JP2000513384A - プロピレンのアクロレインへの改良された気相酸化 - Google Patents

プロピレンのアクロレインへの改良された気相酸化

Info

Publication number: JP2000513384A
Authority: JP; Japan
Prior art keywords: solid; gas; reactor; propylene; metal oxide
Prior art date: 1997-07-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP11507597A

Other languages

English (en)

Japanese (ja)

Inventor

コントラクター，ラシユミカント・マガンラル

アンダーソン，マーク・ウイリアム

キヤンポス，ダニエル

エケ，ジエラール

コトビカ，ローラン

フアム，シヤルロツト

シモン，ミシエル

Original Assignee

イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー

エルフ・アトケム・ソシエテ・アノニム

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-07-15

Filing date

1998-07-14

Publication date

2000-10-10

1998-07-14 Application filed by イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー, エルフ・アトケム・ソシエテ・アノニム filed Critical イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー

2000-10-10 Publication of JP2000513384A publication Critical patent/JP2000513384A/ja

Status Pending legal-status Critical Current

Links

QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 75
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 74
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title claims abstract description 67
238000007254 oxidation reaction Methods 0.000 title claims abstract description 40
230000003647 oxidation Effects 0.000 title claims abstract description 38
239000007787 solid Substances 0.000 claims abstract description 146
239000007789 gas Substances 0.000 claims abstract description 92
238000006243 chemical reaction Methods 0.000 claims abstract description 62
238000000034 method Methods 0.000 claims abstract description 46
229910052760 oxygen Inorganic materials 0.000 claims abstract description 33
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 32
239000001301 oxygen Substances 0.000 claims abstract description 32
230000008569 process Effects 0.000 claims abstract description 23
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 21
150000004706 metal oxides Chemical class 0.000 claims abstract description 19
DKUYEPUUXLQPPX-UHFFFAOYSA-N dibismuth;molybdenum;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mo].[Mo].[Bi+3].[Bi+3] DKUYEPUUXLQPPX-UHFFFAOYSA-N 0.000 claims abstract description 17
239000002245 particle Substances 0.000 claims abstract description 14
230000003134 recirculating effect Effects 0.000 claims abstract description 5
239000011261 inert gas Substances 0.000 claims abstract description 4
230000002829 reductive effect Effects 0.000 claims description 31
239000003054 catalyst Substances 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
239000002253 acid Substances 0.000 claims description 9
229910052751 metal Inorganic materials 0.000 claims description 7
239000002184 metal Substances 0.000 claims description 7
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
239000002002 slurry Substances 0.000 claims description 6
238000001354 calcination Methods 0.000 claims description 5
229910052797 bismuth Inorganic materials 0.000 claims description 3
150000003839 salts Chemical class 0.000 claims description 3
238000001035 drying Methods 0.000 claims description 2
230000004907 flux Effects 0.000 claims description 2
230000006872 improvement Effects 0.000 claims description 2
IYNWNKYVHCVUCJ-UHFFFAOYSA-N bismuth Chemical compound [Bi].[Bi] IYNWNKYVHCVUCJ-UHFFFAOYSA-N 0.000 claims 2
238000001694 spray drying Methods 0.000 claims 2
239000000376 reactant Substances 0.000 abstract description 6
238000012360 testing method Methods 0.000 description 18
230000008929 regeneration Effects 0.000 description 17
238000011069 regeneration method Methods 0.000 description 17
239000000047 product Substances 0.000 description 15
239000007800 oxidant agent Substances 0.000 description 11
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
239000000203 mixture Substances 0.000 description 10
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 9
238000004519 manufacturing process Methods 0.000 description 9
239000011733 molybdenum Substances 0.000 description 9
229910052750 molybdenum Inorganic materials 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
230000001590 oxidative effect Effects 0.000 description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
238000005299 abrasion Methods 0.000 description 6
239000000243 solution Substances 0.000 description 6
229910021529 ammonia Inorganic materials 0.000 description 5
230000007423 decrease Effects 0.000 description 5
238000005243 fluidization Methods 0.000 description 5
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
238000013461 design Methods 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000005516 engineering process Methods 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 4
230000009467 reduction Effects 0.000 description 4
238000012546 transfer Methods 0.000 description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
239000002250 absorbent Substances 0.000 description 3
230000002745 absorbent Effects 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
150000001299 aldehydes Chemical class 0.000 description 3
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
230000008859 change Effects 0.000 description 3
229910001882 dioxygen Inorganic materials 0.000 description 3
239000012153 distilled water Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
238000010791 quenching Methods 0.000 description 3
239000012495 reaction gas Substances 0.000 description 3
230000001172 regenerating effect Effects 0.000 description 3
238000010405 reoxidation reaction Methods 0.000 description 3
238000000926 separation method Methods 0.000 description 3
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
BYUANIDVEAKBHT-UHFFFAOYSA-N [Mo].[Bi] Chemical compound [Mo].[Bi] BYUANIDVEAKBHT-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000001273 butane Substances 0.000 description 2
229910002090 carbon oxide Inorganic materials 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000003795 desorption Methods 0.000 description 2
238000011161 development Methods 0.000 description 2
230000018109 developmental process Effects 0.000 description 2
238000010586 diagram Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 2
239000002243 precursor Substances 0.000 description 2
239000001294 propane Substances 0.000 description 2
238000004064 recycling Methods 0.000 description 2
230000035945 sensitivity Effects 0.000 description 2
239000002344 surface layer Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
241000277331 Salmonidae Species 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
AURGTTBETYANJX-UHFFFAOYSA-N [Bi].C(=O)C=C Chemical compound [Bi].C(=O)C=C AURGTTBETYANJX-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
-1 antimony metal oxide Chemical class 0.000 description 1
239000011324 bead Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000006260 foam Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
239000010410 layer Substances 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
210000000653 nervous system Anatomy 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
JKJKPRIBNYTIFH-UHFFFAOYSA-N phosphanylidynevanadium Chemical compound [V]#P JKJKPRIBNYTIFH-UHFFFAOYSA-N 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000011027 product recovery Methods 0.000 description 1
230000006207 propylation Effects 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
239000004576 sand Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000011973 solid acid Substances 0.000 description 1
238000003746 solid phase reaction Methods 0.000 description 1
238000010671 solid-state reaction Methods 0.000 description 1
241000894007 species Species 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
230000007704 transition Effects 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
239000002912 waste gas Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
- B01J8/1863—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement outside the reactor and subsequently re-entering it
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Combustion & Propulsion (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Catalysts (AREA)

