IL41094A - A process for the production of absorbents for use in extraction chromatography - Google Patents
A process for the production of absorbents for use in extraction chromatographyInfo
- Publication number
- IL41094A IL41094A IL41094A IL4109472A IL41094A IL 41094 A IL41094 A IL 41094A IL 41094 A IL41094 A IL 41094A IL 4109472 A IL4109472 A IL 4109472A IL 41094 A IL41094 A IL 41094A
- Authority
- IL
- Israel
- Prior art keywords
- extractant
- compound
- absorbent
- solution
- mixture
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 28
- 230000002745 absorbent Effects 0.000 title claims 10
- 239000002250 absorbent Substances 0.000 title claims 10
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 238000004587 chromatography analysis Methods 0.000 title 1
- 238000000605 extraction Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 13
- 229920000642 polymer Polymers 0.000 claims abstract 5
- 229920002554 vinyl polymer Polymers 0.000 claims abstract 3
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 6
- ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical group CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 claims 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical group 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 claims 1
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical group CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims 1
- XQRLCLUYWUNEEH-UHFFFAOYSA-L diphosphonate(2-) Chemical group [O-]P(=O)OP([O-])=O XQRLCLUYWUNEEH-UHFFFAOYSA-L 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 125000000468 ketone group Chemical group 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical group [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims 1
- 150000003004 phosphinoxides Chemical group 0.000 claims 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical group [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
- -1 phosphorous acid ester Chemical class 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- 150000003512 tertiary amines Chemical class 0.000 claims 1
- 150000003568 thioethers Chemical group 0.000 claims 1
- ZMBHCYHQLYEYDV-UHFFFAOYSA-N trioctylphosphine oxide Chemical group CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC ZMBHCYHQLYEYDV-UHFFFAOYSA-N 0.000 claims 1
- 229910002007 uranyl nitrate Inorganic materials 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/016—Modification or after-treatment of ion-exchangers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2357/00—Characterised by the use of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
1407257 Extracting uranyl nitrate BAYER AG 18 Dec 1972 [18 Dec 1971] 58277/72 Heading CIA [Also in Division C3] Salts such as uranyl nitrate may be extracted from aqueous solutions containing them, by passing the solution through a column which contains a porous polymer containing pores of molecular dimensions, and which is a polymer of a polyvinyl compound and optionally a monovinyl or monovinylidene compound, which polymer also contains an extractant which is an organic solvent. In the exemplification the polymer is a styrene-divinylbenzene copolymer and the extractant is tri-n-butyl phosphate.
[GB1407257A]
Claims (33)
1. A process for the production of an absorbent based on a synthetic resin, wherein an extractant, a mixture of extractants or a solution of an extractant in a solution promoter is added to a mixture to be polymerised comprising a digovinyl compound and optionally a monomeric monovinyl compound, the extractant, the mixture of extractants or the solution of the extractant in a solution promoter being a solvent for the monomeric monovinyl or oLigovinyl compound but not for the polymer; and wherein polymerisation is carried out in the presence of the extractant, the mixture of extractants or the solution of the extractant in a solution promoter.
2. A process as claimed In claim 1, wherein the extractant, the mixture of extractants or the solution of an extractant in a solution promoter is used in a quantity of from 10 to 90$ by weight, based on the total quantity of absorbent,
3. A process as claimed in claim 1 or 2, wherein the polyvinyl compound is used in a quantity of from 5 to 70$ by weight, based on the total! quantity of absorbent .
4. · A process as claimed in claim 1 or 2, wherein the monoviny compound is gyrene and the polyvinyl compound is divinyl benzene.
5. A process as claimed in any of claims 1 to 4 , wherein the extractant is an ester.
6. A process as claimed in claim 5, wherein the ester is a phosphorous acid ester.
7. · A prooess as claimed in any of claims 1 to 4, wherein the extractant is a primary, secondary or tertiary amine.
