JP2004196684A - Animal repellent - Google Patents
Animal repellent Download PDFInfo
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- JP2004196684A JP2004196684A JP2002364845A JP2002364845A JP2004196684A JP 2004196684 A JP2004196684 A JP 2004196684A JP 2002364845 A JP2002364845 A JP 2002364845A JP 2002364845 A JP2002364845 A JP 2002364845A JP 2004196684 A JP2004196684 A JP 2004196684A
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- animal repellent
- hydrogen
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- 241001465754 Metazoa Species 0.000 title claims abstract description 34
- 230000002940 repellent Effects 0.000 title claims abstract description 28
- 239000005871 repellent Substances 0.000 title claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 24
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- -1 p- tolyl Chemical group 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052802 copper Chemical group 0.000 claims description 8
- 239000010949 copper Chemical group 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 229910052714 tellurium Inorganic materials 0.000 claims description 3
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 125000003282 alkyl amino group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 2
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
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- SQZCAOHYQSOZCE-UHFFFAOYSA-N 1-(diaminomethylidene)-2-(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N=C(N)N=C(N)N SQZCAOHYQSOZCE-UHFFFAOYSA-N 0.000 abstract description 4
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- 229960002447 thiram Drugs 0.000 abstract description 4
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- XGIDEUICZZXBFQ-UHFFFAOYSA-N 1h-benzimidazol-2-ylmethanethiol Chemical compound C1=CC=C2NC(CS)=NC2=C1 XGIDEUICZZXBFQ-UHFFFAOYSA-N 0.000 abstract description 3
- VLCDUOXHFNUCKK-UHFFFAOYSA-N N,N'-Dimethylthiourea Chemical compound CNC(=S)NC VLCDUOXHFNUCKK-UHFFFAOYSA-N 0.000 abstract description 3
- UQJQVUOTMVCFHX-UHFFFAOYSA-L nabam Chemical compound [Na+].[Na+].[S-]C(=S)NCCNC([S-])=S UQJQVUOTMVCFHX-UHFFFAOYSA-L 0.000 abstract description 3
- PGNWIWKMXVDXHP-UHFFFAOYSA-L zinc;1,3-benzothiazole-2-thiolate Chemical compound [Zn+2].C1=CC=C2SC([S-])=NC2=C1.C1=CC=C2SC([S-])=NC2=C1 PGNWIWKMXVDXHP-UHFFFAOYSA-L 0.000 abstract description 3
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- 125000004429 atom Chemical group 0.000 abstract 1
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- IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 abstract 1
