JP2004182829A - Lubricating oil additives - Google Patents

Lubricating oil additives Download PDF

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Publication number
JP2004182829A
JP2004182829A JP2002350362A JP2002350362A JP2004182829A JP 2004182829 A JP2004182829 A JP 2004182829A JP 2002350362 A JP2002350362 A JP 2002350362A JP 2002350362 A JP2002350362 A JP 2002350362A JP 2004182829 A JP2004182829 A JP 2004182829A
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Japan
Prior art keywords
lubricating oil
exhaust gas
internal combustion
harmful substances
additive
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JP2002350362A
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Japanese (ja)
Inventor
Kensaku Hoshiba
賢作 干場
Manabu Hoshiba
学 干場
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Abstract

【課題】ガソリン自動車のエンジン油などの内燃機関用石油燃料を燃焼すれば、有害物質を含む排出ガスが発生し、大気汚染を引き起こし環境ホルモンによる人体の健康への影響、光化学スモッグ発生、二酸化炭素増加による地球環境悪化の原因となっている。地球環境を改善し、人体の健康への影響を軽減すべき従来の基準よりもより一層厳しい基準の燃焼技術の改善が必要となった。そこで、長時間の使用後も内燃機関用潤滑油の摩擦損失を低く維持することにより燃焼効率を向上させ省燃費化を図ることができ、且つ、有害物質を含む排出ガスの大幅な浄化をしうる潤滑油添加剤を提供すること。
【解決手段】内燃機関用の潤滑油にシロキサンなどの混合生成物を添加剤として用いた場合、摩擦損失を低く維持し、燃焼効率が向上し排出ガス中の有害物質である一酸化炭素、炭化水素、窒素酸化物の大幅な浄化が達成でき、省燃費化にも格段の効果を有するものである。
[Problem] When burning petroleum fuel for internal combustion engines such as engine oil of gasoline automobiles, exhaust gas containing harmful substances is generated, causing air pollution and the effect of environmental hormones on human health, generation of photochemical smog, carbon dioxide It causes the global environment to deteriorate due to the increase. There is a need for improved combustion technology that is even stricter than conventional standards that should improve the global environment and reduce the impact on human health. Therefore, by keeping the friction loss of the lubricating oil for an internal combustion engine low even after prolonged use, it is possible to improve the combustion efficiency and reduce fuel consumption, and to greatly purify exhaust gas containing harmful substances. To provide a lubricating oil additive.
When a mixed product such as siloxane is used as an additive in a lubricating oil for an internal combustion engine, friction loss is kept low, combustion efficiency is improved, and harmful substances in exhaust gas, such as carbon monoxide and carbon dioxide, are added. It can greatly purify hydrogen and nitrogen oxides, and has a remarkable effect on fuel economy.

Description

【0001】
【発明の属する技術分野】
本発明は、内燃機関用潤滑油の摩擦損失を低く維持し、排気ガスの大幅浄化を図れる潤滑油添加剤に関するものである。
【0002】
【従来の技術】
従来の技術は、地球温暖化の一因とされる大気中のCO 2濃度の抑制や省資源の観点から、ガソリン自動車用エンジン等の内燃機関に対して、耐摩耗性、酸化安定性、清浄分散性などの性能の他に省燃費性を追求したものであった。
【0003】
【発明が解決しようとする課題】
しかしながら、以上の従来技術によれば排出ガス削減ができず、地球環境悪化に歯止めがかからなく社会問題になり、より有効な発明が待望されている。そこでこの発明は、より一段の長時間の使用後においても内燃機関用潤滑油の摩擦損失を低く維持することによる省燃費化と、排気ガス中の有害物質の大幅な浄化を目指した新たな内燃機関用潤滑油の添加剤を提供することを課題とする。
【0004】
【課題を解決するための手段】
以上の課題を解決するために、請求項1の発明は内燃機関用潤滑油にシロキサンを骨格をし、ホウ素(B)を導入し、これに無機系酸化物(Cu、Fe、Mn)と酸化セリウム、シリカ、タルク、二酸化チタンを添加せしめることを特徴とする潤滑油の長寿命化と排気ガス中の有害物質を大幅に浄化する添加剤である。
【0005】
【発明の実施の形態】
この発明で使用する添加剤基材は、シロキサン骨格にホウ素(B)を導入したボロジフェニルシロキサンポリマーである。このようなボロジフェニルシロキサンポリマーは、市販されているポリマーを利用することができ、例えば菱電化成(株)製の商品名ミオサーモV940−70等が挙げられる。
【0006】
添加剤基材としてのボロジフェニルシロキサンポリマーには、無機系Cu、Fe、Mn、酸化セリウム、シリカ、タルク、二酸化チタン等の酸化物を添加・混合する。これらの無機系酸化物の粒径は、例えば0,01〜1μmが望ましい。
【0007】
本発明において、ボロジフェニルシロキサンポリマーと無機系酸化物の配合割合は、例えばボロジフェニルシロキサンポリマー100重量部に対して無機系酸化物20〜100重量部、好ましくは30〜60重量部がよい。
【0008】
【実施形態の効果】
以下本発明の実施例により更に説明する。ボロジフェニルシロキサンポリマー(菱電化成(株)製商品名ミオサーモV940−70、不揮発成分70%、重合度5000、20℃における粘度25センチポイズ)に対して、無機系酸化物(平均粒径0,05μm)を30重量%配合した。両者をよく混合することにより、添加剤を調製することができた。この添加剤を加えた潤滑油でガソリンエンジンの排気濃度試験を実施した。結果を下記表1に示す。
【表1】

