JP2000265351A - Elastic non-woven fabric having excellent heat sealing property and its production - Google Patents
Elastic non-woven fabric having excellent heat sealing property and its productionInfo
- Publication number
- JP2000265351A JP2000265351A JP7036099A JP7036099A JP2000265351A JP 2000265351 A JP2000265351 A JP 2000265351A JP 7036099 A JP7036099 A JP 7036099A JP 7036099 A JP7036099 A JP 7036099A JP 2000265351 A JP2000265351 A JP 2000265351A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- fibers
- nonwoven fabric
- weight
- melting point
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 77
- 238000007789 sealing Methods 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000000835 fiber Substances 0.000 claims abstract description 218
- 238000002844 melting Methods 0.000 claims abstract description 41
- 230000008018 melting Effects 0.000 claims abstract description 38
- 239000000853 adhesive Substances 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 239000012530 fluid Substances 0.000 claims abstract description 8
- 239000000306 component Substances 0.000 claims description 38
- 239000011347 resin Substances 0.000 claims description 21
- 229920005989 resin Polymers 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 19
- 239000000470 constituent Substances 0.000 claims description 18
- 239000002131 composite material Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 10
- 239000008358 core component Substances 0.000 claims description 5
- 238000002788 crimping Methods 0.000 claims description 5
- 229920002994 synthetic fiber Polymers 0.000 claims description 5
- 239000012209 synthetic fiber Substances 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- -1 polypropylene Polymers 0.000 description 29
- 239000004743 Polypropylene Substances 0.000 description 16
- 229920001155 polypropylene Polymers 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 229920000297 Rayon Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000002964 rayon Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 210000003666 myelinated nerve fiber Anatomy 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Multicomponent Fibers (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、伸縮性に優れ、肌
触りが良好であり、かつヒートシール性に優れた不織布
であって、おむつ部材などの衛生材料、使い捨て肌着、
サポーター、パップ剤基布などに好適な伸縮性不織布に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a nonwoven fabric which is excellent in elasticity, feels good and heat sealability, and is used for sanitary materials such as diaper members, disposable underwear,
The present invention relates to a stretchable nonwoven fabric suitable for a supporter, a poultice base fabric, and the like.
【0002】[0002]
【従来の技術】従来より、伸縮性不織布は様々な用途に
利用されており、特に人体に触れたりする用途において
は、人体にフィットし易く、肌触りのよい不織布が要望
されており、とりわけおむつ部材や使い捨て肌着などに
おいては、同時にヒートシール性も要求されている。上
記用途においては、潜在捲縮性短繊維を主体とした伸縮
性不織布が肌触りの点で優れていることから好ましく使
用されており、これらについて種々の提案がなされてい
る。例えば、特開平2−127553号公報には、ポリ
プロピレン系熱接着性複合繊維を主体としたウェブを、
ウォーターニードル法により絡合させ、熱処理を施して
ウェブを収縮させるとともに繊維同士を接着させた伸縮
性不織布が提案されている。特開平2−182957号
公報には、ポリエステル系潜在捲縮性複合繊維とポリエ
チレンテレフタレート系低融点ポリマーからなる熱接着
性短繊維が混合されてなり、熱接着および捲縮発現処理
された伸縮性不織布が提案されている。また、特開平1
−132861号公報には、捲縮数が20個/25mm以下
のポリオレフィン/ポリエステルからなる複合繊維と捲
縮数が40個/25mm以上のポリオレフィン/ポリエステ
ルからなる複合繊維を含有してなる熱接着性不織布が開
示されている。2. Description of the Related Art Conventionally, stretchable nonwoven fabrics have been used for various applications. In particular, in applications where a human body is touched, there has been a demand for a nonwoven fabric that fits easily to the human body and has a good touch. In addition, heat-sealing properties are also required for disposable underwear and the like. In the above applications, stretchable nonwoven fabrics mainly composed of latently crimpable short fibers are preferably used because of their excellent touch, and various proposals have been made for these. For example, JP-A-2-127553 discloses a web mainly composed of a polypropylene-based heat-adhesive conjugate fiber,
A stretchable nonwoven fabric has been proposed in which the fibers are entangled by a water needle method, heat-treated to shrink the web, and fibers are adhered to each other. JP-A-2-182957 discloses a stretchable nonwoven fabric comprising a mixture of a polyester-based latently crimpable conjugate fiber and a heat-adhesive short fiber made of a polyethylene terephthalate-based low-melting polymer, which is subjected to heat bonding and crimp development treatment. Has been proposed. Also, Japanese Patent Application Laid-Open
Japanese Patent Publication No. 132861 discloses a thermoadhesive composition containing a composite fiber composed of a polyolefin / polyester having a number of crimps of 20/25 mm or less and a composite fiber composed of a polyolefin / polyester having a crimp number of 40/25 mm or more. A nonwoven fabric is disclosed.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、上記不
織布には以下の問題点が挙げられる。特開平2−127
553号公報および特開平2−182957号公報の伸
縮性不織布は、いずれも捲縮発現と同時に繊維同士を熱
接着させているため、伸縮性が阻害され易いだけでな
く、ごわごわした触感となり肌触りが良好とはいえな
い。さらに、ヒートシール性が考慮されていないため、
低温で処理したときに十分なヒートシール強度が得られ
ないなど工程的あるいはコスト的に問題が生じている。
また、特開平1−132861号公報の不織布も上記同
様熱接着されており、さらに異族系のポリマーの組み合
わせからなる複合繊維を使用しているため、ヒートシー
ル強度が不十分である。本発明は、上記問題点を鑑みて
なされたものであり、伸縮性に優れ、肌触りが良好であ
り、かつヒートシール性に優れた様々な用途に好適な伸
縮性不織布を提供することを目的とする。However, the above-mentioned nonwoven fabric has the following problems. JP-A-2-127
553 and JP-A-2-182957, all of the fibers are heat-bonded to each other at the same time as crimping, so that not only the elasticity is easily hindered, but also a rugged feel and a soft touch are obtained. Not good. Furthermore, since heat sealing properties are not considered,
There is a problem in terms of process or cost such that sufficient heat sealing strength cannot be obtained when treated at a low temperature.
Further, the non-woven fabric disclosed in Japanese Patent Application Laid-Open No. 1-128661 is also heat-bonded in the same manner as described above, and further uses a composite fiber composed of a combination of heterogeneous polymers, so that the heat seal strength is insufficient. The present invention has been made in view of the above problems, and has an object to provide a stretchable nonwoven fabric that is excellent in stretchability, has a good touch, and is excellent in heat sealability and is suitable for various uses. I do.
【0004】[0004]
【課題を解決するための手段】本発明の伸縮性不織布
は、前記従来の問題点を解決するため、融点の異なる2
種類以上の重合体からなり、熱処理により立体捲縮が発
現する潜在捲縮性複合繊維(以下、S繊維という)と、
熱接着性繊維(以下、B繊維という)を含有した繊維ウ
ェブが三次元的に絡合している不織布であって、下記の
構成を満たすことを特徴とする。 (a)S繊維が、立体捲縮を捲縮数17個/25mm以上発
現する温度T(℃)よりも高い融点TSL(℃)からなる
樹脂を第1成分とし、TSLより5℃以上高い融点TS
H(℃)からなる樹脂を第2成分としたとき、第1成分
と第2成分が並列型に配置、あるいは第1成分を鞘とし
て第2成分を芯とした偏心鞘芯型に配置された潜在捲縮
性複合繊維であること。 (b)B繊維が、温度T(℃)よりも高い融点TB
L(℃)を低融点成分とし、以下の関係を満たす熱接着
性繊維であること。 TSL−20 ≦ TBL ≦ TSL+20 (c)S繊維が、捲縮数17個/25mm以上に立体捲縮発
現するとともに構成繊維同士が実質的に熱接着されてい
ないこと。 かかる構成を採ることにより、伸縮性が阻害されること
なく、肌触りが良好であり、同時にヒートシール強力に
富む伸縮性不織布が得られる。The stretchable nonwoven fabric of the present invention
In order to solve the above-mentioned conventional problems, 2
Consists of more than two types of polymers, and generates three-dimensional crimps by heat treatment
A latently crimpable conjugate fiber (hereinafter referred to as S fiber),
Fibers containing heat-adhesive fibers (hereinafter referred to as B fibers)
Web is a three-dimensionally entangled non-woven fabric,
It is characterized by satisfying the configuration. (A) S-fiber crevices three-dimensional crimps 17 crimps / 25mm or more
Melting point TS higher than temperature T (° C)L(℃)
Resin as the first component, TSLMelting point TS higher than 5 ℃
H(C) as the second component, the first component
And the second component are arranged in parallel, or the first component is sheathed.
Latent crimp arranged in an eccentric sheath-core type with the second component as the core
It should be a composite fiber. (B) B fiber has a melting point TB higher than the temperature T (° C.)
L(° C) as a low melting point component, thermal bonding satisfying the following relationship
It must be synthetic fiber. TSL-20 ≤ TBL ≤ TSL+20 (c) Three-dimensional crimping of S fibers with a crimp count of 17 / 25mm or more
And the constituent fibers are substantially thermally bonded to each other.
Not that. By adopting such a configuration, the elasticity is hindered.
And feels good, and at the same time has strong heat sealing
A rich stretchable nonwoven fabric is obtained.
【0005】本発明の伸縮性不織布を構成する繊維にお
いて、S繊維が50〜80重量%、B繊維が50〜20
重量%含有することが望ましい。[0005] In the fibers constituting the stretchable nonwoven fabric of the present invention, S fibers are 50 to 80% by weight, and B fibers are 50 to 20% by weight.
Desirably, it is contained by weight.
【0006】前記B繊維は、融点TBL(℃)からなる樹
脂を鞘成分とし、TBLより10℃以上高い融点TBH(℃)
からなる樹脂を芯成分とした同心円鞘芯型複合繊維であ
ると、優れたヒートシール性が得られる。また、S繊維
の第1成分とB繊維の低融点成分が、同一樹脂からなる
ことが望ましい。[0006] The B fibers, the melting point TB L resin consisting of (℃) as the sheath component, TB L than 10 ° C. or more higher than the melting point TB H (℃)
Concentric sheath-core type composite fibers containing a resin consisting of Further, it is desirable that the first component of the S fiber and the low melting point component of the B fiber are made of the same resin.
【0007】また、本発明の伸縮性不織布は、前記繊維
ウェブの少なくとも片面に親水性繊維を含有する繊維ウ
ェブが積層されていると、伸縮性および吸水性に富み、
かつヒートシール性に優れた伸縮性不織布が得られるの
で都合がよい。前記親水性繊維を含有する繊維ウェブ
は、親水性繊維を50〜10重量%、潜在捲縮性複合繊
維を50〜90重量%含有させると、十分な伸縮性が得
られる点で好ましい。Further, the stretchable nonwoven fabric of the present invention is rich in stretchability and water absorption when a fibrous web containing hydrophilic fibers is laminated on at least one surface of the fibrous web,
In addition, a stretchable nonwoven fabric having excellent heat sealability is obtained, which is convenient. It is preferable that the fibrous web containing the hydrophilic fiber contains 50 to 10% by weight of the hydrophilic fiber and 50 to 90% by weight of the latently crimpable conjugate fiber since sufficient elasticity can be obtained.
【0008】前記不織布が開孔面積0.25〜30mm2
の開孔が形成された開孔不織布であると、肌触りが織物
ライクになり、通気性が向上する点で好ましい。The nonwoven fabric has an open area of 0.25 to 30 mm 2
It is preferred that the nonwoven fabric having the openings formed therein has a woven-like feel to the touch and improves air permeability.
【0009】本発明の伸縮性不織布の縦方向および横方
向における破断伸度は、少なくとも100%であり、か
つ不織布の横方向の50%モジュラスが0.7cN/50mm
以下であることが望ましい。The elongation at break in the longitudinal and transverse directions of the stretchable nonwoven fabric of the present invention is at least 100%, and the 50% modulus in the transverse direction of the nonwoven fabric is 0.7 cN / 50 mm.
It is desirable that:
【0010】そして、本発明の伸縮性不織布は、融点の
異なる2種類以上の重合体からなり、熱処理により立体
捲縮が発現するS繊維50〜80重量%と、S繊維の捲
縮数が17個/25mm以上発現する温度T(℃)より高い
融点TBL(℃)を持つB繊維50〜20重量%を含有す
る繊維ウェブに、高圧流体流処理を施して構成繊維同士
を三次元的に絡合させ、しかるのちに構成繊維同士が熱
接着を有しない温度で熱処理を施して、S繊維を立体捲
縮発現させることにより製造することができる。[0010] The stretchable nonwoven fabric of the present invention is composed of two or more polymers having different melting points. the fibrous web containing the B fiber 50 to 20 wt% with higher melting point TB L (° C.) temperature T (° C.) expressing pieces / 25mm or more, the constituent fibers to each other three-dimensionally by applying a high pressure fluid flow treatment It can be manufactured by entanglement, followed by a heat treatment at a temperature at which the constituent fibers do not have thermal bonding, and then the S fibers are three-dimensionally crimped.
【0011】また、別の方法として、融点の異なる2種
類以上の重合体からなり、熱処理により立体捲縮が発現
するS繊維50〜80重量%と、S繊維の捲縮数が17
個/25mm以上発現する温度T(℃)より高い融点TB
L(℃)を持つB繊維50〜20重量%を含有する繊維
ウェブと、親水性繊維50〜10重量%と潜在捲縮性複
合繊維50〜90重量%を含有する繊維ウェブを積層
し、高圧流体流処理を施して構成繊維同士を三次元的に
絡合させ一体化し、しかるのちに構成繊維同士が熱接着
を有しない温度で熱処理を施して、S繊維および/また
は該潜在捲縮性複合繊維を立体捲縮発現させることによ
り、ヒートシール性および吸水性に優れた伸縮性不織布
が得られる。以下、本発明の内容を具体的に説明する。As another method, 50 to 80% by weight of S fiber, which is made of two or more polymers having different melting points and develops three-dimensional crimp by heat treatment, and the number of crimps of S fiber is 17%
Melting point TB higher than the temperature T (° C) at which the temperature is expressed per piece / 25mm or more
A fiber web containing 50 to 20% by weight of a B fiber having L (° C.), a fiber web containing 50 to 10% by weight of a hydrophilic fiber and 50 to 90% by weight of a latent crimpable conjugate fiber are laminated. The constituent fibers are three-dimensionally entangled and integrated by performing a fluid flow treatment, and then subjected to a heat treatment at a temperature at which the constituent fibers do not have thermal adhesion, so that the S fibers and / or the latently crimpable composite By expressing the fibers in a three-dimensional crimp, a stretchable nonwoven fabric excellent in heat sealability and water absorption can be obtained. Hereinafter, the contents of the present invention will be specifically described.