- 241000700159 Rattus Species 0.000 description 9
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- 241000271566 Aves Species 0.000 description 7
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- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 description 4
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- 238000013459 approach Methods 0.000 description 3
- PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 3
- 229950004394 ditiocarb Drugs 0.000 description 3
- 230000009969 flowable effect Effects 0.000 description 3
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 3
- 235000010746 mayonnaise Nutrition 0.000 description 3
- 239000008268 mayonnaise Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000001846 repelling effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 2
- SZUVGFMDDVSKSI-WIFOCOSTSA-N (1s,2s,3s,5r)-1-(carboxymethyl)-3,5-bis[(4-phenoxyphenyl)methyl-propylcarbamoyl]cyclopentane-1,2-dicarboxylic acid Chemical compound O=C([C@@H]1[C@@H]([C@](CC(O)=O)([C@H](C(=O)N(CCC)CC=2C=CC(OC=3C=CC=CC=3)=CC=2)C1)C(O)=O)C(O)=O)N(CCC)CC(C=C1)=CC=C1OC1=CC=CC=C1 SZUVGFMDDVSKSI-WIFOCOSTSA-N 0.000 description 1
- GHYOCDFICYLMRF-UTIIJYGPSA-N (2S,3R)-N-[(2S)-3-(cyclopenten-1-yl)-1-[(2R)-2-methyloxiran-2-yl]-1-oxopropan-2-yl]-3-hydroxy-3-(4-methoxyphenyl)-2-[[(2S)-2-[(2-morpholin-4-ylacetyl)amino]propanoyl]amino]propanamide Chemical compound C1(=CCCC1)C[C@@H](C(=O)[C@@]1(OC1)C)NC([C@H]([C@@H](C1=CC=C(C=C1)OC)O)NC([C@H](C)NC(CN1CCOCC1)=O)=O)=O GHYOCDFICYLMRF-UTIIJYGPSA-N 0.000 description 1
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
- FXQVBOJLSKRNLL-UHFFFAOYSA-N 1,2-bis(4-methylphenyl)guanidine Chemical compound C1=CC(C)=CC=C1NC(N)=NC1=CC=C(C)C=C1 FXQVBOJLSKRNLL-UHFFFAOYSA-N 0.000 description 1
- FXXCHAISRCAUMI-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione;nickel Chemical compound [Ni].C1=CC=C2NC(S)=NC2=C1 FXXCHAISRCAUMI-UHFFFAOYSA-N 0.000 description 1
- LLZHXQRNOOAOFF-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione;zinc Chemical compound [Zn].C1=CC=C2NC(S)=NC2=C1 LLZHXQRNOOAOFF-UHFFFAOYSA-N 0.000 description 1
- RNGRBOULPSEYNL-UHFFFAOYSA-N 1,3-dioctylthiourea Chemical compound CCCCCCCCNC(=S)NCCCCCCCC RNGRBOULPSEYNL-UHFFFAOYSA-N 0.000 description 1
