IT1249955B - Procedimento di idrogenazione della glicerina - Google Patents

Procedimento di idrogenazione della glicerina

Info

Publication number
IT1249955B
IT1249955B ITTO910537A ITTO910537A IT1249955B IT 1249955 B IT1249955 B IT 1249955B IT TO910537 A ITTO910537 A IT TO910537A IT TO910537 A ITTO910537 A IT TO910537A IT 1249955 B IT1249955 B IT 1249955B
Authority
IT
Italy
Prior art keywords
hydrogenation procedure
glycerine hydrogenation
glycerin
glycerine
ethanediol
Prior art date
Application number
ITTO910537A
Other languages
English (en)
Inventor
Bruno Casale
Ana M Gomez
Original Assignee
Menon S R L
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Menon S R L filed Critical Menon S R L
Publication of ITTO910537A0 publication Critical patent/ITTO910537A0/it
Priority to ITTO910537A priority Critical patent/IT1249955B/it
Priority to EP19920830359 priority patent/EP0523015A3/en
Priority to CA002073312A priority patent/CA2073312A1/en
Priority to FI923131A priority patent/FI923131A7/fi
Priority to AU19466/92A priority patent/AU649337B2/en
Priority to NO92922683A priority patent/NO922683L/no
Priority to MX9204041A priority patent/MX9204041A/es
Priority to US07/911,133 priority patent/US5214219A/en
Priority to ZA925178A priority patent/ZA925178B/xx
Publication of ITTO910537A1 publication Critical patent/ITTO910537A1/it
Application granted granted Critical
Publication of IT1249955B publication Critical patent/IT1249955B/it

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Il procedimento di idrogenazione catalitica della glicerina è volto essenzialmente alla produzione di composti ossigenati aventi da 1 a 3 atomi di carbonio, principalmente 1,2 propandiolo e 1,2 etandiolo. Esso prevede di porre a contatto e di far reagire la glicerina con idrogeno in presenza di un catalizzatore comprendente rame-zinco in condizioni di temperatura di almeno 220°C.
ITTO910537A 1991-07-10 1991-07-10 Procedimento di idrogenazione della glicerina IT1249955B (it)

Priority Applications (9)

Application Number Priority Date Filing Date Title
ITTO910537A IT1249955B (it) 1991-07-10 1991-07-10 Procedimento di idrogenazione della glicerina
AU19466/92A AU649337B2 (en) 1991-07-10 1992-07-07 A method of hydrogenating glycerol
CA002073312A CA2073312A1 (en) 1991-07-10 1992-07-07 Method of hydrogenating glycerol
FI923131A FI923131A7 (fi) 1991-07-10 1992-07-07 Menetelmä glyserolin hydrogenoimiseksi
EP19920830359 EP0523015A3 (en) 1991-07-10 1992-07-07 A method of hydrogenating glycerol
NO92922683A NO922683L (no) 1991-07-10 1992-07-08 Fremgangsmaate for hydrogenering av glyserol
MX9204041A MX9204041A (es) 1991-07-10 1992-07-09 Un metodo de hidrogenacion de glicerol.
US07/911,133 US5214219A (en) 1991-07-10 1992-07-09 Method of hydrogenating glycerol
ZA925178A ZA925178B (en) 1991-07-10 1992-07-10 A method of hydrogenating glycerol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITTO910537A IT1249955B (it) 1991-07-10 1991-07-10 Procedimento di idrogenazione della glicerina

Publications (3)

Publication Number Publication Date
ITTO910537A0 ITTO910537A0 (it) 1991-07-10
ITTO910537A1 ITTO910537A1 (it) 1993-01-10
IT1249955B true IT1249955B (it) 1995-03-30

Family

ID=11409476

Family Applications (1)

Application Number Title Priority Date Filing Date
ITTO910537A IT1249955B (it) 1991-07-10 1991-07-10 Procedimento di idrogenazione della glicerina

Country Status (9)

Country Link
US (1) US5214219A (it)
EP (1) EP0523015A3 (it)
AU (1) AU649337B2 (it)
CA (1) CA2073312A1 (it)
FI (1) FI923131A7 (it)
IT (1) IT1249955B (it)
MX (1) MX9204041A (it)
NO (1) NO922683L (it)
ZA (1) ZA925178B (it)

