IT1250045B - Procedimento per la produzione di alcool polivinilico plastificato e suo impiego per la preparazione di composizioni termoplastiche biodegradabili a base di amido. - Google Patents
Procedimento per la produzione di alcool polivinilico plastificato e suo impiego per la preparazione di composizioni termoplastiche biodegradabili a base di amido.Info
- Publication number
- IT1250045B IT1250045B ITTO910849A ITTO910849A IT1250045B IT 1250045 B IT1250045 B IT 1250045B IT TO910849 A ITTO910849 A IT TO910849A IT TO910849 A ITTO910849 A IT TO910849A IT 1250045 B IT1250045 B IT 1250045B
- Authority
- IT
- Italy
- Prior art keywords
- polyvinyl alcohol
- plasticized polyvinyl
- production
- procedure
- preparation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/18—Plasticising macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Biological Depolymerization Polymers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Il procedimento per la produzione di alcool polivinilico plastificato mediante miscelazione di alcool polivinilico in presenza di un plastificante organico e di un contenuto d'acqua insufficiente a disciogliere l'alcool polivinilico in condizioni normali, comprende le fasi di:i) preplastificare l'alcool polivinilico ad una temperatura massima non superiore alla sua temperatura di rammollimento in modo da ottenere un alcool polivinilico pre-plastificato avente una temperatura di fusione inferiore alla temperatura di rammollimento dell'alcool polivinilico impiegato, e ii) ulteriormente processare l'alcool polivinilico pre-plastificato così ottenuto ad una temperatura superiore alla sua temperatura di fusione in condizioni di sforzo di taglio e per un tempo tale da ottenere un fuso sostanzialmente omogeneo.
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITTO910849A IT1250045B (it) | 1991-11-07 | 1991-11-07 | Procedimento per la produzione di alcool polivinilico plastificato e suo impiego per la preparazione di composizioni termoplastiche biodegradabili a base di amido. |
| EP92922965A EP0611382A1 (en) | 1991-11-07 | 1992-11-03 | Method of producing plasticised polyvinyl alcohol, and its use |
| RU94027567/04A RU94027567A (ru) | 1991-11-07 | 1992-11-03 | Способ получения термопластических полимерных композиций, способных к разрушению под действием микроорганизмов |
| HU9401394A HU213950B (en) | 1991-11-07 | 1992-11-03 | Method for producing of biologically degradable polymer compositions |
| CA002123092A CA2123092A1 (en) | 1991-11-07 | 1992-11-03 | Method of producing plasticised polyvinyl alcohol, and its use for the preparation of starch-based, biodegradable thermoplastic compositions |
| JP5508161A JPH07501090A (ja) | 1991-11-07 | 1992-11-03 | 可塑化ポリビニルアルコールの製造法とその使用 |
| AU29088/92A AU661872B2 (en) | 1991-11-07 | 1992-11-03 | A method of producing starch based-biodegradable thermoplastic compositions comprising plasticised polyvinylalcohol |
| PCT/EP1992/002517 WO1993009171A1 (en) | 1991-11-07 | 1992-11-03 | Method of producing plasticised polyvinyl alcohol, and its use |
| FI942097A FI942097L (fi) | 1991-11-07 | 1992-11-03 | Menetelmä pehmitetyn polyvinyylialkoholin valmistamiseksi ja sen käyttö |
| CN92114307.9A CN1073457A (zh) | 1991-11-07 | 1992-11-06 | 生产增塑聚乙烯醇的方法及其用于制备淀粉基可生物降解的热塑性组合物 |
| NO941700A NO941700D0 (no) | 1991-11-07 | 1994-05-06 | Fremgangsmåte for fremstilling av mykgjort polyvinylalkohol |
| US08/280,150 US5462981A (en) | 1991-11-07 | 1994-07-25 | Method of producing plasticized polyvinyl alcohol and its use for the preparation of starch-based, biodegradable thermoplastic compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITTO910849A IT1250045B (it) | 1991-11-07 | 1991-11-07 | Procedimento per la produzione di alcool polivinilico plastificato e suo impiego per la preparazione di composizioni termoplastiche biodegradabili a base di amido. |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITTO910849A0 ITTO910849A0 (it) | 1991-11-07 |