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- UNILWMWFPHPYOR-KXEYIPSPSA-M 1-[6-[2-[3-[3-[3-[2-[2-[3-[[2-[2-[[(2r)-1-[[2-[[(2r)-1-[3-[2-[2-[3-[[2-(2-amino-2-oxoethoxy)acetyl]amino]propoxy]ethoxy]ethoxy]propylamino]-3-hydroxy-1-oxopropan-2-yl]amino]-2-oxoethyl]amino]-3-[(2r)-2,3-di(hexadecanoyloxy)propyl]sulfanyl-1-oxopropan-2-yl Chemical compound O=C1C(SCCC(=O)NCCCOCCOCCOCCCNC(=O)COCC(=O)N[C@@H](CSC[C@@H](COC(=O)CCCCCCCCCCCCCCC)OC(=O)CCCCCCCCCCCCCCC)C(=O)NCC(=O)N[C@H](CO)C(=O)NCCCOCCOCCOCCCNC(=O)COCC(N)=O)CC(=O)N1CCNC(=O)CCCCCN\1C2=CC=C(S([O-])(=O)=O)C=C2CC/1=C/C=C/C=C/C1=[N+](CC)C2=CC=C(S([O-])(=O)=O)C=C2C1 UNILWMWFPHPYOR-KXEYIPSPSA-M 0.000 description 1
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- 239000008186 active pharmaceutical agent Substances 0.000 description 1
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- 239000007864 aqueous solution Substances 0.000 description 1
- VTEKOFXDMRILGB-UHFFFAOYSA-N bis(2-ethylhexyl)carbamothioylsulfanyl n,n-bis(2-ethylhexyl)carbamodithioate Chemical compound CCCCC(CC)CN(CC(CC)CCCC)C(=S)SSC(=S)N(CC(CC)CCCC)CC(CC)CCCC VTEKOFXDMRILGB-UHFFFAOYSA-N 0.000 description 1
- OQSZFKFFOJWHMV-UHFFFAOYSA-L calcium;n,n-diethylcarbamodithioate Chemical compound [Ca+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S OQSZFKFFOJWHMV-UHFFFAOYSA-L 0.000 description 1
- YRGVIQAQIXMJIO-UHFFFAOYSA-L calcium;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Ca+2].[S-]C(=S)NCCNC([S-])=S YRGVIQAQIXMJIO-UHFFFAOYSA-L 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
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- 229940125782 compound 2 Drugs 0.000 description 1
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- 238000007796 conventional method Methods 0.000 description 1
- NSZCUXMZXULZDQ-UHFFFAOYSA-N copper;1,3-dihydrobenzimidazole-2-thione Chemical compound [Cu].C1=CC=C2NC(=S)NC2=C1 NSZCUXMZXULZDQ-UHFFFAOYSA-N 0.000 description 1
- ZOUQIAGHKFLHIA-UHFFFAOYSA-L copper;n,n-dimethylcarbamodithioate Chemical compound [Cu+2].CN(C)C([S-])=S.CN(C)C([S-])=S ZOUQIAGHKFLHIA-UHFFFAOYSA-L 0.000 description 1
- LPITVXZSYRHFAG-UHFFFAOYSA-L copper;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Cu+2].[S-]C(=S)NCCNC([S-])=S LPITVXZSYRHFAG-UHFFFAOYSA-L 0.000 description 1
- SZRLKIKBPASKQH-UHFFFAOYSA-M dibutyldithiocarbamate Chemical compound CCCCN(C([S-])=S)CCCC SZRLKIKBPASKQH-UHFFFAOYSA-M 0.000 description 1
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- GOAJRTRXGRBKTL-UHFFFAOYSA-L dipotassium;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [K+].[K+].[S-]C(=S)NCCNC([S-])=S GOAJRTRXGRBKTL-UHFFFAOYSA-L 0.000 description 1
- AIOREIKMWQQOMJ-UHFFFAOYSA-L disodium;n-[4-(sulfidocarbothioylamino)butyl]carbamodithioate Chemical compound [Na+].[Na+].[S-]C(=S)NCCCCNC([S-])=S AIOREIKMWQQOMJ-UHFFFAOYSA-L 0.000 description 1
