IN2014CN04444A - - Google Patents

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Publication number
IN2014CN04444A
IN2014CN04444A IN4444CHN2014A IN2014CN04444A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A IN 4444CHN2014 A IN4444CHN2014 A IN 4444CHN2014A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A
Authority
IN
India
Prior art keywords
olefin
interpolymer
nonconjugated polyene
ethylene
polymerization
Prior art date
Application number
Inventor
Colin Lipishan
Thomas W Karjala
Michael L Smith
Liam P Spencer
Jerzy Klosin
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of IN2014CN04444A publication Critical patent/IN2014CN04444A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)

Abstract

The invention provides a solution polymerization process to form an ethylene/a olefin/nonconjugated polyene interpolymer said process comprising polymerizing ethylene an a olefin and a nonconjugated polyene in at least one reactor in the presence of a catalyst selected from Formula I as described herein; and wherein the polymerization is conducted in a continuous process; and wherein the interpolymer has a rheology ratio (V0.1/V100 at 19°C) greater than or equal to 20.
IN4444CHN2014 2011-12-20 2012-12-20 IN2014CN04444A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161577720P 2011-12-20 2011-12-20
US201261731891P 2012-11-30 2012-11-30
PCT/US2012/070859 WO2013096573A1 (en) 2011-12-20 2012-12-20 Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

Publications (1)

Publication Number Publication Date
IN2014CN04444A true IN2014CN04444A (en) 2015-09-04

Family

ID=47559697

Family Applications (1)

Application Number Title Priority Date Filing Date
IN4444CHN2014 IN2014CN04444A (en) 2011-12-20 2012-12-20

Country Status (9)

