IL43760A - Polymers based on esters of acrylic and methacrylic acid, their production and use as a means at night - Google Patents

Polymers based on esters of acrylic and methacrylic acid, their production and use as a means at night

Info

Publication number: IL43760A
Authority: IL; Israel
Prior art keywords: polymer; component; polymer according; units; weight
Prior art date: 1972-12-06

Application number

IL43760A

Other languages

English (en)

Hebrew (he)

Other versions

IL43760A0 (en

Original Assignee

Rohm & Haas

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1972-12-06

Filing date

1973-12-05

Publication date

1977-07-31

1973-12-05 Application filed by Rohm & Haas filed Critical Rohm & Haas

1974-03-14 Publication of IL43760A0 publication Critical patent/IL43760A0/xx

1977-07-31 Publication of IL43760A publication Critical patent/IL43760A/en

Links

229920000642 polymer Polymers 0.000 title claims description 74
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims description 19
239000002562 thickening agent Substances 0.000 title claims description 9
238000004519 manufacturing process Methods 0.000 title 1
125000005397 methacrylic acid ester group Chemical group 0.000 title 1
239000000203 mixture Substances 0.000 claims description 40
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 22
238000000034 method Methods 0.000 claims description 19
150000002148 esters Chemical class 0.000 claims description 18
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 16
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 14
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 9
-1 alkyl methacrylates Chemical class 0.000 claims description 9
229940063559 methacrylic acid Drugs 0.000 claims description 9
230000008719 thickening Effects 0.000 claims description 9
QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 claims description 8
229940063557 methacrylate Drugs 0.000 claims description 6
125000005250 alkyl acrylate group Chemical group 0.000 claims description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
229920001577 copolymer Polymers 0.000 claims description 4
150000001875 compounds Chemical class 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 claims description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
150000001735 carboxylic acids Chemical class 0.000 claims description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
125000005336 allyloxy group Chemical group 0.000 claims 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 39
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 29
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 21
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 18
239000000243 solution Substances 0.000 description 17
229910052757 nitrogen Inorganic materials 0.000 description 14
239000007787 solid Substances 0.000 description 14
239000000047 product Substances 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
239000000178 monomer Substances 0.000 description 12
239000002253 acid Substances 0.000 description 11
238000010992 reflux Methods 0.000 description 11
238000006116 polymerization reaction Methods 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 8
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 7
ZCYIYBNDJKVCBR-UHFFFAOYSA-N 2-prop-2-enoxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCC=C ZCYIYBNDJKVCBR-UHFFFAOYSA-N 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
235000011118 potassium hydroxide Nutrition 0.000 description 7
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
239000003921 oil Substances 0.000 description 5
LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 4
238000010526 radical polymerization reaction Methods 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
150000001252 acrylic acid derivatives Chemical class 0.000 description 3
229910000147 aluminium phosphate Inorganic materials 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
238000010533 azeotropic distillation Methods 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000011734 sodium Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
GCYHRYNSUGLLMA-UHFFFAOYSA-N 2-prop-2-enoxyethanol Chemical compound OCCOCC=C GCYHRYNSUGLLMA-UHFFFAOYSA-N 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
235000011114 ammonium hydroxide Nutrition 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
238000001914 filtration Methods 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
239000003999 initiator Substances 0.000 description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
238000011085 pressure filtration Methods 0.000 description 2
150000003839 salts Chemical group 0.000 description 2
229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 description 1
WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
XISLPKAOFISSGR-UHFFFAOYSA-N benzoyl benzenecarboperoxoate;octanoyl octaneperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1.CCCCCCCC(=O)OOC(=O)CCCCCCC XISLPKAOFISSGR-UHFFFAOYSA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
229940018557 citraconic acid Drugs 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
MRIZMKJLUDDMHF-UHFFFAOYSA-N cumene;hydrogen peroxide Chemical class OO.CC(C)C1=CC=CC=C1 MRIZMKJLUDDMHF-UHFFFAOYSA-N 0.000 description 1
239000003599 detergent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
238000012674 dispersion polymerization Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000005553 drilling Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
239000011953 free-radical catalyst Substances 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
150000007529 inorganic bases Chemical class 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
FEZFGASTIQVZSC-UHFFFAOYSA-N nonanoyl nonaneperoxoate Chemical compound CCCCCCCCC(=O)OOC(=O)CCCCCCCC FEZFGASTIQVZSC-UHFFFAOYSA-N 0.000 description 1
239000002674 ointment Substances 0.000 description 1
238000006384 oligomerization reaction Methods 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000006072 paste Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229960005235 piperonyl butoxide Drugs 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000003822 preparative gas chromatography Methods 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000002453 shampoo Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
239000000606 toothpaste Substances 0.000 description 1
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
229960004418 trolamine Drugs 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/40—Esters of unsaturated alcohols, e.g. allyl (meth)acrylate
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/14—Clay-containing compositions
- C09K8/18—Clay-containing compositions characterised by the organic compounds
- C09K8/22—Synthetic organic compounds
- C09K8/24—Polymers
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/932—Thickener or dispersant for aqueous system