Families Citing this family (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4442124A1 (de) 1994-11-26 1996-05-30 Basf Ag Verfahren zur Herstellung von Propandiol-1,2
US7663004B2 (en) 2002-04-22 2010-02-16 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
US8252961B2 (en) 2002-04-22 2012-08-28 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
US8017816B2 (en) 2002-04-22 2011-09-13 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
EP2298721B1 (en) * 2004-03-25 2014-06-04 Galen J. Suppes Process for producing an antifreeze composition containing lower alcohols and glycerol via alcoholysis of a glyceride
US7131446B2 (en) * 2004-03-25 2006-11-07 Tang Kenneth Y Light-triggered tattoo process
GB0514593D0 (en) * 2005-07-15 2005-08-24 Davy Process Techn Ltd Process
CA2634712C (en) * 2005-12-21 2015-11-24 Virent Energy Systems, Inc. Catalysts and methods for reforming oxygenated compounds
WO2007099161A1 (en) * 2006-03-03 2007-09-07 Basf Se Process for the preparation of 1,2-propanediol
ES2547913T3 (es) 2006-05-08 2015-10-09 Virent, Inc. Métodos para generar polioles
US20080045749A1 (en) * 2006-06-07 2008-02-21 The Procter & Gamble Company Process for the alternating conversion of glycerol to propylene glycol or amino alcohols
US7619119B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Processes for converting glycerol to amino alcohols
US7619118B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Process for the conversion of glycerol to propylene glycol and amino alcohols
GB0614823D0 (en) 2006-07-26 2006-09-06 Davy Process Techn Ltd Process
EP1889825A1 (de) * 2006-08-17 2008-02-20 Cognis Oleochemicals GmbH Verfahren zur Herstellung von 1,2-Propandiol
WO2008020077A1 (de) * 2006-08-17 2008-02-21 Cognis Oleochemicals Gmbh Verfahren zur herstellung von 1,2-propandiol
DE102007027374A1 (de) 2007-06-11 2008-12-18 Cognis Oleochemicals Gmbh Verfahren zur Herstellung von 1,2-Propandiol
US7928148B2 (en) 2006-10-23 2011-04-19 Archer Daniels Midland Company Hydrogenolysis of glycerol and products produced therefrom
WO2008057317A1 (en) * 2006-10-27 2008-05-15 Archer-Daniels-Midland Company Processes for isolating or purifying propylene glycol, ehtylene glycol and products produced therefrom
DE102006050751A1 (de) * 2006-10-27 2008-05-08 Clariant International Limited Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin
AU2007353527B2 (en) * 2006-12-20 2012-12-20 Virent, Inc. Reactor system for producing gaseous products
GB0625614D0 (en) 2006-12-27 2007-01-31 Leuven K U Res & Dev Catalytic process for the production of oxygenated hydrocarbons
US20100094066A1 (en) * 2007-01-17 2010-04-15 The Curators Of The University Of Missouri Gas phase reaction process for polyhydric compounds
DE102007003188B3 (de) 2007-01-22 2008-06-05 Clariant International Ltd. Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin
RU2472840C2 (ru) * 2007-03-08 2013-01-20 Вайрент, Инк. Синтез жидкого топлива и химических реактивов из кислородсодержащих углеводородов
WO2008129933A1 (ja) 2007-04-17 2008-10-30 Kao Corporation 多価アルコールの水素化分解物の製造方法
DK2162416T3 (en) 2007-05-18 2019-02-11 Biofuel Solution I Malmoe Ab GAS PHASE PROCEDURE FOR PREPARING MONOAL ALCOHOL FROM GLYCEROL
CN101085719B (zh) * 2007-06-29 2011-09-21 上海华谊丙烯酸有限公司 一种甘油加氢制备1,2-丙二醇的方法
US8058484B2 (en) 2007-08-24 2011-11-15 Syntroleum Corporation Flexible glycerol conversion process
