IT1256800B - Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento. - Google Patents

Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.

Info

Publication number
IT1256800B
IT1256800B ITTO920079A ITTO920079A IT1256800B IT 1256800 B IT1256800 B IT 1256800B IT TO920079 A ITTO920079 A IT TO920079A IT TO920079 A ITTO920079 A IT TO920079A IT 1256800 B IT1256800 B IT 1256800B
Authority
IT
Italy
Prior art keywords
procedure
polyols
production
catalyst
catalyst used
Prior art date
Application number
ITTO920079A
Other languages
English (en)
Inventor
Bruno Casale
Original Assignee
Novamont Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novamont Spa filed Critical Novamont Spa
Publication of ITTO920079A0 publication Critical patent/ITTO920079A0/it
Priority to ITTO920079A priority Critical patent/IT1256800B/it
Priority to EP93101313A priority patent/EP0553815B1/en
Priority to DK93101313.0T priority patent/DK0553815T3/da
Priority to DE69314506T priority patent/DE69314506T2/de
Priority to US08/010,564 priority patent/US5403805A/en
Priority to ES93101313T priority patent/ES2109379T3/es
Priority to AT93101313T priority patent/ATE159187T1/de
Publication of ITTO920079A1 publication Critical patent/ITTO920079A1/it
Priority to US08/376,802 priority patent/US5600028A/en
Application granted granted Critical
Publication of IT1256800B publication Critical patent/IT1256800B/it
Priority to US08/832,763 priority patent/USRE37329E1/en
Priority to GR980400004T priority patent/GR3025830T3/el

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Catalizzatore di idrogenazione a base di rutenio su carbone attivo, particolarmente adatto per l'idrogenolisi sotto pressione di polioli superiori, comprendente rutenio supportato su carbone attivo granulare e detto catalizzatore presentante:- una superficie specifica da 600 a 1000 m2/gr;- un volume totale dei pori da 0,5 e 1,2 cm3/gr;- un peso specifico apparente (bulk density) da 0,45 a 0,55 gr/cm3;- un peso specifico reale da 1,9 a 2,3 gr/cm3;- un volume totale dei micropori avente raggio inferiore a 75 A da 0,4 a 0,55 cm3/gr, e - un contenuto di ceneri da 2 a 5% in peso.Il catalizzatore è impiegato in un procedimento per la produzione in continuo, in reattore a letto fisso, di polioli inferiori, mediante idrogenolisi sotto pressione di polioli superiori.
ITTO920079A 1992-01-31 1992-01-31 Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento. IT1256800B (it)

Priority Applications (10)

Application Number Priority Date Filing Date Title
ITTO920079A IT1256800B (it) 1992-01-31 1992-01-31 Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.
US08/010,564 US5403805A (en) 1992-01-31 1993-01-28 Ruthenium-based catalyst for producing lower polyhydric alcohols
DK93101313.0T DK0553815T3 (da) 1992-01-31 1993-01-28 Fremgangsmåde til fremstilling af lavere polyvalente alkoholer og en ny ruthenium-baseret katalysator anvendt i denne fremgangsmåde
DE69314506T DE69314506T2 (de) 1992-01-31 1993-01-28 Verfahren zur Herstellung niederer mehrwertiger Alkohole und neuer Katalysator auf Grund von Ruthenium verwendbar für dieses Verfahren
EP93101313A EP0553815B1 (en) 1992-01-31 1993-01-28 A method for producing lower polyhydric alcohols and a new ruthenium-based catalyst used in this method
ES93101313T ES2109379T3 (es) 1992-01-31 1993-01-28 Un metodo para producir alcoholes polihidricos inferiores y un nuevo catalizador a base de rutenio utilizado en este metodo.
AT93101313T ATE159187T1 (de) 1992-01-31 1993-01-28 Verfahren zur herstellung niederer mehrwertiger alkohole und neuer katalysator auf grund von ruthenium verwendbar für dieses verfahren
US08/376,802 US5600028A (en) 1992-01-31 1995-01-23 Method for producing lower polyhydric alcohols and a new ruthenium-based catalyst used in this method
US08/832,763 USRE37329E1 (en) 1992-01-31 1997-04-04 Ruthenium-based catalyst for producing lower polyhydric alcohols
GR980400004T GR3025830T3 (en) 1992-01-31 1998-01-07 A method for producing lower polyhydric alcohols and a new ruthenium-based catalyst used in this method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITTO920079A IT1256800B (it) 1992-01-31 1992-01-31 Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.

Publications (3)

Publication Number Publication Date
ITTO920079A0 ITTO920079A0 (it) 1992-01-31
ITTO920079A1 ITTO920079A1 (it) 1993-07-31
IT1256800B true IT1256800B (it) 1995-12-15

Family

ID=11409987

Family Applications (1)

Application Number Title Priority Date Filing Date
ITTO920079A IT1256800B (it) 1992-01-31 1992-01-31 Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.

Country Status (8)

Country Link
US (3) US5403805A (it)
EP (1) EP0553815B1 (it)
AT (1) ATE159187T1 (it)
DE (1) DE69314506T2 (it)
DK (1) DK0553815T3 (it)
ES (1) ES2109379T3 (it)
GR (1) GR3025830T3 (it)
IT (1) IT1256800B (it)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1256800B (it) * 1992-01-31 1995-12-15 Novamont Spa Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.
US5356849A (en) * 1993-01-21 1994-10-18 Calgon Carbon Corporation Catalytic carbon
US5444031A (en) * 1993-01-21 1995-08-22 Calgon Carbon Corporation Process for making catalytic carbon
US5543398A (en) * 1995-08-31 1996-08-06 International Flavors & Fragrances Inc. Para-C5 alkyl-substituted ethoxycyclohexanes, organoleptic uses thereof and processes for preparing same
US5610133A (en) * 1995-08-31 1997-03-11 International Flavors & Fragrances Inc. Alkyl-substituted-C1 -C3 alkoxy-C6 -cycloaliphatic compounds, organoleptic uses thereof and processes for preparing same
IN191521B (it) * 1996-04-02 2003-12-06 Du Pont
US6403844B1 (en) 1998-11-24 2002-06-11 Board Of Trustees Of Michigan State University Condensed phase catalytic hydrogenation of lactic acid to propylene glycol
US6291725B1 (en) * 2000-03-03 2001-09-18 Board Of Trustees Operating Michigan State University Catalysts and process for hydrogenolysis of sugar alcohols to polyols
EP1292556B1 (en) 2000-06-20 2004-01-07 E.I. Dupont De Nemours And Company Catalytic dehydroxylation of diols and polyols
GB0022895D0 (en) * 2000-09-19 2000-11-01 Johnson Matthey Plc Anode structure
US6841085B2 (en) 2001-10-23 2005-01-11 Battelle Memorial Institute Hydrogenolysis of 6-carbon sugars and other organic compounds
US6479713B1 (en) 2001-10-23 2002-11-12 Battelle Memorial Institute Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen
ITMI20030971A1 (it) * 2003-05-15 2004-11-16 Solvay Solexis Spa Preparazione di perfluoropolieteri aventi almeno un terminale -ch2oh oppure -ch(cf3)oh.
GB0325386D0 (en) * 2003-10-30 2003-12-03 Davy Process Techn Ltd Process
US8450542B2 (en) * 2005-12-16 2013-05-28 Phillips 66 Company Integrated process for converting carbohydrates to hydrocarbons
US7678950B2 (en) * 2005-12-16 2010-03-16 Conocophillips Company Process for converting carbohydrates to hydrocarbons
CN101346302B (zh) * 2005-12-21 2013-07-10 维仁特公司 用于重整含氧化合物的催化剂及方法
RU2455338C2 (ru) 2006-03-24 2012-07-10 Висконсин Эламнай Рисерч Фаундейшн Способ получения биотоплива, где теплоту от реакций образования углерод-углеродных связей используют для проведения реакций газификации биомассы
CN103360205A (zh) 2006-05-08 2013-10-23 维仁特公司 用于生成多元醇的方法和系统
US20080103340A1 (en) * 2006-10-27 2008-05-01 Archer-Daniels-Midland Company Applications of biobased glycol compositions
CA2671730A1 (en) 2006-12-20 2008-11-20 Virent Energy Systems, Inc. Reactor system for producing gaseous products
US20100094066A1 (en) * 2007-01-17 2010-04-15 The Curators Of The University Of Missouri Gas phase reaction process for polyhydric compounds
CN101012387B (zh) * 2007-02-01 2011-05-11 淮北中润生物能源技术开发有限公司 高效纤维素生物质生产液体燃料工艺
US7977517B2 (en) 2007-03-08 2011-07-12 Virent Energy Systems, Inc. Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
NZ591808A (en) * 2008-08-27 2012-12-21 Virent Inc Synthesis of C6+ alkanes from saccharides utilising multistage catalytic processes
US8252963B2 (en) * 2009-06-09 2012-08-28 University Of Kansas Nano-metal catalysts for polyol hydrogenolysis
MX2011013988A (es) * 2009-06-30 2012-09-07 Virent Inc Proceso y sistemas de reactores para convertir azucares y alcoholes sacarosos.
DE102009051462B4 (de) 2009-10-30 2015-02-05 Clariant International Ag Verfahren zur Herstellung eines Kompositmaterials, Kompositmaterial und dessen Verwendung
CN101966457B (zh) * 2010-09-25 2012-07-25 郴州高鑫铂业有限公司 一种高活性羰基加氢钌炭催化剂的制备方法
CN102463111B (zh) * 2010-11-04 2014-05-21 中国石油化工股份有限公司 一种山梨醇氢解催化剂的制备方法
CN102464572B (zh) * 2010-11-04 2015-08-12 中国石油化工股份有限公司 一种山梨醇氢解的方法
CN103041806B (zh) * 2011-10-17 2015-04-15 中国石油化工股份有限公司 Ru/C催化剂的制备方法和甘油氢解的方法
US20130102819A1 (en) 2011-10-19 2013-04-25 Normen Szesni Catalyst composition for selective hydrogenation with improved characteristics
CN103357427B (zh) * 2013-07-31 2015-03-25 合肥工业大学 一种纳米金属/固体碱复合催化剂、其制备方法及其用途
CN105517983B (zh) * 2013-08-26 2018-08-10 国际壳牌研究有限公司 制备二醇类的方法
EP3110541B1 (en) 2014-02-10 2020-11-18 Archer-Daniels-Midland Company Improved multiphase low mixing processes
WO2016126671A1 (en) * 2015-02-03 2016-08-11 Archer Daniels Midland Company One vessel process for making 1,2-propanediol from a high fructose feedstock
JP2016159256A (ja) * 2015-03-04 2016-09-05 株式会社クレハ 触媒複合体
CN105195188B (zh) * 2015-09-29 2017-09-05 中国石油大学(北京) 镍‑碳化钨/多孔碳纳米纤维复合催化剂及中间体与制备
GB2630272B (en) 2023-05-15 2025-07-02 Johnson Matthey Plc Ruthenium eggshell catalyst

