IN2014CN04444A - - Google Patents

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Publication number
IN2014CN04444A
IN2014CN04444A IN4444CHN2014A IN2014CN04444A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A IN 4444CHN2014 A IN4444CHN2014 A IN 4444CHN2014A IN 2014CN04444 A IN2014CN04444 A IN 2014CN04444A
Authority
IN
India
Prior art keywords
olefin
interpolymer
nonconjugated polyene
ethylene
polymerization
Prior art date
Application number
Inventor
Colin Lipishan
Thomas W Karjala
Michael L Smith
Liam P Spencer
Jerzy Klosin
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of IN2014CN04444A publication Critical patent/IN2014CN04444A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)

Abstract

The invention provides a solution polymerization process to form an ethylene/a olefin/nonconjugated polyene interpolymer said process comprising polymerizing ethylene an a olefin and a nonconjugated polyene in at least one reactor in the presence of a catalyst selected from Formula I as described herein; and wherein the polymerization is conducted in a continuous process; and wherein the interpolymer has a rheology ratio (V0.1/V100 at 19°C) greater than or equal to 20.
IN4444CHN2014 2011-12-20 2012-12-20 IN2014CN04444A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161577720P 2011-12-20 2011-12-20
US201261731891P 2012-11-30 2012-11-30
PCT/US2012/070859 WO2013096573A1 (en) 2011-12-20 2012-12-20 Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

Publications (1)

Publication Number Publication Date
IN2014CN04444A true IN2014CN04444A (en) 2015-09-04

Family

ID=47559697

Family Applications (1)

Application Number Title Priority Date Filing Date
IN4444CHN2014 IN2014CN04444A (en) 2011-12-20 2012-12-20

Country Status (9)

Country Link
US (1) US9422383B2 (en)
EP (1) EP2794693B1 (en)
JP (1) JP6189325B2 (en)
KR (1) KR101989206B1 (en)
CN (1) CN104169313B (en)
BR (1) BR112014014855B1 (en)
ES (1) ES2835807T3 (en)
IN (1) IN2014CN04444A (en)
WO (1) WO2013096573A1 (en)

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BR112015013530B1 (en) 2013-01-18 2021-10-13 Dow Global Technologies Llc PROCESS TO FORM AN ETHYLENE-BASED POLYMER AND METALLIC COMPLEX
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JP6752794B2 (en) * 2014-12-29 2020-09-09 ダウ グローバル テクノロジーズ エルエルシー Methods for Forming Ethylene / Alpha-Olefin Interpolymers
JP6718453B2 (en) * 2014-12-29 2020-07-08 ダウ グローバル テクノロジーズ エルエルシー Method for forming oil-containing ethylene-based polymer
JP6948948B2 (en) * 2015-03-31 2021-10-13 ダウ グローバル テクノロジーズ エルエルシー Method for Producing Ultra High Molecular Weight Ethylene / α-olefin / Non-Conjugated Interpolymer with Low Level Long Chain Branching
EP3303427B1 (en) * 2015-05-28 2023-11-29 Dow Global Technologies LLC Process to form ethylene/alpha-olefin/diene interpolymers
CA2996615C (en) * 2015-09-02 2023-10-03 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
WO2017040089A1 (en) * 2015-09-02 2017-03-09 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
JP6936795B2 (en) * 2015-10-29 2021-09-22 ダウ グローバル テクノロジーズ エルエルシー Crosslinkable polymer compositions for flexible crosslinked cable insulators, and methods for making flexible crosslinked cable insulators.
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US11981802B2 (en) 2016-06-30 2024-05-14 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene based compositions
CN109601004B (en) * 2016-06-30 2022-08-09 陶氏环球技术有限责任公司 Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same
CN109641990B (en) 2016-07-13 2022-08-19 埃克森美孚化学专利公司 Dual metallocene catalyst copolymer compositions
CN109641989B (en) 2016-07-13 2022-05-03 埃克森美孚化学专利公司 Bimetallic metallocene catalyst copolymer composition
JP6850862B2 (en) 2016-07-14 2021-03-31 エクソンモービル・ケミカル・パテンツ・インク Bimodal copolymer composition polymerized with a binary metallocene catalyst useful as a viscosity modifier
US10221260B2 (en) 2016-07-29 2019-03-05 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
WO2018022279A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
KR102413982B1 (en) * 2016-07-29 2022-06-30 다우 글로벌 테크놀로지스 엘엘씨 Mixed catalyst systems for the production of multimodal elastomers
KR102653792B1 (en) * 2016-12-26 2024-04-03 다우 글로벌 테크놀로지스 엘엘씨 Ethylene/α-olefin/non-conjugated polyene interpolymer compositions and articles made therefrom
BR112019020417B1 (en) * 2017-03-31 2023-04-04 Dow Global Technologies Llc CATALYST SYSTEM AND POLYMERIZATION PROCESS TO PRODUCE AN ETHYLENE-BASED POLYMER
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KR102715918B1 (en) * 2019-03-29 2024-10-15 다우 글로벌 테크놀로지스 엘엘씨 Oil-extended pelletized ethylene alpha-olefin diene interpolymer for thermoplastic vulcanizates
CN113874439B (en) * 2019-04-30 2024-03-29 陶氏环球技术有限责任公司 Ethylene/propylene/non-conjugated diene interpolymer compositions
EP4034597B1 (en) 2019-09-24 2025-12-31 Dow Global Technologies LLC ETHYLENE/ALPHA-OLEFIN/POLYENE COMPOSITIONS
US12448506B2 (en) 2019-09-24 2025-10-21 Dow Global Technologies Llc Polymer compositions for extruded profiles
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CN114846035A (en) * 2019-12-27 2022-08-02 陶氏环球技术有限责任公司 Ethylene/butylene multi-block copolymer and preparation method thereof
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Also Published As

Publication number Publication date
KR20140107263A (en) 2014-09-04
EP2794693A1 (en) 2014-10-29
JP6189325B2 (en) 2017-08-30
ES2835807T3 (en) 2021-06-23
CN104169313A (en) 2014-11-26
US20150322185A1 (en) 2015-11-12
JP2015500920A (en) 2015-01-08
BR112014014855A2 (en) 2017-06-13
BR112014014855B1 (en) 2022-01-11
KR101989206B1 (en) 2019-09-24
WO2013096573A1 (en) 2013-06-27
CN104169313B (en) 2016-09-21
US9422383B2 (en) 2016-08-23
EP2794693B1 (en) 2020-09-23

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