IT1251686B - Processo per l'allontanamento del cadmio da soluzioni di acido fosforico. - Google Patents
Processo per l'allontanamento del cadmio da soluzioni di acido fosforico.Info
- Publication number
- IT1251686B IT1251686B ITMI912704A IT1251686B IT 1251686 B IT1251686 B IT 1251686B IT MI912704 A ITMI912704 A IT MI912704A IT 1251686 B IT1251686 B IT 1251686B
- Authority
- IT
- Italy
- Prior art keywords
- phosphoric acid
- cadmium
- acid solutions
- removal
- addition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G11/00—Compounds of cadmium
- C01G11/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/237—Selective elimination of impurities
- C01B25/238—Cationic impurities, e.g. arsenic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B17/00—Obtaining cadmium
- C22B17/04—Obtaining cadmium by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Removal Of Specific Substances (AREA)
- Television Systems (AREA)
- Reduction Or Emphasis Of Bandwidth Of Signals (AREA)
- Measurement And Recording Of Electrical Phenomena And Electrical Characteristics Of The Living Body (AREA)
Abstract
Processo per l'allontanamento del cadmio da soluzioni di acido fosforico provenienti dalla digestione solforica e nitrica delle rocce fosfatiche comprendente le seguenti operazioni fondamentali:- aggiunta alla soluzione di acido fosforico di ioni bromuro, come acido bromidrico o bromuri di metalli alcalini, in quantità comprese tra 100 e 3500 ppm;- aggiunta alla stessa soluzione di almeno un composto polifosfatico condensato in concentrazione compresa fra l'1 e il 5% in peso;- eluizione della miscela così ottenuta attraverso, almeno, due letti di resina a scambio ionico a matrice stirenica divinilbenzenica, ad una temperatura variabile fra 15 e 50°C.
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT91MI2704 IT1251686B (it) | 1991-10-11 | 1991-10-11 | Processo per l'allontanamento del cadmio da soluzioni di acido fosforico. |
| FI921862A FI921862L (fi) | 1991-10-11 | 1992-04-24 | Foerfarande foer avlaegsning av kadium av fosforsyraloesningar |
| CA 2067263 CA2067263A1 (en) | 1991-10-11 | 1992-04-27 | Process for the removal of cadmium from solutions of phosphoric acid |
| ZA923087A ZA923087B (en) | 1991-10-11 | 1992-04-28 | Process for the removal of cadmium from solutions of phosphoric acid |
| EP19920107224 EP0536466B1 (en) | 1991-10-11 | 1992-04-28 | Process for the removal of cadmium from solutions of phosphoric acid |
| AT92107224T ATE132835T1 (de) | 1991-10-11 | 1992-04-28 | Verfahren zur entfernung von kadmium aus phosphorsäurelösungen |
| DE69207542T DE69207542D1 (de) | 1991-10-11 | 1992-04-28 | Verfahren zur Entfernung von Kadmium aus Phosphorsäurelösungen |
| IL10170992A IL101709A (en) | 1991-10-11 | 1992-04-28 | Removal of cadmium from solutions of phosphoric acid |
| OA60202A OA09581A (en) | 1991-10-11 | 1992-04-30 | Process for the removal of cadmium from solutions of phosphoric acid |
| US07/877,866 US5246681A (en) | 1991-10-11 | 1992-05-04 | Process for the removal of cadmium from solutions of phosphoric acid |
| JP11774292A JPH05213608A (ja) | 1991-10-11 | 1992-05-11 | リン酸の溶液からのカドミウムの除去方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT91MI2704 IT1251686B (it) | 1991-10-11 | 1991-10-11 | Processo per l'allontanamento del cadmio da soluzioni di acido fosforico. |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI912704A0 ITMI912704A0 (it) | 1991-10-11 |