| ITTO910849A1 ITTO910849A1 (it) | 1993-05-07 |
| IT1250045B true IT1250045B (it) | 1995-03-30 |
Family
ID=11409699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITTO910849A IT1250045B (it) | 1991-11-07 | 1991-11-07 | Procedimento per la produzione di alcool polivinilico plastificato e suo impiego per la preparazione di composizioni termoplastiche biodegradabili a base di amido. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5462981A (it) |
| EP (1) | EP0611382A1 (it) |
| JP (1) | JPH07501090A (it) |
| CN (1) | CN1073457A (it) |
| AU (1) | AU661872B2 (it) |
| CA (1) | CA2123092A1 (it) |
| FI (1) | FI942097L (it) |
| HU (1) | HU213950B (it) |
| IT (1) | IT1250045B (it) |
| NO (1) | NO941700D0 (it) |
| RU (1) | RU94027567A (it) |
| WO (1) | WO1993009171A1 (it) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU6022694A (en) * | 1993-01-08 | 1994-08-15 | Parke, Davis & Company | Biodegradable thermoplastic polymer blend compositions with accelerated biodegradation |
| DE19512252C2 (de) * | 1995-03-31 | 2000-05-31 | Fraunhofer Ges Forschung | Verfahren zur Herstellung von Folien aus Stärke und mit diesem Verfahren hergestellte Folien |
| WO1997009379A1 (en) * | 1995-09-08 | 1997-03-13 | Solplax Limited | Biodegradable plastic material and a method for its manufacture |
| FR2742443B1 (fr) * | 1995-12-15 | 1999-02-19 | Soltec Dev Sa | Compositions thermoplastiques a base d'alcool polyvinylique, procede d'homogeneisation et les produits obtenus |
| DK0947559T3 (da) | 1996-11-05 | 2005-02-14 | Novamont Spa | Biologisk nedbrydelige polymersammensætninger, som indeholder stivelse og en termoplastisk polymer |
| IT1289966B1 (it) * | 1997-02-25 | 1998-10-19 | Cedal Srl | Procedimento a tre stadi per la preparazione di composizioni solide termoplastiche a base polivinilalcol e composizioni stampabili ed |
| DE69841061D1 (de) * | 1997-10-31 | 2009-09-24 | Metabolix Inc | Verwendung von organischen Phosphon- oder Phosphinsäuren, oder von Metall-oxiden oder -hydroxiden, oder von Carbonsäuresalzen eines Metalls als Hitzestabilisatoren für Polyhydroxyalkanoate |
| US6660211B2 (en) | 2001-04-23 | 2003-12-09 | Kimberly-Clark Worldwide, Inc. | Methods of making biodegradable films having enhanced ductility and breathability |
| US6905759B2 (en) * | 2001-04-23 | 2005-06-14 | Kimberly Clark Worldwide, Inc. | Biodegradable films having enhanced ductility and breathability |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7622523B2 (en) | 2002-08-12 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| WO2004014997A2 (en) | 2002-08-12 | 2004-02-19 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| GB0226763D0 (en) * | 2002-11-15 | 2002-12-24 | Polyval Plc | Polyvinyl alcohol composition and film |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| CA2541089C (en) * | 2003-10-06 | 2011-12-06 | Yara International Asa | Method of improving the crushing strength, impact resistance and compressibility of urea, and urea composition |
| US7713451B2 (en) | 2003-10-29 | 2010-05-11 | Prysmian Cavi E Sistemi Energia S.R.L. | Process for manufacturing a water-resistant telecommunication cable |
| GB0410388D0 (en) * | 2004-05-11 | 2004-06-16 | Adept Polymers Ltd | An extrusion process |
| KR100623111B1 (ko) * | 2004-09-21 | 2006-09-19 | 오티스 엘리베이터 컴파니 | 중실체의 도어 프레임 및 이를 구비한 자동 도어 조립체 |
| WO2006037157A1 (en) * | 2004-10-05 | 2006-04-13 | Plantic Technologies Ltd | Mouldable biodegradable polymer |