JP11507597A 1997-07-15 1998-07-14 プロピレンのアクロレインへの改良された気相酸化 Pending JP2000513384A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US5569397P	1997-07-15	1997-07-15
US60/055,693		1997-07-15
PCT/US1998/014511 WO1999003809A1 (en)	1997-07-15	1998-07-14	Improved vapor phase oxidation of propylene to acrolein

Publications (1)

Publication Number	Publication Date
JP2000513384A true JP2000513384A (ja)	2000-10-10

Family

ID=21999559

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP11507597A Pending JP2000513384A (ja)	1997-07-15	1998-07-14	プロピレンのアクロレインへの改良された気相酸化

Country Status (12)

Country	Link
EP (1)	EP0998440A1 (id)
JP (1)	JP2000513384A (id)
KR (1)	KR20010021832A (id)
CN (1)	CN1263519A (id)
AR (1)	AR013221A1 (id)
AU (1)	AU8400798A (id)
BR (1)	BR9810715A (id)
CA (1)	CA2291769A1 (id)
ID (1)	ID24324A (id)
TW (1)	TW477786B (id)
WO (1)	WO1999003809A1 (id)
ZA (1)	ZA986280B (id)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2005105714A1 (ja) *	2004-04-30	2005-11-10	Mitsubishi Chemical Corporation	（メタ）アクリル酸または（メタ）アクロレインの製造方法
JP2009524629A (ja) *	2006-02-07	2009-07-02	アルケマフランス	アクロレインの製法方法

