JP2000233961A - Mortar composition - Google Patents

Mortar composition

Info

Publication number
JP2000233961A
JP2000233961A JP35315899A JP35315899A JP2000233961A JP 2000233961 A JP2000233961 A JP 2000233961A JP 35315899 A JP35315899 A JP 35315899A JP 35315899 A JP35315899 A JP 35315899A JP 2000233961 A JP2000233961 A JP 2000233961A
Authority
JP
Japan
Prior art keywords
mortar
strength
glass
mortar composition
aggregate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP35315899A
Other languages
Japanese (ja)
Inventor
Fumio Nakayama
文雄 中山
Muneyuki Watanabe
宗幸 渡辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CRYSTAL CLAY KK
OBANAYA SANGYO KK
Original Assignee
CRYSTAL CLAY KK
OBANAYA SANGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CRYSTAL CLAY KK, OBANAYA SANGYO KK filed Critical CRYSTAL CLAY KK
Priority to JP35315899A priority Critical patent/JP2000233961A/en
Publication of JP2000233961A publication Critical patent/JP2000233961A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04—Portland cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/22—Glass ; Devitrified glass
    • C04B14/24—Glass ; Devitrified glass porous, e.g. foamed glass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain lightweight mortar having sufficient strength and excellent also in adhesive power. SOLUTION: A mortar composition containing cement and a glass aggregate obtained by mixing glass powder with a blowing agent, granulating and calcining the mixture is kneaded with water and hardened to obtain lightweight mortar having sufficient strength and excellent adhesiveness. The strength, particularly compressive strength is enhanced by using silica fume as part of a binder. The strength and adhesiveness are further improved by adding a polymer binder. Since waste glass can be used as the material of the glass aggregate, the mortar is excellent also in the aspect of recycling.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、モルタル組成物の
技術分野に属する。
The present invention belongs to the technical field of mortar compositions.

【0002】[0002]

【従来の技術】構造物の巨大化や高層化に対応し、施行
の省力化を図るため、より軽量、高強度のモルタル組成
物が求められている。そうした要望に応えるために、骨
材の軽量化と高強度化が研究されている。
2. Description of the Related Art In order to cope with an increase in the size and height of a structure and to save labor, a mortar composition having a lighter weight and a higher strength is required. In order to meet such demands, research has been conducted on reducing the weight and increasing the strength of the aggregate.

【0003】従来、天然物に由来する軽量骨材として
は、パーライト(黒曜石)やシラスバルーン等があり、
また人工物では発泡スチロールの粉砕品等が使用されて
いた。
Conventionally, lightweight aggregates derived from natural products include pearlite (obsidian), shirasu balloon, and the like.
In addition, in the case of an artificial product, a styrene foam pulverized product or the like has been used.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、上記の
従来の軽量骨材は、いずれも強度が十分ではなく、水を
吸いやすいために硬化後のモルタルが凍害を受けたり防
水性も劣っていた。また、パーライトは、2mmを超え
る粒径であると壊れやすく、骨材として不安定でもあっ
た。しかも、コンクリートの補修用として1回で20〜
30mm以上塗布する厚付けが行われることがあるが、
パーライトは厚付けに適していなかった。
However, all of the above-mentioned conventional lightweight aggregates have insufficient strength and are easy to absorb water, so that the mortar after hardening is damaged by freezing and has poor waterproofness. Further, pearlite having a particle size exceeding 2 mm was easily broken, and was also unstable as an aggregate. Moreover, it is 20-
Thickening to apply more than 30mm may be performed,
Perlite was not suitable for thickening.

【0005】さらに、発泡スチロールは、セメントペー
ストとのなじみ(付着性)が弱く、硬化後のモルタルの
強度も低く、量によっては可燃性となる欠点もある。
[0005] Furthermore, styrene foam has a drawback that it has low compatibility (adhesion) with the cement paste, low strength of the mortar after hardening, and becomes flammable depending on the amount.

【0006】[0006]

【課題を解決するための手段】上記課題を解決するため
の請求項1記載のモルタル組成物は、セメントと、ガラ
ス粉末に発泡剤を混合し、造粒し、焼成して製造された
ガラス骨材とを含むことを特徴とする。
According to a first aspect of the present invention, there is provided a mortar composition comprising a mixture of cement, glass powder, a foaming agent, granulation, and firing. And a material.