【0012】[0012]
【発明の実施の形態】本発明に用いられる潜在捲縮性複
合繊維(以下、S繊維という)は、融点の異なる2種類
以上の重合体からなり、熱処理により立体捲縮が発現す
るものであり、温度T(℃)において、S繊維の捲縮数
が17個/25mm以上発現するものが好ましい。より好ま
しくは、30個/25mm以上発現するものである。ここで
いう「立体捲縮」とは、図1〜図3に示すように、螺旋
状の捲縮のみならず、緩やかなカーブを描いて二次元方
向に屈曲しているもの、あるいは二次元的な屈曲に三次
元的な曲部が加わったもの等を含む意であり、クリンパ
ー等で付与される機械捲縮と区別するために使用される
語である。S繊維の捲縮数が17個/25mm未満である
と、得られる不織布の伸縮性が不十分であり、耐久性に
も劣るからである。前記捲縮数の範囲を満たすS繊維と
しては、並列、あるいは偏心芯鞘形状の断面を持つ複合
繊維が挙げられ、例えば、共重合ポリエステル/ポリエ
チレンテレフタレート、エチレン−プロピレン共重合体
/ポリプロピレンやエチレン−ブテン−1−プロピレン
三元共重合体/ポリプロピレン等のプロピレン系共重合
体/ポリプロピレン、ポリエチレン/ポリエチレンテレ
フタレート、ポリエチレン/ポリブチレンテレフタレー
トなどの複合繊維等が挙げられ、これらの中から任意に
一あるいは二以上選択して使用することができる。BEST MODE FOR CARRYING OUT THE INVENTION The latently crimpable conjugate fiber (hereinafter referred to as "S fiber") used in the present invention is composed of two or more polymers having different melting points, and develops three-dimensional crimp by heat treatment. At the temperature T (° C.), it is preferable that the number of crimps of the S fiber is 17 or more / 25 mm. More preferably, the expression is 30/25 mm or more. As used herein, the term “three-dimensional crimp” refers to not only a spiral crimp, but also a two-dimensionally bent one that draws a gentle curve as shown in FIGS. It is intended to include a case where a three-dimensional curved portion is added to a natural bend, and is a word used to distinguish it from a mechanical crimp given by a crimper or the like. If the number of crimps of the S fiber is less than 17/25 mm, the resulting nonwoven fabric has insufficient elasticity and poor durability. Examples of the S fibers satisfying the range of the number of crimps include conjugate fibers having a parallel or eccentric core-sheath cross section. For example, copolymerized polyester / polyethylene terephthalate, ethylene-propylene copolymer / polypropylene and ethylene- Propylene-based copolymers such as butene-1-propylene terpolymer / polypropylene / polypropylene, composite fibers such as polyethylene / polyethylene terephthalate, polyethylene / polybutylene terephthalate, and the like. The above can be selected and used.
【0013】特に、S繊維が、融点TSL(℃)からなる
樹脂を第1成分とし、TSLより5℃以上高い融点TS
H(℃)からなる樹脂を第2成分としたとき、第1成分
と第2成分が並列型に配置、あるいは第1成分を鞘と
し、第2成分を芯とした偏心鞘芯型に配置された潜在捲
縮性複合繊維であることが好ましく、共重合ポリエステ
ル/ポリエチレンテレフタレート、エチレン−プロピレ
ン共重合体/ポリプロピレン、エチレン−ブテン−1−
プロピレン三元共重合体/ポリプロピレンの組み合わせ
が、低温で高度な捲縮数を得る点で好ましい。In particular, the S fiber has a resin having a melting point of TS L (° C.) as a first component and has a melting point TS higher than T SL by 5 ° C. or more.
When the resin composed of H (° C.) is used as the second component, the first component and the second component are arranged in a side-by-side configuration, or are arranged in an eccentric sheath-core configuration in which the first component is a sheath and the second component is a core. Is preferably a latently crimpable conjugate fiber, such as copolymerized polyester / polyethylene terephthalate, ethylene-propylene copolymer / polypropylene, and ethylene-butene-1-.
A propylene terpolymer / polypropylene combination is preferred in that a high number of crimps can be obtained at low temperatures.
【0014】次に、繊維ウェブとして前記S繊維と混綿
される熱接着性繊維(以下、B繊維という)は、温度T
(℃)よりも高い融点TBL(℃)を低融点成分とし、以
下の関係を満たす熱接着性繊維であることが好ましい。 TSL−20 ≦ TBL ≦ TSL+20 上記の関係を満たすと、伸縮性および肌触りなどの柔軟
な風合いを維持しつつ、優れたヒートシール性が得られ
る点で好ましい。より好ましくは、TBLが(TSL−10)
〜(TSL+10)であり、さらに好ましくは、S繊維の
第1成分とB繊維の低融点成分が、同一樹脂からなるこ
とである。ここでいう、同一樹脂とは、明らかに構造の
相違する樹脂を除き、また共重合成分を含むものであれ
ば、その共重合成分の含有量が5重量%以上差のあるも
のを除く概念である。TBLがTSL−20未満であると、S
繊維が十分に捲縮発現しないうちにB繊維が融着してし
まい、伸縮性に優れた不織布が得られず、TBLがTSL+2
0を超えると、低温ヒートシール性に劣るだけでなく、
十分なヒートシール強力が得られなかったりするからで
ある。Next, a thermoadhesive fiber (hereinafter referred to as a B fiber) mixed with the S fiber as a fibrous web has a temperature T.
(℃) higher than the melting point TB L (℃) and low melting point component is preferably a heat-bondable fibers to satisfy the following relation. When meeting the TS L -20 ≦ TB L ≦ TS L +20 above relationship, while maintaining a soft texture, such as stretch and soft, preferable in that excellent heat-sealing properties is obtained. More preferably, TB L is (TS L -10)
To (TS L +10), and more preferably, the first component of the S fiber and the low melting point component of the B fiber are made of the same resin. Here, the term “identical resin” refers to a concept that excludes resins having obviously different structures, and excludes resins having a difference of 5% by weight or more in the content of a copolymer component if the resin contains a copolymer component. is there. If TB L is less than TS L -20, S
Fiber ends up B fiber fusion in less sufficiently crimp development, excellent non-woven fabric can not be obtained in elasticity, TB L is TS L +2
If it exceeds 0, not only is it inferior to low-temperature heat sealability,
This is because sufficient heat sealing strength may not be obtained.
【0015】B繊維の形態としては、単一、複合の円形
あるいは異形いずれであってもよく、複合形態である場
合、前記樹脂が少なくとも1成分とする混合タイプ、繊
維断面が並列型、偏心鞘芯型、同心円鞘芯型、分割型、
海島型などが挙げられる。なかでも、融点TBL(℃)か
らなる樹脂を鞘成分とし、TBLより10℃以上高い融点T
BH(℃)からなる樹脂を芯成分とした同心円鞘芯型複合
繊維であることが好ましい。例えば、ポリエチレン/ポ
リプロピレン、エチレン−プロピレン共重合体/ポリプ
ロピレン、エチレン−ブテン−1−プロピレン三元共重
合体/ポリプロピレン、ポリエチレン/ポリエチレンテ
レフタレートなどが挙げられる。特に、S繊維の第1成
分と、同心円鞘芯型熱接着性複合繊維の鞘成分が同一樹
脂からなると、高度なヒートシール性が得られ、好まし
い。The form of the B-fiber may be any of a single form, a composite form of a circle and a modified form, and in the case of a composite form, the resin is a mixed type having at least one component, a fiber section is a parallel type, and an eccentric sheath. Core type, concentric sheath core type, split type,
Sea-island type and the like. Among them, the melting point TB L resin consisting of (℃) as the sheath component, TB L than 10 ° C. or more higher than the melting point T
It is preferably a concentric sheath-core composite fiber containing a resin composed of BH (° C) as a core component. For example, polyethylene / polypropylene, ethylene-propylene copolymer / polypropylene, ethylene-butene-1-propylene terpolymer / polypropylene, polyethylene / polyethylene terephthalate and the like can be mentioned. In particular, when the first component of the S fiber and the sheath component of the concentric sheath-core type heat-adhesive conjugate fiber are made of the same resin, high heat sealing properties can be obtained, which is preferable.
【0016】前記繊維ウェブにおいて、S繊維が50〜
80重量%、B繊維が50〜20重量%含有することが
好ましい。S繊維が50重量%未満、あるいはB繊維が
50重量%を超えると、十分な伸縮性が得られず、S繊
維が80重量%を超える、あるいはB繊維が20重量%
未満であると、十分なヒートシール性が得られないから
である。In the above fibrous web, the S fiber is 50 to 50%.
It is preferable to contain 80% by weight and 50 to 20% by weight of the B fiber. If the S fiber is less than 50% by weight or the B fiber exceeds 50% by weight, sufficient elasticity cannot be obtained, and the S fiber exceeds 80% by weight or the B fiber contains 20% by weight.
