JOP20170146B1 - طريقة لإنتاج كبريتات الكالسيوم - Google Patents

طريقة لإنتاج كبريتات الكالسيوم

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Publication number
JOP20170146B1
JOP20170146B1 JOP/2017/0146A JOP20170146A JOP20170146B1 JO P20170146 B1 JOP20170146 B1 JO P20170146B1 JO P20170146 A JOP20170146 A JO P20170146A JO P20170146 B1 JOP20170146 B1 JO P20170146B1
Authority
JO
Jordan
Prior art keywords
calcium sulphate
slurry
aqueous phase
free
dcp
Prior art date
Application number
JOP/2017/0146A
Other languages
English (en)
Inventor
Thomas Henry
Tibaut THEYS
Original Assignee
Prayon Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Prayon Tech filed Critical Prayon Tech
Publication of JOP20170146A1 publication Critical patent/JOP20170146A1/ar
Application granted granted Critical
Publication of JOP20170146B1 publication Critical patent/JOP20170146B1/ar

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/18—Phosphoric acid
    • C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
    • C01B25/2208—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with an acid or a mixture of acids other than sulfuric acid
    • C01B25/2212—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with an acid or a mixture of acids other than sulfuric acid with hydrochloric acid or hydrogen chloride in aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/18—Phosphoric acid
    • C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
    • C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
    • C01B25/228—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen one form of calcium sulfate being formed and then converted to another form
    • C01B25/231—Dihydrate-hemihydrate process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/32—Phosphates of magnesium, calcium, strontium, or barium
    • C01B25/324—Preparation from a reaction solution obtained by acidifying with an acid other than orthophosphoric acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/46—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/46—Sulfates
    • C01F11/466—Conversion of one form of calcium sulfate to another
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B11/00—Calcium sulfate cements
    • C04B11/26—Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B11/00—Calcium sulfate cements
    • C04B11/26—Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke
    • C04B11/266—Chemical gypsum
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C01P2006/82—Compositional purity water content

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

يتعلق الاختراع الحالي بطريقة لتحضير كبريتات الكالسيوم تتضمن إنتاج DCP بمهاجمة مصدر فوسفات بحمض واستيعاب DCP المنعزل بحمض الكبريتيك في ظل ظروف تسمح بتكوين مادة أولى من الجبس المعلق في طور مائي حمض يحتوي على أقل من أو ما يعادل 1.5 % من SO3 الحُر ويحتوي على P2O5 الحُر، وتحويل جزء على الأقل من المادة الأولى المذكورة بالتسخين إلى ما يزيد على 80 درجة مئوية واحتمال إضافة حمض الكبريتيك مع ذوبان بلورات الجبس وإعادة تبلور كبريتات الكالسيوم المذابة في مادة ثانية من ?-نصف هيدرات كبريتات الكالسيوم المعلقة في طور مائي يحتوي على قاعدة حمض الفسفوريك حيث يقل محتوى SO3 عن 10% بالوزن، وفصل الطور المائي المذكور وقالب المرشح القائم على andalpha;-نصف هيدرات كبريتات الكالسيوم النقي على وجه الخصوص.
JOP/2017/0146A 2016-06-23 2017-06-20 طريقة لإنتاج كبريتات الكالسيوم JOP20170146B1 (ar)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE2016/5463A BE1023754B1 (fr) 2016-06-23 2016-06-23 Procede de production de sulfate de calcium

Publications (2)

Publication Number Publication Date
JOP20170146A1 JOP20170146A1 (ar) 2019-01-30
JOP20170146B1 true JOP20170146B1 (ar) 2021-08-17

Family

ID=56511279

Family Applications (1)

Application Number Title Priority Date Filing Date
JOP/2017/0146A JOP20170146B1 (ar) 2016-06-23 2017-06-20 طريقة لإنتاج كبريتات الكالسيوم

Country Status (11)

