IN2014CN04444A - - Google Patents
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- Publication number
- IN2014CN04444A IN2014CN04444A IN4444CHN2014A IN2014CN04444A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A IN 4444CHN2014 A IN4444CHN2014 A IN 4444CHN2014A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A
- Authority
- IN
- India
- Prior art keywords
- olefin
- interpolymer
- nonconjugated polyene
- ethylene
- polymerization
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 150000004291 polyenes Chemical class 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 238000000518 rheometry Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Abstract
The invention provides a solution polymerization process to form an ethylene/a olefin/nonconjugated polyene interpolymer said process comprising polymerizing ethylene an a olefin and a nonconjugated polyene in at least one reactor in the presence of a catalyst selected from Formula I as described herein; and wherein the polymerization is conducted in a continuous process; and wherein the interpolymer has a rheology ratio (V0.1/V100 at 19°C) greater than or equal to 20.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2014CN04444A true IN2014CN04444A (en) | 2015-09-04 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN4444CHN2014 IN2014CN04444A (en) | 2011-12-20 | 2012-12-20 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (en) |
| EP (1) | EP2794693B1 (en) |
| JP (1) | JP6189325B2 (en) |
| KR (1) | KR101989206B1 (en) |
| CN (1) | CN104169313B (en) |
| BR (1) | BR112014014855B1 (en) |
| ES (1) | ES2835807T3 (en) |
| IN (1) | IN2014CN04444A (en) |
| WO (1) | WO2013096573A1 (en) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9422383B2 (en) | 2011-12-20 | 2016-08-23 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
| JP5946331B2 (en) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | Ethylene / α-olefin non-conjugated polyene copolymer rubber pellets |
| SG11201504003XA (en) * | 2012-11-30 | 2015-06-29 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| SG11201503581PA (en) * | 2012-12-27 | 2015-06-29 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| BR112015013530B1 (en) | 2013-01-18 | 2021-10-13 | Dow Global Technologies Llc | PROCESS TO FORM AN ETHYLENE-BASED POLYMER AND METALLIC COMPLEX |
| RU2690373C2 (en) * | 2014-05-31 | 2019-06-03 | Бриджстоун Корпорейшн | Metal complex catalyst, polymerisation methods using same and obtained polymer products |
| JP6763857B2 (en) * | 2014-12-04 | 2020-09-30 | ダウ グローバル テクノロジーズ エルエルシー | Five-coordinated bis-phenylphenoxy catalyst for preparation of ethylene polymers |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| JP6752794B2 (en) * | 2014-12-29 | 2020-09-09 | ダウ グローバル テクノロジーズ エルエルシー | Methods for Forming Ethylene / Alpha-Olefin Interpolymers |
| JP6718453B2 (en) * | 2014-12-29 | 2020-07-08 | ダウ グローバル テクノロジーズ エルエルシー | Method for forming oil-containing ethylene-based polymer |
| JP6948948B2 (en) * | 2015-03-31 | 2021-10-13 | ダウ グローバル テクノロジーズ エルエルシー | Method for Producing Ultra High Molecular Weight Ethylene / α-olefin / Non-Conjugated Interpolymer with Low Level Long Chain Branching |
| EP3303427B1 (en) * | 2015-05-28 | 2023-11-29 | Dow Global Technologies LLC | Process to form ethylene/alpha-olefin/diene interpolymers |
| CA2996615C (en) * | 2015-09-02 | 2023-10-03 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| WO2017040089A1 (en) * | 2015-09-02 | 2017-03-09 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| JP6936795B2 (en) * | 2015-10-29 | 2021-09-22 | ダウ グローバル テクノロジーズ エルエルシー | Crosslinkable polymer compositions for flexible crosslinked cable insulators, and methods for making flexible crosslinked cable insulators. |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| WO2017206008A1 (en) * | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| US11981802B2 (en) | 2016-06-30 | 2024-05-14 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| CN109601004B (en) * | 2016-06-30 | 2022-08-09 | 陶氏环球技术有限责任公司 | Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same |
| CN109641990B (en) | 2016-07-13 | 2022-08-19 | 埃克森美孚化学专利公司 | Dual metallocene catalyst copolymer compositions |
| CN109641989B (en) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | Bimetallic metallocene catalyst copolymer composition |
| JP6850862B2 (en) | 2016-07-14 | 2021-03-31 | エクソンモービル・ケミカル・パテンツ・インク | Bimodal copolymer composition polymerized with a binary metallocene catalyst useful as a viscosity modifier |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| KR102413982B1 (en) * | 2016-07-29 | 2022-06-30 | 다우 글로벌 테크놀로지스 엘엘씨 | Mixed catalyst systems for the production of multimodal elastomers |
| KR102653792B1 (en) * | 2016-12-26 | 2024-04-03 | 다우 글로벌 테크놀로지스 엘엘씨 | Ethylene/α-olefin/non-conjugated polyene interpolymer compositions and articles made therefrom |