KR100870369B1 (ko) 2007-08-29 2008-11-25 지에스칼텍스 주식회사 프로판디올 제조용 촉매의 제조 방법 및 이를 이용한프로판디올의 제조 방법
PL2200958T3 (pl) 2007-08-31 2016-04-29 Basf Se Sposób wytwarzania 1,2-propanodiolu drogą uwodorniania glicerolu w dwustopniowej kaskadzie reaktorów
EP2200960B1 (de) 2007-08-31 2015-11-04 Basf Se Verfahren zur herstellung von 1,2-propandiol durch niederdruck-hydrierung von glycerin
WO2009027501A2 (de) 2007-08-31 2009-03-05 Basf Se Verfahren zur herstellung von 1,2-propandiol durch hydrierung von glycerin in wenigstens drei hintereinandergeschalteten reaktoren
MY148339A (en) 2007-10-31 2013-03-29 Mitsui Chemicals Inc Process for producing propylene glycol
US8177980B2 (en) * 2007-11-09 2012-05-15 Archer Daniels Midland Company Separation of a mixture of polyhydric alcohols
WO2009070694A2 (en) * 2007-11-28 2009-06-04 North American Galvanizing Company Composition for preparing a surface for coating and methods of making and using same
MY165217A (en) 2007-12-19 2018-03-09 Univ Missouri Method of producing lower alcohols from glycerol
JP5305669B2 (ja) 2008-01-21 2013-10-02 花王株式会社 多価アルコールの水素化分解物の製造方法
AR072446A1 (es) 2008-03-02 2010-09-01 Dow Global Technologies Inc Proceso de hidrogenacion mejorado
DE102008013474B4 (de) * 2008-03-10 2013-08-08 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Katalytisches Verfahren zur Gewinnung von chemischen Grundstoffen aus nachwachsenden Rohstoffen
JP5350059B2 (ja) * 2008-04-22 2013-11-27 三井化学株式会社 プロピレングリコールの製造方法
WO2009133066A1 (de) * 2008-04-28 2009-11-05 Basf Se Verfahren zur hydrogenolyse von polyolen
MY150295A (en) 2008-04-30 2013-12-31 Mitsui Chemicals Inc Method of producing propylene glycol
DE102008026583A1 (de) 2008-06-03 2009-12-24 Bayer Technology Services Gmbh Verfahren zur Herstellung von Kraftstoffadditiven aus Glycerin
BRPI0909963A2 (pt) 2008-06-05 2019-03-06 Huntsman Petrochemical Llc processo para a produção e purificação de propileno glicol
DE102008027601A1 (de) 2008-06-10 2009-12-17 Clariant International Limited Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin
JP5462258B2 (ja) * 2008-07-16 2014-04-02 ハー・マジェスティ・ザ・クイーン・イン・ライト・オブ・カナダ・アズ・リプリゼンテッド・バイ・ザ・ミニスター・オブ・ナチュラル・リソーシーズ・カナダ グリセロールの、ナフサの範囲の酸素化物への転換
US8137527B1 (en) 2008-07-28 2012-03-20 Primafuel, Inc. Carbon dioxide isolation and generation
WO2010016462A1 (ja) * 2008-08-04 2010-02-11 チッソ株式会社 グリセリンからのグリコール及び1-プロパノールの製造方法
MX2011002059A (es) * 2008-08-27 2011-05-10 Virent Energy Systems Inc Sintesis de combustibles liquidos provenientes de biomasa.
CN101422739B (zh) * 2008-11-03 2011-12-14 大连大学 催化氢解甘油制备二元醇的负载型催化剂及其制备方法
PT2358653E (pt) * 2008-11-05 2015-11-16 Biofuel Solution I Malmö Ab Processo para a preparação de hidrocarbonetos inferiores a partir de glicerol
SG173818A1 (en) 2009-02-25 2011-09-29 Grace W R & Co Process for making 1, 2-propane diol from hydrogenation of glycerol
EP2419393B1 (en) 2009-04-16 2013-07-24 CHEMTEX ITALIA S.p.A. Method for hydrogenolysis of sugar alcohols
WO2010150278A2 (en) 2009-06-15 2010-12-29 Ganapati Dadasaheb Yadav; Hydrogenolysis of polyhydroxy alcohols using metal incorporated manganese oxide octahedral molecular sieve as a catalyst
EP2448675A2 (en) * 2009-06-30 2012-05-09 Virent, Inc. Process and reactor systems for converting sugars and sugar alcohols
WO2011009936A2 (en) 2009-07-24 2011-01-27 Basf Se Process for the preparation of 1,2-propanediol from glycerol
DE102010015006A1 (de) 2010-04-14 2011-11-24 Tu Darmstadt Katalysator zur Hydrierung von wässrigen mehrwertigen Alkohollösungen