If it is less than this, sufficient heat sealing properties cannot be obtained.
【0017】前記繊維ウェブにおいて、必要に応じて前
記S繊維およびB繊維以外の素材を混綿してもよいが、
S繊維の捲縮数が17個/25mm以上に発現させたときに
接着性能を有するもの以外であれば特に限定されない。
素材としては、例えば、綿、絹等の天然繊維、レーヨン
等の再生繊維、アセテート等の半合成繊維、アクリル系
繊維、ナイロン6、ナイロン66等のポリアミド系繊
維、ポリエチレンテレフタレート、ポリブチレンテレフ
タレート等のポリエステル系繊維、ポリエチレン、ポリ
プロピレン等のポリオレフィン系繊維等が挙げられ、繊
維形状も特に限定されず、単一繊維、鞘芯型複合繊維、
分割型複合繊維、異形断面繊維等が挙げられ、これらの
中から任意に一あるいは二以上選択して使用するとよ
い。In the fibrous web, if necessary, materials other than the S fiber and the B fiber may be mixed.
The S fiber is not particularly limited as long as it has an adhesive property when the number of crimps of the S fiber is 17 pieces / 25 mm or more.
Examples of the material include natural fibers such as cotton and silk, regenerated fibers such as rayon, semi-synthetic fibers such as acetate, acrylic fibers, polyamide fibers such as nylon 6, nylon 66, polyethylene terephthalate, and polybutylene terephthalate. Polyester-based fibers such as polyester fibers, polyethylene, and polypropylene, and the like, and the fiber shape is not particularly limited, single fibers, sheath-core composite fibers,
Examples thereof include splittable conjugate fibers and modified cross-section fibers, and one or more of these may be arbitrarily selected and used.
【0018】また、本発明の伸縮性不織布は、前記繊維
ウェブの少なくとも片面に親水性繊維を含有する繊維ウ
ェブを積層してもよい。積層方法は繊維ウェブ状態であ
っても不織布形態であってもいずれでもよいが、後述す
る三次元的に絡合させた時の絡合性を考慮すると、繊維
ウェブ状態で積層するのが好ましい。親水性繊維を含有
する繊維ウェブが積層されていると、伸縮性および吸水
性に富み、かつヒートシール性に優れた伸縮性不織布が
得られるので都合がよい。親水性繊維としては、綿、
絹、毛等の天然繊維、レーヨン等の再生繊維、アセテー
ト等の半合成繊維、アクリル系繊維、あるいは合成繊維
に親水化処理を施したものなどが挙げられる。In the stretchable nonwoven fabric of the present invention, a fiber web containing hydrophilic fibers may be laminated on at least one surface of the fiber web. The laminating method may be either a fibrous web state or a nonwoven fabric form, but it is preferable to laminate in a fibrous web state in consideration of the entanglement property when three-dimensionally entangled as described later. When a fiber web containing hydrophilic fibers is laminated, a stretchable nonwoven fabric having excellent stretchability and water absorption and excellent heat sealability can be obtained, which is convenient. As hydrophilic fibers, cotton,
Natural fibers such as silk and wool, regenerated fibers such as rayon, semi-synthetic fibers such as acetate, acrylic fibers, and synthetic fibers subjected to a hydrophilic treatment are exemplified.
【0019】前記親水性繊維を含有する繊維ウェブは、
親水性繊維を50〜10重量%、潜在捲縮性複合繊維を
50〜90重量%含有させることが好ましい。ここでい
う潜在捲縮性複合繊維は、前記S繊維であってもよい
し、別の繊維であってもよいが、ヒートシール性を向上
させる場合には、S繊維を用いるとよい。親水性繊維が
10重量%未満、あるいは潜在捲縮性複合繊維を90重
量%を超えると、親水性が不十分であり、親水性繊維が
50重量%を超える、あるいは潜在捲縮性複合繊維が5
0重量%未満であると、不織布の伸縮性が不十分となる
からである。The fibrous web containing the hydrophilic fibers,
It is preferable to contain 50 to 10% by weight of a hydrophilic fiber and 50 to 90% by weight of a latent crimpable conjugate fiber. The latently crimpable conjugate fiber mentioned here may be the above-mentioned S fiber or another fiber. However, in order to improve the heat sealing property, it is preferable to use the S fiber. If the hydrophilic fiber is less than 10% by weight or the latent crimping conjugate fiber exceeds 90% by weight, the hydrophilicity is insufficient, and the hydrophilic fiber exceeds 50% by weight or the latent crimping conjugate fiber is less than 50% by weight. 5
If the amount is less than 0% by weight, the elasticity of the nonwoven fabric becomes insufficient.
【0020】次に、本発明の伸縮性不織布の製造方法に
ついて説明する。繊維ウェブの形態としては、特に限定
されず、ステープル繊維からなるパラレルウェブ、セミ
ランダムウェブ、ランダムウェブ、長繊維からなるスパ
ンボンドウェブなどが挙げられるが、後述する高圧流体
流処理における交絡性を考慮すると、繊維長25〜80
mmからなるステープル繊維が好ましい。また、前記のよ
うに親水性繊維を含有する繊維ウェブと積層する場合、
後述する高圧流体流処理を施す前に積層するとよい。Next, a method for producing a stretchable nonwoven fabric of the present invention will be described. The form of the fibrous web is not particularly limited, and examples thereof include a parallel web made of staple fibers, a semi-random web, a random web, and a spunbonded web made of long fibers. Then, fiber length 25-80
Staple fibers of mm are preferred. Further, when laminated with a fiber web containing hydrophilic fibers as described above,
It is advisable to stack the layers before performing a high-pressure fluid flow treatment described later.
【0021】繊維ウェブの目付は、最終的に得られる伸
縮性不織布の用途等に応じて決定される。例えば、おむ
つのバックシートなどおむつ部材に使用する場合は、1
0〜120g/m2の繊維ウェブを形成するとよい。The basis weight of the fibrous web is determined according to the use of the finally obtained elastic nonwoven fabric. For example, when used for diaper members such as diaper back sheets, 1
A fibrous web of 0-120 g / m 2 may be formed.
【0022】そして、繊維ウェブは三次元的に絡合され
る。絡合方法としては、ニードルパンチ法あるいは高圧
流体流法などが挙げられるが、風合いを重視するのであ
れば、高圧水流法が好適である。このとき噴射される水
は、柱状流、あるいは放射状流などいずれであってもよ
く、高圧流体流の噴射は、例えば、高圧柱状流であれ
ば、孔径0.05〜2mmのオリフィスが間隔0.5〜5
mmで設けられたノズルから圧力1〜10MPaで噴射する
とよい。Then, the fibrous web is three-dimensionally entangled. Examples of the entanglement method include a needle punching method and a high-pressure fluid flow method. If emphasis is placed on the feeling, the high-pressure water flow method is suitable. The water injected at this time may be a columnar flow or a radial flow. For example, in the case of a high pressure columnar flow, the orifice having a hole diameter of 0.05 to 2 mm is used in the case of a high pressure columnar flow. 5-5
It is good to spray at a pressure of 1 to 10 MPa from a nozzle provided in mm.
【0023】また、このとき繊維ウェブを開孔形成用支
持体上に載置して高圧流体流処理を施してもよい。かか
る処理を施すと、不織布に開孔面積0.25〜30mm2
程度の多数の開孔が形成され、意匠性や通気性の点で優
れた不織布が得られる。開孔形成用支持体としては、例
えば、モノフィラメントや金属線を織成して形成したパ
ターンネットや、突起物を設けたロール等が挙げられ
る。得られる開孔形状は特に限定されず、円状、楕円
状、菱形、長方形等いずれであってもよく、開孔パター
ンも千鳥状、格子状等いずれであってもよい。At this time, the fibrous web may be placed on a support for forming openings to perform high-pressure fluid flow treatment. When such a treatment is performed, the nonwoven fabric has an open area of 0.25 to 30 mm 2.
A large number of openings are formed, and a nonwoven fabric excellent in design and air permeability can be obtained. Examples of the support for forming openings include a pattern net formed by weaving monofilaments and metal wires, and a roll provided with protrusions. The shape of the obtained aperture is not particularly limited, and may be any of a circle, an ellipse, a rhombus, a rectangle, and the like, and the aperture pattern may be any of a zigzag, a lattice, and the like.
【0024】得られた絡合不織布は、構成繊維同士が熱
接着を有しない温度で熱処理を施してS繊維を立体捲縮
発現させ、構成繊維同士が実質的に熱接着されていない
伸縮性不織布となす。ここでいう、実質的に熱接着され
ていないとは、樹脂の軟化などによる繊維同士の密着を
含み、少なくとも樹脂の一部が溶融したものを含まない
概念である。熱処理温度は、捲縮数が17個/25mm以上
発現する温度T(℃)以上で、S繊維の融点TSL(℃)
およびB繊維の融点TBL(℃)未満の温度で熱処理する
とよい。そして前記熱処理は、ピンテンター、クリップ
テンター、コンベア式熱風処理機などを用い、弛緩状態
あるいは少なくとも一方向を緊張状態で施される。特
に、不織布全面に伸縮性を付与する場合は、弛緩状態で
熱処理するとよく、例えば、絡合不織布を機械方向に5
0〜150%オーバーフィードさせながら、幅方向に0
〜50%収縮させると、伸縮性および風合いが良好な伸
縮性不織布が得られる。The obtained entangled nonwoven fabric is subjected to a heat treatment at a temperature at which the constituent fibers do not have a thermal bond, so that the S fibers are three-dimensionally crimped, and the stretchable nonwoven fabric has no constituent fibers substantially thermally bonded. And Here, the term “substantially not thermally bonded” is a concept that includes the adhesion between fibers due to softening of the resin and does not include at least a part of the resin that is melted. The heat treatment temperature is above the temperature T (° C.) at which the number of crimps is expressed as 17 pieces / 25 mm or more, and the melting point TS L (° C.) of the S fiber.
And B melting point TB L (° C.) of the fiber may be heat treated at a temperature below. The heat treatment is performed using a pin tenter, a clip tenter, a conveyor-type hot-air treatment machine, or the like, in a relaxed state or in a tension state in at least one direction. In particular, when imparting elasticity to the entire surface of the nonwoven fabric, the heat treatment is preferably performed in a relaxed state.
0 to 150% overfeed, 0
When contracted by 50%, a stretchable nonwoven fabric having good stretchability and texture can be obtained.
【0025】このようにして得られた伸縮性不織布の縦
方向および横方向における破断伸度は、少なくとも10
0%であり、かつ不織布の横方向の50%モジュラスが
0.7cN/50mm以下であることが好ましい。破断伸度が
100%未満、かつ50%モジュラスが0.7cN/50mm
を超えると、不織布が身体の動きに追随せず、圧迫感が
あるので好ましくない。The elongation at break of the stretchable nonwoven fabric thus obtained in the longitudinal and transverse directions is at least 10
Preferably, it is 0% and the 50% modulus in the transverse direction of the nonwoven fabric is 0.7 cN / 50 mm or less. Elongation at break less than 100% and 50% modulus 0.7cN / 50mm
Exceeding the range is not preferable because the nonwoven fabric does not follow the movement of the body and has a feeling of pressure.
【0026】そして、本発明の伸縮性不織布は、繊維ウ
ェブ、短繊維や長繊維からなる不織布、編織物、網状
物、またはフィルムなどに積層させたり、あるいは自己
同士を重ね合わせたり、積層させて、構成繊維の軟化点
以上の温度でヒートシールすると、その効果が十分に発
揮され、ヒートシール部分における剥離強力に優れると
ともに非ヒートシール部分では高度な伸縮性と良好な風
合いが維持されたものとなる。The stretchable nonwoven fabric of the present invention may be laminated on a fibrous web, a nonwoven fabric composed of short fibers or long fibers, a knitted fabric, a net, a film, or the like, or may be laminated or laminated on itself. When heat-sealing at a temperature higher than the softening point of the constituent fibers, the effect is sufficiently exerted, the peeling strength in the heat-sealed part is excellent, and the high stretchability and good texture are maintained in the non-heat-sealed part. Become.
【0027】[0027]
【実施例】以下、本発明の内容を実施例により説明す
る。なお、各繊維の捲縮数、融点、得られた伸縮性不織
布の引張強力、破断伸度、50%モジュラス、およびヒ
ートシール強力はそれぞれ以下の方法で測定した。DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the contents of the present invention will be described with reference to embodiments. The number of crimps, melting point, tensile strength, elongation at break, 50% modulus, and heat seal strength of the obtained elastic nonwoven fabric were measured by the following methods.
【0028】[捲縮数]まず、繊維を約200本束ね、
繊維束の一端(端から約2mm付近)を綿糸で縛り、他端
は無荷重とし、乾燥機内に吊しておく。次に、乾燥機内
を徐々に昇温していき、所定の温度で5分間恒温状態を
保持した後、繊維束の中から繊維を5本取り出し、この
操作を10℃毎に繰り返す。そして、JIS L 10
15に準じて、取り出した繊維の捲縮数を測定した。[Number of crimps] First, about 200 fibers were bundled,
One end (approximately 2 mm from the end) of the fiber bundle is tied with a cotton thread, and the other end is unloaded and suspended in a dryer. Next, the temperature inside the dryer is gradually increased, and after maintaining a constant temperature state at a predetermined temperature for 5 minutes, five fibers are taken out of the fiber bundle, and this operation is repeated every 10 ° C. And JIS L 10
According to No. 15, the number of crimps of the fiber taken out was measured.
【0029】[融点(DSC測定)]セイコー電子工業
(株)製SSC−5000を用いて、6mgの繊維を昇温
速度10℃/min 、窒素ガスの条件下で測定した。[Melting Point (DSC Measurement)] Using SSC-5000 manufactured by Seiko Denshi Kogyo Co., Ltd., 6 mg of fiber was measured at a heating rate of 10 ° C./min under nitrogen gas conditions.
【0030】[引張強力、破断伸度]複合シートの横方
向を長さ方向とする幅5cm、長さ15cmの試料片を、つ
かみ間隔10cmで把持し定速伸長型引張試験機(商品
名:テンシロン オリエンテック(株)製)を用いて3
0cm/分の速度で伸長し、切断時の荷重値を引張強力と
した。[Tensile Strength, Elongation at Break] A constant speed elongation type tensile tester (trade name: 3 using Tensilon Orientec Co., Ltd.
The film was stretched at a speed of 0 cm / min, and the load value at the time of cutting was defined as tensile strength.
【0031】[50%モジュラス]複合シートの横方向
を長さ方向とする幅5cm、長さ15cmの試料片を、つか
み間隔10cmで把持し、上記定速伸長型引張試験機を用
いて30cm/分の速度で50%伸長させたときの荷重値
を50%モジュラスとした。[50% Modulus] A sample piece having a width of 5 cm and a length of 15 cm, the length of which is the transverse direction of the composite sheet, is gripped at a gripping interval of 10 cm, and 30 cm / cm is measured using the above constant-speed elongation type tensile tester. The load value at the time of 50% elongation at the speed of minutes was defined as 50% modulus.
【0032】[ヒートシール強力]横方向を長さ方向と
する幅2.5cm、長さ15cmの試料片2枚準備し、それ
を重ね合わせる。重ね合わせた試料片の長さ方向末端3
cmの位置で幅方向に、ヒートシール機(ヒートシールテ
スター上下温調TYPE「TP-701-B」 テスター産業(株)
製)を用いて、ヒートシール幅2mm、温度165℃、圧
力6.1kg/cm2、0.4秒間ヒートシール処理を行っ
た。そして、ヒートシール後の試料片をつかみ間隔10
cmで把持し、上記定速伸長型引張試験機を用いて10cm
/分の速度で伸長させたときの極大値3点および極小値
3点の計6点の荷重値を平均したものをヒートシール強
力とした。[Heat Seal Strength] Two specimens each having a width of 2.5 cm and a length of 15 cm, whose length is in the horizontal direction, are prepared and superposed. Lengthwise end 3 of superimposed sample pieces
In the width direction at the position of cm, heat seal machine (heat seal tester vertical temperature control TYPE "TP-701-B" Tester Sangyo Co., Ltd.
Was heat-sealed at a heat seal width of 2 mm, a temperature of 165 ° C., a pressure of 6.1 kg / cm 2 , and 0.4 seconds. Then, the sample piece after the heat sealing is grasped at an interval of 10
cm, and 10 cm using the constant-speed extension type tensile tester.
The average of the load values at a maximum of 3 points and a minimum of 3 points at the time of elongation at a rate of / min, which is a total of 6 points, was defined as the heat sealing strength.
【0033】[実施例1]S繊維として、鞘成分をTSL
=142℃のエチレン−プロピレン共重合体とし、芯成
分をTSH=163℃のポリプロピレンとし、これらが偏
心鞘芯型に配置された温度T=130℃における捲縮数
が20個/25mmの立体捲縮発現を有する繊度2.2dte
x、繊維長51mmのポリプロピレン系潜在捲縮性複合繊
維(大和紡績(株)製)を70重量%、B繊維として、
鞘成分をTBL=142℃のエチレン−プロピレン共重合
体とし、芯成分をTBH=163℃のポリプロピレンと
し、これらが同心円鞘芯型に配置された繊度2.2dte
x、繊維長51mmのポリプロピレン系複合繊維(大和紡
績(株)製)を30重量%からなる目付40g/m2のパラ
レルウェブを作製した。そして、繊維ウェブに孔径0.
12mmのオリフィスが0.6mm間隔で穿設されたノズル
から3MPa の水流を積層体の表裏それぞれ2回噴射して
絡合一体化させたあと、70℃で乾燥して絡合シートと
なした。[0033] [Example 1] S fiber, the sheath component TS L
= Of 142 ° C. Ethylene - a propylene copolymer, a core component and TS H = 163 ° C. polypropylene, reduced number of winding in these arrangement temperatures T = 130 ° C. in an eccentric sheath-core type 20 / 25mm stereoscopic Fineness of 2.2 dte with crimp development
x, 70% by weight of a polypropylene-based latent crimpable conjugate fiber (manufactured by Daiwa Spinning Co., Ltd.) having a fiber length of 51 mm as B fiber,
Ethylene sheath component TB L = 142 ℃ - a propylene copolymer, a core component and TB H = 163 ° C. polypropylene, fineness they are arranged concentrically sheath-core type 2.2dte
x, a parallel web with a basis weight of 40 g / m 2 consisting of 30% by weight of a polypropylene-based composite fiber (manufactured by Daiwa Spinning Co., Ltd.) having a fiber length of 51 mm. The fiber web has a pore size of 0.
A water stream of 3 MPa was jetted twice from each of the nozzles having 12 mm orifices at 0.6 mm intervals on each of the front and back sides of the laminate to form an entangled body, and then dried at 70 ° C. to form an entangled sheet.
【0034】次いで、ピンテンターを用いて、熱処理温
度135℃、縦方向に65%オーバーフィードさせて、
絡合シートに熱処理を施し、目付70g/m2の構成繊維同
士が熱接着されていない伸縮性不織布を得た。Next, using a pin tenter, heat-treating temperature is 135 ° C., and over-feed is performed 65% in the vertical direction.
The entangled sheet was subjected to a heat treatment to obtain a stretchable nonwoven fabric having a basis weight of 70 g / m 2 in which the constituent fibers were not thermally bonded.
【0035】[実施例2]実施例1の繊維ウェブに孔径
0.12mmのオリフィスが0.6mm間隔で穿設されたノ
ズルから2MPa の水流を積層体の表裏それぞれ2回噴射
して予備絡合一体化させたあと、開孔形成用支持体(日
本フィルコン(株)製平織物25メッシュ)上で、孔径
0.12mmのオリフィスが0.6mm間隔で設けられたノ
ズルから水圧7MPaの水流を噴射し、開孔を形成させた
あと、70℃で乾燥して絡合シートとなした。次いで、
ピンテンターを用いて、熱処理温度135℃、縦方向に
65%オーバーフィードさせて、絡合シートに熱処理を
施し、目付70g/m2の構成繊維同士が熱接着されていな
い伸縮性開孔不織布を得た。なお、得られた開孔不織布
の平均開孔面積は2mm2、開孔率は13%であった。[Example 2] A water stream of 2 MPa was jetted twice from a nozzle in which orifices having a hole diameter of 0.12 mm were drilled at intervals of 0.6 mm to the fiber web of Example 1 twice for each of the front and back sides of the laminate to perform preliminary entanglement. After being integrated, a water stream with a water pressure of 7 MPa is injected from a nozzle provided with orifices having a hole diameter of 0.12 mm at intervals of 0.6 mm on a support for forming pores (25-mesh plain fabric manufactured by Nippon Filcon Co., Ltd.). Then, after forming an opening, it was dried at 70 ° C. to form an entangled sheet. Then
Using a pin tenter to give a heat treatment temperature of 135 ° C., in the longitudinal direction is 65% overfeed, subjected to heat treatment entangled sheet, a stretchable opening nonwoven fabric constituting fibers having a basis weight of 70 g / m 2 is not heat-bonded Was. The average open area of the obtained nonwoven fabric was 2 mm 2 , and the open area ratio was 13%.
【0036】[実施例3]第1繊維ウェブとして、目付
を20g/m2とした以外は、実施例1と同様の組み合わせ
からなるパラレルウェブを第1繊維ウェブとし、実施例
1のポリプロピレン系潜在捲縮性複合繊維(大和紡績
(株)製)を70重量%、および繊度1.67dtex、繊
維長40mmのレーヨン繊維(ダイワボウレーヨン(株)
製)を30重量%からなる目付20g/m2のパラレルウェ
ブを第2繊維ウェブとした。そして、第1繊維ウェブと
第2繊維ウェブとを積層した繊維ウェブに孔径0.12
mmのオリフィスが0.6mm間隔で穿設されたノズルから
3MPa の水流を積層体の表裏それぞれ1回噴射して予備
絡合一体化させたあと、開孔形成用支持体(日本フィル
コン(株)製平織物25メッシュ)上で、孔径0.12
mmのオリフィスが0.6mm間隔で設けられたノズルから
水圧7MPaの水流を噴射し、開孔を形成させたあと、7
0℃で乾燥して絡合シートとなした。次いで、ピンテン
ターを用いて、熱処理温度135℃、縦方向に65%オ
ーバーフィードさせて、絡合シートに熱処理を施し、目
付70g/m2の構成繊維同士が熱接着されていない伸縮性
開孔不織布を得た。なお、得られた開孔不織布の平均開
孔面積は2mm2、開孔率は13%であった。Example 3 A parallel web made of the same combination as in Example 1 except that the basis weight was set to 20 g / m 2 was used as the first fibrous web. 70% by weight of crimpable conjugate fiber (manufactured by Daiwa Spinning Co., Ltd.), rayon fiber having a fineness of 1.67 dtex and a fiber length of 40 mm (Daiwabo Rayon Co., Ltd.)
Was produced as a second fiber web using a parallel web composed of 30% by weight and having a basis weight of 20 g / m 2 . Then, the fiber web obtained by laminating the first fiber web and the second fiber web has a pore size of 0.12.
A water stream of 3 MPa is jetted once from each of the front and back sides of the laminated body from a nozzle in which orifices of 0.6 mm are bored at intervals of 0.6 mm to perform pre-entanglement and integration, and then a support for forming an opening (Nippon Filcon Co., Ltd.) 25 woven fabric), with a pore size of 0.12
After a water stream with a water pressure of 7 MPa is jetted from a nozzle provided with 0.6 mm orifices at 0.6 mm intervals to form openings,
It was dried at 0 ° C. to form an entangled sheet. Then, by using a pin tenter, heat treatment temperature 135 ° C., longitudinally direction by 65% overfeed, subjected to heat treatment entangled sheet, stretchable opening nonwoven fabric constituting fibers having a basis weight of 70 g / m 2 is not heat-bonded I got The average opening area of the obtained nonwoven fabric was 2 mm 2 , and the opening ratio was 13%.
【0037】[比較例1]B繊維として、鞘成分をTBL
=132℃の高密度ポリエチレンとし、芯成分をTBH=
163℃のポリプロピレンとし、これらが同心円鞘芯型
に配置された繊度2.2dtex、繊維長51mmの熱接着性
複合繊維(大和紡績(株)製)とした以外は、実施例2
と同様の方法で目付70g/m2の構成繊維同士が熱接着さ
れた伸縮性開孔不織布を得た。なお、得られた開孔不織
布の平均開孔面積は2mm2、開孔率は13%であった。[0037] [Comparative Example 1] B fiber, the sheath component TB L
= High-density polyethylene at 132 ° C and core component TB H =
Example 2 except that polypropylene was used at 163 ° C., and these were heat-adhesive composite fibers (manufactured by Daiwa Spinning Co., Ltd.) having a concentric sheath-core type of 2.2 dtex and a fiber length of 51 mm.
In the same manner as described above, a stretched open nonwoven fabric was obtained in which constituent fibers having a basis weight of 70 g / m 2 were thermally bonded to each other. The average open area of the obtained nonwoven fabric was 2 mm 2 , and the open area ratio was 13%.
【0038】[比較例2]S繊維として、実施例1のポ
リプロピレン系潜在捲縮性複合繊維(大和紡績(株)
製)を70重量%、繊度1.67dtex、繊維長40mmの
レーヨン繊維(ダイワボウレーヨン(株)製)を30重
量%とした以外は、実施例2と同様の方法で目付70g/
m2の構成繊維同士が熱接着されていない伸縮性開孔不織
布を得た。なお、得られた開孔不織布の平均開孔面積は
3mm2、開孔率は13%であった。実施例1〜3および
比較例1〜2の諸性能を表1に示す。Comparative Example 2 As the S fiber, the polypropylene-based latently crimpable conjugate fiber of Example 1 (Daiwa Spinning Co., Ltd.)
70% by weight, a rayon fiber having a fineness of 1.67 dtex and a fiber length of 40 mm (manufactured by Daiwabo Rayon Co., Ltd.) was changed to 30% by weight in the same manner as in Example 2 except that the basis weight was 70 g / g.
Configuration fibers of m 2 was obtained stretchable opening nonwoven fabric which has not been heat-bonded. The average open area of the obtained nonwoven fabric was 3 mm 2 , and the open area ratio was 13%. Table 1 shows various performances of Examples 1 to 3 and Comparative Examples 1 and 2.
【0039】[0039]
【表1】 [Table 1]
【0040】実施例1〜3において、ポリプロピレン系
潜在捲縮性複合繊維(S繊維)が捲縮発現するととも
に、構成繊維同士が熱接着されていないので、伸縮性に
優れた不織布が得られ、これをヒートシール処理する
と、強固に接着させることができた。また、実施例2、
実施例3は、開孔が形成されており、通気性に優れてい
た。一方、比較例1は、熱接着性複合繊維(B繊維)の
融点以上の温度で熱処理したため、構成繊維同士が接着
されており、ヒートシール強力には優れているものの、
伸縮性が阻害されるだけでなく、風合いも硬く、おむつ
部材など人肌に接触する用途には不向きであった。ま
た、比較例2は、熱接着性繊維(B繊維)が存在しない
ため、ヒートシール強力が極端に低下した。In Examples 1 to 3, the polypropylene-based latently crimpable conjugate fiber (S fiber) was crimped and the constituent fibers were not thermally bonded to each other, so that a non-woven fabric excellent in elasticity was obtained. When this was heat-sealed, it could be firmly adhered. Example 2
In Example 3, the openings were formed and the air permeability was excellent. On the other hand, in Comparative Example 1, since the heat treatment was performed at a temperature equal to or higher than the melting point of the heat-adhesive conjugate fiber (B fiber), the constituent fibers were bonded to each other, and although the heat sealing strength was excellent,
Not only the elasticity is impaired, but also the texture is hard, and it is not suitable for uses such as diaper members that come in contact with human skin. In Comparative Example 2, the heat-sealing strength was extremely reduced because no heat-adhesive fiber (B fiber) was present.
【0041】[0041]
【発明の効果】本発明の伸縮性不織布は、特定の潜在捲
縮性複合繊維および熱接着性繊維からなる繊維ウェブを
用い、潜在捲縮性複合繊維の捲縮数が17個/25mm以上
に立体捲縮発現させるとともに、構成繊維同士を実質的
に熱接着させていないことにより、伸縮性が阻害される
ことなく、肌触りが良好であり、同時にヒートシール強
力に富む伸縮性不織布が得られる。また、前記繊維ウェ
ブの少なくとも片面に親水性繊維を含有する繊維ウェブ
を積層させると、伸縮性および吸水性に富み、かつヒー
トシール性に優れた伸縮性不織布が得られる。The stretchable nonwoven fabric of the present invention uses a fiber web composed of a specific latent crimpable conjugate fiber and a heat-adhesive fiber, and the number of crimps of the latent crimpable conjugate fiber is 17/25 mm or more. Since a three-dimensional crimp is developed and the constituent fibers are not substantially thermally bonded to each other, a stretchable nonwoven fabric that has a good touch and a high heat-sealing strength without obstructing stretchability can be obtained. In addition, when a fiber web containing hydrophilic fibers is laminated on at least one surface of the fiber web, a stretchable nonwoven fabric which is rich in stretchability and water absorption and excellent in heat sealability can be obtained.
【0042】さらに、本発明の伸縮性不織布は、開孔面
積0.25〜30mm2の開孔を形成させた開孔不織布と
することにより、肌触りが織物ライクであり、通気性に
優れた伸縮性不織布が得られる。そして、本発明の伸縮
性不織布は、例えば、おむつ部材などの衛生材料、使い
捨て肌着、サポーター、パップ剤基布などに好適であ
る。[0042] Furthermore, the stretchable nonwoven fabric of the present invention, by the opening nonwoven fabric obtained by forming an opening of the open area 0.25~30Mm 2, touch is woven like, highly breathable stretch A nonwoven fabric is obtained. The stretchable nonwoven fabric of the present invention is suitable for, for example, sanitary materials such as diaper members, disposable undergarments, supporters, cataplasms and the like.
【図1】本発明に用いられる立体捲縮性繊維における捲
縮形態の一例を示す。FIG. 1 shows an example of a crimped form in a three-dimensional crimpable fiber used in the present invention.
【図2】本発明に用いられる立体捲縮性繊維における捲
縮形態の別の一例を示す。FIG. 2 shows another example of a crimped form in the three-dimensionally crimpable fiber used in the present invention.
【図3】本発明に用いられる立体捲縮性繊維における捲
縮形態の別の一例を示す。FIG. 3 shows another example of a crimped form in the three-dimensionally crimpable fiber used in the present invention.