| US20060214050A1 (en) * | 2004-11-17 | 2006-09-28 | Naeckel Arno T | Disposable variable depth anchor cable pack |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| GB2422150B (en) * | 2005-01-13 | 2009-11-25 | Pvaxx Res & Dev Ltd | PVA-containing compositions |
| CN101218296B (zh) | 2005-07-15 | 2010-12-08 | 埃克森美孚化学专利公司 | 弹性体组合物 |
| CN1935881B (zh) * | 2005-09-21 | 2012-05-09 | 李小鲁 | 水溶性可生物降解材料及其制备方法以及发泡类制品 |
| CN1935883B (zh) * | 2005-09-21 | 2011-06-08 | 李小鲁 | 水溶性可生物降解材料及其制备方法以及膜制品 |
| CN1935886B (zh) * | 2005-09-21 | 2011-09-28 | 李小鲁 | 水溶性可生物降解材料及其制备方法以及注射类成型制品 |
| CN1935882B (zh) * | 2005-09-21 | 2011-07-27 | 李小鲁 | 水溶性可生物降解材料及其制备方法以及片材类成型制品 |
| CN1939965B (zh) * | 2005-09-30 | 2012-05-09 | 李小鲁 | 疏水性可生物降解材料及其制备方法以及片材类成型制品 |
| CN1939967B (zh) * | 2005-09-30 | 2010-09-29 | 李小鲁 | 疏水性可生物降解材料及其制备方法以及发泡类制品 |
| CN1939966B (zh) * | 2005-09-30 | 2010-11-03 | 李小鲁 | 疏水性可生物降解材料及其制备方法以及膜制品 |
| CN1939968B (zh) * | 2005-09-30 | 2011-11-09 | 李小鲁 | 疏水性可生物降解材料及其制备方法以及注射类成型制品 |
| CN104945683A (zh) * | 2006-04-18 | 2015-09-30 | 普朗蒂克科技有限公司 | 聚合物膜 |
| DE102006024568A1 (de) * | 2006-05-23 | 2007-12-06 | Huhtamaki Forchheim Zweigniederlassung Der Huhtamaki Deutschland Gmbh & Co. Kg | Verfahren zur Herstellung einer biologisch abbaubaren Kunststofffolie und Folie |
| ITMI20062374A1 (it) * | 2006-12-12 | 2008-06-13 | Novamont Spa | Materiale biodegradabile per stampaggio a iniezione ed articoli da esso ottenuti |
| ITMI20062375A1 (it) * | 2006-12-12 | 2008-06-13 | Novamont Spa | Composizione biodegradabile avente elevate caratteristiche meccaniche |
| US8592641B2 (en) * | 2006-12-15 | 2013-11-26 | Kimberly-Clark Worldwide, Inc. | Water-sensitive biodegradable film |
| US7781506B2 (en) * | 2007-01-26 | 2010-08-24 | E.I. Du Pont De Nemours And Company | Poly(vinyl alcohol) composition comprising a polyol |
| CN101293994B (zh) * | 2007-04-25 | 2012-05-30 | 河南天冠企业集团有限公司 | 一种多组分可完全降解的聚合物复合材料及其制备方法 |
| US8329977B2 (en) | 2007-08-22 | 2012-12-11 | Kimberly-Clark Worldwide, Inc. | Biodegradable water-sensitive films |
| CN101143936B (zh) * | 2007-09-05 | 2010-05-26 | 哈尔滨工业大学 | 一种完全生物降解的高直链淀粉基薄膜的制备方法 |
| ES2293859B1 (es) * | 2007-09-28 | 2009-04-01 | Plasticos Hidrosolubles, S.L. | Procedimiento para la elaboracion de una granza de polietenol de alta fluidez. |
| FR2934272B1 (fr) * | 2008-07-24 | 2013-08-16 | Roquette Freres | Procede de preparation de compositions a base de matiere amylacee et de polymere synthetique. |
| US8907155B2 (en) | 2010-11-19 | 2014-12-09 | Kimberly-Clark Worldwide, Inc. | Biodegradable and flushable multi-layered film |
| WO2013042104A1 (en) * | 2011-09-25 | 2013-03-28 | Hewlett Packard Indigo B.V. | Blanket tensioning device |
| EP2776513A1 (de) * | 2011-11-12 | 2014-09-17 | QMilch IP GmbH | Verfahren zur herstellung eines milchprotein-kunststoffes (mp - kunststoff) |
| US9327438B2 (en) | 2011-12-20 | 2016-05-03 | Kimberly-Clark Worldwide, Inc. | Method for forming a thermoplastic composition that contains a plasticized starch polymer |
| US9718258B2 (en) | 2011-12-20 | 2017-08-01 | Kimberly-Clark Worldwide, Inc. | Multi-layered film containing a biopolymer |
| CN105037815A (zh) * | 2015-06-25 | 2015-11-11 | 张家港市大能塑料制品有限公司 | 一种适用于手机壳的可降解塑料及其制备方法 |
| CN104945681A (zh) * | 2015-06-25 | 2015-09-30 | 张家港市大能塑料制品有限公司 | 一种可降解塑料及其制备方法 |
| CN105037816A (zh) * | 2015-06-25 | 2015-11-11 | 张家港市大能塑料制品有限公司 | 一种适用于手机壳的抗菌塑料及其制备方法 |
| US10316120B2 (en) * | 2015-09-18 | 2019-06-11 | Aquapak Polymer Limited | Process and apparatus for manufacture of processable polyvinyl alcohol |
| PL3529309T3 (pl) | 2016-10-18 | 2025-06-02 | Kuraray Co., Ltd. | Zastosowanie związku polihydroksylowego jako plastyfikatora poli(alkoholu winylowego) w sposobach druku 3D |
| FR3068633B1 (fr) * | 2017-07-04 | 2019-08-23 | Bostik Sa | Preparation d'une composition adhesive dans une extrudeuse |