Country Link
US (1) US10662072B2 (ar)
EP (1) EP3475221B1 (ar)
CN (1) CN109476484B (ar)
BE (1) BE1023754B1 (ar)
EA (1) EA038221B1 (ar)
JO (1) JOP20170146B1 (ar)
PL (1) PL3475221T3 (ar)
RS (1) RS61355B1 (ar)
SA (1) SA117380751B1 (ar)
WO (1) WO2017220718A1 (ar)
ZA (1) ZA201808559B (ar)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2020001482A (es) * 2017-08-11 2020-08-20 Prayon Tech Proceso de ataque con acido de una fuente de fosfato.
CN110282998A (zh) * 2019-08-01 2019-09-27 陶合体科技(苏州)有限责任公司 基于硫酸钙盐包覆的磷酸钙多孔陶瓷及其制备方法
JP6964300B2 (ja) * 2019-10-15 2021-11-10 静岡県 廃石膏ボードの石膏を利用したリン回収技術
DE102020100249A1 (de) 2020-01-08 2021-07-08 Thyssenkrupp Ag Integriertes Verfahren zur kommerziellen und industriellen Verwertung von Kalziumsulfat unter Gewinnung von Seltenen Erden aus der Phosphorsäureproduktion
DE102020100241A1 (de) 2020-01-08 2021-07-08 Thyssenkrupp Ag Verfahren zur Herstellung von Phosphorsäure und Klinkerprozess-geeigneter Kalziumsulfatqualität zur kommerziellen und industriellen Verwertung von Kalziumsulfat
CN111362605B (zh) * 2020-04-29 2022-01-28 太原科技大学 利用工业副产石膏生产α型半水石膏的生产设备和方法
CN113443614A (zh) * 2021-07-14 2021-09-28 东华工程科技股份有限公司 一种二水-半水湿法浸提磷酸工艺中二水硫酸钙转化α-半水硫酸钙的方法
RU2768022C1 (ru) * 2021-08-02 2022-03-23 Тураев Дмитрий Юрьевич Способ получения кислых и среднего фосфатов кальция
WO2023126349A1 (fr) 2021-12-27 2023-07-06 Prayon Méthode de purification d'au moins une solution aqueuse d'acide phosphorique
CN116040662B (zh) * 2022-01-09 2024-08-27 四川大学 硝酸法富集磷矿脱镁液的综合回收利用方法
CN115724453B (zh) * 2022-12-12 2024-02-23 新希望化工投资有限公司 一种磷酸铁母液的净化回收方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2013970A (en) 1933-02-10 1935-09-10 U S Phosphoric Products Corp Process of producing phosphoric acid and derivatives of the same
IL23004A (en) * 1964-02-27 1969-03-27 Fosindus Co Process for the purification of residual gypsum produced in the manufacture of phosphoric acid by the reaction of sulphuric acid with natural phosphates
KR810000069B1 (ko) 1975-11-24 1981-02-12 쌔디이어스 에스 스넬 인산염광물 함유 물질로부터 인산염을 회수하는 방법
FR2409230A1 (fr) * 1977-11-16 1979-06-15 Rhone Poulenc Ind Procede de fabrication d'acide phosphorique
LU84713A1 (fr) * 1983-03-25 1984-11-14 Prayon Soc Procede et preparation d'acide phosphorique et de sulfate de calcium hemihydrate alpha
ZA989823B (en) * 1998-10-28 1999-07-28 Dirk Guustaaf Mantel Treatment of phospho gypsum
BE1015840A3 (fr) * 2003-12-24 2005-10-04 Ecophos Procede d'attaque de minerai de phosphate.
CN1803589A (zh) * 2006-01-25 2006-07-19 四川省犍为明丰化工有限公司 磷矿盐酸回收法生产饲料级磷酸氢钙和工业级磷酸的方法
CN101434386A (zh) * 2007-11-12 2009-05-20 黄明科 一种稀酸分解中低品位磷矿生产精细磷酸盐的方法
CN101337657A (zh) * 2008-08-06 2009-01-07 黄明科 混酸分解磷矿联产磷酸二氢钾、磷酸氢钙和复肥的方法
CA2739515C (en) 2008-10-16 2015-04-28 Ecophos Sa Process for the production of high purity phosphoric acid
BR112013030374B1 (pt) * 2011-06-01 2019-12-31 Prayon Tech método para a produção de ácido fosfórico
TN2016000226A1 (en) * 2013-12-02 2017-10-06 Ecophos S A Source of phosphate for agriculture and the food industry.

Also Published As

Publication number Publication date
CA3028833A1 (fr) 2017-12-28
EA201892676A1 (ru) 2019-05-31
CN109476484B (zh) 2022-07-15
BR112018076310A2 (pt) 2019-03-26
JOP20170146A1 (ar) 2019-01-30
US20190322540A1 (en) 2019-10-24
RS61355B1 (sr) 2021-02-26
EP3475221A1 (fr) 2019-05-01
ZA201808559B (en) 2020-02-26
PL3475221T3 (pl) 2021-05-04
SA117380751B1 (ar) 2021-07-07
CN109476484A (zh) 2019-03-15
BE1023754B1 (fr) 2017-07-12
EP3475221B1 (fr) 2020-10-14
EA038221B1 (ru) 2021-07-26
US10662072B2 (en) 2020-05-26
WO2017220718A1 (fr) 2017-12-28

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