| BR112019020417B1 (en) * | 2017-03-31 | 2023-04-04 | Dow Global Technologies Llc | CATALYST SYSTEM AND POLYMERIZATION PROCESS TO PRODUCE AN ETHYLENE-BASED POLYMER |
| US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| CN111148641B (en) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | ethylene/C5-C10 alpha-olefin/polyene interpolymers |
| EP3752560B1 (en) | 2018-02-14 | 2024-09-25 | Dow Global Technologies LLC | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
| WO2020046597A1 (en) | 2018-08-29 | 2020-03-05 | Exxonmobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (en) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | Method for preparing vinyl aromatic compound-vinylcyan compound copolymer and method for preparing thermoplastic resin composition comprising the copolymer |
| EP3940009A4 (en) | 2019-03-12 | 2023-03-15 | Mitsui Chemicals, Inc. | OLEFIN-BASED RESIN, CROSSLINKING PRODUCT THEREOF AND METHOD OF MANUFACTURE THEREOF |
| KR102715918B1 (en) * | 2019-03-29 | 2024-10-15 | 다우 글로벌 테크놀로지스 엘엘씨 | Oil-extended pelletized ethylene alpha-olefin diene interpolymer for thermoplastic vulcanizates |
| CN113874439B (en) * | 2019-04-30 | 2024-03-29 | 陶氏环球技术有限责任公司 | Ethylene/propylene/non-conjugated diene interpolymer compositions |
| EP4034597B1 (en) | 2019-09-24 | 2025-12-31 | Dow Global Technologies LLC | ETHYLENE/ALPHA-OLEFIN/POLYENE COMPOSITIONS |
| US12448506B2 (en) | 2019-09-24 | 2025-10-21 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
| EP4034598A1 (en) | 2019-09-24 | 2022-08-03 | Dow Global Technologies LLC | Polymer compositions with excellent electrical and mechanical properties |
| CN114846035A (en) * | 2019-12-27 | 2022-08-02 | 陶氏环球技术有限责任公司 | Ethylene/butylene multi-block copolymer and preparation method thereof |
| JP2021147420A (en) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | Method for producing olefin-cyclic olefin copolymer |
| EP4127001A1 (en) * | 2020-03-27 | 2023-02-08 | Dow Global Technologies LLC | A process for producing long-chain branched ethylene-based polymers |
| US12410273B2 (en) | 2020-03-30 | 2025-09-09 | Exxonmobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| JP2024500603A (en) * | 2020-12-28 | 2024-01-10 | サビック エスケー ネクスレン カンパニー プライヴェート リミテッド | Metal-ligand complex, catalyst composition for producing an ethylene polymer containing the same, and method for producing an ethylene polymer using the same |
| KR20240074467A (en) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | Method for preparing ethylene/alpha-olefin copolymer |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| US6897276B2 (en) * | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| JP2008509277A (en) | 2004-08-09 | 2008-03-27 | ダウ グローバル テクノロジーズ インコーポレイティド | Supported bis (hydroxyarylaryloxy) catalysts for the production of polymers |
| CN101490094B (en) | 2006-05-17 | 2013-06-26 | 陶氏环球技术有限责任公司 | High temperature polyethylene solution polymerization process |
| US8420760B2 (en) | 2007-11-19 | 2013-04-16 | Dow Global Technologies Llc | Long chain branched propylene-alpha-olefin copolymers |
| EP2328944B1 (en) | 2008-09-16 | 2018-01-24 | Dow Global Technologies LLC | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| EP2448979B1 (en) | 2009-07-01 | 2013-05-01 | Dow Global Technologies LLC | Ethylenic polymer and its use |
| SG177446A1 (en) | 2009-07-01 | 2012-02-28 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| KR101741857B1 (en) | 2009-07-15 | 2017-05-30 | 다우 글로벌 테크놀로지스 엘엘씨 | Polymer compositions, methods of making the same, and articles prepared from the same |
| ES2659733T3 (en) * | 2010-08-25 | 2018-03-19 | Dow Global Technologies Llc | Polymerizable olefin polymerization process and catalyst for it |
| JP6104277B2 (en) * | 2011-12-13 | 2017-03-29 | ダウ グローバル テクノロジーズ エルエルシー | Ethylene-propylene-diene copolymer composition |
| US9422383B2 (en) | 2011-12-20 | 2016-08-23 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
-
2012
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/en active Active
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/en active Active
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/en active IP Right Grant
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/en active Active
- 2012-12-20 ES ES12815929T patent/ES2835807T3/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140107263A (en) | 2014-09-04 |
| EP2794693A1 (en) | 2014-10-29 |
| JP6189325B2 (en) | 2017-08-30 |
| ES2835807T3 (en) | 2021-06-23 |
| CN104169313A (en) | 2014-11-26 |
| US20150322185A1 (en) | 2015-11-12 |
| JP2015500920A (en) | 2015-01-08 |
| BR112014014855A2 (en) | 2017-06-13 |
| BR112014014855B1 (en) | 2022-01-11 |
| KR101989206B1 (en) | 2019-09-24 |
| WO2013096573A1 (en) | 2013-06-27 |
| CN104169313B (en) | 2016-09-21 |
| US9422383B2 (en) | 2016-08-23 |
| EP2794693B1 (en) | 2020-09-23 |
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