【0007】請求項2記載のモルタル組成物は、請求項
1記載のモルタル組成物において、シリカヒュームを含
むことを特徴とする。請求項3記載のモルタル組成物
は、請求項1または2記載のモルタル組成物において、
ポリマ結合剤を含むことを特徴とする。
The mortar composition according to the second aspect is characterized in that the mortar composition according to the first aspect contains silica fume. The mortar composition according to claim 3 is the mortar composition according to claim 1 or 2,
It is characterized by including a polymer binder.

【0008】請求項4記載のモルタル組成物は、請求項
1ないし3のいずれか記載のモルタル組成物において、
前記ガラス粉末は廃ガラスに由来することを特徴とす
る。
[0008] The mortar composition according to claim 4 is the mortar composition according to any one of claims 1 to 3,
The glass powder is derived from waste glass.

【0009】[0009]

【発明の実施の形態】本発明のモルタル組成物に使用さ
れるセメントとしては、ポルトランドセメントやアルミ
ナセメントが例示されるが、特に制限はなくどのような
種類のセメントでも使用できる。
BEST MODE FOR CARRYING OUT THE INVENTION As the cement used in the mortar composition of the present invention, portland cement and alumina cement are exemplified, but there is no particular limitation, and any kind of cement can be used.

【0010】ガラス骨材は、ガラス粉末に焼成時に気体
を発生させる発泡剤(例えば石灰石粉末)を混合し、造
粒し、焼成して製造される発泡粒体である。このような
ガラス骨材の製造例は特開平10−45449号公報に
記載されており、本発明のガラス骨材も特開平10−4
5449号公報に記載の方法で製造されるものを使用す
ればよい。
[0010] The glass aggregate is a foamed granule produced by mixing a glass powder with a foaming agent (for example, limestone powder) that generates a gas during firing, granulating and firing. An example of manufacturing such a glass aggregate is described in JP-A-10-45449, and the glass aggregate of the present invention is also disclosed in JP-A-10-4549.
What is manufactured by the method described in Japanese Patent No. 5449 may be used.

【0011】ガラス骨材は、ガラスを主成分とする粒体
であるから高強度で吸水性はなく、骨材として広く使用
されている珪砂と同様に取り扱うことができる。しか
も、発泡剤の働きにより内部に気泡ができるから断熱
性、防音性に優れている。また、造粒によりほぼ球形の
形状とできるから、モルタル骨材として理想的な形状で
もある。その上、ガラス自体に有害性はないから、取り
扱いや廃棄に当たって公害などを生じるおそれもない。
The glass aggregate is a granular material containing glass as a main component, and has high strength and no water absorption, and can be handled in the same manner as silica sand widely used as an aggregate. In addition, since bubbles are formed inside by the action of the foaming agent, the heat insulating property and the soundproof property are excellent. In addition, since it can be formed into a substantially spherical shape by granulation, it is also an ideal shape as a mortar aggregate. In addition, since the glass itself has no harm, there is no possibility of causing pollution or the like in handling and disposal.

【0012】ガラス骨材の粒径は造粒時に任意に設定で
きるが、好ましくは0.3〜5.0mmである。また、
ガラス骨材の嵩比重は0.26〜0.42であり、モル
タル組成物の軽量化が可能になる。
The particle size of the glass aggregate can be arbitrarily set at the time of granulation, but is preferably 0.3 to 5.0 mm. Also,
The bulk specific gravity of the glass aggregate is 0.26 to 0.42, and the mortar composition can be reduced in weight.

【0013】シリカヒュームは、セメント等の結合材の
一部として使用される。一般に、軽量骨材を混合したモ
ルタルは、圧縮強度、曲げ強度共低下する傾向にある。
しかし、シリカヒュームを混合することにより、強度、
特に圧縮強度が向上する。シリカヒュームの配合割合
は、セメント等の結合材全体の5〜35%、好ましくは
10〜25%の範囲である。シリカヒュームの混合によ
り強度が向上するので、今後用途が拡大予想されるコン
クリートの補修用モルタルとして適している。
[0013] Silica fume is used as part of a binder such as cement. In general, mortar mixed with lightweight aggregate tends to decrease both compressive strength and bending strength.
However, by mixing silica fume, strength,
In particular, the compressive strength is improved. The mixing ratio of silica fume is in the range of 5 to 35%, preferably 10 to 25% of the whole binder such as cement. Since the strength is improved by mixing silica fume, it is suitable as a mortar for repairing concrete, whose use is expected to expand in the future.

