrate Drugs 0.000 claims 4
- 241000196324 Embryophyta Species 0.000 claims 3
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 claims 3
- 150000007513 acids Chemical class 0.000 claims 3
- 150000001340 alkali metals Chemical class 0.000 claims 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 3
- 150000001768 cations Chemical class 0.000 claims 3
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 3
- 229910052749 magnesium Inorganic materials 0.000 claims 3
- 239000011777 magnesium Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims 2
- NAOLWIGVYRIGTP-UHFFFAOYSA-N 1,3,5-trihydroxyanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1 NAOLWIGVYRIGTP-UHFFFAOYSA-N 0.000 claims 2
- QPDSQDQXUUHGIA-UHFFFAOYSA-L C(=O)([O-])C(O)C(O)C(=O)[O-].[Al+3].[Mn+2] Chemical compound C(=O)([O-])C(O)C(O)C(=O)[O-].[Al+3].[Mn+2] QPDSQDQXUUHGIA-UHFFFAOYSA-L 0.000 claims 2
- QGKGPRSAGKUWOY-UHFFFAOYSA-K C(=O)([O-])C(O)C(O)C(=O)[O-].[Al+3].[NH4+].C(=O)([O-])C(O)C(O)C(=O)[O-] Chemical compound C(=O)([O-])C(O)C(O)C(=O)[O-].[Al+3].[NH4+].C(=O)([O-])C(O)C(O)C(=O)[O-] QGKGPRSAGKUWOY-UHFFFAOYSA-K 0.000 claims 2
- INJBRCBVFOLIDB-UHFFFAOYSA-L C(=O)([O-])C(O)C(O)C(=O)[O-].[Mg+2].[Al+3] Chemical compound C(=O)([O-])C(O)C(O)C(=O)[O-].[Mg+2].[Al+3] INJBRCBVFOLIDB-UHFFFAOYSA-L 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 2
- RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 claims 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 2
- DSLZVSRJTYRBFB-UHFFFAOYSA-N Galactaric acid Natural products OC(=O)C(O)C(O)C(O)C(O)C(O)=O DSLZVSRJTYRBFB-UHFFFAOYSA-N 0.000 claims 2
- 108010061711 Gliadin Proteins 0.000 claims 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- 108010055615 Zein Proteins 0.000 claims 2
- 229920002494 Zein Polymers 0.000 claims 2
- 239000012675 alcoholic extract Substances 0.000 claims 2
- 239000000783 alginic acid Substances 0.000 claims 2
- 235000010443 alginic acid Nutrition 0.000 claims 2
- 229920000615 alginic acid Polymers 0.000 claims 2
- 229960001126 alginic acid Drugs 0.000 claims 2
- 150000004781 alginic acids Chemical class 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 229910001963 alkali metal nitrate Inorganic materials 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 229910001964 alkaline earth metal nitrate Inorganic materials 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- 229910000147 aluminium phosphate Chemical class 0.000 claims 2
- ALHCMDWAWCPRKD-UHFFFAOYSA-K aluminum 2-hydroxypropane-1,2,3-tricarboxylate manganese(2+) Chemical compound C(CC(O)(C(=O)[O-])CC(=O)[O-])(=O)[O-].[Al+3].[Mn+2] ALHCMDWAWCPRKD-UHFFFAOYSA-K 0.000 claims 2
- LEWCAQWVBYTPMP-UHFFFAOYSA-K aluminum;magnesium;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Mg+2].[Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O LEWCAQWVBYTPMP-UHFFFAOYSA-K 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 2
- NPGANCAPTYDBSJ-UHFFFAOYSA-K azanium 2-[(4,5-dioxo-1,3,2-dioxalumolan-2-yl)oxy]-2-oxoacetate Chemical compound [NH4+].[Al+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O NPGANCAPTYDBSJ-UHFFFAOYSA-K 0.000 claims 2
- NGPGDYLVALNKEG-UHFFFAOYSA-N azanium;azane;2,3,4-trihydroxy-4-oxobutanoate Chemical compound [NH4+].[NH4+].[O-]C(=O)C(O)C(O)C([O-])=O NGPGDYLVALNKEG-UHFFFAOYSA-N 0.000 claims 2
- 239000004202 carbamide Substances 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 2
- 235000019506 cigar Nutrition 0.000 claims 2
- 235000019504 cigarettes Nutrition 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 2
- 229920000591 gum Polymers 0.000 claims 2
- 150000002402 hexoses Chemical class 0.000 claims 2
- 150000004679 hydroxides Chemical class 0.000 claims 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 2
- 239000003446 ligand Substances 0.000 claims 2
- 235000013918 magnesium diglutamate Nutrition 0.000 claims 2
- 229940063886 magnesium glutamate Drugs 0.000 claims 2
- MYUGVHJLXONYNC-QHTZZOMLSA-L magnesium;(2s)-2-amino-5-hydroxy-5-oxopentanoate Chemical compound [Mg+2].[O-]C(=O)[C@@H](N)CCC(O)=O.[O-]C(=O)[C@@H](N)CCC(O)=O MYUGVHJLXONYNC-QHTZZOMLSA-L 0.000 claims 2
- 150000002696 manganese Chemical class 0.000 claims 2
- 229910052748 manganese Inorganic materials 0.000 claims 2
- 239000011572 manganese Substances 0.000 claims 2
- 239000011707 mineral Substances 0.000 claims 2
- 235000010755 mineral Nutrition 0.000 claims 2
- 150000007522 mineralic acids Chemical class 0.000 claims 2
- 230000007935 neutral effect Effects 0.000 claims 2
- 229910017604 nitric acid Inorganic materials 0.000 claims 2
- 235000006408 oxalic acid Nutrition 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 239000001814 pectin Substances 0.000 claims 2
- 235000010987 pectin Nutrition 0.000 claims 2
- 229920001277 pectin Polymers 0.000 claims 2
- 150000002972 pentoses Chemical class 0.000 claims 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 239000000779 smoke Substances 0.000 claims 2
- 239000011975 tartaric acid Substances 0.000 claims 2
- 235000002906 tartaric acid Nutrition 0.000 claims 2
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims 2
- 239000002699 waste material Substances 0.000 claims 2
- 239000005019 zein Substances 0.000 claims 2
- 229940093612 zein Drugs 0.000 claims 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- AJCRLWHLHSRUIX-UHFFFAOYSA-L C(C(=O)[O-])(=O)[O-].[Al+3].[Mg+2] Chemical compound C(C(=O)[O-])(=O)[O-].[Al+3].[Mg+2] AJCRLWHLHSRUIX-UHFFFAOYSA-L 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 108010068370 Glutens Proteins 0.000 claims 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- FRHBOQMZUOWXQL-UHFFFAOYSA-K azane;2-hydroxypropane-1,2,3-tricarboxylate;iron(3+) Chemical compound N.[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FRHBOQMZUOWXQL-UHFFFAOYSA-K 0.000 claims 1
- ZCLVNIZJEKLGFA-UHFFFAOYSA-H bis(4,5-dioxo-1,3,2-dioxalumolan-2-yl) oxalate Chemical compound [Al+3].[Al+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O ZCLVNIZJEKLGFA-UHFFFAOYSA-H 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Chemical group 0.000 claims 1
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical group [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 235000015165 citric acid Nutrition 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 239000004313 iron ammonium citrate Substances 0.000 claims 1
- 235000000011 iron ammonium citrate Nutrition 0.000 claims 1
- KZLJDAVUYZOARA-UHFFFAOYSA-N iron(3+);manganese(2+) Chemical compound [Mn+2].[Fe+3] KZLJDAVUYZOARA-UHFFFAOYSA-N 0.000 claims 1
- 125000000468 ketone group Chemical group 0.000 claims 1
- 159000000003 magnesium salts Chemical class 0.000 claims 1
- WBLYAHNHROUWRN-UHFFFAOYSA-N magnesium;iron(3+) Chemical compound [Mg+2].[Fe+3] WBLYAHNHROUWRN-UHFFFAOYSA-N 0.000 claims 1
- 239000001630 malic acid Substances 0.000 claims 1
- 235000011090 malic acid Nutrition 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 239000010318 polygalacturonic acid Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Tobacco Products (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Paper (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Claims (1)
1. Patent Claims 1. Smokable product comprising a combustible material based on cellulose, characterised in that the smokable product contains metal (ill) chelate compounds of alkaline earth metals and/or of manganese (II) , the "metal (ill) chelate compounds" being complex anions which contain trivalent iron or aluminium as the central atom and anions of chelate-forming organic carboxylic acids as ligands. 