US9227896B2 (en) 2010-08-18 2016-01-05 Eastman Chemical Company Process for the separation and purification of a mixed diol stream
US8829248B2 (en) 2010-08-18 2014-09-09 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8466328B2 (en) 2010-08-18 2013-06-18 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8785686B2 (en) 2010-09-23 2014-07-22 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8709376B2 (en) 2010-09-23 2014-04-29 Eastman Chemical Company Process for recovering and recycling an acid catalyst
CN102225883B (zh) * 2011-03-10 2013-08-21 江苏大学 Cu/TiO2催化剂、制备方法及催化甘油氢解的方法
EP2686290B1 (en) 2011-03-14 2017-09-27 Archer-Daniels-Midland Company Improved methods for producing bioderived propylene glycol
EP2565175B1 (en) 2011-08-31 2021-04-21 Aristotle University of Thessaloniki Catalytic process for the production of 1,2-propanediol from crude glycerol stream
CN102584532A (zh) * 2011-12-06 2012-07-18 复旦大学 一种提高丙三醇重整-加氢制备1,2-丙二醇的选择性的方法
WO2013148505A1 (en) 2012-03-27 2013-10-03 Eastman Chemical Company Process for the separation and purification of a mixed diol stream
US8703999B2 (en) 2012-03-27 2014-04-22 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US8829234B2 (en) 2012-03-27 2014-09-09 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst
US8927766B2 (en) 2012-03-27 2015-01-06 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration
WO2014134733A1 (en) 2013-03-07 2014-09-12 University Of Saskatchewan Process for hydrogenolysis of glycerol
AR095195A1 (es) 2013-03-15 2015-09-30 W R Grace & Co -Conn Proceso para la producción selectiva de propanoles por hidrogenación de glicerol
US9938215B2 (en) 2014-04-22 2018-04-10 Archer Daniels Midland Company Process of making bioderived propylene glycol
CN105771999B (zh) * 2016-03-25 2019-02-26 北京石油化工学院 一种甘油加氢催化剂及其制备方法与应用
CN108636404B (zh) * 2018-04-16 2021-05-04 江苏七洲绿色化工股份有限公司 一种甘油水溶液加氢制备1,3-丙二醇的规整催化剂及1,3-丙二醇的制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE541362C (de) * 1927-10-25 1932-01-11 I G Farbenindustrie Akt Ges Verfahren zur Hydrierung von Polyoxyverbindungen
GB430576A (en) * 1932-12-23 1935-06-21 Du Pont Improvements in or relating to the manufacture of glycerol and glycols
FR860273A (fr) * 1938-09-23 1941-01-10 Bombrini Parodi Delfino Procédé pour la production de glycérine par la réduction d'hydrates de carbone
BR8204165A (pt) * 1981-07-22 1983-07-12 Du Pont Processo para hidrogenolise de pentitois e misturas de pentitois com outros glicois hexitois e misturas de hexitois com outros poliois e poliois para etileno glicol
US4404411A (en) * 1982-02-01 1983-09-13 E. I. Du Pont De Nemours And Company Hydrogenolysis of polyols to ethylene glycol in nonaqueous solvents
GB8702654D0 (en) * 1987-02-06 1987-03-11 Davy Mckee Ltd Process
US5120885A (en) * 1990-09-21 1992-06-09 Kao Corporation Process for producing alcohol

Also Published As

Publication number Publication date
CA2073312A1 (en) 1993-01-11
FI923131L (fi) 1993-01-11
ITTO910537A0 (it) 1991-07-10
EP0523015A2 (en) 1993-01-13
MX9204041A (es) 1993-07-01
NO922683L (no) 1993-01-11
FI923131A7 (fi) 1993-01-11
ZA925178B (en) 1993-04-28
AU1946692A (en) 1993-02-25
EP0523015A3 (en) 1993-05-26
US5214219A (en) 1993-05-25
AU649337B2 (en) 1994-05-19
ITTO910537A1 (it) 1993-01-10
NO922683D0 (no) 1992-07-08
FI923131A0 (fi) 1992-07-07

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