【0014】ポリマ結合剤としては、エチレン酢酸ビニ
ル系、酢酸ビニル系、アクリル系、SBR系、クロロプ
レン系等の公知の粉末及びエマルジョンのものを限定無
く使用できるが、本発明には粉末ポリマの方が適してい
る。このモルタル組成物には、強度の向上を目的として
ビニロンやアクリルの短繊維を添加できる。また、骨材
として珪砂を添加することでも強度を向上できる。さら
に、公知の添加剤、例えば増粘剤、作業性改良剤、消泡
剤、減水剤等を添加できる。
As the polymer binder, known powders and emulsions of ethylene vinyl acetate, vinyl acetate, acrylic, SBR, chloroprene and the like can be used without limitation. Is suitable. To this mortar composition, short fibers of vinylon or acrylic can be added for the purpose of improving the strength. The strength can also be improved by adding silica sand as an aggregate. Further, known additives such as a thickener, a workability improver, an antifoaming agent and a water reducing agent can be added.

【0015】本発明のモルタル組成物における、ガラス
骨材の比率は全体の30〜55重量%(体積比では全体
の30〜70%)が好ましい。この配合比の上限(55
重量%、70体積%)を超えると、強度低下のおそれが
あり、またコテ塗り作業性の低下(バサツキ)やポンプ
での圧送性の低下もある。一方、下限(30重量%、3
00体積%)に満たない場合には、十分な軽量化が期待
できない。
The proportion of the glass aggregate in the mortar composition of the present invention is preferably 30 to 55% by weight (30 to 70% by volume). The upper limit of this mixing ratio (55
(% By weight, 70% by volume), the strength may be reduced, the workability of ironing work may be deteriorated (basketiness), and the pumpability of the pump may be reduced. On the other hand, the lower limit (30% by weight, 3
(00% by volume), sufficient weight reduction cannot be expected.

【0016】他の成分(セメント、ポリマ等)の配合比
は、モルタルの用途などに応じて適宜決められればよい
が、モルタル100重量部につき、セメントは25〜5
0重量部、ポリマは2〜10重量部とするのが好まし
い。また、珪砂は10〜30重量部が好ましいが、珪砂
の配合比が大きくなるとモルタル組成物の軽量性が損な
われるので、ガラス骨材の80%以下に抑える方がよ
い。短繊維は0.2〜3.0重量部が好ましく、下限に
満たない場合は強度の向上が十分ではなく、また上限を
超えると逆に強度を低下させるおそれがある。その他の
添加剤(増粘剤、作業性改良剤、消泡剤、減水剤等)
は、定法にしたがった配合比でよい。
The mixing ratio of the other components (cement, polymer, etc.) may be appropriately determined according to the use of the mortar, etc., and the cement is 25 to 5 per 100 parts by weight of the mortar.
0 parts by weight and the amount of the polymer is preferably 2 to 10 parts by weight. The silica sand is preferably used in an amount of 10 to 30 parts by weight. However, if the mixing ratio of the silica sand is increased, the lightness of the mortar composition is impaired. The short fiber content is preferably 0.2 to 3.0 parts by weight. If it is less than the lower limit, the strength is not sufficiently improved, and if it exceeds the upper limit, the strength may be reduced. Other additives (thickeners, workability improvers, defoamers, water reducers, etc.)
May be a compounding ratio according to a standard method.

【0017】[0017]

【実施例】次に、本発明の実施例により発明の実施の形
態をより具体的に説明する。下記の表1に示す配合でモ
ルタル組成物を製造した。なお、表中の数値の単位は重
量部である。
Next, embodiments of the present invention will be described more specifically with reference to examples of the present invention. A mortar composition was prepared according to the formulation shown in Table 1 below. The units of the numerical values in the table are parts by weight.