2„ Smokable product according to claim 1, characterised in that it contains chelate compounds of the general formula (i): Kz [Mex Ry] (Ϊ) in which; K represents magnesium, calcium or manganese (II ) , Me represents trivalent iron or aluminium, R represents the radical of a chelate-forming organic carboxylic acid, x and y_ denote small integers which depend on the stoichiometric composition of the anion complex which is formed, and z indicates the number of divalent cations K. 3. Smokable product according to claims 1 and 2, characterised in that it contains magnesium-metal (ill) chelate compounds , ¾. Smokable product according to claims 1 to 3, characterised in that the chelate compounds contain, as chelate-forming organic carboxylic acids, carboxylic acids which contain 2 to 8 carbon atoms and which in addition to b ou contain at least on h d ox l ou 5. Smokable product according to claims 1 to t characterised in that the chelate compounds contain dicarboxyl acids or hydroxycarboxylic acids as chelate-forming carboxylic acid. 6. Smokable product according to claims 1 to 5» characterised in that the chelate-forming carboxylic acids contained in the chelate compounds are monodicarboxylic acids and dicarboxylic acids derived from pentoses and hexoses. 7. Smokable product according to claims 1 to 6, characterised in that the chelate-forming carboxylic acids contained in the chelate compounds are oxalic acid, glyceric acid, glycol^ic acid, malic acid, tartaric acid, citric acid, galactaric acid and saccharic acid. 8. Smokable product according to claims 1 to 7, characterised in that the smokable product contains magnesium-iron(lll) glycol/ate , magnesium-iron(lIl)-oxalate , magnesium-iron(lll) citrate, magnesium-iron(III)tartrate , magnesium-iron(III)galactarate , magnesium-iron(III) saccharate , magnesium-aluminium glycol/iate, magnesium-aluminium oxalate, magnesium-aluminium citrate, magnesium-aluminium tartrate, magnesium-aluminium galactarate, magnesium-aluminium-saccharat manganese-iron(III) glycol^ate, manganese-iron(III) oxalate, manganese-iron(ill) citrate, manganese-iron(ill) tartrate, manganese-iron(III) galactarate, manganese-iron(ill) saccharate, manganese-aluminium glycol^ate, manganese-aluminium oxalate, manganese-aluminium citrate, manganese-aluminium tartrate, manganese-aluminium galactarate, manganese-aluminium saccharate. 9. Smokable product according to claims 1 to 8, characterised in that, in the general formual (I), x represents 1 or 2, v_ represents integers of from 1 to and z represents the number of divalent cations K per anion, which number depends on the free negative charges remaining in the anion complex. 10 „ Smokable product according to claims 1 to 9, characterised in that the combustible material used is cellulose-containing plant material, in particular tobacco, tobacco waste products, decomposed cellulose-containing-plant material, cellulose or cellulose derivatives, alone or in mixtures. 11. Smokable product according to claims 1 to 10, characterised in that the product contains about 0.5 to 70$ b weight of chelate compound based on the total weight of combustible material. 12. Smokable product according to claims 1 to 11, characterised in that the product contains about 5 to 5 $ by weight of chelate compound based on the total weight of combustible material. 13. Smokable product according to claims 1 to 12, characterised in that the smoking product contains in addition a filler. 14. Smokable product according to claim 13, characterised in that minerals and salts which are inert under the condition of smoking, and hydroxides and hydrated oxides which split off 15* Smokable product according to claims 13 and 14, characterised in that the fillers used are hydrated oxides of aluminium and/or silicic acid. 16. Smokable product according to claims 13 to 15» characterised in that the fillers are used in quantities of about 1 to 70$ by weight, based on the total weight of smokable product. 17. Smokable product according to claims 1 to 16, characterised in that the smokable product contains in addition compounds which split off ammonia under smoking conditions . 18. Smokable product according to claim 17, characterised in that the compounds which split off ammonia are ammonia salts or inorganic acids and organic carboxylic acids and salts of amino acids and acid amides. 19. Smokable product according to claims 17 and 18, characterised in that acid and neutral ammonium salts of carbonic acid, nitric acid and phosphoric acid are used. 20. Smokable product according to claims 17 and 18, characterised in that the ammonium salts used are organic carboxylic acids which have a carbon/oxygen ratio of about 2:1 to 1:2 in the summation formula. 21. Smokable product according to claims 17, 18 and 20, characterised in that the compound which splits off ammonia is ammonium citrate and/or ammonium tartrate. 22. Smokable product according to claims 17 and 18, characterised in that the compounds which split off ammonia are ammonium salts, magnesium salts or manganese salts of amino-acids . 23. Smokable product according to claims 17, 18 and 22, characterised in that the compound which splits off ammonia is magnesium glutamate. 2k, Smokable product according to claims 17 and 18, characterised in that the compound which splits off ammonia is urea. 25. Smokable product according to claim 17, characterised in that the compounds which split off ammonia are the ammonium salts corresponding to the chelate compounds used according to the invention. 26. Smokable product according to claims 17 and 25, characterised in that the compounds which split off ammonia are ammonium-iro (ill) glycol^ate, ammonium-iron(ill) oxalate, ammonium-iron (ill) citrate, ammonium- iron( III) tartrate, ammonium-iron-(lll) galactarate, ammonium-iron (ill) saccharate, ammonium-aluminium glycol/ate, ammonium-aluminium oxalate, ammonium-aluminium citrate, ammonium-aluminium tartrate, ammonium-aluminium galactarate and ammonium-aluminium saccharate. 27. Smokable product according to claims 17 to 26, characterised in that the compounds which split off ammonia are contained in the product in such quantities that the smoke is 28. Smokable product according to claims 1 to 27, characterised in that the product contains in addition 0.01 to 7$ by weight, based on the total weight, of an oxidizing agent. 29· Smokable product according to claim 28, characterised in that the product contains oxidizing agents in quantities of 1 to 5 by weight, based on the total weight. 30. Smokable product according to claims 28 and 29, characterised in that the oxidizing agents used are alkali metal or alkaline earth metal nitrates. 31. Smokable product according to claims 28 and 29, characterised in that the oxidizing agents used are alkali metal permanganates. 32. Smokable product according to claims 1 to 31, characterised in that the product contains in addition about 0.01 to 10$ by weight of ammonium salts of polygalacturonic acids and/or ammonium salts of carboxymethylcellulose . 33. Smokable product according to claim 32, characterised in that the polygalacturonic acid used is pectin, alginic acid or gum arable. 34. Smokable product according to claims 1 to 33, characterised in that the product contains 0.01 to 5 by weight of proteins which have a low sulphur content. 35 Smokable product according to claim 3½, characterised in that the proteins with a low sulphur content used are zein, hordein or gliadin. 36. Smokable product according to claims b " h and 35 , characterised in that alcoholic extracts of the low sulphur proteins are used. 37. Smokable product according to claims 1 to 36 , characterised in that the product contains about 0.1 to 50$ by weight of tobacco constituents, based on the total weight of the product. 38. Smokable product according to claims 1 to 37 , characterised in that the products according to the invention are in the form of paper-like webs with a surface weight of 10 to 250 g/m2 and a thickness of 10 to 120 u. 39. Process for the production of smokable products, characterised in that metal (ill)-chelate compounds of alkaline earth metals and/or of manganese (il) are introduced into a combustible material based on cellulose, the metal (III)-chelate compounds being complex anions which contain trivalent iron or aluminium as the central atom and anions of chelate-forming organic carboxylic acids as ligands. 