IN2012DN02308A - - Google Patents

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Publication number
IN2012DN02308A
IN2012DN02308A IN2308DEN2012A IN2012DN02308A IN 2012DN02308 A IN2012DN02308 A IN 2012DN02308A IN 2308DEN2012 A IN2308DEN2012 A IN 2308DEN2012A IN 2012DN02308 A IN2012DN02308 A IN 2012DN02308A
Authority
IN
India
Prior art keywords
catalyst
reactions
ionic liquid
acid
catalyst system
Prior art date
Application number
Inventor
Anders Riisager
Rasmus Fehrmann
Jianmin Xiong
Suarex Eduardo J Garcia
Original Assignee
Univ Denmark Tech Dtu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Denmark Tech Dtu filed Critical Univ Denmark Tech Dtu
Publication of IN2012DN02308A publication Critical patent/IN2012DN02308A/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0285—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre also containing elements or functional groups covered by B01J31/0201 - B01J31/0274
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/20—Non-coordinating groups comprising halogens
    • B01J2540/22—Non-coordinating groups comprising halogens comprising fluorine, e.g. trifluoroacetate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention concerns a catalyst system in particular a catalyst system comprising Palladium (Pd), a zwitterion and/or an acid-functionalized ionic liquid, and one or more phosphine ligands, wherein the Pd catalyst can be provided by a complex precursor, such as Pd(CH3COO)2, PdCI2, Pd(CH3COCHCOCH3), Pd (CF3COO)2, Pd(PPh3)4 or Pd2(dibenzylideneacetone)3. Such catalyst systems can be used for e.g. alkoxycarbonylation reactions, carboxylation reactions, and/or in a co-polymerization reaction, e.g. in the production of methyl propionate and/or propanoic acid, optionally in processes forming methyl methacrylate and/or methacrylic acid. Catalyst systems according to the invention are suitable for reactions forming separable product and catalyst phases and supported ionic liquid phase SILP applications.
IN2308DEN2012 2009-09-03 2010-09-01 IN2012DN02308A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09011313 2009-09-03
PCT/EP2010/062797 WO2011026860A1 (en) 2009-09-03 2010-09-01 Palladium catalyst system comprising zwitterion and/or acid-functionalized ionic liquid

Publications (1)

Publication Number Publication Date
IN2012DN02308A true IN2012DN02308A (en) 2015-08-21

Family

ID=41314501

Family Applications (1)

Application Number Title Priority Date Filing Date
IN2308DEN2012 IN2012DN02308A (en) 2009-09-03 2010-09-01

Country Status (8)

Country Link
EP (1) EP2473277B1 (en)
JP (1) JP5918695B2 (en)
KR (1) KR101763377B1 (en)
CN (1) CN102625731B (en)
IN (1) IN2012DN02308A (en)
MY (1) MY162567A (en)
SG (1) SG178878A1 (en)
WO (1) WO2011026860A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602370B (en) * 2017-02-28 2020-12-08 新疆中泰化学股份有限公司 Method for synthesizing acrylic acid or acrylic ester
EP3441137B1 (en) * 2017-08-08 2019-12-25 Evonik Operations GmbH The pd-catalytic decomposition of formic acid
CN107570210B (en) * 2017-09-05 2020-09-22 河北工业大学 Ionic liquid-polymer loaded Pd-M-based catalyst and preparation method and application thereof
CN111533837B (en) * 2020-04-20 2022-02-11 浙江师范大学 Acidic polymeric ionic liquid and preparation method and application thereof
CN112939776B (en) * 2021-02-02 2022-10-25 中国科学院过程工程研究所 Method for reinforcing long-chain olefin hydrogen esterification reaction by ionic liquid
CN114409598A (en) * 2021-12-07 2022-04-29 中海油天津化工研究设计院有限公司 Preparation method of ionic liquid 1-methyl 3- (4-sulfobutyl) imidazole bisulfate
CN114989073A (en) * 2021-12-07 2022-09-02 中海油天津化工研究设计院有限公司 Method for preparing 1-methyl3- (4-sulfobutyl) pyridine bisulfate serving as ionic liquid

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5210177A (en) * 1991-05-31 1993-05-11 Shell Oil Company Polymerization of co/olefin with tetra ethyl diphosphine
GB9425911D0 (en) * 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
US6103927A (en) * 1996-04-16 2000-08-15 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds
WO2001092348A2 (en) * 2000-05-31 2001-12-06 E.I. Du Pont De Nemours And Company Polymerization of olefins
JP3443644B2 (en) * 2000-09-14 2003-09-08 独立行政法人産業技術総合研究所 Method for producing esters and amides
ZA200108461B (en) * 2000-10-27 2002-06-06 Celanese Chem Europe Gmbh Process of telomerizing conjugated dienes.
KR100989299B1 (en) * 2002-04-05 2010-10-22 유니버시티 오브 사우스 앨라배마 Functionalized ionic liquids, and methods of use thereof
TW200517375A (en) * 2003-09-18 2005-06-01 Sumitomo Chemical Co A novel acidic ionic liquid and method of reaction using the same
FR2860170B1 (en) * 2003-09-29 2006-04-21 Atofina Res IONIC LIQUIDS FOR OLEFIN POLYMERIZATION CATALYSTS
FR2862237B1 (en) * 2003-11-14 2008-11-14 Atofina Res IONIC LIQUIDS AS SOLVENTS FOR OLEFIN POLYMERIZATION CATALYSTS
JP4565927B2 (en) * 2004-01-30 2010-10-20 川研ファインケミカル株式会社 Palladium catalyst for Heck reaction generating a carbon-carbon bond
ZA200710490B (en) * 2005-05-20 2009-04-29 Wacker Chemie Ag A process for continuous carbonylation by supported ionic liquid-phase catalysis
PT1883616E (en) 2005-05-20 2009-11-24 Wacker Chemie Ag A process for continuous carbonylation by supported ionic liquid-phase catalysis
CN100374412C (en) * 2006-06-16 2008-03-12 浙江大学 Method for amide carbonylation reaction in ion liquid
CN1931845B (en) * 2006-09-29 2012-07-04 华东师范大学 Alkaline ionic liquid and its prepn process and application
WO2008145312A1 (en) * 2007-05-25 2008-12-04 Dsm Ip Assets B.V. Method of making a lactam in an ionic liquid
CN101865235B (en) 2010-07-07 2012-01-04 南京捷诺环境技术有限公司 Vibration isolation buffer for resisting strong impact

Also Published As

Publication number Publication date
JP2013503733A (en) 2013-02-04
KR101763377B1 (en) 2017-07-31
WO2011026860A1 (en) 2011-03-10
CN102625731B (en) 2016-04-06
CN102625731A (en) 2012-08-01
MY162567A (en) 2017-06-30
KR20120057639A (en) 2012-06-05
JP5918695B2 (en) 2016-05-18
EP2473277A1 (en) 2012-07-11
SG178878A1 (en) 2012-04-27
EP2473277B1 (en) 2019-07-03

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