IL91633A - Nickel-base superalloys for producing single crystal articles having improved tolerance to low angle grain boundaries - Google Patents
Nickel-base superalloys for producing single crystal articles having improved tolerance to low angle grain boundariesInfo
- Publication number
- IL91633A IL91633A IL9163389A IL9163389A IL91633A IL 91633 A IL91633 A IL 91633A IL 9163389 A IL9163389 A IL 9163389A IL 9163389 A IL9163389 A IL 9163389A IL 91633 A IL91633 A IL 91633A
- Authority
- IL
- Israel
- Prior art keywords
- nickel
- article
- single crystal
- balance
- grain boundaries
- Prior art date
Links
- 229910000601 superalloy Inorganic materials 0.000 title claims description 67
- 239000013078 crystal Substances 0.000 title claims description 51
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 40
- 239000012535 impurity Substances 0.000 claims description 27
- 229910052759 nickel Inorganic materials 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 description 19
- 239000008186 active pharmaceutical agent Substances 0.000 description 17
- 229910045601 alloy Inorganic materials 0.000 description 16
- 239000000956 alloy Substances 0.000 description 16
- 229910052796 boron Inorganic materials 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 230000003647 oxidation Effects 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 229910052735 hafnium Inorganic materials 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 125000004122 cyclic group Chemical group 0.000 description 10
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 10
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 9
- 238000005266 casting Methods 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 8
- 238000007711 solidification Methods 0.000 description 8
- 230000008023 solidification Effects 0.000 description 8
- 229910052726 zirconium Inorganic materials 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000005162 X-ray Laue diffraction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000002939 deleterious effect Effects 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000011651 chromium Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000976 Electrical steel Inorganic materials 0.000 description 1
- 240000008669 Hedera helix Species 0.000 description 1
- 208000035155 Mitochondrial DNA-associated Leigh syndrome Diseases 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000035475 disorder Diseases 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 208000003531 maternally-inherited Leigh syndrome Diseases 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 102200080066 rs122460151 Human genes 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000010671 solid-state reaction Methods 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/057—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being less 10%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/056—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B11/00—Single-crystal growth by normal freezing or freezing under temperature gradient, e.g. Bridgman-Stockbarger method
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/52—Alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8607773A GB2234521B (en) | 1986-03-27 | 1986-03-27 | Nickel-base superalloys for producing single crystal articles having improved tolerance to low angle grain boundaries |
| DE3612628A DE3612628C2 (de) | 1986-03-27 | 1986-04-15 | Gußwerkstücke und gegossenes Einkristallwerkstück aus Superlegierungen auf Nickelbasis zur Herstellung von Einkristall-Gegenständen mit verbesserter Kleinwinkel-Korngrenzen-Toleranz |
| FR8605809A FR2731714B1 (fr) | 1986-03-27 | 1986-04-22 | Superalliages a base de nickel pour la production d'articles monocristallins ayant une tolerance amelioree aux joints de grains a faible desorientation |
| CA000516576A CA1337624C (fr) | 1986-03-27 | 1986-08-22 | Superalliages a base de nickel pour la production d'articles monocristallins a tolerance amelioree aux joints de grain a angle faible |
| JP80001689A JP3402603B2 (ja) | 1986-03-27 | 1989-05-30 | 単結晶製品を製造するための改善された低角粒界耐性を有するニッケル基―超合金 |
| IL9163389A IL91633A (en) | 1986-03-27 | 1989-09-14 | Nickel-base superalloys for producing single crystal articles having improved tolerance to low angle grain boundaries |