40. Process according to claim 39 , characterised in that chelate compounds of the general formula (I): are introduced in which: K represents magnesium calcium or manganese (il); Me represents trivalent iron or aluminium; R represents the radical of a chelate-forming organic carboxylic acid; 41. Process according to claims 39 and 40, characterised in that magnesium-metal (ill) chelate compounds are introduced. 42. Process according to claims 39 to 41 characterised in that chelate compounds are used which contain, as chelate-forming carboxylic acids, organic carboxylic acids which contain 2 to 8 carbon atoms and which in addition to the carboxyl group contain at least one hydroxyl group, keto group or additional carboxyl group. 3. Process according to claims 39 to 42, characterised in that chelate compounds are used in which the chelate-forming carboxylic acids are dicarboxylic acids or hydroxycarbox lic acids o 44. Process according to claims 39 to 43, characterised in that chelate compounds are used in which the chelate forming carboxylic acids are mono- and dicarboxylic acids derived from pentoses and hexoses. 45. Process according to claims 39 to 44, characterised in that chelate compounds are used in which the chelate-forming carboxylic acid is oxalic acid, glyceric acid, glycol/ic acid, tartaric acid, citric acid, galactaric acid or saccharic acid. 46. Process according to claims 39 to 45, characterised in that the chelate-forming compounds introduced are magnesium iron (ill) glycol ate, magnesium-iron (ill) oxalate magnesium-iron (III) citrate, magnesium-iron (ill) tartrate, magnesium-iron (ill) galactarate, magnesium-iron (ill) saccharate, magnesium-aluminium glycol,_tate , magnesium aluminium oxalate, magnesium-aluminium citrate, magnesium-aluminium tartrate, magnesium-aluminium galactarate, magnesium-aluminium saccharate, manganese-iron(lll) glycol ate, manganese-Iron (ill) oxalate, manganese-iron (ill) citrate, manganese-iron (ill) tartrate, manganese-iron (ill) galactarate, manganese-iron (ill) saccharate, manganese-aluminium glycol^ate, manganese-aluminium oxalate, manganese-aluminium citrate, manganese-aluminium tartrate, manganese-aluminium galactarate and manganese-aluminium saccharate. 47. Process according to claims 39 to 4(5, characterised in that chelate compounds according to the general formula (i) are used in which x represents 1 or 2, _ represents integers of from 1 to 4 and z represents the number of divalent cations K per anion, which depends on the free negative charges remaining in the anion complex. 48. Process according to claims 39 to 47, characterised in that the combustible material used is cellulose-containing plant material, in particular tobacco, tobacco waste products, decomposed cellulose-containing plant material, cellulose or cellulose derivatives, either alone or as mixtures. 49. Process according to claims 39 to 48, characterised in that the chelate compounds used according to the invention are introduced in quantities of about 0.5 to by weight, based on the total weight of combustible material. 50. Process according to claims 39 to 49, characterised in that the chelate compounds used according to the invention are introduced in quantities of about 5 to 50 by weight based on the total weight of combustible material. 51. Process according to claims 39 to 50 , characterised in that the chelate compounds used according to the invention are applied to the combustible material in the form of aqueous solutions by spraying, painting or immersion followed by drying. 52. Process according to claims 39 to 51 , characterised in that the chelate compounds used are directly introduced into a casting solution. 53. Process according to claims 39 to 52 , characterised in that in addition a filler is introduced into the combustible material. 54. Process according to claim 53 , characterised in that the fillers introduced are minerals and salts which are inert under smoking conditions and hydroxides and hydrated oxides which split off water under smoking conditions. 