Figure 2004182829
上記の表より、本発明の潤滑油添加剤は排気ガス中の有害物質であるCO、HCが大幅に減少している、又、CO2は増加していることにより完全燃焼が起こり、燃焼効率は向上していることを確認できた。
【0009】
【発明の効果】
本発明は、特定の混合比を用いて得られるシロキサンの混合生成物であり、内燃機関用潤滑油の添加剤として用いた場合、長期間の使用においても低い摩擦損失を維持できるため省燃費化にも格段の効果を有し、排気ガス中の有害物質を大幅に浄化を達成するものである。[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to a lubricating oil additive capable of maintaining a low friction loss of a lubricating oil for an internal combustion engine and greatly purifying exhaust gas.
[0002]
[Prior art]
Conventional technologies are designed to reduce wear, oxidation stability, and cleanliness of internal combustion engines such as gasoline automobile engines from the viewpoint of suppressing CO 2 concentration in the atmosphere, which is a cause of global warming, and saving resources. It pursued fuel economy in addition to performance such as dispersibility.
[0003]
[Problems to be solved by the invention]
However, according to the above-described conventional technology, it is not possible to reduce the exhaust gas, and there is no stopping the deterioration of the global environment, which is a social problem, and a more effective invention is expected. Accordingly, the present invention provides a new internal combustion engine that aims to save fuel by maintaining a low friction loss of the lubricating oil for an internal combustion engine even after a longer period of use, and to significantly purify harmful substances in exhaust gas. An object of the present invention is to provide an additive for an engine lubricating oil.
[0004]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, the invention of claim 1 comprises a siloxane skeleton in a lubricating oil for an internal combustion engine, boron ( B ) introduced therein, and an inorganic oxide (Cu, Fe, Mn) and an oxidized oxide. It is an additive that adds cerium, silica, talc, and titanium dioxide to extend the life of lubricating oil and greatly purify harmful substances in exhaust gas.
[0005]
BEST MODE FOR CARRYING OUT THE INVENTION
The additive base material used in the present invention is a borodiphenylsiloxane polymer having boron ( B ) introduced into a siloxane skeleton. As such a borodiphenylsiloxane polymer, a commercially available polymer can be used, and examples thereof include Myothermo V 940-70 (trade name, manufactured by Ryoden Kasei Corporation).
[0006]
The boro diphenylsiloxane polymers as additives substrate, inorganic Cu, Fe, M n, cerium oxide, silica, talc is added and mixed oxides such as titanium dioxide. The particle size of these inorganic oxides, for example 0,01~1Myu m is desirable.
[0007]
In the present invention, the blending ratio of the borodiphenylsiloxane polymer and the inorganic oxide is, for example, 20 to 100 parts by weight, preferably 30 to 60 parts by weight of the inorganic oxide per 100 parts by weight of the borodiphenylsiloxane polymer.
[0008]
Effects of the embodiment
Hereinafter, the present invention will be further described with reference to examples. For a borodiphenyl siloxane polymer (trade name: Myothermo V 940-70, manufactured by Ryoden Kasei Co., Ltd., nonvolatile component 70%, degree of polymerization 5000, viscosity at 20 ° C .: 25 centipoise), inorganic oxide (average particle diameter: 0, 05μ m) was blended 30% by weight. By mixing both well, an additive could be prepared. An exhaust gas concentration test of a gasoline engine was performed using the lubricating oil to which this additive was added. The results are shown in Table 1 below.
[Table 1]
Figure 2004182829
From the above table, it can be seen from the above table that the lubricating oil additive of the present invention significantly reduces CO and HC , which are harmful substances in exhaust gas, and complete increase in CO 2 due to increase in CO 2, resulting in combustion efficiency. Was confirmed to have improved.
[0009]
【The invention's effect】
The present invention is a mixed product of a siloxane obtained by using a specific mixing ratio, and when used as an additive for a lubricating oil for an internal combustion engine, can maintain low friction loss even over a long period of use, so that fuel consumption can be reduced. It also has a remarkable effect, and achieves significant purification of harmful substances in exhaust gas.

Claims (1)

シロキサンを骨格にホウ素(B)を導入し、これに無機系酸化物(Cu、Fe、Mn)と酸化セリウム、シリカ、タルク、二酸化チタンを添加せしめることを特徴とする燃焼効率改善と潤滑油の劣化改善、排気ガス中の有害物質を大幅に浄化をする内燃機関用潤滑油添加剤である。The improvement of combustion efficiency and lubricating oil characterized by introducing borane ( B ) into a siloxane skeleton and adding inorganic oxides (Cu, Fe, Mn) and cerium oxide, silica, talc and titanium dioxide to the skeleton. It is a lubricant additive for internal combustion engines that improves deterioration and significantly purifies harmful substances in exhaust gas.
JP2002350362A 2002-12-02 2002-12-02 Lubricating oil additives Pending JP2004182829A (en)

Priority Applications (1)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005012465A1 (en) * 2003-07-30 2005-02-10 Oxonica Ltd Cerium oxide nanoparticles as fuel supplements
US7615520B2 (en) 2005-03-14 2009-11-10 Afton Chemical Corporation Additives and lubricant formulations for improved antioxidant properties
US7615519B2 (en) 2004-07-19 2009-11-10 Afton Chemical Corporation Additives and lubricant formulations for improved antiwear properties
US7709423B2 (en) 2005-11-16 2010-05-04 Afton Chemical Corporation Additives and lubricant formulations for providing friction modification
US7767632B2 (en) 2005-12-22 2010-08-03 Afton Chemical Corporation Additives and lubricant formulations having improved antiwear properties
US7772167B2 (en) 2006-12-06 2010-08-10 Afton Chemical Corporation Titanium-containing lubricating oil composition
US7776800B2 (en) 2005-12-09 2010-08-17 Afton Chemical Corporation Titanium-containing lubricating oil composition
US7879774B2 (en) 2004-07-19 2011-02-01 Afton Chemical Corporation Titanium-containing lubricating oil composition
US8048834B2 (en) 2007-05-08 2011-11-01 Afton Chemical Corporation Additives and lubricant formulations for improved catalyst performance
WO2018116495A1 (en) * 2016-12-19 2018-06-28 株式会社Vab Lubricating oil additive, lubricating oil, grease composition, fuel oil additive, fuel oil, and oil sludge suppression method
JP7607301B1 (en) 2024-04-30 2024-12-27 克治 沖浦 Additive, method for producing additive, additive-containing lubricant, and method for producing additive-containing lubricant.

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005012465A1 (en) * 2003-07-30 2005-02-10 Oxonica Ltd Cerium oxide nanoparticles as fuel supplements
US7879774B2 (en) 2004-07-19 2011-02-01 Afton Chemical Corporation Titanium-containing lubricating oil composition
US7615519B2 (en) 2004-07-19 2009-11-10 Afton Chemical Corporation Additives and lubricant formulations for improved antiwear properties
CN1724622B (en) * 2004-07-19 2010-05-26 雅富顿公司 Additives and lubricant formulations for improved antiwear properties
US7615520B2 (en) 2005-03-14 2009-11-10 Afton Chemical Corporation Additives and lubricant formulations for improved antioxidant properties
US7709423B2 (en) 2005-11-16 2010-05-04 Afton Chemical Corporation Additives and lubricant formulations for providing friction modification
US7776800B2 (en) 2005-12-09 2010-08-17 Afton Chemical Corporation Titanium-containing lubricating oil composition
US7767632B2 (en) 2005-12-22 2010-08-03 Afton Chemical Corporation Additives and lubricant formulations having improved antiwear properties
US7772167B2 (en) 2006-12-06 2010-08-10 Afton Chemical Corporation Titanium-containing lubricating oil composition
US8048834B2 (en) 2007-05-08 2011-11-01 Afton Chemical Corporation Additives and lubricant formulations for improved catalyst performance
WO2018116495A1 (en) * 2016-12-19 2018-06-28 株式会社Vab Lubricating oil additive, lubricating oil, grease composition, fuel oil additive, fuel oil, and oil sludge suppression method
JP7607301B1 (en) 2024-04-30 2024-12-27 克治 沖浦 Additive, method for producing additive, additive-containing lubricant, and method for producing additive-containing lubricant.
JP2025169044A (en) * 2024-04-30 2025-11-12 克治 沖浦 Additive, method for producing additive, additive-containing lubricant, and method for producing additive-containing lubricant.

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