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2868847A (en) * 1956-10-05 1959-01-13 Engelhard Ind Inc Hydrogenation of mono-and disaccharides to polyols
NL7502968A (nl) * 1975-03-13 1976-09-15 Stamicarbon Werkwijze voor het bereiden van edelmetaal- katalysatoren.
US3978000A (en) * 1975-03-19 1976-08-31 American Cyanamid Company Catalysts based on carbon supports
US4111842A (en) * 1977-06-01 1978-09-05 Stamicarbon, B.V. Process for the preparation of supported catalysts
GB2034292B (en) * 1978-10-12 1982-11-10 British Petroleum Co Production of ammonia
DE3227327A1 (de) * 1981-07-28 1983-02-17 Institut Français du Pétrole, 92502 Rueil-Malmaison, Hauts-de-Seine Verfahren zur herstellung von methan durch katalytische reduktion von kohlenoxiden in waessriger phase
CA1219285A (en) * 1981-09-30 1987-03-17 Union Carbide Corporation Hydrogenolysis process for the production of monoethylene glycol monomethyl ether, monoethylene glycol and ethanol
US4430253A (en) * 1982-02-11 1984-02-07 Ethyl Corporation Sulfide-modified ruthenium catalyst
US4476331A (en) * 1982-02-11 1984-10-09 Ethyl Corporation Two stage hydrogenolysis of carbohydrate to glycols using sulfide modified ruthenium catalyst in second stage
US4496780A (en) * 1983-06-22 1985-01-29 Uop Inc. Hydrocracking of polyols
US4560672A (en) * 1984-06-04 1985-12-24 The Standard Oil Company Ruthenium-copper-containing, activated-carbon-supported catalyst and process for making alcohol using same
US4591578A (en) * 1985-02-04 1986-05-27 American Cyanamid Company Catalyst of molybdenum on wide-pore carbon support
IT1256800B (it) * 1992-01-31 1995-12-15 Novamont Spa Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.