55. Process according to claims 53 and 5 , characterised in that the fillers used are hydrated oxides of aluminium and/or silicic acid. 56. Process according to claims 53 to 55 , characterised in that the fillers are used in quantities of about 1 to 70% by weight, based on the total, weight of smokable product. 57. Process according to claims 39 to 56 , characterised in that in addition, compounds which split off ammonia under smoking conditions are introduced into the combustible material . 58. Process according to claim 57 , characterised in that the compounds which split off ammonia are ammonium salts of inorganic acids and organic carboxylic acids as well as salts of aminoacids and acid amides. 59. Process according to claims 57 and 58 , characterised in that the compounds which split off ammonia are acid and neutral salts of carbonic acid, nitric acid and phosphoric acid. 60. Process according to claims 57 and 58 , characterised in that the compounds which split off ammonia are ammonium salts of organic carboxylic acids which have a carbon/oxygen ratio of about 2 : 1 to 1 : 2 in the summation formula. 61. Process according to claims 57 , 58 and 60 , characterised in that the compound which splits off ammonia is ammonium citrate and/or ammonium tartrate. 62. Process according to claims 57 and 58 , characterised in that the compounds which split off ammonia are ammonium, magnesium or manganese salts of amino acids. 63. Process according to claims 57 , 58 and 62 , characterised in that the compound which splits off ammonia is magnesium glutamate. V 6k. Process according to claims 57 and 58 , characterised in that the Compound which splits off ammonia is urea. 65. Process according to claim 57 , characterised in that the ammonium salts which correspond to the chelate compounds used according to the invention are introduced as compounds which split off ammonia. 66. Process according to claims 57 and 65 , characterised in that the compounds which split off ammonia are ammonium-iron (ill) glycol ate, ammonium-iron (ill) oxalate, ammonium-iron (III) citrate, ammonium-iron (ill) tartrate, ammonium-iron- (ill) galactarate, ammonium-iron (ill) saccharate, ammonium-aluminium glycoliate , ammonium-aluminium oxalate, ammonium-aluminium citrate, ammonium-aluminium tartrate, ammonium-aluminium galactarate and ammonium-aluminium saccharate. 67. Process according to claims 57 to 66 , characterised in that the compounds which split off ammonia are introduced into the combustible material in such quantities that the smoke is adjusted to a pH of 5 to 8. 68. Process according to claims 39 to 67 , characterised in that 0.01 to 7$ by weight of an oxidizing agent, based on the total weight, is in addition introduced into the combustible material. 69. Process according to claim 68 , characterised in that the oxidizing agent is introduced in quantities of 1 to 5$ by weight, based on the total weight. ♦ 70. Process according to claims 68 and 69 , characterised in that the oxidizing agents used are ammonium nitrate, alkali metal nitrates or alkaline earth metal nitrates. 71 . Process according to claims 68 to 70 , characterised in that the oxidizing agents used are alkali metal permanganates . 72. Process according to claims 39 to 71 , characterised in that the smokable product contains in addition about 0.01 to 10$ by weight of ammonium salts of polygalacturonic acids and/or ammonium salts of carboxymethylcellulose. 73. Process according to claim 72 , characterised in that the polygalacturonic acids used are pectin, alginic acid or gum arable. 7½ . Process according to claims 39 to 73 , characterised in that the smokable product contains 0.01 to 5$ by weight of low sulphur proteins. 75. Process according to claim 7¾ , characterised in that the low sulphur proteins used are zein, hordeln or gliadin. 76. Process according to claims I and 75 , characterised in that alcoholic extracts of low sulphur proteins are used. 77 „ Process according to claims 39 to 76 , characterised in that about 0. 