JP2000509741A - エチレンおよびα―オレフィンコポリマーの製造法 - Google Patents

エチレンおよびα―オレフィンコポリマーの製造法

Info

Publication number: JP2000509741A
Authority: JP; Japan
Prior art keywords: group; transition metal; ligand; groups; copolymer
Prior art date: 1996-05-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP9539793A

Other languages

English (en)

Japanese (ja)

Inventor

レンケマ，ヤコブ

ミュスケンス，ベルナルダス，ヨハンナ

ベーク，ヨハネス，アントニウス，マリアファン

ドレミエル，ゲラルダス，ヘンリカス，ヨセフスファン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Koninklijke DSM NV

Original Assignee

DSM NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-05-03

Filing date

1997-05-01

Publication date

2000-08-02

1997-05-01 Application filed by DSM NV filed Critical DSM NV

2000-08-02 Publication of JP2000509741A publication Critical patent/JP2000509741A/ja

Status Pending legal-status Critical Current

Links

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239000005977 Ethylene Substances 0.000 title claims abstract description 24
239000004711 α-olefin Substances 0.000 title claims abstract description 22
229920000089 Cyclic olefin copolymer Polymers 0.000 title claims abstract description 10
238000004519 manufacturing process Methods 0.000 title claims description 14
150000003624 transition metals Chemical class 0.000 claims abstract description 74
229910052723 transition metal Inorganic materials 0.000 claims abstract description 73
239000003446 ligand Substances 0.000 claims abstract description 65
238000000034 method Methods 0.000 claims abstract description 46
230000000737 periodic effect Effects 0.000 claims abstract description 20
230000008569 process Effects 0.000 claims abstract description 8
239000003054 catalyst Substances 0.000 claims description 42
238000006116 polymerization reaction Methods 0.000 claims description 33
239000000203 mixture Substances 0.000 claims description 30
125000005842 heteroatom Chemical group 0.000 claims description 29
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125000001424 substituent group Chemical group 0.000 claims description 17
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 15
230000007935 neutral effect Effects 0.000 claims description 14
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125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 12
125000000129 anionic group Chemical group 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 11
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IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
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125000003118 aryl group Chemical group 0.000 claims description 9
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238000007254 oxidation reaction Methods 0.000 claims description 9
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229910000085 borane Inorganic materials 0.000 claims 1
CMWCOKOTCLFJOP-UHFFFAOYSA-N titanium(3+) Chemical group [Ti+3] CMWCOKOTCLFJOP-UHFFFAOYSA-N 0.000 abstract description 3
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238000011065 in-situ storage Methods 0.000 description 5
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238000001157 Fourier transform infrared spectrum Methods 0.000 description 2
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125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
SVFAGVSFZREYAA-UHFFFAOYSA-N ethyl 3-(dibutylamino)propanoate Chemical compound CCCCN(CCCC)CCC(=O)OCC SVFAGVSFZREYAA-UHFFFAOYSA-N 0.000 description 1
IZMJWGJGVGRWBW-UHFFFAOYSA-N ethyl 3-(dimethylamino)propanoate Chemical compound CCOC(=O)CCN(C)C IZMJWGJGVGRWBW-UHFFFAOYSA-N 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
230000011987 methylation Effects 0.000 description 1
238000007069 methylation reaction Methods 0.000 description 1
XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
RVUMUBOXGHTMGZ-UHFFFAOYSA-N n,n-dimethyl-2-[2,3,4-tri(propan-2-yl)cyclopenta-1,3-dien-1-yl]ethanamine Chemical compound CC(C)C1=C(C(C)C)C(C(C)C)=C(CCN(C)C)C1 RVUMUBOXGHTMGZ-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
GCKZPELTJOBCOU-UHFFFAOYSA-N n-butyl-n-[2-(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)ethyl]butan-1-amine Chemical compound CCCCN(CCCC)CCC1C(C)=C(C)C(C)=C1C GCKZPELTJOBCOU-UHFFFAOYSA-N 0.000 description 1
150000002829 nitrogen Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
BEZDDPMMPIDMGJ-UHFFFAOYSA-N pentamethylbenzene Chemical group CC1=CC(C)=C(C)C(C)=C1C BEZDDPMMPIDMGJ-UHFFFAOYSA-N 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
238000010094 polymer processing Methods 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
125000000719 pyrrolidinyl group Chemical group 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
230000007017 scission Effects 0.000 description 1
238000010008 shearing Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
ONQCKWIDZTZEJA-UHFFFAOYSA-N sodium;pentane Chemical compound [Na+].CCCC[CH2-] ONQCKWIDZTZEJA-UHFFFAOYSA-N 0.000 description 1
125000005504 styryl group Chemical group 0.000 description 1
238000000859 sublimation Methods 0.000 description 1
230000008022 sublimation Effects 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
125000004001 thioalkyl group Chemical group 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
MDCWDBMBZLORER-UHFFFAOYSA-N triphenyl borate Chemical compound C=1C=CC=CC=1OB(OC=1C=CC=CC=1)OC1=CC=CC=C1 MDCWDBMBZLORER-UHFFFAOYSA-N 0.000 description 1
125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

JP9539793A 1996-05-03 1997-05-01 エチレンおよびα―オレフィンコポリマーの製造法 Pending JP2000509741A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP96201114.4		1996-05-03
EP96201114		1996-05-03
PCT/NL1997/000243 WO1997042241A1 (en)	1996-05-03	1997-05-01	PROCESS FOR THE PREPARATION OF AN ETHYLENE AND α-OLEFIN COPOLYMER

Publications (1)

Publication Number	Publication Date
JP2000509741A true JP2000509741A (ja)	2000-08-02