- 229940088679 drug related substance Drugs 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- WHDGWKAJBYRJJL-UHFFFAOYSA-K ferbam Chemical compound [Fe+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S WHDGWKAJBYRJJL-UHFFFAOYSA-K 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】
【発明の属する技術分野】
本発明は、動物忌避剤に係り、特に、鳥、鼠、犬並びに猫等の小動物に対して、それを塗布しあるいは散布した物品に忌避効果のある動物忌避剤に関するものである。
【０００２】
【従来の技術】
【特許文献１】特開昭５６−８３４０８号公報
【特許文献２】特開昭６３−３０４０１号公報
【特許文献３】特開平２−１１３８３６号公報
鳥、鼠、犬並びに猫等の小動物によって、近年、住環境を汚染されることがしばしば見られる。
そのため、一般家庭等から出される生ごみ類は、カラス、鼠、野良犬又は野良猫等に食されて散乱しないように、ビニール袋やポリ容器等に入れ、さらには化学繊維製の防御ネット等を被せて、街中の所定のごみ収集場所に集積し、決められた日時に巡回してくるごみ回収車によって回収し、ごみ処理場で処分している。
しかしながら、上記の従来の方法では、ごみ収集場所に人の気配がなくなると、カラス、野良犬又は野良猫等が生ごみから発生する臭気を感じて集まり、ビニール袋やポリ容器から生ごみを引き出して食い散らかし、その結果、ごみ収集場所の周囲に悪臭を放ち、衛生状態を悪くするという問題を引起こしていた。
【０００３】
【発明が解決しようとする課題】
本発明は、上記従来技術の問題点を解決し、それを塗布し、散布した物品に小動物の忌避効果があり、住環境の衛生状態を良好に維持することができる動物忌避剤を提供することを課題とする。
【０００４】
【課題を解決するための手段】
上記課題を解決するために、本発明では、下記一般式（I）〜一般式（Ｖ）の化合物を含有することを特徴とする動物忌避剤としたものである。
一般式（I）
【化６】
【０００５】
一般式（II）
【化７】
一般式（III）
【化８】
【０００６】
一般式（IＶ）
【化９】
一般式（Ｖ）
【化１０】
【０００７】
【発明の実施の形態】
本発明に係る動物忌避剤は、鳥、鼠、犬並びに猫等の小動物に対して忌避効果のある臭気あるいは食味を発生するものである。特に、これらの忌避剤は、鳥類に経口接種されると、喉の粘膜を刺激（痛覚刺激）し、忌避効果を発揮する。これにより、動物忌避剤を塗布したビニール袋やポリ容器等には、鳥、鼠、犬並びに猫等の小動物が近寄らなくなる。また、この動物忌避塗料を食物用倉庫あるいは農園用のビニールハウス等の壁や窓に塗布することにより、食物用倉庫に収納した食品やビニールハウスで栽培した農作物等を鼠等の食害から守ることも可能である。本発明に係る動物忌避剤は、ペレット状に加工したものでも良い。この場合、長期間安定かつ有効な動物忌避剤を提供することが可能となる。
また、本発明に係る動物忌避剤を塗布した物品は、動物に対して忌避効果のある臭気あるいは食味を発生する動物忌避剤を混入させた動物忌避塗料が物品本体の表面に塗布されている。これにより、表面に塗布された物品本体から動物が忌避する臭気が発散し、物品本体に動物が近寄らなくなる。ここで、物品本体には、ビニール袋、ポリ容器、ケーブル並びに柵があげられる。
【０００８】
本発明で動物忌避剤に用いる化合物は、具体的には一般式（I）の化合物としては、Ｎ，Ｎ’−ジメチルチオ尿素、Ｎ，Ｎ’−ジエチルチオ尿素、Ｎ，Ｎ’−ジオクチルチオ尿素、Ｎ，Ｎ’−ジフェニルチオ尿素、１，３−ジフェニルグアニジン、ジ−ｏ−トリルグアニジン、ジ−ｐ−トリルグアニジン又は１−ｏ−トリルビグアニド、一般式（II）の化合物としては、２−メルカプトベンゾイミダゾール、２−メルカプトメチルベンゾイミダゾール、２−メルカプトベンゾイミダゾール亜鉛塩、２−メルカプトベンゾイミダゾールニッケル塩又は２−メルカプトベンゾイミダゾール銅塩、一般式（III）の化合物としては、２−メルカプト−１，３−ベンゾチアゾール、２，２−ビス（ベンゾチアゾリル）ジスルフィド、Ｎ−シクロヘキシル−１，３−ベンゾチアゾル−２−スルフェンアミド、Ｎ−ｔ−ブチル−１，３−ベンゾチアゾル−２−スルフェンアミド、Ｎ−オキシジエチレン−１，３−ベンゾチアゾル−２−スルフェンアミド、Ｎ，Ｎ−ジシクロヘキシル−１，３−ベンゾチアゾル−２−スルフェンアミド、２−メルカプトベンゾチアゾール亜鉛塩又は２−メルカプトベンゾチアゾール銅塩等が挙げられる。
【０００９】
また、一般式（IＶ）の化合物としては、テトラメチルチウラムジスルフィド、テトラエチルチウラムジスルフィド、テトラブチルチウラムジスルフィド、テトラキス（２−エチルヘキシル）チウラムジスルフィド、ジメチルジチオカルバミン酸亜鉛、ジエチルジチオカルバミン酸亜鉛、ジブチルジチオカルバミン酸亜鉛、ジベンジルジチオカルバミン酸亜鉛、ジエチルジチオカルバミン酸ナトリウム、ジエチルジチオカルバミン酸カリウム、ジエチルジチオカルバミン酸カルシウム、ジメチルジチオカルバミン酸銅、ジメチルジチオカルバミン酸第二鉄、ジエチルジチオカルバミン酸テルル、ジメエチルジチオカルバミン酸ニッケル、ジブチルジチオカルバミン酸ニッケル、ジメチルジチオカルバミン酸マンガン又はジブチルジチオカルバミン酸マンガン、一般式（Ｖ）の化合物としては、エチレンビスジチオカルバミン酸ナトリウム、エチレンビスジチオカルバミン酸カリウム、エチレンビスジチオカルバミン酸アンモニウム、エチレンビスジチオカルバミン酸カルシウム、エチレンビスジチオカルバミン酸銅、エチレンビスジチオカルバミン酸ニッケル、エチレンビスジチオカルバミン酸マンガン、ブチレンビスジチオカルバミン酸ナトリウム又はブチレンビスジチオカルバミン酸マンガン等が挙げられる。