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6281384B1 (en) *	1998-06-26	2001-08-28	E. I. Du Pont Nemours And Company	Vapor phase catalytic oxidation of propylene to acrylic acid
FR2782513B1 (fr) *	1998-08-21	2000-09-15	Atochem Elf Sa	Procede de fabrication de methacroleine a partir d'isobutene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans ladite reaction
FR2782512B1 (fr) *	1998-08-21	2000-09-15	Atochem Elf Sa	Procede de fabrication d'acroleine a partir du propylene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans la dite reaction
AU2318801A (en) *	1999-07-09	2001-01-30	E.I. Du Pont De Nemours And Company	Vapor phase catalytic oxidation of propylene to acrylic acid
US7102050B1 (en) *	2000-05-04	2006-09-05	Exxonmobil Chemical Patents Inc.	Multiple riser reactor
FR2821840B1 (fr) *	2001-03-07	2004-07-16	Atofina	Procede de fabrication d'acide acrylique a partir de propane, en l'absence d'oxygene moleculaire
MXPA04012278A (es)	2002-12-23	2005-02-25	Du Pont	Proceso de fibra bicomponente de poli(tereftalato de trimetileno).
US7785507B2 (en)	2004-04-30	2010-08-31	E. I. Du Pont De Nemours And Company	Spinning poly(trimethylene terephthalate) yarns
US20060041039A1 (en)	2004-08-20	2006-02-23	Gyorgyi Fenyvesi	Fluorescent poly(alkylene terephthalate) compositions
FR2880346B1 (fr) *	2004-12-30	2007-02-23	Arkema Sa	Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau
FR2920767B1 (fr)	2007-09-06	2009-12-18	Arkema France	Procede de vaporisation reactive de glycerol
DE102008051738A1 (de)	2008-10-15	2010-04-22	Trevira Gmbh	PTT-Faser mit verbesserter Einkräuselung
US10479760B2 (en)	2017-02-08	2019-11-19	Clariant Corporation	Synthetic methods for the preparation of propylene ammoxidation catalysts
US10479759B2 (en)	2017-02-08	2019-11-19	Clariant Corporation	Synthetic methods for the preparation of propylene ammoxidation catalysts

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4341717A (en) *	1973-03-08	1982-07-27	The Standard Oil Company	Reactor for contacting gases and a particulate solid
JPS56113726A (en) *	1980-02-08	1981-09-07	Standard Oil Co	Manufacture of aldehyde and carboxylic acid
JPS6133234A (ja) *	1984-07-23	1986-02-17	Mitsubishi Petrochem Co Ltd	触媒の再生法
US4659689A (en) *	1986-03-05	1987-04-21	The Standard Oil Company	Method of preparation of high active phase (AMM)oxidation catalysts with improved performance and attrition resistance
DE4436385A1 (de) *	1994-10-12	1996-04-18	Basf Ag	Verfahren zur katalytischen oxidativen Dehydrierung von Alkylaromaten und Paraffinen

1998
- 1998-07-14 CA CA002291769A patent/CA2291769A1/en not_active Abandoned
- 1998-07-14 ID IDW20000066A patent/ID24324A/id unknown
- 1998-07-14 KR KR1020007000396A patent/KR20010021832A/ko not_active Withdrawn
- 1998-07-14 CN CN98807181A patent/CN1263519A/zh active Pending
- 1998-07-14 BR BR9810715-1A patent/BR9810715A/pt not_active IP Right Cessation
- 1998-07-14 WO PCT/US1998/014511 patent/WO1999003809A1/en not_active Ceased
- 1998-07-14 JP JP11507597A patent/JP2000513384A/ja active Pending
- 1998-07-14 EP EP98934499A patent/EP0998440A1/en not_active Ceased
- 1998-07-14 AU AU84007/98A patent/AU8400798A/en not_active Abandoned
- 1998-07-15 AR ARP980103439A patent/AR013221A1/es not_active Application Discontinuation
- 1998-07-15 ZA ZA9806280A patent/ZA986280B/xx unknown
- 1998-09-08 TW TW087111503A patent/TW477786B/zh active