Also Published As

Publication number Publication date
ITTO920079A1 (it) 1993-07-31
ITTO920079A0 (it) 1992-01-31
EP0553815A1 (en) 1993-08-04
US5403805A (en) 1995-04-04
DE69314506T2 (de) 1998-03-12
EP0553815B1 (en) 1997-10-15
USRE37329E1 (en) 2001-08-14
DE69314506D1 (de) 1997-11-20
DK0553815T3 (da) 1998-01-26
US5600028A (en) 1997-02-04
GR3025830T3 (en) 1998-04-30
ATE159187T1 (de) 1997-11-15
ES2109379T3 (es) 1998-01-16

Similar Documents

Publication Publication Date Title
ITTO920079A1 (it) Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.
GB8310797D0 (en) Vapour phase hydrogenation of esters
ZA954428B (en) Process for the separation of catalyst-free working solution from the hydrogenation circuit of the anthraquinone process for the manufacture of hydrogen peroxide
CA2057184A1 (en) Active carbon materials, process for the preparation thereof and the use thereof
ATE161866T1 (de) Selektive, die porengrösse betreffende chemische modifikation poröser materialien
AU8832191A (en) Hydrogen and carbon monoxide production by hydrocarbon steam reforming and pressure swing adsorption purification
CA2207527A1 (en) Method of producing a chemical compound
ES2016658B3 (es) Procedimiento mejorado para la hidrogenacion selectiva de acetilenos.
AU1556888A (en) Hydrogenation catalyst
GB0226514D0 (en) Fischer-tropsch catalysts
EP0192314A3 (en) Process for the catalytic reforming of hydrocarbons, and catalyst carrier therefor
EG19591A (en) Process for the preparation of hydrocarbons
EP0324190A3 (en) Process for the production of 4,4'-diamino-dicyclohexylmethane with a low trans-trans isomer content by the catalytic hydrogenation of 4,4'-diaminodiphenylmethane
KR910011716A (ko) 1,1-디클로로-1-플루오로에탄으로부터 비닐리덴 클로라이드의 제거방법
GB1333665A (en) Hydrogenation of hydrocarbons
SG77102A1 (en) Hydroconversion catalyst
TW276246B (it)
GB1513853A (en) Hydrogenation of olefine polymers
MY129982A (en) Catalyst and process for the catalytic partial oxidation of hydrocarbons.
GR3002130T3 (en) High macropore selective hydrogenation catalyst
NL7214647A (en) Hydro-desulphurising residual hydrocarbons - on catalysts with pore diameter and particle size related to hydrogen pressure
CA2037169A1 (en) System for the distribution of gas in catalytic beds and for the support with minimum dimensions of the catalyst in reactors for heterogeneous synthesis
EP0208303A3 (en) Process and apparatus for the anaerobic biological treatment of organic polluted liquids and/or liquid-solid mixtures
CA2078966A1 (en) Process for elimination of low concentrations of hydrogen sulfide in gas mixtures by catalytic oxidation
RU96120382A (ru) Способ получения активных углей

Legal Events

Date Code Title Description
0001 Granted
TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19970128