ITUA20163932A1 - Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati - Google Patents

Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Info

Publication number
ITUA20163932A1
ITUA20163932A1 ITUA2016A003932A ITUA20163932A ITUA20163932A1 IT UA20163932 A1 ITUA20163932 A1 IT UA20163932A1 IT UA2016A003932 A ITUA2016A003932 A IT UA2016A003932A IT UA20163932 A ITUA20163932 A IT UA20163932A IT UA20163932 A1 ITUA20163932 A1 IT UA20163932A1
Authority
IT
Italy
Prior art keywords
azotate
bone
iron
complex
polymerization
Prior art date
Application number
ITUA2016A003932A
Other languages
English (en)
Inventor
Guido Pampaloni
Anna Sommazzi
Giovanni Ricci
Francesco Masi
Giuseppe Leone
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Priority to ITUA2016A003932A priority Critical patent/ITUA20163932A1/it
Priority to US16/300,597 priority patent/US20190374932A1/en
Priority to KR1020187028725A priority patent/KR102383025B1/ko
Priority to CA3016659A priority patent/CA3016659C/en
Priority to EA201891812A priority patent/EA037267B1/ru
Priority to PCT/IB2017/053142 priority patent/WO2017208128A1/en
Priority to CN201780026611.5A priority patent/CN109071719B/zh
Priority to BR112018074845-5A priority patent/BR112018074845B1/pt
Publication of ITUA20163932A1 publication Critical patent/ITUA20163932A1/it
Priority to ZA2018/05991A priority patent/ZA201805991B/en
Priority to SA518400113A priority patent/SA518400113B1/ar
Priority to US17/204,570 priority patent/US11872548B2/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003—Bidentate ligand
    • C08F4/7004—Neutral ligand
    • C08F4/7008—NO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/708—Tetra- or multi-dentate ligand
    • C08F4/7081—Neutral ligand
    • C08F4/7083—ONNO
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
ITUA2016A003932A 2016-05-30 2016-05-30 Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati ITUA20163932A1 (it)

Priority Applications (11)

Application Number Priority Date Filing Date Title
ITUA2016A003932A ITUA20163932A1 (it) 2016-05-30 2016-05-30 Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
PCT/IB2017/053142 WO2017208128A1 (en) 2016-05-30 2017-05-29 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
KR1020187028725A KR102383025B1 (ko) 2016-05-30 2017-05-29 옥소-질화된 철 착물, 상기 옥소-질화된 철 착물을 포함하는 촉매 시스템, 및 컨쥬게이션된 디엔의 (공)중합을 위한 방법
CA3016659A CA3016659C (en) 2016-05-30 2017-05-29 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
EA201891812A EA037267B1 (ru) 2016-05-30 2017-05-29 Оксоазотсодержащий комплекс железа, каталитическая система, включающая указанный оксоазотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов
US16/300,597 US20190374932A1 (en) 2016-05-30 2017-05-29 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
CN201780026611.5A CN109071719B (zh) 2016-05-30 2017-05-29 氧代氮化铁络合物、包含其的催化体系以及用于共轭二烯的(共)聚合的工艺
BR112018074845-5A BR112018074845B1 (pt) 2016-05-30 2017-05-29 Complexo de ferro oxo-nitrogenado, sistema catalítico compreendendo o referido complexo de ferro oxo-nitrogenado e processo para a (co)polimerização de dienos conjugados
ZA2018/05991A ZA201805991B (en) 2016-05-30 2018-09-06 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
SA518400113A SA518400113B1 (ar) 2016-05-30 2018-09-26 نظام حفزي يشتمل على معقد حديد معالج بالأوكسونيتروجين
US17/204,570 US11872548B2 (en) 2016-05-30 2021-03-17 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITUA2016A003932A ITUA20163932A1 (it) 2016-05-30 2016-05-30 Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Publications (1)

Publication Number Publication Date
ITUA20163932A1 true ITUA20163932A1 (it) 2017-11-30

Family

ID=57045300

Family Applications (1)

Application Number Title Priority Date Filing Date
ITUA2016A003932A ITUA20163932A1 (it) 2016-05-30 2016-05-30 Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Country Status (9)

Country Link
US (2) US20190374932A1 (it)
KR (1) KR102383025B1 (it)
CN (1) CN109071719B (it)
BR (1) BR112018074845B1 (it)
EA (1) EA037267B1 (it)
IT (1) ITUA20163932A1 (it)
SA (1) SA518400113B1 (it)
WO (1) WO2017208128A1 (it)
ZA (1) ZA201805991B (it)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10981846B1 (en) * 2019-08-16 2021-04-20 The United States Of America, As Represented By The Secretary Of The Navy Producing cyclic fuels from conjugated diene

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6160063A (en) * 1999-12-30 2000-12-12 Bridgestone Corporation Iron-based catalyst for producing binary cis-1,4-/1,2-polybutadiene
US6211313B1 (en) * 1999-11-12 2001-04-03 Bridgestone Corporation Iron-based catalyst composition and process for producing conjugated diene polymers