8. A process as claimed in any of claims 1 to 4 wherein the ex rac ant is a sulphide.
9. A process as olaimed in any of claims 1 to 4 wherein the extractant is a sulphoxide.
10. A process as olaimed in any of claims 1 to 4 wherein the extractant is a phosphinoxide.
11. A process as claimed in any of claims 1 to 4 wherein the extractant is a phosphonate.
12. A process as claimed in any of claims 1 to 4 wherein the extractant is a diphosphonate .
13. A process as claimed in any of claims 1 ;to 4 wherein the extractant is a phosphinate.
14. A process as claimed in any of claims 1 to 4 wherein the extractant is a sulphonium saltί ·
15. A process as claimed in any of claims 1 to 4 wherein the extractant is a ketone.
16. A process as claimed in any of claims 1 to 4 wherein the extractant is an ether.
17. A process as claimed in any of claims 1 to 4 wherein the extractant is a carboxylic acid.
18. A process as claimed in claim 6, wherein the extractant is tri-n-butylphosphate .
19. * A process as claimed in claim 6, wherein the extractant is a tri-hexylphosphonate.
20. A process as claimed in claim 10, wherein the extractant is trioctyl phosphinoxide.
21. A process as claimed in claim 6, wherein the extractant is phosphoric acid-bis-(2-ethylhexyl)-ester.
22. A process as claimed in claim 9, wherein the extractant is diootyl sulphoxide.
23. A process as claimed in claim' 14, therein the extractant is trldeoyl sulphoulum chloride.
24. .24. A process aa claimed in any of claims 1 to 23, wherein the extractant» the mixture of extraotants or the solution of an- extractant in a solution promoter is used in a quantity of from 40 to 75# by weight, based on the total quantity of monomer.
25. · A process as claimed in any of claims 1 to 24» wherein polymerisation is carried out in the presence of a polymerisation catalyet.
26. A process as claimed in any of claims 1 to .25, wherein polymerisation is carried out at a temperature in the range of 30°C to 150°C.
27. A process as claimed in claim 1 substantially as herein described with reference to any of the,specific Examples.
28. An absorbent when prepared by a process claimed ixc any of claims 1 to 27*
29. * An absorbent as claimed in claim 28, wherein styrene
30. An absorbent as olaimed in claim 28, wherein styrene is used as the monovinyl compound, dirinyl benzene as the 'cfligoyinyl eompound and phosphoric acid-bia-(2-ethylhexyl)- ether as the extractant.
31. An absorbent as claimed in claim 28, wherein styrene is used as monovinyl compound, dlrinyl benzene as the pligorinyl compound and dloctyl sulphoxide as the extractant.
32. An absorbent as claimed in claim 28, wherein styrene is used as the monovinyl compound, dlrinyl benzene as the oligorinyl compound and trioctylphosphinaxide as the extractant
33. An absorbent as claimed in claim 28, substantially as herein described with reference to either of the accompanying drawings. Le A H 052
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2162951A DE2162951C2 (en) | 1971-12-18 | 1971-12-18 | Crosslinked copolymers and use of crosslinked copolymers containing extraction agents as adsorbents for extraction chromatographic separation processes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL41094A0 IL41094A0 (en) | 1973-02-28 |
| IL41094A true IL41094A (en) | 1976-02-29 |
Family
ID=5828438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL41094A IL41094A (en) | 1971-12-18 | 1972-12-15 | A process for the production of absorbents for use in extraction chromatography |
Country Status (22)
| Country | Link |
|---|---|
| JP (1) | JPS5648828B2 (en) |
| AR (1) | AR193157A1 (en) |
| AT (1) | AT334868B (en) |
| BE (1) | BE792928A (en) |
| BR (1) | BR7208859D0 (en) |
| CA (1) | CA1014689A (en) |
| CH (1) | CH597307A5 (en) |
| CS (1) | CS171740B2 (en) |
| DD (1) | DD102391A5 (en) |
| DE (1) | DE2162951C2 (en) |
| ES (1) | ES409725A1 (en) |
| FR (1) | FR2163763B1 (en) |
| GB (1) | GB1407257A (en) |
| IL (1) | IL41094A (en) |
| IT (1) | IT974064B (en) |
| NL (1) | NL156710B (en) |
| OA (1) | OA04296A (en) |
| PL (1) | PL79180B1 (en) |
| RO (1) | RO63158A (en) |
| SE (1) | SE396016B (en) |
| SU (1) | SU520052A3 (en) |
| ZA (1) | ZA728893B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1980002687A1 (en) * | 1979-06-08 | 1980-12-11 | Ici Australia Ltd | Process for composite polymer beads |
| US4447475A (en) * | 1980-12-03 | 1984-05-08 | Ici Australia Limited | Process for composite polymer beads |
| EP0073750B1 (en) * | 1981-02-27 | 1989-07-05 | Monocure Pty. Limited | Aqueous polymerizable compositions |
| HU203252B (en) * | 1986-01-16 | 1991-06-28 | Nitrokemia Ipartelepek | Process for producing ion-exchange resins with grain size mainly less than ten microns for analytical and preparative purposes |
| JPH01142462A (en) * | 1987-11-30 | 1989-06-05 | Japan Atom Energy Res Inst | Manufacture of extracted chromatography material |
| NL9400013A (en) * | 1994-01-06 | 1995-08-01 | Akzo Nobel Nv | Material for extracting metal ions from an aqueous solution. |
| NL9400012A (en) * | 1994-01-06 | 1995-08-01 | Akzo Nobel Nv | Material for removing gaseous impurities from a gas mixture. |
| US6355094B1 (en) | 1994-01-06 | 2002-03-12 | Akzo Nobel N.V. | Material for the removal of gaseous impurities from a gas mixture |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1483946A (en) * | 1966-04-28 | 1967-06-09 | Dia Prosim | Process for preparing macroporous resins, and applications thereof for obtaining ion exchangers |
| US3547684A (en) * | 1968-08-08 | 1970-12-15 | Dow Chemical Co | Process for making organic polymer filled gas chromatographic columns |
-
0
- BE BE792928D patent/BE792928A/en unknown
-
1971
- 1971-12-18 DE DE2162951A patent/DE2162951C2/en not_active Expired
-
1972
- 1972-12-14 CS CS8602A patent/CS171740B2/cs unknown
- 1972-12-14 IT IT54703/72A patent/IT974064B/en active
- 1972-12-15 RO RO7200073165A patent/RO63158A/en unknown
- 1972-12-15 ZA ZA728893A patent/ZA728893B/en unknown
- 1972-12-15 IL IL41094A patent/IL41094A/en unknown
- 1972-12-15 AT AT1070672A patent/AT334868B/en not_active IP Right Cessation
- 1972-12-15 SU SU1862289A patent/SU520052A3/en active
- 1972-12-15 NL NL7217118.A patent/NL156710B/en not_active IP Right Cessation
- 1972-12-15 DD DD167581A patent/DD102391A5/xx unknown
- 1972-12-15 SE SE7216473A patent/SE396016B/en unknown
- 1972-12-15 CA CA158,931A patent/CA1014689A/en not_active Expired
- 1972-12-15 BR BR8859/72A patent/BR7208859D0/en unknown
- 1972-12-16 JP JP12583472A patent/JPS5648828B2/ja not_active Expired
- 1972-12-16 PL PL1972159572A patent/PL79180B1/pl unknown
- 1972-12-16 ES ES409725A patent/ES409725A1/en not_active Expired
- 1972-12-18 AR AR245705A patent/AR193157A1/en active
- 1972-12-18 CH CH1839072A patent/CH597307A5/xx not_active IP Right Cessation
- 1972-12-18 FR FR7245101A patent/FR2163763B1/fr not_active Expired
- 1972-12-18 GB GB5827772A patent/GB1407257A/en not_active Expired
- 1972-12-18 OA OA54785A patent/OA04296A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA728893B (en) | 1973-09-26 |
| CS171740B2 (en) | 1976-10-29 |
| FR2163763B1 (en) | 1978-03-10 |
| AR193157A1 (en) | 1973-03-30 |
| DE2162951C2 (en) | 1982-07-01 |
| IL41094A0 (en) | 1973-02-28 |
| ES409725A1 (en) | 1975-11-16 |
| ATA1070672A (en) | 1976-06-15 |
| PL79180B1 (en) | 1975-06-30 |
| NL156710B (en) | 1978-05-16 |
| FR2163763A1 (en) | 1973-07-27 |
| BR7208859D0 (en) | 1973-09-20 |
| CA1014689A (en) | 1977-07-26 |
| DE2162951A1 (en) | 1973-06-20 |
| JPS5648828B2 (en) | 1981-11-18 |
| RO63158A (en) | 1978-06-15 |
| SU520052A3 (en) | 1976-06-30 |
| CH597307A5 (en) | 1978-03-31 |
| NL7217118A (en) | 1973-06-20 |
| IT974064B (en) | 1974-06-20 |
| BE792928A (en) | 1973-06-18 |
| SE396016B (en) | 1977-09-05 |
| GB1407257A (en) | 1975-09-24 |
| JPS4870594A (en) | 1973-09-25 |
| OA04296A (en) | 1979-12-31 |
| AT334868B (en) | 1977-02-10 |
| DD102391A5 (en) | 1973-12-12 |
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