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Organic Chemistry (AREA)
Veterinary Medicine (AREA)
Animal Behavior & Ethology (AREA)
Engineering & Computer Science (AREA)
Public Health (AREA)
General Health & Medical Sciences (AREA)
Materials Engineering (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Chemical Kinetics & Catalysis (AREA)
General Life Sciences & Earth Sciences (AREA)
Oral & Maxillofacial Surgery (AREA)
Dispersion Chemistry (AREA)
Wood Science & Technology (AREA)
Birds (AREA)
Epidemiology (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Macromonomer-Based Addition Polymer (AREA)
Cosmetics (AREA)

IL43760A 1972-12-06 1973-12-05 Polymers based on esters of acrylic and methacrylic acid, their production and use as a means at night IL43760A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/312,433 US4085167A (en)	1972-12-06	1972-12-06	Carboxylic polymeric thickeners

Publications (2)

Publication Number	Publication Date
IL43760A0 IL43760A0 (en)	1974-03-14
IL43760A true IL43760A (en)	1977-07-31

Family

ID=23211414

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL43760A IL43760A (en)	1972-12-06	1973-12-05	Polymers based on esters of acrylic and methacrylic acid, their production and use as a means at night

Country Status (18)

Country	Link
US (1)	US4085167A (fr)
JP (1)	JPS4999188A (fr)
KR (1)	KR790000286B1 (fr)
AR (1)	AR200665A1 (fr)
AU (1)	AU476006B2 (fr)
BE (1)	BE808255A (fr)
BR (1)	BR7309527D0 (fr)
CA (1)	CA1006299A (fr)
DE (1)	DE2357615A1 (fr)
ES (1)	ES421135A1 (fr)
FR (1)	FR2209788B1 (fr)
GB (1)	GB1447556A (fr)
IL (1)	IL43760A (fr)
IT (1)	IT1003271B (fr)
NL (1)	NL7316672A (fr)
SE (1)	SE403619B (fr)
TR (1)	TR17712A (fr)
ZA (1)	ZA738651B (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4336345A (en) *	1971-04-23	1982-06-22	Rohm And Haas Company	Composition comprising condensation cross-linkable novel methacrylate polymers
JPS5759553Y2 (fr) *	1977-08-22	1982-12-20
US4268641A (en) *	1979-04-24	1981-05-19	Union Carbide Corporation	Acrylic acid-acrylate copolymer thickening agents
US4509949A (en) *	1983-06-13	1985-04-09	The B. F. Goodrich Company	Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters
CS249989B1 (en) *	1984-04-06	1987-04-16	Otto Wichterle	Hydrophilic thre-dimensional polymer and method of its production
FR2581651B1 (fr) *	1985-05-13	1988-02-26	Rhone Poulenc Spec Chim	Dispersants pour fluides de forage et fluides de forage les contenant
US5053448A (en) *	1989-07-21	1991-10-01	S. C. Johnson & Son, Inc.	Polymeric thickener and methods of producing the same
US5292828A (en) *	1992-05-29	1994-03-08	Union Carbide Chemicals & Plastics Technology Corporation	Polymers containing complex hydrophobic groups
WO1993024545A1 (fr) *	1992-05-29	1993-12-09	Union Carbide Chemicals & Plastics Technology Corporation	Latex aqueux renfermant des macromonomeres
US5739378A (en) *	1992-05-29	1998-04-14	Union Carbide Chemicals & Plastics Technology Corporation	Complex hydrophobe-containing oligomers
US5461100A (en) *	1992-05-29	1995-10-24	Union Carbide Chemicals & Plastics Technology Corporation	Aircraft anti-icing fluids
US5426182A (en) *	1992-05-29	1995-06-20	Union Carbide Chemical & Plastics Technology Corporation	Polysaccharides containing complex hydrophobic groups
US5292843A (en) *	1992-05-29	1994-03-08	Union Carbide Chemicals & Plastics Technology Corporation	Polymers containing macromonomers
US5488180A (en) *	1992-05-29	1996-01-30	Union Carbide Chemicals & Plastics Technology Corporation	Complex hydrophobe compounds
US5399618A (en) *	1993-06-28	1995-03-21	Union Carbide Chemical & Plastics Technology Corporation	Processes for preparing aqueous polymer emulsions
US5708068A (en) *	1995-01-16	1998-01-13	Union Carbide Chemicals & Plastics Technology Corporation	Aircraft deicing/anti-icing fluids thickened by associative polymers
WO2000040628A1 (fr) *	1998-12-30	2000-07-13	The B.F. Goodrich Company	Copolymeres ramifies/sequences permettant de traiter des substrats keratiniques
US7456750B2 (en) *	2000-04-19	2008-11-25	Federal Express Corporation	Fire suppression and indicator system and fire detection device
US6410005B1 (en)	2000-06-15	2002-06-25	Pmd Holdings Corp.	Branched/block copolymers for treatment of keratinous substrates
FR2832719B1 (fr) *	2001-11-29	2004-02-13	Oreal	Copolymeres ethyleniques sequences adhesifs, compositions cosmetiques les contenant, et utilisation de ces copolymeres en cosmetique
US7810577B2 (en) *	2005-08-30	2010-10-12	Federal Express Corporation	Fire sensor, fire detection system, fire suppression system, and combinations thereof
CA2899556C (fr) *	2006-03-22	2018-02-06	Federal Express Corporation	Dispositif et procede d'extinction d'incendie avec agent expansif
JP2020180260A (ja) *	2019-04-26	2020-11-05	株式会社大阪ソーダ	アクリル酸エステル系化合物からなる架橋剤、当該架橋剤を含有する吸水性樹脂用組成物、及び吸水性樹脂

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL194077A (fr) *	1954-01-18
BE535125A (fr) *	1954-01-25
DE1070381B (de) *	1957-03-15	1959-12-03	Rohm & LIaas Company, Philadelphia, Pa. (V. St. A.)	Verfahren zur Herstellung von Ionenaustauscherharzen auf Basis der Acrylsäuren und Methacrylsäuren
NL108604C (fr) *	1957-08-27
US3180844A (en) *	1960-11-09	1965-04-27	Dow Chemical Co	Salts of monocarboxylic acid copolymers as thickeners for non-polar solvents
US3501445A (en) *	1968-02-28	1970-03-17	Celanese Corp	Polyacrylate thickeners and copolymers used to produce same
US3708445A (en) *	1970-04-20	1973-01-02	Gen Latex And Chem Corp	Polymeric thickeners and method of preparing and using the same

1972
- 1972-12-06 US US05/312,433 patent/US4085167A/en not_active Expired - Lifetime
1973
- 1973-10-31 JP JP48122661A patent/JPS4999188A/ja active Pending
- 1973-11-08 KR KR7301852A patent/KR790000286B1/ko not_active Expired
- 1973-11-12 ZA ZA00738651A patent/ZA738651B/xx unknown
- 1973-11-19 DE DE2357615A patent/DE2357615A1/de active Pending
- 1973-11-20 AU AU62710/73A patent/AU476006B2/en not_active Expired
- 1973-11-21 TR TR17712A patent/TR17712A/xx unknown
- 1973-11-27 CA CA186,813A patent/CA1006299A/en not_active Expired
- 1973-11-27 AR AR251185A patent/AR200665A1/es active
- 1973-12-03 SE SE7316309A patent/SE403619B/xx unknown
- 1973-12-04 ES ES421135A patent/ES421135A1/es not_active Expired
- 1973-12-05 NL NL7316672A patent/NL7316672A/xx not_active Application Discontinuation
- 1973-12-05 BR BR9527/73A patent/BR7309527D0/pt unknown
- 1973-12-05 IL IL43760A patent/IL43760A/en unknown
- 1973-12-05 FR FR7343376A patent/FR2209788B1/fr not_active Expired
- 1973-12-05 BE BE138546A patent/BE808255A/fr unknown
- 1973-12-06 GB GB5666773A patent/GB1447556A/en not_active Expired
- 1973-12-27 IT IT32250/73A patent/IT1003271B/it active

Also Published As

Publication number	Publication date
US4085167A (en)	1978-04-18
IT1003271B (it)	1976-06-10
IL43760A0 (en)	1974-03-14
AU476006B2 (en)	1976-09-09
FR2209788A1 (fr)	1974-07-05
TR17712A (tr)	1975-07-23
AR200665A1 (es)	1974-11-29
KR790000286B1 (en)	1979-04-16
BE808255A (fr)	1974-06-05
ES421135A1 (es)	1976-10-16
JPS4999188A (fr)	1974-09-19
DE2357615A1 (de)	1974-06-12
SE403619B (sv)	1978-08-28
AU6271073A (en)	1975-05-22
ZA738651B (en)	1975-04-30
NL7316672A (fr)	1974-06-10
CA1006299A (en)	1977-03-01
GB1447556A (en)	1976-08-25
FR2209788B1 (fr)	1978-10-20
BR7309527D0 (pt)	1974-09-05

Publication	Publication Date	Title
US4167502A (en)	1979-09-11	Carboxylic polymeric thickeners
US4085167A (en)	1978-04-18	Carboxylic polymeric thickeners
CA1329678C (fr)	1994-05-17	Preparation de copolymeres reticulises pulverulents finement divises
AU676841B2 (en)	1997-03-27	Easy to disperse polycarboxylic acid thickeners
EP0510002B1 (fr)	1996-04-24	Suspensions de polymeres reticules ou non reticules d'anhydride de l'acide maleique-ether vinyle alkyle
EP0123108A1 (fr)	1984-10-31	Copolymère d'acide maléique, sa préparation et agent empêchant le tartrage le contenant
US6143817A (en)	2000-11-07	Use of derivatives of polyamino acids as emulsifiers stabilizers in aqueous free radical emulsion polymerization
US6566549B1 (en)	2003-05-20	Continuous polymerization process and products therefrom
CN107108809B (zh)	2021-03-09	制备甲基丙烯酸烷基酯和马来酸酐的共聚物的方法
KR100298515B1 (ko)	2001-10-22	카복실그룹을함유한가교중합체의제조방법
JPH0136486B2 (fr)	1989-08-01
CN111032776A (zh)	2020-04-17	含羧基聚合物组合物及其制造方法
CN121378562A (zh)	2026-01-23	一种基于中间转化法制备烯丙醇共聚物的方法、烯丙醇共聚物及其应用
JPS6225165B2 (fr)	1987-06-02
US4772674A (en)	1988-09-20	Solventless process for producing dialkyl fumarate-vinyl acetate copolymers
JPS6228804B2 (fr)	1987-06-23
EP0436960B1 (fr)	1993-09-08	Composition cosmetique ou pharmaceutique comprenant copolymères carboxyliques réticulés utiles comme épaississeurs
CN1204345A (zh)	1999-01-06	羧酸和多烯不饱和羧酸衍生物的共聚物及其作为增稠剂或分散剂的使用
EP0838498A1 (fr)	1998-04-29	Composition de polymere carboxylee
EP0343490A2 (fr)	1989-11-29	Procédé de préparation de polymères réticulés contenant des groupes carboxyliques
JP3658032B2 (ja)	2005-06-08	ポリアクリル酸ソーダの製造方法
CA2379418A1 (fr)	2001-01-18	Processus de production d'une resine de dispersion aqueuse
JP6815418B2 (ja)	2021-01-20	グラフトコポリマーおよびその組成物
JP3970597B2 (ja)	2007-09-05	無機顔料用分散剤及び紙塗工顔料分散液
JP2801141B2 (ja)	1998-09-21	吸水性樹脂の製造方法