| AU41640/89A AU626581B2 (en) | 1986-03-27 | 1989-09-20 | Nickel-base single crystal superalloys |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8607773A GB2234521B (en) | 1986-03-27 | 1986-03-27 | Nickel-base superalloys for producing single crystal articles having improved tolerance to low angle grain boundaries |
| DE3612628A DE3612628C2 (de) | 1986-03-27 | 1986-04-15 | Gußwerkstücke und gegossenes Einkristallwerkstück aus Superlegierungen auf Nickelbasis zur Herstellung von Einkristall-Gegenständen mit verbesserter Kleinwinkel-Korngrenzen-Toleranz |
| FR8605809A FR2731714B1 (fr) | 1986-03-27 | 1986-04-22 | Superalliages a base de nickel pour la production d'articles monocristallins ayant une tolerance amelioree aux joints de grains a faible desorientation |
| CA000516576A CA1337624C (fr) | 1986-03-27 | 1986-08-22 | Superalliages a base de nickel pour la production d'articles monocristallins a tolerance amelioree aux joints de grain a angle faible |
| IL9163389A IL91633A (en) | 1986-03-27 | 1989-09-14 | Nickel-base superalloys for producing single crystal articles having improved tolerance to low angle grain boundaries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL91633A true IL91633A (en) | 1994-11-11 |
Family
ID=27508252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL9163389A IL91633A (en) | 1986-03-27 | 1989-09-14 | Nickel-base superalloys for producing single crystal articles having improved tolerance to low angle grain boundaries |
Country Status (6)
| Country | Link |
|---|---|
| AU (1) | AU626581B2 (fr) |
| CA (1) | CA1337624C (fr) |
| DE (1) | DE3612628C2 (fr) |
| FR (1) | FR2731714B1 (fr) |
| GB (1) | GB2234521B (fr) |
| IL (1) | IL91633A (fr) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5366695A (en) * | 1992-06-29 | 1994-11-22 | Cannon-Muskegon Corporation | Single crystal nickel-based superalloy |
| DE4323486C2 (de) * | 1992-07-23 | 2001-09-27 | Abb Research Ltd | Ausscheidungshärtbare Nickelbasis-Superlegierung und Verwendung der Legierung als Werkstoff bei der Herstellung eines gerichteten erstarrten Bauteils, wie insbesondere einer Gasturbinenschaufel |
| US5549765A (en) * | 1993-03-18 | 1996-08-27 | Howmet Corporation | Clean single crystal nickel base superalloy |
| DE69423061T2 (de) * | 1993-08-06 | 2000-10-12 | Hitachi, Ltd. | Gasturbinenschaufel, Verfahren zur Herstellung derselben sowie Gasturbine mit dieser Schaufel |
| FR2712307B1 (fr) * | 1993-11-10 | 1996-09-27 | United Technologies Corp | Articles en super-alliage à haute résistance mécanique et à la fissuration et leur procédé de fabrication. |
| US5489346A (en) * | 1994-05-03 | 1996-02-06 | Sps Technologies, Inc. | Hot corrosion resistant single crystal nickel-based superalloys |
| EP0763604B1 (fr) * | 1995-09-18 | 2007-08-22 | Howmet Corporation | Superalliage monocristallin de haute pureté à base de nickel |
| RU2130088C1 (ru) * | 1997-10-23 | 1999-05-10 | Уфимский государственный авиационный технический университет | Жаропрочный сплав на основе никеля |
| WO1999067435A1 (fr) * | 1998-06-23 | 1999-12-29 | Siemens Aktiengesellschaft | Alliage a solidification directionnelle a resistance transversale a la rupture amelioree |
| EP1054072B1 (fr) | 1999-05-20 | 2003-04-02 | ALSTOM (Switzerland) Ltd | Superalliage à base de Nickel |
| EP1078996B1 (fr) | 1999-08-09 | 2004-02-11 | ALSTOM (Switzerland) Ltd | Procédé pour renforcer les joints de grains d'une composant en superalliage de nickel |
| EP1211336B1 (fr) * | 2000-11-30 | 2007-05-30 | ONERA (Office National d'Etudes et de Recherches Aérospatiales) | Superalliage à base de nickel pour aubes monocristallines de turbines industrielles ayant une résistance élevée à la corrosion à chaud |
| US6558119B2 (en) * | 2001-05-29 | 2003-05-06 | General Electric Company | Turbine airfoil with separately formed tip and method for manufacture and repair thereof |
| US20030111138A1 (en) * | 2001-12-18 | 2003-06-19 | Cetel Alan D. | High strength hot corrosion and oxidation resistant, directionally solidified nickel base superalloy and articles |
| CH695497A5 (de) | 2002-04-30 | 2006-06-15 | Alstom Technology Ltd | Nickel-Basis-Superlegierung. |
| JP4036091B2 (ja) † | 2002-12-17 | 2008-01-23 | 株式会社日立製作所 | ニッケル基耐熱合金及びガスタービン翼 |
| AU2003255216B8 (en) * | 2003-10-21 | 2008-05-01 | Ansaldo Energia Ip Uk Limited | Nickel-base superalloy |
| DE10361882B4 (de) * | 2003-12-19 | 2013-08-22 | Rolls-Royce Deutschland Ltd & Co Kg | Rotor für die Hochdruckturbine eines Flugtriebwerks |
| ES2444407T3 (es) | 2006-09-07 | 2014-02-24 | Alstom Technology Ltd | Procedimiento para el tratamiento térmico de súper-aleaciones a base de níquel |
| JP5133453B2 (ja) | 2009-08-10 | 2013-01-30 | 株式会社Ihi | Ni基単結晶超合金及びタービン翼 |
| CH702642A1 (de) | 2010-02-05 | 2011-08-15 | Alstom Technology Ltd | Nickel-Basis-Superlegierung mit verbessertem Degradationsverhalten. |
| EP2876176B1 (fr) | 2013-11-25 | 2017-06-21 | Mitsubishi Hitachi Power Systems, Ltd. | Superalliage de coulée à base de Ni et article moulé à partir de celui-ci |
| JP6528926B2 (ja) | 2014-05-21 | 2019-06-12 | 株式会社Ihi | 原子力施設の回転機器 |
| EP2949768B1 (fr) * | 2014-05-28 | 2019-07-17 | Ansaldo Energia IP UK Limited | Précipitation gamma prime renforcée par un superalliage à base de nickel destinée à être utilisée dans un processus de fabrication d'additif à base de poudre |
| US10577679B1 (en) * | 2018-12-04 | 2020-03-03 | General Electric Company | Gamma prime strengthened nickel superalloy for additive manufacturing |
| CN113186431A (zh) * | 2021-05-06 | 2021-07-30 | 哈尔滨工业大学(深圳) | 一种适用于粉末冶金的镍基高温合金粉末及其制备方法 |
| FR3139197B1 (fr) * | 2022-08-25 | 2024-07-19 | Safran | Procédé de contrôle de l’état cristallin d’une pièce de fonderie monocristalline |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3494709A (en) * | 1965-05-27 | 1970-02-10 | United Aircraft Corp | Single crystal metallic part |
| US3567526A (en) * | 1968-05-01 | 1971-03-02 | United Aircraft Corp | Limitation of carbon in single crystal or columnar-grained nickel base superalloys |
| IL42133A (en) * | 1972-06-09 | 1975-12-31 | Gen Electric | Nickel base alloy |
| GB1449273A (en) * | 1973-07-25 | 1976-09-15 | Gen Electric | Heat treatment of alloys |
| US3897815A (en) * | 1973-11-01 | 1975-08-05 | Gen Electric | Apparatus and method for directional solidification |
| US4116723A (en) * | 1976-11-17 | 1978-09-26 | United Technologies Corporation | Heat treated superalloy single crystal article and process |
| US4206348A (en) * | 1978-06-05 | 1980-06-03 | Eastman Kodak Company | Optical scanner with electrooptical feedback for beam positioning |
| GB2071695A (en) * | 1980-03-13 | 1981-09-23 | Rolls Royce | An alloy suitable for making single-crystal castings and a casting made thereof |
| US4402772A (en) * | 1981-09-14 | 1983-09-06 | United Technologies Corporation | Superalloy single crystal articles |
| IL65897A0 (en) * | 1981-10-02 | 1982-08-31 | Gen Electric | Single crystal nickel-base superalloy,article and method for making |
| US4475980A (en) * | 1982-06-01 | 1984-10-09 | United Technologies Corporation | Solid state production of multiple single crystal articles |
| US4574015A (en) * | 1983-12-27 | 1986-03-04 | United Technologies Corporation | Nickle base superalloy articles and method for making |
| CA1291350C (fr) * | 1986-04-03 | 1991-10-29 | United Technologies Corporation | Articles monocristallins a anisotropie reduite |
-
1986
- 1986-03-27 GB GB8607773A patent/GB2234521B/en not_active Expired - Lifetime
- 1986-04-15 DE DE3612628A patent/DE3612628C2/de not_active Expired - Lifetime
- 1986-04-22 FR FR8605809A patent/FR2731714B1/fr not_active Expired - Lifetime
- 1986-08-22 CA CA000516576A patent/CA1337624C/fr not_active Expired - Fee Related
-
1989
- 1989-09-14 IL IL9163389A patent/IL91633A/en not_active IP Right Cessation
- 1989-09-20 AU AU41640/89A patent/AU626581B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| GB2234521B (en) | 1991-05-01 |
| AU626581B2 (en) | 1992-08-06 |
| GB2234521A (en) | 1991-02-06 |
| FR2731714A1 (fr) | 1996-09-20 |
| FR2731714B1 (fr) | 1997-08-14 |
| AU4164089A (en) | 1991-03-28 |
| DE3612628C2 (de) | 2001-11-08 |
| DE3612628A1 (de) | 1998-11-05 |
| CA1337624C (fr) | 1995-11-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| KB | Patent renewed | ||
| KB | Patent renewed | ||
| MM9K | Patent not in force due to non-payment of renewal fees |