Country Link
US (1) US9422383B2 (en)
EP (1) EP2794693B1 (en)
JP (1) JP6189325B2 (en)
KR (1) KR101989206B1 (en)
CN (1) CN104169313B (en)
BR (1) BR112014014855B1 (en)
ES (1) ES2835807T3 (en)
IN (1) IN2014CN04444A (en)
WO (1) WO2013096573A1 (en)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6189325B2 (en) 2011-12-20 2017-08-30 ダウ グローバル テクノロジーズ エルエルシー Ethylene / alphaolefin / nonconjugated polyene copolymer and method for forming the same
JP5946331B2 (en) * 2012-06-01 2016-07-06 三井化学株式会社 Ethylene / α-olefin non-conjugated polyene copolymer rubber pellets
JP6320407B2 (en) * 2012-11-30 2018-05-09 ダウ グローバル テクノロジーズ エルエルシー Ethylene / α-olefin / polyene composition
US9751998B2 (en) * 2012-12-27 2017-09-05 Dow Global Technologies Llc Catalyst systems for olefin polymerization
JP6175146B2 (en) 2013-01-18 2017-08-02 ダウ グローバル テクノロジーズ エルエルシー Polymerization process for high molecular weight polyolefins.
JP6673596B2 (en) 2014-05-31 2020-03-25 株式会社ブリヂストン Metal complex catalyst, polymerization method using the same, and polymer product thereof
KR102569866B1 (en) * 2014-12-04 2023-08-24 다우 글로벌 테크놀로지스 엘엘씨 Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
EP3240809B1 (en) 2014-12-29 2021-02-17 Dow Global Technologies LLC Process to form oil containing ethylene-based polymers
BR112017013863B1 (en) * 2014-12-29 2021-12-14 Dow Global Technologies Llc PROCESS FOR FORMING A FIRST COMPOSITION COMPRISING A FIRST ETHYLENE/AL-OLEFIN INTERPOLYMER AND A SECOND ETHYLENE/AL-OLEFIN INTERPOLYMER, COMPOSITION AND ARTICLE
BR112017020525B1 (en) * 2015-03-31 2022-07-19 Dow Global Technologies Llc PROCESS FOR FORMING A POLYMER COMPOSITION
WO2016191076A1 (en) * 2015-05-28 2016-12-01 Dow Global Technologies Llc Process to form ethylene/alpha-olefin interpolymers
WO2017040088A1 (en) * 2015-09-02 2017-03-09 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
MX2018002459A (en) * 2015-09-02 2018-06-15 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation.
CA3003170C (en) * 2015-10-29 2023-09-12 Dow Global Technologies Llc Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
EP3478762A1 (en) 2016-06-30 2019-05-08 Dow Global Technologies, LLC Ethylene/alpha-olefin/polyene based compositions
EP4029886B1 (en) 2016-06-30 2024-10-09 Dow Global Technologies LLC Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same
CN109641989B (en) 2016-07-13 2022-05-03 埃克森美孚化学专利公司 Bimetallic metallocene catalyst copolymer composition
WO2018013284A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
EP3484931A1 (en) 2016-07-14 2019-05-22 ExxonMobil Chemical Patents Inc. Dual metallocene-catalyzed bimodal copolymer compositions
WO2018022279A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
SG11201900655UA (en) * 2016-07-29 2019-02-27 Dow Global Technologies Llc Mixed catalyst systems for producing multimodal elastomers
US10221260B2 (en) 2016-07-29 2019-03-05 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
JP6884865B2 (en) * 2016-12-26 2021-06-09 ダウ グローバル テクノロジーズ エルエルシー Ethylene / α-olefin / non-conjugated polyene interpolymer compositions and articles made from them
WO2018183700A1 (en) * 2017-03-31 2018-10-04 Dow Global Technologies Llc Bis-biphenyl-phenoxy catalysts for olefin polymerization
WO2018231224A1 (en) * 2017-06-14 2018-12-20 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
JP7381449B2 (en) 2017-08-24 2023-11-15 ダウ グローバル テクノロジーズ エルエルシー Ethylene/C5-C10 alpha-olefin/polyethylene interpolymer
BR112020016302A2 (en) 2018-02-14 2020-12-15 Dow Global Technologies Llc COMPOSITIONS OF ETHYLENE / ALPHA-OLEPHINE INTERPOLYMER WITH IMPROVED LONG TERM THERMAL AGING PERFORMANCE
WO2020046597A1 (en) 2018-08-29 2020-03-05 Exxonmobil Chemical Patents Inc. Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes
KR102538844B1 (en) * 2018-12-21 2023-06-01 주식회사 엘지화학 Method for preparing vinyl aromatic compound-vinylcyan compound copolymer and method for preparing thermoplastic resin composition comprising the copolymer
WO2020184421A1 (en) 2019-03-12 2020-09-17 三井化学株式会社 Olefin-based resin, product of crosslinking thereof, and production methods therefor
US12378391B2 (en) * 2019-03-29 2025-08-05 Dow Global Technologies Llc Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates
KR102690386B1 (en) 2019-04-30 2024-08-05 다우 글로벌 테크놀로지스 엘엘씨 Ethylene/propylene/non-conjugated diene interpolymer composition
WO2021061578A1 (en) 2019-09-24 2021-04-01 Dow Global Technologies Llc Polymer compositions with excellent electrical and mechanical properties
JP7689948B2 (en) * 2019-09-24 2025-06-09 ダウ グローバル テクノロジーズ エルエルシー Polymer Compositions for Extrusion Profiles
WO2021061577A1 (en) 2019-09-24 2021-04-01 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene interpolymer compositions
US20230074326A1 (en) * 2019-12-27 2023-03-09 Dow Global Technologies Llc Ethylene/Butene Multi-Block Copolymer and Process for Producing Same
JP2021147420A (en) * 2020-03-16 2021-09-27 三井化学株式会社 Method for producing olefin-cyclic olefin copolymer
BR112022019374A2 (en) * 2020-03-27 2022-11-16 Dow Global Technologies Llc PROCESS FOR POLYMERIZING ETHYLENE-BASED POLYMERS
EP4127061A1 (en) 2020-03-30 2023-02-08 ExxonMobil Chemical Patents Inc. Comb-block copolymers and methods thereof
US20230303597A1 (en) * 2020-12-28 2023-09-28 Sabic Sk Nexlene Company Pte. Ltd. Metal-ligand complex, catalyst composition for preparing ethylene-based polymer containing the same, and preparation method of ethylene -based polymer using the same
KR20240074467A (en) * 2022-11-21 2024-05-28 롯데케미칼 주식회사 Method for preparing ethylene/alpha-olefin copolymer
WO2025117273A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Support-bound activators, supported catalyst systems, and processes for use thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US6680361B1 (en) * 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
US6841502B2 (en) * 2002-04-24 2005-01-11 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
JP2008509277A (en) 2004-08-09 2008-03-27 ダウ グローバル テクノロジーズ インコーポレイティド Supported bis (hydroxyarylaryloxy) catalysts for the production of polymers
EP2024402B2 (en) 2006-05-17 2023-01-25 Dow Global Technologies LLC High temperature solution polymerization process
ES2435568T3 (en) 2007-11-19 2013-12-20 Dow Global Technologies Llc Propylene-alpha-olefin copolymers with long chain branching
WO2010033601A1 (en) 2008-09-16 2010-03-25 Dow Global Technologies Inc. Polymeric compositions and foams, methods of making the same, and articles prepared from the same
CN106939057B (en) 2009-07-01 2021-04-23 陶氏环球技术有限责任公司 Ethylene polymer and use thereof
WO2011002998A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylenic polymer and its use
BRPI1010079B1 (en) 2009-07-15 2019-10-08 Dow Global Technologies Llc POLYMERIC COMPOSITION AND ARTICLE
ES2659733T3 (en) * 2010-08-25 2018-03-19 Dow Global Technologies Llc Polymerizable olefin polymerization process and catalyst for it
JP6104277B2 (en) * 2011-12-13 2017-03-29 ダウ グローバル テクノロジーズ エルエルシー Ethylene-propylene-diene copolymer composition
JP6189325B2 (en) 2011-12-20 2017-08-30 ダウ グローバル テクノロジーズ エルエルシー Ethylene / alphaolefin / nonconjugated polyene copolymer and method for forming the same

Also Published As

Publication number Publication date
EP2794693A1 (en) 2014-10-29
BR112014014855B1 (en) 2022-01-11
JP2015500920A (en) 2015-01-08
ES2835807T3 (en) 2021-06-23
WO2013096573A1 (en) 2013-06-27
JP6189325B2 (en) 2017-08-30
CN104169313A (en) 2014-11-26
KR101989206B1 (en) 2019-09-24
CN104169313B (en) 2016-09-21
EP2794693B1 (en) 2020-09-23
BR112014014855A2 (en) 2017-06-13
US9422383B2 (en) 2016-08-23
KR20140107263A (en) 2014-09-04
US20150322185A1 (en) 2015-11-12

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