Family

ID=8223923

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP9539793A Pending JP2000509741A (ja)	1996-05-03	1997-05-01	エチレンおよびα―オレフィンコポリマーの製造法

Country Status (10)

Country	Link
EP (1)	EP0896599A1 (id)
JP (1)	JP2000509741A (id)
KR (1)	KR20000010946A (id)
AU (1)	AU2411997A (id)
BR (1)	BR9709194A (id)
CA (1)	CA2253542A1 (id)
EA (1)	EA199800977A1 (id)
ID (1)	ID16857A (id)
TW (1)	TW370537B (id)
WO (1)	WO1997042241A1 (id)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2012176915A (ja) *	2011-02-28	2012-09-13	Ube Industries Ltd	アルキルシクロペンタジエン化合物及びその製造方法

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US6635715B1 (en)	1997-08-12	2003-10-21	Sudhin Datta	Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7232871B2 (en)	1997-08-12	2007-06-19	Exxonmobil Chemical Patents Inc.	Propylene ethylene polymers and production process
US6921794B2 (en)	1997-08-12	2005-07-26	Exxonmobil Chemical Patents Inc.	Blends made from propylene ethylene polymers
JP2002519497A (ja)	1998-07-01	2002-07-02	エクソンモービル・ケミカル・パテンツ・インク	結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド
WO2000018808A1 (en) *	1998-09-30	2000-04-06	Exxon Chemical Patents Inc.	Cationic group 3 catalyst system
DE60238049D1 (de)	2001-04-12	2010-12-02	Exxonmobil Chem Patents Inc	Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
EP1444276A1 (en)	2001-11-06	2004-08-11	Dow Global Technologies, Inc.	Isotactic propylene copolymers, their preparation and use
US6906160B2 (en)	2001-11-06	2005-06-14	Dow Global Technologies Inc.	Isotactic propylene copolymer fibers, their preparation and use
US6943215B2 (en)	2001-11-06	2005-09-13	Dow Global Technologies Inc.	Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
US6927256B2 (en)	2001-11-06	2005-08-09	Dow Global Technologies Inc.	Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
KR100830317B1 (ko) *	2001-12-27	2008-05-16	삼성토탈 주식회사	시클로펜타디엔계열 및 카르보디이미드계열 리간드의 킬레이트 화합물 촉매를 이용한 에틸렌 중합 또는 공중합방법
JP4728643B2 (ja)	2002-10-02	2011-07-20	ダウグローバルテクノロジーズエルエルシー	液状およびゲル状の低分子量エチレンポリマー類
WO2004035680A1 (en)	2002-10-17	2004-04-29	Dow Global Technologies Inc.	Highly filled polymer compositions
US7459500B2 (en)	2002-11-05	2008-12-02	Dow Global Technologies Inc.	Thermoplastic elastomer compositions
US7579407B2 (en)	2002-11-05	2009-08-25	Dow Global Technologies Inc.	Thermoplastic elastomer compositions
DE602004010412T2 (de)	2003-08-19	2008-10-16	Dow Global Technologies, Inc., Midland	Mischpolymerisate als schmelzkleber und verfahren zu deren herstellung

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NZ235032A (en) *	1989-08-31	1993-04-28	Dow Chemical Co	Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5278272A (en) *	1991-10-15	1994-01-11	The Dow Chemical Company	Elastic substantialy linear olefin polymers
US5374696A (en) *	1992-03-26	1994-12-20	The Dow Chemical Company	Addition polymerization process using stabilized reduced metal catalysts
JPH10508055A (ja) *	1994-10-31	1998-08-04	ディーエスエムエヌ．ブイ．	オレフィン重合用触媒組成物及びオレフィン重合法

1997
- 1997-04-14 TW TW086104786A patent/TW370537B/zh active
- 1997-05-01 KR KR1019980709095A patent/KR20000010946A/ko not_active Withdrawn
- 1997-05-01 EP EP97919763A patent/EP0896599A1/en not_active Withdrawn
- 1997-05-01 BR BR9709194A patent/BR9709194A/pt unknown
- 1997-05-01 CA CA002253542A patent/CA2253542A1/en not_active Abandoned
- 1997-05-01 WO PCT/NL1997/000243 patent/WO1997042241A1/en not_active Ceased
- 1997-05-01 AU AU24119/97A patent/AU2411997A/en not_active Abandoned
- 1997-05-01 EA EA199800977A patent/EA199800977A1/ru unknown
- 1997-05-01 JP JP9539793A patent/JP2000509741A/ja active Pending
- 1997-05-02 ID IDP971471A patent/ID16857A/id unknown

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2012176915A (ja) *	2011-02-28	2012-09-13	Ube Industries Ltd	アルキルシクロペンタジエン化合物及びその製造方法

Also Published As

Publication number	Publication date
WO1997042241A1 (en)	1997-11-13
KR20000010946A (ko)	2000-02-25
TW370537B (en)	1999-09-21
BR9709194A (pt)	1999-08-10
ID16857A (id)	1997-11-13
AU2411997A (en)	1997-11-26
EA199800977A1 (ru)	1999-04-29
EP0896599A1 (en)	1999-02-17
CA2253542A1 (en)	1997-11-13

Publication	Publication Date	Title
RU2135522C1 (ru)	1999-08-27	Каталитическая композиция и способ полимеризации олефинов
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JP2000509741A - エチレンおよびα―オレフィンコポリマーの製造法 - Google Patents

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Applications Claiming Priority (3)

Publications (1)

Family

ID=8223923

Family Applications (1)

Country Status (10)

Cited By (1)

Families Citing this family (16)

Family Cites Families (4)

Cited By (1)

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