1 to $0% by weight of tobacco constituents, based on the total weight of smokable product, are introduced into the combustible material. 78. Process according to claims 39 to 76 , characterised in that the products according to the invention are produced in the form of paper-like webs with a surface weight of 10 to 250 g/m2 and a thickness of 10 to 120 p. 79. Use of smokable products according to claims 1 38, alone or as mixing components, in cigarette tobacco, cigar tobacco or pipe tobacco. 80. Use of smoking products according to claims 1 t as cigarette paper or cigar wrappers. For the Applicants PR. REINHQID COHN AND PART ERS Le A 14 086 - 57 -
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2157370A DE2157370A1 (en) | 1971-11-19 | 1971-11-19 | Smoking mixture - based on cellulose and metal chelate cpds |
| DE19722215412 DE2215412A1 (en) | 1972-03-29 | 1972-03-29 | Smoking mixture - based on cellulose and metal chelate cpds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL40860A0 IL40860A0 (en) | 1973-01-30 |
| IL40860A true IL40860A (en) | 1976-04-30 |
Family
ID=25762035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL40860A IL40860A (en) | 1971-11-19 | 1972-11-16 | Smokable products and their production |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US3924642A (en) |
| JP (1) | JPS5715874B2 (en) |
| AR (1) | AR195306A1 (en) |
| AT (1) | AT334266B (en) |
| BE (1) | BE791554A (en) |
| CA (1) | CA978819A (en) |
| CH (1) | CH569428A5 (en) |
| CS (1) | CS164938B2 (en) |
| DD (1) | DD105716A5 (en) |
| DK (1) | DK147252C (en) |
| EG (1) | EG11093A (en) |
| FI (1) | FI58254C (en) |
| FR (1) | FR2161705A5 (en) |
| GB (1) | GB1390777A (en) |
| HU (1) | HU168783B (en) |
| IE (1) | IE37185B1 (en) |
| IL (1) | IL40860A (en) |
| IN (1) | IN139200B (en) |
| IT (1) | IT1045265B (en) |
| LU (1) | LU66490A1 (en) |
| NL (1) | NL179967C (en) |
| NO (1) | NO131152C (en) |
| SE (1) | SE409166B (en) |
| SU (1) | SU516333A3 (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2729759C2 (en) * | 1977-07-01 | 1985-05-30 | Bayer Ag, 5090 Leverkusen | Smokable products |
| US4825884A (en) * | 1986-02-24 | 1989-05-02 | Brown & Williamson Tobacco Corporation | Process for forming flavor compounds in tobacco |
| IE873108L (en) * | 1986-12-12 | 1988-06-12 | Huels Chemische Werke Ag | Impact modifying agent for use with smoking articles |
| US4830028A (en) * | 1987-02-10 | 1989-05-16 | R. J. Reynolds Tobacco Company | Salts provided from nicotine and organic acid as cigarette additives |
| US4804002A (en) * | 1987-05-29 | 1989-02-14 | P. H. Glatfelter Company | Tobacco product containing side stream smoke flavorant |
| US4920990A (en) * | 1988-11-23 | 1990-05-01 | R. J. Reynolds Tobacco Company | Cigarette |
| US5031646A (en) * | 1990-01-16 | 1991-07-16 | R. J. Reynolds Tobacco Company | Cigarette |
| DE4334222C3 (en) * | 1993-10-07 | 2001-07-26 | Reemtsma H F & Ph | Stick-shaped smoking product |
| HRP940578B1 (en) * | 1993-10-07 | 1999-10-31 | Hans Noe | Rod-shaped smoking article |
| US5559263A (en) * | 1994-11-16 | 1996-09-24 | Tiorco, Inc. | Aluminum citrate preparations and methods |
| US7428905B2 (en) * | 2004-07-30 | 2008-09-30 | R.J. Reynolds Tobacco Company | Method of making smokeable tobacco substitute filler having an increased fill value |
| US7690387B2 (en) * | 2004-10-25 | 2010-04-06 | Philip Morris Usa Inc. | Synthesis and incorporation of high-temperature ammonia-release agents in lit-end cigarettes |
| BR112017014792A2 (en) | 2015-01-07 | 2018-01-09 | British American Tobacco Investments Ltd | smokable sheet material, method of preparing a smokable sheet, smoking article and use of a smokable sheet material |
| BR112017014790A2 (en) | 2015-01-07 | 2018-01-09 | British American Tobacco Investments Ltd | smokable material for inclusion in a smoking article, method of obtaining smokable material, smoking article and use of an acacia gum solution |
| CN105286078B (en) * | 2015-11-21 | 2017-05-10 | 安徽中烟再造烟叶科技有限责任公司 | Method for papermaking method reconstituted tobacco by replacing wood pulp fibers through cotton stalk bark fibers |