| US20220117714A1 (en) * | 2020-10-15 | 2022-04-21 | Zinpro Corporation | Biodegradable wrap for veterinary use, especially leg wraps for cattle |
| CN112679893B (zh) * | 2020-11-24 | 2022-02-01 | 常州绿之源高分子材料有限公司 | 一种高强度常温不溶pva购物袋 |
| WO2025154704A1 (ja) * | 2024-01-15 | 2025-07-24 | 三菱ケミカル株式会社 | 樹脂組成物、フィルム又はシート、及び多層構造体 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2127896A (en) * | 1936-08-13 | 1938-08-23 | Vohrer Herbert | Method of producing elastic objects from polyvinyl alcohols |
| GB1003178A (en) * | 1961-05-27 | 1965-09-02 | Kurashiki Rayon Kk | Method of manufacturing water soluble film |
| US3312641A (en) * | 1963-06-19 | 1967-04-04 | Staley Mfg Co A E | Polyvinyl alcohol plasticized amylose compositions |
| NL128915C (it) * | 1966-01-29 | |||
| US4007152A (en) * | 1974-05-30 | 1977-02-08 | Toray Industries, Inc. | Sealing material for preventing water-leakage and method of manufacturing same |
| US3949145A (en) * | 1975-02-27 | 1976-04-06 | The United States Of America As Represented By The Secretary Of Agriculture | Degradable starch-based agricultural mulch film |
| DE2964688D1 (en) * | 1978-03-23 | 1983-03-17 | Hoechst Ag | Polyvinyl alcohol pellets containing a plasticizer, and method for their preparation |
| GB2214918B (en) * | 1988-02-03 | 1992-10-07 | Warner Lambert Co | Polymeric materials made from starch and at least one synthetic thermoplastic polymeric material |
| IL93620A0 (en) * | 1989-03-09 | 1990-12-23 | Butterfly Srl | Biodegradable articles based on starch and process for producing them |
| IT1233599B (it) * | 1989-05-30 | 1992-04-06 | Butterfly Srl | Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione |
| IT1232910B (it) * | 1989-08-07 | 1992-03-05 | Butterfly Srl | Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione |
| IT1232909B (it) * | 1989-08-07 | 1992-03-05 | Butterfly Srl | Composizione polimerica per la produzione di articoli di materiale plastico biodegradabile comprendente amido destrutturato e copolimero di etilene |
| DE4117628C3 (de) * | 1991-05-29 | 1999-02-11 | Inventa Ag | Verfahren und Vorrichtung zur Herstellung von Stärkeschmelze sowie nach diesem Verfahren erhältliche Produkte |
-
1991
- 1991-11-07 IT ITTO910849A patent/IT1250045B/it active IP Right Grant
-
1992
- 1992-11-03 FI FI942097A patent/FI942097L/fi not_active Application Discontinuation
- 1992-11-03 RU RU94027567/04A patent/RU94027567A/ru unknown
- 1992-11-03 HU HU9401394A patent/HU213950B/hu not_active IP Right Cessation
- 1992-11-03 CA CA002123092A patent/CA2123092A1/en not_active Abandoned
- 1992-11-03 JP JP5508161A patent/JPH07501090A/ja active Pending
- 1992-11-03 WO PCT/EP1992/002517 patent/WO1993009171A1/en not_active Ceased
- 1992-11-03 AU AU29088/92A patent/AU661872B2/en not_active Ceased
- 1992-11-03 EP EP92922965A patent/EP0611382A1/en not_active Withdrawn
- 1992-11-06 CN CN92114307.9A patent/CN1073457A/zh active Pending
-
1994
- 1994-05-06 NO NO941700A patent/NO941700D0/no unknown
- 1994-07-25 US US08/280,150 patent/US5462981A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ITTO910849A0 (it) | 1991-11-07 |
| AU661872B2 (en) | 1995-08-10 |
| HU9401394D0 (en) | 1994-08-29 |
| CA2123092A1 (en) | 1993-05-13 |
| NO941700L (no) | 1994-05-06 |
| WO1993009171A1 (en) | 1993-05-13 |
| FI942097A7 (fi) | 1994-06-03 |
| NO941700D0 (no) | 1994-05-06 |
| FI942097A0 (fi) | 1994-05-06 |
| CN1073457A (zh) | 1993-06-23 |
| AU2908892A (en) | 1993-06-07 |
| HU213950B (en) | 1997-11-28 |
| FI942097L (fi) | 1994-06-03 |
| US5462981A (en) | 1995-10-31 |
| ITTO910849A1 (it) | 1993-05-07 |
| RU94027567A (ru) | 1996-04-20 |
| JPH07501090A (ja) | 1995-02-02 |
| EP0611382A1 (en) | 1994-08-24 |
| HUT68005A (en) | 1995-05-29 |
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