【0018】[0018]

【表1】 [Table 1]

【0019】実施例1〜4のモルタル組成物に水を添加
してミキサにて混合して得たモルタルは、コテ塗り性、
ポンプ圧送性とも良好であった。また、これらのモルタ
ルを硬化させたものは、下記の表2に示すように、軽量
かつ強度も十分で接着力にも優れ、厚付けにも適してい
る。なお、表中の各強度の単位はMPaである。
The mortars obtained by adding water to the mortar compositions of Examples 1 to 4 and mixing with a mixer have an ironing property,
Pumpability was also good. Further, those obtained by curing these mortars are lightweight, have sufficient strength, have excellent adhesive strength, and are suitable for thickening, as shown in Table 2 below. The unit of each strength in the table is MPa.

【0020】[0020]

【表2】 [Table 2]

【0021】また、比較例として従来軽量モルタル及び
公知の普通モルタルの強度測定結果を表3に示す(各強
度の単位はMPa)。なお、従来軽量モルタルには、骨
材としてパーライト、シラスバルーン、発泡スチロール
粉砕品が用いられているが、一例として下記の配合によ
るパーライト入りモルタルがある。
As comparative examples, Table 3 shows the strength measurement results of a conventional lightweight mortar and a known ordinary mortar (the unit of each strength is MPa). Conventionally, pearlite, shirasu balloon, and styrene foam pulverized products have been used as aggregates in lightweight mortars. One example is a mortar containing pearlite having the following composition.

【0022】 材料 配合(重量部) ポルトランドセメント 50 パーライト 10 珪砂 20 無機質粉体(炭酸カルシウム、クレー) 10 粉末ポリマ 7 添加剤(消泡剤、増粘剤等) 3 Material mix (parts by weight) Portland cement 50 Perlite 10 Silica sand 20 Inorganic powder (calcium carbonate, clay) 10 Powder polymer 7 Additives (antifoaming agent, thickener, etc.) 3

【0023】[0023]

【表3】 [Table 3]

【0024】次に、シリカヒュームを配合した実施例5
〜7を説明する。下記の表4に示す配合でモルタル組成
物を製造した。なお、表中の数値の単位は重量部であ
る。
Next, Example 5 containing silica fume was used.
7 will be described. The mortar composition was manufactured with the composition shown in Table 4 below. The units of the numerical values in the table are parts by weight.

【0025】[0025]

【表4】 [Table 4]

【0026】実施例5〜7のモルタル組成物に水を添加
してミキサにて混合して得たモルタルは、コテ塗り性、
ポンプ圧送性とも良好であった。また、これらのモルタ
ルを硬化させたものは、下記の表5に示すように、軽量
かつ強度も十分で接着力にも優れ、厚付けにも適してい
る。なお、表中の各強度の単位はMPaである。
The mortars obtained by adding water to the mortar compositions of Examples 5 to 7 and mixing with a mixer have the following properties.
Pumpability was also good. Further, those obtained by curing these mortars are lightweight, have sufficient strength, have excellent adhesive strength, and are suitable for thickening as shown in Table 5 below. The unit of each strength in the table is MPa.

【0027】[0027]

【表5】 [Table 5]

【0028】[0028]

【発明の効果】以上詳しく説明したように、請求項1〜
4のモルタル組成物を用いれば、軽量かつ強度も十分で
接着力にも優れているモルタルを得ることができる。ま
た、ガラス骨材は吸水性がないから、硬化後のモルタル
が凍害を受けたり防水性が低くなることもなく、可燃性
となることもない。しかも、コテ塗り性は良好で厚付け
にも適しており、ポンプ圧送性も良好である。
As described in detail above, claims 1 to 1
When the mortar composition of No. 4 is used, it is possible to obtain a mortar which is lightweight, has sufficient strength, and is excellent in adhesive strength. Moreover, since the glass aggregate has no water absorption, the mortar after hardening does not suffer from freezing damage, does not have low waterproofness, and does not become flammable. In addition, the ironing property is good and suitable for thickening, and the pumping property is also good.