【００１０】
【実施例】
次に、実施例を挙げて本発明を説明する。
実施例１
本実施例は、次の化合物１〜１４及び比較例１〜３の化合物を用いて行った。
化合物１：Ｎ，Ｎ’−ジメチルチオ尿素（Ｃ）
化合物２：１−ｏ−トリルビグアニド（ＢＧ）
化合物３：ジ−ｏ−トリルグアニジン（ＤＴ）
化合物４：２−メルカプト−１，３−ベンゾチアゾール（Ｍ）
化合物５：２−メルカプトベンゾチアゾール亜鉛塩（ＭＺ）
化合物６：Ｎ−ｔ−ブチル−１，３−ベンゾチアゾル−２−スルフェンアミド（ＮＳ）
化合物７：Ｎ，Ｎ−ジシクロヘキシル−１，３−ベンゾチアゾル−２−スルフェンアミド（ＤＺ）
【００１１】
化合物８：テトラメチルチウラムジスルフィド（ＴＴ）
化合物９：テトラブチルチウラムジスルフィド（ＴＢＴ）
化合物１０：ジメチルジチオカルバミン酸亜鉛（ＰＺ）
化合物１１：２−メルカプトメチルベンゾイミダゾール（ＭＭＢ）
化合物１２：エチレンビスジチオカルバミン酸ナトリウム（ナバーム）
化合物１３：ジエチルジチオカルバミン酸ナトリウム（ＳＤＣ）
化合物１４：エチレンビスジチオカルバミン酸マンガン（マンネブ）
比較例１：３，４−ジクロルアリニン（特開昭５６−８３４０８号公報）
比較例２：アントラヒドロキノン（特開昭６３−３０４０１号公報）
比較例３：２−ブトキシエタノール（特開平２−１１３８３６号公報）
【００１２】
効果を確認するための試験は次のように行った。
縦５ｍ、横４ｍ、高さ３ｍの金網を張った小屋を用意した。
小屋には、高さ２ｍのところに止まり木を横に取付け、カラスが小屋の中で自由に行動できるように工夫した。
この中にハシブトカラス１２羽を捕獲して入れ、慣らすために１週間、肉などのエサを与えて飼育した。
その後、１日絶食させてから、食パン片（８ｃｍ×５ｃｍ×２ｃｍ）を用意し、この裏、表にマヨネーズを塗り、その上に前記の試験用の化合物を振掛けて小屋の中にセットし、カラスの挙動を、ビデオカメラと５０ｍ離れたカラスから見えにくい場所を選んで双眼鏡とで観察した。また、１時間毎に近づいてエサの状態を観察した。
【００１３】
１回の試験に６個の各化合物をふりかけた食パン片を用意し、これらは毎朝小屋の中に各３０ｃｍ間隔で並べて、同様の試験を毎日繰り返した。
双眼鏡による目視の観察、ビデオによる観察、及びエサの状態から、今回用意した化合物の中には、化合物が振掛けられているにもかかわらず即食するもの、一度口に入れてから吐き出すもの、まったく食しないものの３つに分かれることが確認された。
その結果を表１に示す。
なお、評価は、即食するもの（−）、なかなか食しないが結局食したもの（＋）、一度口に入れてから吐き出したもの（＋＋）、まったく食しないもの（＋＋＋）とした。
まったく食しなかったものについては、味か臭味かの判断に迷うところであるが、今回は両方の相乗効果であると評価した。
【００１４】
【表１】
【００１５】
実施例２
実施例１では、試験用のマヨネーズを塗った食パン片に化合物の原体を直接１０ｇ程度ふりかけて試験したが、実施例２では、各化合物を２０％濃度のフロアブルにして、これを霧吹き器で１５ｍｌ程度噴霧してマヨネーズを塗った食パン片に掛け、実施例１と同様の試験を行った。
（フロアブルの製造例）
水２７ｇにノイゲンＥＡ−１３７（第一工業製薬）３ｇを溶解し、これに実施例１と同じ化合物２０ｇ加えて、ホモミキサーで一次混合を行った。
これとは別に、水４９．７ｇにロードポール２３（ローヌ・プーランジャパン）０．２ｇとＰＶＰ Ｋ−９０（五協産業）０．１を溶解した水溶液を用意した。
次に、この両者を撹拌機の付いたビーカに入れ、数１０分撹拌してフロアブル化物を得た。
（試験の結果）
試験の評価は、実施例１と全く同様の結果であった。
【００１６】
【発明の効果】
本発明の動物忌避剤は、鳥、鼠、犬並びに猫等の小動物に対して忌避効果のある臭気あるいは食味を発生する。動物忌避剤を塗布したビニール袋やポリ容器等には、鳥、鼠、犬並びに猫等の小動物が近寄らなくなり、住環境の衛生状態を良好に維持することができる。また、この動物忌避剤を含有させた塗料を、食物用倉庫あるいは農園用のビニールハウス等の壁や窓に塗布することにより、食物用倉庫に収納した食品やビニールハウスで栽培した農作物等を、鼠等の食害から守ることも可能である。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an animal repellent, and more particularly, to an animal repellent having a repellent effect on small animals, such as birds, rats, dogs, and cats, which are applied or sprayed on small animals.
[0002]
[Prior art]
[Patent Document 1] JP-A-56-83408 [Patent Document 2] JP-A-63-30401 [Patent Document 3] JP-A-2-113836 By small animals such as birds, rats, dogs and cats, In recent years, the living environment is often polluted.