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2005105714A1 (ja) *	2004-04-30	2005-11-10	Mitsubishi Chemical Corporation	（メタ）アクリル酸または（メタ）アクロレインの製造方法
US7388107B2 (en)	2004-04-30	2008-06-17	Mitsubishi Chemical Corporation	Process for producing (meth)acrylic acid or (meth)acrolein
JP2009524629A (ja) *	2006-02-07	2009-07-02	アルケマフランス	アクロレインの製法方法

Also Published As

Publication number	Publication date
CN1263519A (zh)	2000-08-16
CA2291769A1 (en)	1999-01-28
ID24324A (id)	2000-07-13
TW477786B (en)	2002-03-01
ZA986280B (en)	2000-01-17
EP0998440A1 (en)	2000-05-10
KR20010021832A (ko)	2001-03-15
AU8400798A (en)	1999-02-10
BR9810715A (pt)	2000-08-08
AR013221A1 (es)	2000-12-13
WO1999003809A1 (en)	1999-01-28

Publication	Publication Date	Title
JP2000513384A (ja)	2000-10-10	プロピレンのアクロレインへの改良された気相酸化
US6437193B1 (en)	2002-08-20	Vapor phase oxidation of propylene to acrolein
US6781017B2 (en)	2004-08-24	Method for the production of acrolein or acrylic acid or the mixture thereof from propane
US4668802A (en)	1987-05-26	Improved vapor phase catalytic oxidation of butane to maleic anhydride
JP2001213821A (ja)	2001-08-07	不飽和のアルデヒドおよび酸を製造するための高炭化水素空間速度プロセス
US6310240B1 (en)	2001-10-30	Vapor phase oxidation of acrolein to acrylic acid
JP5114474B2 (ja)	2013-01-09	主要反応器および後方反応器中でのｏ−キシロールの気相酸化による無水フタル酸の製造
KR20090014298A (ko)	2009-02-09	ｏ-크실렌 기상 산화에 의한 프탈산 무수물의 제조
US6281384B1 (en)	2001-08-28	Vapor phase catalytic oxidation of propylene to acrylic acid
TW200307575A (en)	2003-12-16	Method for reactivating catalyst for production of methacrylic acid
US2526689A (en)	1950-10-24	Process for controlled catalytic oxidation
JP4221060B2 (ja)	2009-02-12	その場での触媒のか焼／活性化を包含するｎ−ブタンの無水マレイン酸への気相触媒酸化
JP5260300B2 (ja)	2013-08-14	プロパンからのアクロレイン、又はアクリル酸、又はその混合物の製法
KR20030036171A (ko)	2003-05-09	저 올레핀을 불포화 알데히드로 산화하기 위한 촉매, 그제조방법 및 그 이용
WO2001004079A1 (en)	2001-01-18	Vapor phase catalytic oxidation of propylene to acrylic acid
CN101087648A (zh)	2007-12-12	在不存在水蒸汽的情况下由丙烷制备丙烯酸的方法
JPS62132832A (ja)	1987-06-16	メタクリル酸および／またはメタクロレインの製造方法
JP3813021B2 (ja)	2006-08-23	メタクリル酸の製造方法
MXPA99011530A (en)	2001-06-26	Improved vapor phase oxidation of propylene to acrolein
CN100577285C (zh)	2010-01-06	包括将丙烷部分氧化成丙烯的制备丙烯酸的方法
JP3036938B2 (ja)	2000-04-24	飽和炭化水素の酸化方法
JP2000016959A (ja)	2000-01-18	メタクロレインの製造方法
Mills et al.	1995	Industrial heterogeneous gas-phase oxidation processes
JP2000239268A (ja)	2000-09-05	無水マレイン酸の製造方法
JP2007031400A (ja)	2007-02-08	アクリル酸の製造方法