| ITMI912704A1 ITMI912704A1 (it) | 1993-04-11 |
| IT1251686B true IT1251686B (it) | 1995-05-19 |
Family
ID=11360857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT91MI2704 IT1251686B (it) | 1991-10-11 | 1991-10-11 | Processo per l'allontanamento del cadmio da soluzioni di acido fosforico. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5246681A (it) |
| EP (1) | EP0536466B1 (it) |
| JP (1) | JPH05213608A (it) |
| AT (1) | ATE132835T1 (it) |
| CA (1) | CA2067263A1 (it) |
| DE (1) | DE69207542D1 (it) |
| FI (1) | FI921862L (it) |
| IL (1) | IL101709A (it) |
| IT (1) | IT1251686B (it) |
| OA (1) | OA09581A (it) |
| ZA (1) | ZA923087B (it) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69932857T2 (de) * | 1998-12-28 | 2007-03-01 | Toyo Boseki K.K. | Verfahren zur reinigung von phosphorsäure |
| CN100339299C (zh) * | 1998-12-28 | 2007-09-26 | 东洋纺织株式会社 | 精制磷酸的方法 |
| US7731920B2 (en) | 2005-06-03 | 2010-06-08 | Brookhaven Science Associates | System and method for separating tellurium from cadmium waste |
| FR3151032B1 (fr) | 2023-07-12 | 2026-02-27 | Univ Mohammed Vi Polytechnique | Procédé d’élimination de métaux lourds contenus dans les solutions d’acide phosphorique |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3306702A (en) * | 1962-06-18 | 1967-02-28 | Nalco Chemical Co | Removal of metal salt contaminants from acidic aqueous liquids |
| JPS54133495A (en) * | 1978-04-10 | 1979-10-17 | Asahi Chem Ind Co Ltd | Recovering method for liquid phase oxidation catalyst |
| US4511541A (en) * | 1982-12-02 | 1985-04-16 | J. R. Simplot Company | Process for the recovery of cadmium and other metals from solution |
| NL8601101A (nl) * | 1986-04-29 | 1987-11-16 | Unie Van Kunstmestfab Bv | Werkwijze voor het verwijderen van cadmium uit zure, fosfaathoudende waterige media. |
| US4877594A (en) * | 1988-12-13 | 1989-10-31 | J. R. Simplot Co. | Purification of phosphoric acid |
-
1991
- 1991-10-11 IT IT91MI2704 patent/IT1251686B/it active IP Right Grant
-
1992
- 1992-04-24 FI FI921862A patent/FI921862L/fi not_active Application Discontinuation
- 1992-04-27 CA CA 2067263 patent/CA2067263A1/en not_active Abandoned
- 1992-04-28 ZA ZA923087A patent/ZA923087B/xx unknown
- 1992-04-28 IL IL10170992A patent/IL101709A/en not_active IP Right Cessation
- 1992-04-28 DE DE69207542T patent/DE69207542D1/de not_active Expired - Lifetime
- 1992-04-28 EP EP19920107224 patent/EP0536466B1/en not_active Expired - Lifetime
- 1992-04-28 AT AT92107224T patent/ATE132835T1/de not_active IP Right Cessation
- 1992-04-30 OA OA60202A patent/OA09581A/en unknown
- 1992-05-04 US US07/877,866 patent/US5246681A/en not_active Expired - Fee Related
- 1992-05-11 JP JP11774292A patent/JPH05213608A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI912704A0 (it) | 1991-10-11 |
| EP0536466B1 (en) | 1996-01-10 |
| OA09581A (en) | 1993-01-31 |
| ZA923087B (en) | 1993-04-28 |
| ITMI912704A1 (it) | 1993-04-11 |
| IL101709A (en) | 1995-12-31 |
| DE69207542D1 (de) | 1996-02-22 |
| FI921862A0 (fi) | 1992-04-24 |
| US5246681A (en) | 1993-09-21 |
| ATE132835T1 (de) | 1996-01-15 |
| FI921862A7 (fi) | 1993-04-12 |
| JPH05213608A (ja) | 1993-08-24 |
| EP0536466A1 (en) | 1993-04-14 |
| FI921862L (fi) | 1993-04-12 |
| CA2067263A1 (en) | 1993-04-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 0001 | Granted | ||
| TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19971014 |