For this reason, garbage from general households should be placed in plastic bags, plastic containers, etc. so that they will not be eaten and scattered by crows, rats, stray dogs or stray cats. Garbage is collected at a predetermined garbage collection point in the city, collected by a garbage truck that goes around at a fixed date and time, and disposed of at a garbage disposal site.
However, according to the above-mentioned conventional method, when there is no sign of the garbage collection place, crows, stray dogs or stray cats, etc., gather due to the odor generated from the garbage, pull out the garbage from a plastic bag or a plastic container and eat it. Scattering and, as a result, stinking around the garbage collection point, causing a problem of poor hygiene.
[0003]
[Problems to be solved by the invention]
An object of the present invention is to provide an animal repellent which solves the above-mentioned problems of the prior art, and which has an effect of repelling small animals on articles applied and sprayed thereon, and which can maintain a good hygiene condition of a living environment. As an issue.
[0004]
[Means for Solving the Problems]
In order to solve the above problems, the present invention provides an animal repellent comprising a compound represented by any one of the following general formulas (I) to (V).
General formula (I)
Embedded image
[0005]
General formula (II)
Embedded image
General formula (III)
Embedded image
[0006]
General formula (IV)
Embedded image
General formula (V)
Embedded image
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
The animal repellent according to the present invention generates an odor or taste having a repellent effect on small animals such as birds, rats, dogs and cats. In particular, when these repellents are orally inoculated into birds, they stimulate the throat mucous membrane (painful stimuli) and exert a repellent effect. As a result, small animals such as birds, rats, dogs and cats do not approach the plastic bags or plastic containers coated with the animal repellent. In addition, by applying this animal repellent paint to the walls and windows of a food warehouse or a farm greenhouse, etc., the food stored in the food warehouse or the crops cultivated in the greenhouse can be protected from damage by rats and other animals. Is also possible. The animal repellent according to the present invention may be processed into a pellet. In this case, it is possible to provide a stable and effective animal repellent for a long period of time.
