IL45564A - Process for chlorinating ethylene polymers - Google Patents

Process for chlorinating ethylene polymers

Info

Publication number: IL45564A
Authority: IL; Israel
Prior art keywords: chlorination; process according; ethylene; weight; polymer
Prior art date: 1973-08-28

Application number

IL45564A

Other languages

English (en)

Other versions

IL45564A0 (en

Original Assignee

Stamicarbon

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-08-28

Filing date

1974-08-28

Publication date

1977-06-30

1974-08-28 Application filed by Stamicarbon filed Critical Stamicarbon

1974-11-29 Publication of IL45564A0 publication Critical patent/IL45564A0/xx

1977-06-30 Publication of IL45564A publication Critical patent/IL45564A/en

Links

238000000034 method Methods 0.000 title claims description 55
229920000573 polyethylene Polymers 0.000 title claims description 53
230000008569 process Effects 0.000 title claims description 46
238000005660 chlorination reaction Methods 0.000 claims description 120
239000000725 suspension Substances 0.000 claims description 45
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 32
239000000460 chlorine Substances 0.000 claims description 32
229910052801 chlorine Inorganic materials 0.000 claims description 32
229920000642 polymer Polymers 0.000 claims description 25
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 23
239000005977 Ethylene Substances 0.000 claims description 23
230000008018 melting Effects 0.000 claims description 13
238000002844 melting Methods 0.000 claims description 13
239000003999 initiator Substances 0.000 claims description 10
238000009835 boiling Methods 0.000 claims description 8
238000000354 decomposition reaction Methods 0.000 claims description 4
239000003792 electrolyte Substances 0.000 claims description 4
238000001035 drying Methods 0.000 claims description 2
230000005855 radiation Effects 0.000 claims description 2
238000009736 wetting Methods 0.000 claims 2
239000002253 acid Substances 0.000 claims 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
239000000203 mixture Substances 0.000 claims 1
150000003839 salts Chemical class 0.000 claims 1
-1 polyethylenes Polymers 0.000 description 43
239000004698 Polyethylene Substances 0.000 description 40
239000002245 particle Substances 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000000047 product Substances 0.000 description 6
239000004709 Chlorinated polyethylene Substances 0.000 description 5
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000002845 discoloration Methods 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
125000001183 hydrocarbyl group Chemical group 0.000 description 3
229910000041 hydrogen chloride Inorganic materials 0.000 description 3
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
229920001684 low density polyethylene Polymers 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000002904 solvent Substances 0.000 description 3
SURLGNKAQXKNSP-DBLYXWCISA-N chlorin Chemical compound C\1=C/2\N/C(=C\C3=N/C(=C\C=4NC(/C=C\5/C=CC/1=N/5)=CC=4)/C=C3)/CC\2 SURLGNKAQXKNSP-DBLYXWCISA-N 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
230000004927 fusion Effects 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000004702 low-density polyethylene Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000036632 reaction speed Effects 0.000 description 2
238000010992 reflux Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000080 wetting agent Substances 0.000 description 2
NFPBWZOKGZKYRE-UHFFFAOYSA-N 2-propan-2-ylperoxypropane Chemical group CC(C)OOC(C)C NFPBWZOKGZKYRE-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
101100366940 Mus musculus Stom gene Proteins 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
230000008901 benefit Effects 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
238000007664 blowing Methods 0.000 description 1
235000015115 caffè latte Nutrition 0.000 description 1
BBBFJLBPOGFECG-VJVYQDLKSA-N calcitonin Chemical compound N([C@H](C(=O)N[C@@H](CC(C)C)C(=O)NCC(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CO)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CC=1NC=NC=1)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](CC=1C=CC(O)=CC=1)C(=O)N1[C@@H](CCC1)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H]([C@@H](C)O)C(=O)NCC(=O)N[C@@H](CO)C(=O)NCC(=O)N[C@@H]([C@@H](C)O)C(=O)N1[C@@H](CCC1)C(N)=O)C(C)C)C(=O)[C@@H]1CSSC[C@H](N)C(=O)N[C@@H](CO)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CO)C(=O)N[C@@H]([C@@H](C)O)C(=O)N1 BBBFJLBPOGFECG-VJVYQDLKSA-N 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003518 caustics Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000007789 gas Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
238000000227 grinding Methods 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
230000026030 halogenation Effects 0.000 description 1
238000005658 halogenation reaction Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
230000001788 irregular Effects 0.000 description 1
LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical group N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
238000010951 particle size reduction Methods 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000004978 peroxycarbonates Chemical class 0.000 description 1
HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

IL45564A 1973-08-28 1974-08-28 Process for chlorinating ethylene polymers IL45564A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
NL7311780.A NL159678B (nl)	1973-08-28	1973-08-28	Werkwijze voor het chloreren van etheenpolymeren.