【0029】特に、請求項2記載のように結合材の一部
にシリカヒュームを使用すると、軽量骨材を混合したモ
ルタルにおいて、その強度、特に圧縮強度を向上させる
ことができるので、例えばコンクリートの補修用モルタ
ルとして好適である。また、請求項4記載のように廃ガ
ラスを原料とできるから資源のリサイクルの面で優れて
いる。
Particularly, when silica fume is used as a part of the binder as described in claim 2, the strength, particularly the compressive strength, of the mortar mixed with the lightweight aggregate can be improved. It is suitable as a repair mortar. Further, since waste glass can be used as a raw material as described in claim 4, it is excellent in terms of resource recycling.

【0030】以上、本発明の実施の形態について説明し
たが、本発明は上記の例に限定されるものではなく、本
発明の要旨を逸脱しない範囲でさまざまに実施できるこ
とは言うまでもない。
Although the embodiments of the present invention have been described above, the present invention is not limited to the above examples, and it goes without saying that various embodiments can be made without departing from the gist of the present invention.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C04B 18:16) 111:40 (72)発明者 渡辺 宗幸 三重県員弁郡北勢町東村字小山1339 株式 会社尾花屋産業三重工場内──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme Court (Reference) C04B 18:16) 111: 40 (72) Inventor Muneyuki 1339 Koyama, Higashimura Higashimura, Kitase-cho, Inaba-gun, Mie Pref. Obaya Sangyo Mie Plant

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 セメントと、ガラス粉末に発泡剤を混合
し、造粒し、焼成して製造されたガラス骨材とを含むこ
とを特徴とするモルタル組成物。
1. A mortar composition comprising cement and a glass aggregate produced by mixing a foaming agent into glass powder, granulating and firing.
【請求項2】 請求項1記載のモルタル組成物におい
て、シリカヒュームを含むことを特徴とするモルタル組
成物。
2. The mortar composition according to claim 1, further comprising silica fume.
【請求項3】 請求項1または2記載のモルタル組成物
において、ポリマ結合剤を含むことを特徴とするモルタ
ル組成物。
3. The mortar composition according to claim 1, further comprising a polymer binder.
【請求項4】 請求項1ないし3のいずれか記載のモル
タル組成物において、前記ガラス粉末は廃ガラスに由来
することを特徴とするモルタル組成物。
4. The mortar composition according to claim 1, wherein the glass powder is derived from waste glass.
JP35315899A 1998-12-15 1999-12-13 Mortar composition Pending JP2000233961A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP35315899A JP2000233961A (en) 1998-12-15 1999-12-13 Mortar composition

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP35637098 1998-12-15
JP10-356370 1998-12-15
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101096513B1 (en) 2011-08-08 2011-12-20 이동우 Mortar composition for cross-sectional reinforcement of concrete structures containing fast-hardening binders using industrial by-products and methods for repairing and reinforcing cross-sections of concrete structures using the same
KR101110731B1 (en) 2009-09-22 2012-02-15 주식회사 대원바텍 High Strength Pile Mixer with Waste Amorphous Ceramic Powder
JP2012214354A (en) * 2011-03-25 2012-11-08 Ube Industries Ltd Method for repairing concrete structure
JP2012214355A (en) * 2011-03-25 2012-11-08 Ube Industries Ltd Cement composition, mortar composition, and mortar cured body
WO2022102882A1 (en) * 2020-11-11 2022-05-19 경기대학교 산학협력단 Cross section repair material based on halophilic slime-forming bacteria

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101110731B1 (en) 2009-09-22 2012-02-15 주식회사 대원바텍 High Strength Pile Mixer with Waste Amorphous Ceramic Powder
JP2012214354A (en) * 2011-03-25 2012-11-08 Ube Industries Ltd Method for repairing concrete structure
JP2012214355A (en) * 2011-03-25 2012-11-08 Ube Industries Ltd Cement composition, mortar composition, and mortar cured body
KR101096513B1 (en) 2011-08-08 2011-12-20 이동우 Mortar composition for cross-sectional reinforcement of concrete structures containing fast-hardening binders using industrial by-products and methods for repairing and reinforcing cross-sections of concrete structures using the same
WO2022102882A1 (en) * 2020-11-11 2022-05-19 경기대학교 산학협력단 Cross section repair material based on halophilic slime-forming bacteria

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