Further, in the article coated with the animal repellent according to the present invention, an animal repellent paint mixed with an animal repellent which generates an odor or taste having an effect of repelling an animal is applied to the surface of the article body. As a result, the odor at which the animal repels is emitted from the article body applied to the surface, and the animal does not approach the article body. Here, the article body includes a plastic bag, a plastic container, a cable and a fence.
[0008]
Compounds used as animal repellents in the present invention include, specifically, compounds of general formula (I) such as N, N′-dimethylthiourea, N, N′-diethylthiourea, N, N′-dioctylthiourea, N, N'-diphenylthiourea, 1,3-diphenylguanidine, di-o-tolylguanidine, di-p-tolylguanidine or 1-o-tolylbiguanide, and as the compound of the general formula (II), 2-mercapto Benzimidazole, 2-mercaptomethylbenzimidazole, 2-mercaptobenzimidazole zinc salt, 2-mercaptobenzimidazole nickel salt or 2-mercaptobenzimidazole copper salt, and the compound of the general formula (III) include 2-mercapto-1, 3-benzothiazole, 2,2-bis (benzothiazolyl) disulfide, N-cyclohexyl-1,3 -Benzothiazol-2-sulfenamide, Nt-butyl-1,3-benzothiazol-2-sulfenamide, N-oxydiethylene-1,3-benzothiazol-2-sulfenamide, N, N-dicyclohexyl- Examples thereof include 1,3-benzothiazole-2-sulfenamide, zinc 2-mercaptobenzothiazole, and copper 2-mercaptobenzothiazole.
[0009]
Compounds of the general formula (IV) include tetramethylthiuram disulfide, tetraethylthiuram disulfide, tetrabutylthiuram disulfide, tetrakis (2-ethylhexyl) thiuram disulfide, zinc dimethyldithiocarbamate, zinc diethyldithiocarbamate, zinc dibutyldithiocarbamate, Zinc dibenzyldithiocarbamate, sodium diethyldithiocarbamate, potassium diethyldithiocarbamate, calcium diethyldithiocarbamate, copper dimethyldithiocarbamate, ferric dimethyldithiocarbamate, tellurium diethyldithiocarbamate, nickel dimethylethyldithiocarbamate, nickel dibutyldithiocarbamate, dimethyl Manganese dithiocarbamate or dibutyldithiocarbamate Manganese acid, compounds of the general formula (V) include sodium ethylenebisdithiocarbamate, potassium ethylenebisdithiocarbamate, ammonium ethylenebisdithiocarbamate, calcium ethylenebisdithiocarbamate, copper ethylenebisdithiocarbamate, nickel ethylenebisdithiocarbamate, Examples include manganese ethylenebisdithiocarbamate, sodium butylenebisdithiocarbamate, and manganese butylenebisdithiocarbamate.
[0010]
【Example】
Next, the present invention will be described with reference to examples.
Example 1
In this example, the following compounds 1 to 14 and comparative examples 1 to 3 were used.
Compound 1: N, N'-dimethylthiourea (C)
Compound 2: 1-o-tolylbiguanide (BG)
Compound 3: di-o-tolylguanidine (DT)
Compound 4: 2-mercapto-1,3-benzothiazole (M)
Compound 5: 2-mercaptobenzothiazole zinc salt (MZ)
Compound 6: Nt-butyl-1,3-benzothiazol-2-sulfenamide (NS)
Compound 7: N, N-dicyclohexyl-1,3-benzothiazol-2-sulfenamide (DZ)
[0011]
Compound 8: tetramethylthiuram disulfide (TT)
Compound 9: tetrabutylthiuram disulfide (TBT)
Compound 10: zinc dimethyldithiocarbamate (PZ)
Compound 11: 2-mercaptomethylbenzimidazole (MMB)
Compound 12: Sodium ethylenebisdithiocarbamate (Nabalm)
Compound 13: sodium diethyldithiocarbamate (SDC)
Compound 14: Manganese ethylenebisdithiocarbamate (Maneb)
Comparative Example 1: 3,4-dichloroalinine (JP-A-56-83408)
Comparative Example 2: Anthrahydroquinone (JP-A-63-30401)
Comparative Example 3: 2-butoxyethanol (Japanese Unexamined Patent Application Publication No. 2-113836)
[0012]
The test for confirming the effect was performed as follows.