Publications (2)

Publication Number	Publication Date
IL45564A0 IL45564A0 (en)	1974-11-29
IL45564A true IL45564A (en)	1977-06-30

Family

ID=19819471

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL45564A IL45564A (en)	1973-08-28	1974-08-28	Process for chlorinating ethylene polymers

Country Status (17)

Country	Link
US (1)	US3935181A (da)
JP (1)	JPS5228476B2 (da)
AT (1)	AT333029B (da)
BE (1)	BE819263A (da)
CA (1)	CA1026047A (da)
DE (1)	DE2441197A1 (da)
DK (1)	DK143232C (da)
ES (1)	ES429593A1 (da)
FR (1)	FR2257610B1 (da)
GB (1)	GB1462835A (da)
IL (1)	IL45564A (da)
IN (1)	IN142397B (da)
IT (1)	IT1019138B (da)
NL (1)	NL159678B (da)
NO (1)	NO143749C (da)
SE (1)	SE419448B (da)
SU (1)	SU791250A3 (da)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
USRE29350E (en) *	1973-08-28	1977-08-09	Stamicarbon, B.V.	Process for chlorinating ethylene polymers
US4377459A (en) *	1980-08-14	1983-03-22	The B. F. Goodrich Company	Process for chlorination of poly(vinyl chloride) with liquid chlorine, and chlorinated poly(vinyl chloride) composition
DE3105404A1 (de) *	1981-02-14	1982-09-02	Hoechst Ag, 6000 Frankfurt	Verfahren zur herstellung eines feinkoernigen nichtagglomerierenden chlorpolyethylens
JPS5842779A (ja) *	1981-09-09	1983-03-12	Toyo Soda Mfg Co Ltd	塩素化ポリビニル芳香族化合物の製造方法
US4405760A (en) *	1981-12-28	1983-09-20	E. I. Du Pont De Nemours & Company	Chlorination and crosslinking of selected polymers with Cl2 O or HOCl
JPS61209204A (ja) *	1985-03-13	1986-09-17	Nippon Oil Co Ltd	塩素化された直鎖状超低密度ポリエチレンの製造方法
CH663958A5 (de)	1985-03-14	1988-01-29	Dow Chemical Europ	Verfahren zum beschichten von kunststoffgegenstaenden.
JPH0696609B2 (ja) *	1985-05-08	1994-11-30	鐘淵化学工業株式会社	改良されたポリオレフイン系樹脂粒子及びその製造方法
CN1016429B (zh) *	1986-11-18	1992-04-29	昭和电工株式会社	氯化乙烯-丙烯类共聚物的生产方法
JP2725483B2 (ja) *	1991-07-08	1998-03-11	ダイソー株式会社	塩素化ポリオレフィンの製造法
DE4203439B4 (de) *	1992-02-06	2006-04-13	Showa Denko K.K.	Verfahren zur Herstellung von chlorierten Polyolefinen
DE4237148A1 (de) *	1992-11-04	1994-05-05	Bitterfeld Wolfen Chemie	Verfahren zur Herstellung von pulverförmigen chlorierten Polymeren durch Lösungschlorierung
CN102260361B (zh) *	2011-06-03	2013-05-22	杭州新元化工技术开发有限公司	一种氯化聚乙烯的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3454544A (en) *	1963-05-06	1969-07-08	Dow Chemical Co	Process for the chlorination of polyolefins
US3563974A (en) *	1964-03-24	1971-02-16	Dow Chemical Co	Linear polyethylene chlorination
US3467640A (en) *	1965-02-15	1969-09-16	Hoechst Ag	Process for the manufacture of chlorinated polyolefins
GB1299710A (en) *	1970-11-03	1972-12-13	Osaka Soda Co Ltd	Process for the preparation of chlorinated ethylene polymers and compositions thereof