| US20180103680A1 (en) * | 2016-10-18 | 2018-04-19 | Altria Client Services Llc | Methods and systems for improving stability of the pre-vapor formulation of an e-vaping device |
| CN109567254B (en) * | 2018-12-20 | 2021-07-30 | 陕西科技大学 | A kind of tobacco sheet and preparation method thereof, substrate and preparation method of coating liquid |
| WO2024127456A1 (en) * | 2022-12-12 | 2024-06-20 | 日本たばこ産業株式会社 | Tobacco sheet, method for producing tobacco sheet, tobacco filler, and smoking article |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2108860A (en) * | 1934-11-12 | 1938-02-22 | Paul Bechtner | Method of and substance for treating tobacco smoke |
| US2171986A (en) * | 1937-08-13 | 1939-09-05 | Poetschke Paul | Paper and paper making |
| US3109436A (en) * | 1961-11-02 | 1963-11-05 | Bavley Abraham | Tobacco products |
| US3459195A (en) * | 1966-06-16 | 1969-08-05 | Philip Morris Inc | Reinforced reconstituted tobacco sheet |
| US3461879A (en) * | 1967-06-30 | 1969-08-19 | Celanese Corp | Oxidized cellulose tobacco substitute composition |
| US3572348A (en) * | 1968-08-01 | 1971-03-23 | Liggett & Myers Inc | Tobacco composition |
| US3529602A (en) * | 1969-02-27 | 1970-09-22 | Philip Morris Inc | Tobacco substitute sheet material |
| US3724469A (en) * | 1971-09-23 | 1973-04-03 | Eastman Kodak Co | Tobacco smoke filter |
-
0
- BE BE791554D patent/BE791554A/en not_active IP Right Cessation
-
1972
- 1972-10-23 CH CH1544572A patent/CH569428A5/xx not_active IP Right Cessation
- 1972-11-13 SU SU1845206A patent/SU516333A3/en active
- 1972-11-15 US US306655A patent/US3924642A/en not_active Expired - Lifetime
- 1972-11-16 IL IL40860A patent/IL40860A/en unknown
- 1972-11-16 FI FI3222/72A patent/FI58254C/en active
- 1972-11-16 NL NLAANVRAGE7215529,A patent/NL179967C/en not_active IP Right Cessation
- 1972-11-17 SE SE7214999A patent/SE409166B/en unknown
- 1972-11-17 CS CS7814A patent/CS164938B2/cs unknown
- 1972-11-17 DK DK576472A patent/DK147252C/en not_active IP Right Cessation
- 1972-11-17 NO NO4212/72A patent/NO131152C/no unknown
- 1972-11-17 LU LU66490A patent/LU66490A1/xx unknown
- 1972-11-17 IE IE1593/72A patent/IE37185B1/en unknown
- 1972-11-17 AT AT979472A patent/AT334266B/en not_active IP Right Cessation
- 1972-11-17 FR FR7240995A patent/FR2161705A5/fr not_active Expired
- 1972-11-17 CA CA156,795A patent/CA978819A/en not_active Expired
- 1972-11-17 IT IT31834/72A patent/IT1045265B/en active
- 1972-11-18 EG EG472/72A patent/EG11093A/en active
- 1972-11-18 HU HUHA945A patent/HU168783B/hu unknown
- 1972-11-18 IN IN1946/72A patent/IN139200B/en unknown
- 1972-11-20 AR AR245213A patent/AR195306A1/en active
- 1972-11-20 JP JP11572572A patent/JPS5715874B2/ja not_active Expired
- 1972-11-20 DD DD166953A patent/DD105716A5/xx unknown
- 1972-11-20 GB GB5350472A patent/GB1390777A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SU516333A3 (en) | 1976-05-30 |
| IN139200B (en) | 1976-05-22 |
| NL7215529A (en) | 1973-05-22 |
| CA978819A (en) | 1975-12-02 |
| CH569428A5 (en) | 1975-11-28 |
| IE37185L (en) | 1973-05-19 |
| CS164938B2 (en) | 1975-11-28 |
| USB306655I5 (en) | 1975-01-28 |
| BE791554A (en) | 1973-05-17 |
| IE37185B1 (en) | 1977-05-25 |
| DK147252C (en) | 1984-12-03 |
| FR2161705A5 (en) | 1973-07-06 |
| AT334266B (en) | 1976-01-10 |
| LU66490A1 (en) | 1973-02-01 |
| FI58254B (en) | 1980-09-30 |
| DK147252B (en) | 1984-05-28 |
| ATA979472A (en) | 1976-04-15 |
| HU168783B (en) | 1976-07-28 |
| IL40860A0 (en) | 1973-01-30 |
| DD105716A5 (en) | 1974-05-12 |
| EG11093A (en) | 1976-12-31 |
| US3924642A (en) | 1975-12-09 |
| IT1045265B (en) | 1980-05-10 |
| SE409166B (en) | 1979-08-06 |
| JPS4861696A (en) | 1973-08-29 |
| FI58254C (en) | 1981-01-12 |
| GB1390777A (en) | 1975-04-16 |
| JPS5715874B2 (en) | 1982-04-01 |
| NO131152B (en) | 1975-01-06 |
| NL179967C (en) | 1986-12-16 |
| AR195306A1 (en) | 1973-09-28 |
| NO131152C (en) | 1975-04-16 |
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