1 潜在捲縮性複合繊維 2 立体捲縮 1 Latent crimped conjugate fiber 2 3D crimp
Claims (10)
り、熱処理により立体捲縮が発現する潜在捲縮性複合繊
維(以下、S繊維という)と、熱接着性繊維(以下、B
繊維という)を含有した繊維ウェブが三次元的に絡合し
ている不織布であって、下記の構成を満たすことを特徴
とするヒートシール性に優れた伸縮性不織布。 (a)S繊維が、立体捲縮を捲縮数17個/25mm以上発
現する温度T(℃)よりも高い融点TSL(℃)からなる
樹脂を第1成分とし、TSLより5℃以上高い融点TS
H(℃)からなる樹脂を第2成分としたとき、第1成分
と第2成分が並列型に配置、あるいは第1成分を鞘とし
て第2成分を芯とした偏心鞘芯型に配置された潜在捲縮
性複合繊維であること。 (b)B繊維が、温度T(℃)よりも高い融点TB
L(℃)を低融点成分とし、以下の関係を満たす熱接着
性繊維であること。 TSL−20 ≦ TBL ≦ TSL+20 (c)S繊維が、捲縮数17個/25mm以上に立体捲縮発
現するとともに、構成繊維同士が実質的に熱接着されて
いないこと。1. A method comprising two or more polymers having different melting points.
Latently crimped composite fiber
Wei (hereinafter referred to as S fiber) and heat-adhesive fiber (hereinafter referred to as B fiber)
Fibrous web containing fibers)
Characterized by satisfying the following configuration
Stretch nonwoven fabric with excellent heat sealability. (A) S-fiber crevices three-dimensional crimps 17 crimps / 25mm or more
Melting point TS higher than temperature T (° C)L(℃)
Resin as the first component, TSLMelting point TS higher than 5 ℃
H(C) as the second component, the first component
And the second component are arranged in parallel, or the first component is sheathed.
Latent crimp arranged in an eccentric sheath-core type with the second component as the core
It should be a composite fiber. (B) B fiber has a melting point TB higher than the temperature T (° C.)
L(° C) as a low melting point component, thermal bonding satisfying the following relationship
It must be synthetic fiber. TSL-20 ≤ TBL ≤ TSL+20 (c) Three-dimensional crimping of S fibers with a crimp count of 17 / 25mm or more
As well as the constituent fibers are substantially thermally bonded
Not that.
0〜20重量%含有することを特徴とする請求項1に記
載のヒートシール性に優れた伸縮性不織布。2. The S fiber is 50 to 80% by weight and the B fiber is 5% by weight.
The stretchable nonwoven fabric having excellent heat sealability according to claim 1, which contains 0 to 20% by weight.
点樹脂を鞘成分とし、TBLより10℃以上高い融点TB
H(℃)からなる高融点樹脂を芯成分とした同心円鞘芯
型複合繊維であることを特徴とする請求項1または2に
記載のヒートシール性に優れた伸縮性不織布。Wherein B fibers, the melting point TB L a low melting point resin comprising (℃) as the sheath component, TB L than 10 ° C. or more higher than the melting point TB
The stretchable nonwoven fabric having excellent heat-sealing properties according to claim 1 or 2, wherein the stretchable nonwoven fabric is a concentric sheath-core composite fiber having a core component of a high melting point resin composed of H (° C).
が、同一樹脂からなることを特徴とする請求項1〜3の
いずれかに記載のヒートシール性に優れた伸縮性不織
布。4. The heat-sealing stretchable nonwoven fabric according to claim 1, wherein the first component of the S fiber and the low melting point component of the B fiber are made of the same resin.
ェブの少なくとも片面に親水性繊維を含有する繊維ウェ
ブが積層されてなるヒートシール性に優れた伸縮性不織
布。5. A stretchable nonwoven fabric having excellent heat sealing properties, wherein a fibrous web containing hydrophilic fibers is laminated on at least one surface of the fibrous web according to any one of claims 1 to 4.
水性繊維を50〜10重量%、潜在捲縮性複合繊維を5
0〜90重量%含有することを特徴とする請求項5記載
のヒートシール性に優れた伸縮性不織布。6. A fibrous web containing hydrophilic fibers, comprising 50 to 10% by weight of hydrophilic fibers and 5 to 5% of latently crimpable conjugate fibers.
The stretchable nonwoven fabric excellent in heat sealability according to claim 5, which contains 0 to 90% by weight.
開孔が形成された開孔不織布であることを特徴とする請
求項1〜6のいずれかに記載のヒートシール性に優れた
伸縮性不織布。7. The heat-sealing property according to claim 1, wherein the non-woven fabric is an open non-woven fabric having an opening having an opening area of 0.25 to 30 mm 2 . Stretch nonwoven.
断伸度が少なくとも100%であり、かつ不織布の横方
向の50%モジュラスが0.7cN/50mm以下であること
を特徴とする請求項1〜7のいずれかに記載のヒートシ
ール性に優れた伸縮性不織布。8. The nonwoven fabric according to claim 1, wherein the elongation at break in the machine direction and the transverse direction is at least 100%, and the 50% modulus in the transverse direction of the nonwoven fabric is 0.7 cN / 50 mm or less. 7. The stretchable nonwoven fabric according to any one of 7 above, which is excellent in heat sealability.
り、熱処理により立体捲縮が発現するS繊維50〜80
重量%と、S繊維の捲縮数が17個/25mm以上発現する
温度T(℃)より高い融点TBL(℃)を持つB繊維50
〜20重量%を含有する繊維ウェブに、高圧流体流処理
を施して構成繊維同士を三次元的に絡合させ、しかるの
ちに構成繊維同士が熱接着を有しない温度で熱処理を施
して、S繊維を立体捲縮発現させることを特徴とするヒ
ートシール性に優れた伸縮性不織布の製造方法。9. S-fibers 50 to 80 comprising two or more kinds of polymers having different melting points and exhibiting a three-dimensional crimp by heat treatment.
B fiber 50 having a weight percent, the temperature reduced number winding of S fibers express 17 / 25mm or more T a (℃) higher than the melting point TB L (℃)
The fiber web containing 2020% by weight is subjected to a high-pressure fluid flow treatment so that the constituent fibers are three-dimensionally entangled, and then subjected to a heat treatment at a temperature at which the constituent fibers do not have thermal adhesion. A method for producing a stretchable nonwoven fabric having excellent heat sealability, characterized in that fibers are three-dimensionally crimped.
なり、熱処理により立体捲縮が発現するS繊維50〜8
0重量%と、S繊維の捲縮数が17個/25mm以上発現す
る温度T(℃)より高い融点TBL(℃)を持つB繊維5
0〜20重量%を含有する繊維ウェブと、親水性繊維5
0〜10重量%と潜在捲縮性複合繊維50〜90重量%
を含有する繊維ウェブを積層し、高圧流体流処理を施し
て構成繊維同士を三次元的に絡合させ一体化し、しかる
のちに構成繊維同士が熱接着を有しない温度で熱処理を
施して、S繊維および/または該潜在捲縮性複合繊維を
立体捲縮発現させることを特徴とするヒートシール性に
優れた伸縮性不織布の製造方法。10. S fibers 50 to 8 comprising two or more kinds of polymers having different melting points and exhibiting three-dimensional crimp by heat treatment.
B fiber 5 having 0% by weight and a melting point TB L (° C.) higher than the temperature T (° C.) at which the number of crimps of the S fiber is 17 pieces / 25 mm or more
A fibrous web containing from 0 to 20% by weight;
0 to 10% by weight and 50 to 90% by weight of latently crimpable conjugate fiber
Are laminated and subjected to a high-pressure fluid flow treatment to entangle and integrate the constituent fibers three-dimensionally, and then heat-treated at a temperature at which the constituent fibers do not have thermal adhesion, A method for producing a stretchable nonwoven fabric having excellent heat sealability, characterized in that fibers and / or the latently crimpable conjugate fibers are expressed in three-dimensional crimps.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7036099A JP4320080B2 (en) | 1999-03-16 | 1999-03-16 | Stretchable nonwoven fabric excellent in heat sealability and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7036099A JP4320080B2 (en) | 1999-03-16 | 1999-03-16 | Stretchable nonwoven fabric excellent in heat sealability and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000265351A true JP2000265351A (en) | 2000-09-26 |
| JP4320080B2 JP4320080B2 (en) | 2009-08-26 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7036099A Expired - Lifetime JP4320080B2 (en) | 1999-03-16 | 1999-03-16 | Stretchable nonwoven fabric excellent in heat sealability and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4320080B2 (en) |
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