A hut with a wire mesh of 5 m in length, 4 m in width and 3 m in height was prepared.
A perch is attached to the hut at a height of 2 m, so that the crow can freely move in the hut.
In this, 12 crows were collected and bred for one week to feed them.
Then, after fasting for one day, a piece of bread (8 cm x 5 cm x 2 cm) was prepared, and the back and the front were coated with mayonnaise, and the above-mentioned test compound was sprinkled thereon and set in a cabin. The behavior of the crow was observed with binoculars at a place that was difficult to see from the crow 50 m away from the video camera. In addition, the state of the food was observed every hour.
[0013]
Bread pieces sprinkled with each of the six compounds were prepared for one test, and they were arranged in the hut every morning at intervals of 30 cm, and the same test was repeated every day.
From the visual observation with binoculars, video observation, and the state of the food, some of the compounds prepared this time are those that eat immediately despite the compound being sprinkled, those that once put in the mouth and then exhale, It was confirmed that the food was not eaten.
Table 1 shows the results.
In addition, the evaluation was made for those who eat immediately (-), those who did not eat easily but eventually ate (+), those who put it in their mouth once and exhaled (++), and those who did not eat at all (++).
For those who did not eat at all, it is difficult to judge whether it tastes or smells, but this time it was evaluated as a synergistic effect of both.
[0014]
[Table 1]
[0015]
Example 2
In Example 1, a test piece was sprinkled with about 10 g of the drug substance directly on a piece of bread coated with mayonnaise for testing, but in Example 2, each compound was flowable to a concentration of 20%, and this was sprayed with a sprayer. The same test as in Example 1 was performed by spraying about 15 ml on a piece of bread coated with mayonnaise.
(Example of manufacture of flowable)
3 g of Neugen EA-137 (Daiichi Kogyo Seiyaku) was dissolved in 27 g of water, 20 g of the same compound as in Example 1 was added thereto, and primary mixing was performed with a homomixer.
Separately, an aqueous solution was prepared by dissolving 0.2 g of road pole 23 (Rhone Poulin Japan) and 0.1 of PVP K-90 (Gokyo Sangyo) in 49.7 g of water.
Next, both were put into a beaker with a stirrer and stirred for several tens of minutes to obtain a flowable product.
(Test results)
The evaluation of the test was exactly the same as in Example 1.
[0016]
【The invention's effect】
The animal repellent of the present invention produces an odor or taste that has a repellent effect on small animals such as birds, rats, dogs and cats. Small animals such as birds, rats, dogs and cats do not approach the plastic bags or plastic containers coated with the animal repellent, and the sanitary condition of the living environment can be maintained well. In addition, by applying the paint containing the animal repellent to the walls and windows of a food warehouse or a greenhouse for a farm or the like, the food stored in the food warehouse or the crops cultivated in the greenhouse can be used. It is also possible to protect rats from feeding damage.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002364845A JP2004196684A (en) | 2002-12-17 | 2002-12-17 | Animal repellent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002364845A JP2004196684A (en) | 2002-12-17 | 2002-12-17 | Animal repellent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2004196684A true JP2004196684A (en) | 2004-07-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002364845A Pending JP2004196684A (en) | 2002-12-17 | 2002-12-17 | Animal repellent |
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| JP (1) | JP2004196684A (en) |
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