1973
- 1973-08-28 NL NL7311780.A patent/NL159678B/xx not_active IP Right Cessation
1974
- 1974-08-26 SE SE7410820A patent/SE419448B/xx not_active IP Right Cessation
- 1974-08-27 US US05/500,942 patent/US3935181A/en not_active Expired - Lifetime
- 1974-08-27 SU SU742060701A patent/SU791250A3/ru active
- 1974-08-28 IT IT52777/74A patent/IT1019138B/it active
- 1974-08-28 JP JP49098839A patent/JPS5228476B2/ja not_active Expired
- 1974-08-28 GB GB3768374A patent/GB1462835A/en not_active Expired
- 1974-08-28 DE DE2441197A patent/DE2441197A1/de not_active Ceased
- 1974-08-28 AT AT695074A patent/AT333029B/de not_active IP Right Cessation
- 1974-08-28 CA CA207,988A patent/CA1026047A/en not_active Expired
- 1974-08-28 DK DK457774A patent/DK143232C/da not_active IP Right Cessation
- 1974-08-28 NO NO743076A patent/NO143749C/no unknown
- 1974-08-28 ES ES429593A patent/ES429593A1/es not_active Expired
- 1974-08-28 IL IL45564A patent/IL45564A/en unknown
- 1974-08-28 FR FR7429381A patent/FR2257610B1/fr not_active Expired
- 1974-08-28 BE BE147957A patent/BE819263A/xx not_active IP Right Cessation
- 1974-08-30 IN IN1949/CAL/74A patent/IN142397B/en unknown

Also Published As

Publication number	Publication date
SE419448B (sv)	1981-08-03
SE7410820L (da)	1975-03-03
FR2257610A1 (da)	1975-08-08
ATA695074A (de)	1976-02-15
IL45564A0 (en)	1974-11-29
JPS5228476B2 (da)	1977-07-27
CA1026047A (en)	1978-02-07
DE2441197A1 (de)	1975-03-06
BE819263A (fr)	1975-02-28
AT333029B (de)	1976-10-25
ES429593A1 (es)	1976-09-01
IT1019138B (it)	1977-11-10
NO743076L (da)	1975-03-24
JPS5051190A (da)	1975-05-07
NO143749C (no)	1981-04-08
DK457774A (da)	1975-04-28
GB1462835A (en)	1977-01-26
FR2257610B1 (da)	1979-06-15
DK143232C (da)	1981-11-30
NO143749B (no)	1980-12-29
NL7311780A (nl)	1975-03-04
US3935181A (en)	1976-01-27
SU791250A3 (ru)	1980-12-23
DK143232B (da)	1981-07-27
NL159678B (nl)	1979-03-15
IN142397B (da)	1977-07-02

Publication	Publication Date	Title
US4975496A (en)	1990-12-04	Process for brominating aromatic resins
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IL45564A (en)	1977-06-30	Process for chlorinating ethylene polymers
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US3574177A (en)	1971-04-06	Production of acrylonitrile polymers
US3420807A (en)	1969-01-07	Vinyl chloride polymerization
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US5006607A (en)	1991-04-09	Dispersant system for making polyvinyl chloride which produces low color chlorinated polyvinyl chloride
US2975162A (en)	1961-03-14	Process for the production of polymerization products of vinyl chloride
WO1990012036A1 (en)	1990-10-18	High solids copolymerization process of maleic anhydride and alkyl vinyl ether
US3963687A (en)	1976-06-15	Two step continuous polymerization method to form acrylonitrile copolymers
US3031437A (en)	1962-04-24	Vinylidene fluoride polymers and copolymers
US3206445A (en)	1965-09-14	Vinyl aromatic sulfonate polymerization process and product
DE2521766A1 (de)	1975-12-04	Ischpolymer und verfahren zu dessen herstellung
US3423355A (en)	1969-01-21	Catalytic ketone solution process for preparing high bulk density,high molecular weight styrene-maleic anhydride polymers
US4342856A (en)	1982-08-03	Propylene polymerization process and product