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IT1231774B (it) 1989-08-03 1991-12-21 Enichem Anic Spa Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine.
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
CA2024830A1 (en) 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
CA2027145C (en) 1989-10-10 2002-12-10 Michael J. Elder Metallocene catalysts with lewis acids and aluminum alkyls
EP0551277B2 (en) 1990-06-22 2005-03-09 ExxonMobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
EP0548274B1 (en) 1990-09-14 1996-02-28 Exxon Chemical Patents Inc. Ionic catalyst for the production of poly-alpha-olefins of controlled tacticity
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5258475A (en) 1991-07-12 1993-11-02 Mobil Oil Corporation Catalyst systems for polymerization and copolymerization of olefins
US6180734B1 (en) 1998-10-14 2001-01-30 Bridgestone Corporation Process for producing syndiotactic 1,2-polybutadiene and iron-based catalyst compositions for use therein
US6284702B1 (en) 1998-10-14 2001-09-04 Bridgestone Corporation Iron-based catalyst composition and process for producing syndiotactic 1,2-polybutadiene
US6277779B1 (en) 1998-10-14 2001-08-21 Bridgestone Corporation Process and iron-based catalyst composition for the production of syndiotactic 1,2-polybutadiene
GB0112023D0 (en) * 2001-05-17 2001-07-11 Bp Chem Int Ltd Polymerisation catalyst
GB0305927D0 (en) * 2003-03-14 2003-04-23 Ic Innovations Ltd Compound
JP5683583B2 (ja) 2009-07-10 2015-03-11 グラフィック パッケージング インターナショナル インコーポレイテッド 容器用パッケージ
ITMI20122201A1 (it) * 2012-12-20 2014-06-21 Versalis Spa Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6211313B1 (en) * 1999-11-12 2001-04-03 Bridgestone Corporation Iron-based catalyst composition and process for producing conjugated diene polymers
US6160063A (en) * 1999-12-30 2000-12-12 Bridgestone Corporation Iron-based catalyst for producing binary cis-1,4-/1,2-polybutadiene

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; SAKAYORI, TAKAFUMI ET AL: "Radical polymerization reaction of styrene-based monomers catalyzed by iron complexes bearing .beta.-aminoketonato ligand", XP002763775, retrieved from STN Database accession no. 2015:940732 *

Also Published As

Publication number Publication date
SA518400113B1 (ar) 2021-10-26
WO2017208128A1 (en) 2017-12-07
EA037267B1 (ru) 2021-03-01
WO2017208128A8 (en) 2018-11-01
KR20190015189A (ko) 2019-02-13
CN109071719B (zh) 2021-07-30
US20210245145A1 (en) 2021-08-12
BR112018074845B1 (pt) 2022-08-30
CN109071719A (zh) 2018-12-21
EA201891812A1 (ru) 2019-06-28
US11872548B2 (en) 2024-01-16
US20190374932A1 (en) 2019-12-12
ZA201805991B (en) 2019-12-18
BR112018074845A2 (pt) 2019-03-19
KR102383025B1 (ko) 2022-04-04
CA3016659A1 (en) 2017-12-07

Similar Documents

Publication Publication Date Title
IT201600105714A1 (it) Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso piridilico di ferro(iii)
EP3528716A4 (en) OSTEOTOMY SYSTEMS, DEVICES AND METHODS
EP3386440A4 (en) DEVICES, SYSTEMS AND METHOD FOR FORMING A HEADLOCK RING
EP3439412A4 (en) METHOD FOR CONFIGURING AND SENDING A PREAMBLE AND APPROPRIATE DEVICES
WO2015161054A3 (en) Methods and systems for nucleic acid amplification
HK1253348A1 (zh) 用於遗传变异的非侵入性评估的方法和过程
IL264322A (en) Systems and methods for targeted deep hyperthermia by time-shared rf inductive applicators
ITUB20160977A1 (it) Sistema di apertura ed erogazione per contenitori pre-riempiti, relativi contenitori pre-riempiti e procedimenti per la loro realizzazione
DK3515918T3 (da) Fremgangsmåde til fremstilling af 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptan
FR3044663B1 (fr) Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene.
EP3734470A4 (en) DESTINATION PROPOSAL SYSTEM, PROPOSAL SYSTEM AND PROPOSAL PROCESS
ZA201802338B (en) Vanadium pyridine-imine complex, catalytic system comprising said vanadium pyridine-immine complex and a (co) polymerization process of conjugated dienes
ZA201700837B (en) Pyridine complex of zirconium, catalytic system comprising said pyridine complex of zirconium and process of (co)polymerization of conjugated dienes
PL3277421T3 (pl) Katalizator odwodornienia i sposób stosowania tego katalizatora
ZA201807579B (en) Catalyst for the hydroformylation of olefins, and use thereof
IT201700109176A1 (it) Complesso bis-imminico di titanio, sistema catalitico comprendente detto complesso bis-imminico di titanio e procedimento per la (co)polimerizzazione di dieni coniugati
PL3596443T3 (pl) Urządzenia, systemy i sposoby do analizowania gazu rozpuszczonego
IT201700057307A1 (it) Sistema ip-gpio, apparecchiatura e procedimento corrispondenti
IT201700006307A1 (it) Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
PL3237463T3 (pl) Okso-nitrowany kompleks wanadowy, układ katalityczny zawierający ten okso-nitrowany kompleks wanadowy i sposób (co)polimeryzacji sprzężonych dienów
PL3335791T3 (pl) Układ katalizatorów i sposób, w którym stosuje się układ katalizatorów
ITUB20152581A1 (it) Complesso azotato di titanio, sistema catalitico comprendente detto complesso azotato di titanio e procedimento per la (co)polimerizzazione di dieni coniugati
GB201615271D0 (en) Proximity detection utilising location beacons
ZA201701180B (en) Phosphinic vanadium complex, catalytic system comprising said phosphinic vanadium complex and process for the (co) polymerization of conjugated dienes
ZA201805991B (en) Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes