JP2004231963A - 高支持性軟質ポリウレタン発泡体、その製造方法およびその圧潰力の低下方法 - Google Patents
高支持性軟質ポリウレタン発泡体、その製造方法およびその圧潰力の低下方法 Download PDFInfo
- Publication number
- JP2004231963A JP2004231963A JP2004019509A JP2004019509A JP2004231963A JP 2004231963 A JP2004231963 A JP 2004231963A JP 2004019509 A JP2004019509 A JP 2004019509A JP 2004019509 A JP2004019509 A JP 2004019509A JP 2004231963 A JP2004231963 A JP 2004231963A
- Authority
- JP
- Japan
- Prior art keywords
- polyol
- high support
- weight
- parts
- polyurethane foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02B—HYDRAULIC ENGINEERING
- E02B3/00—Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
- E02B3/04—Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
- E02B3/12—Revetment of banks, dams, watercourses, or the like, e.g. the sea-floor
- E02B3/14—Preformed blocks or slabs for forming essentially continuous surfaces; Arrangements thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/06—Flexible foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Environmental Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/352,614 US6855742B2 (en) | 2003-01-28 | 2003-01-28 | Agents for reducing the force-to-crush (FTC) of high support flexible foams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004231963A true JP2004231963A (ja) | 2004-08-19 |
| JP2004231963A5 JP2004231963A5 (2) | 2007-03-08 |
Family
ID=32736019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004019509A Withdrawn JP2004231963A (ja) | 2003-01-28 | 2004-01-28 | 高支持性軟質ポリウレタン発泡体、その製造方法およびその圧潰力の低下方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6855742B2 (2) |
| JP (1) | JP2004231963A (2) |
| KR (1) | KR20040069274A (2) |
| CN (1) | CN1320016C (2) |
| CA (1) | CA2455513C (2) |
| MX (1) | MXPA04000795A (2) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008050487A (ja) * | 2006-08-25 | 2008-03-06 | Bridgestone Corp | ポリウレタンフォーム成形品及びその製造方法 |
| JP2008514742A (ja) * | 2004-09-28 | 2008-05-08 | ビーエーエスエフ ソシエタス・ヨーロピア | 軟質ポリウレタンフォームの製造方法 |
| JP2008514741A (ja) * | 2004-09-28 | 2008-05-08 | ビーエーエスエフ ソシエタス・ヨーロピア | 軟質ポリウレタンフォームの製造方法 |
| JP2008518055A (ja) * | 2004-10-25 | 2008-05-29 | ダウ グローバル テクノロジーズ インコーポレイティド | 植物油ベースのヒドロキシル含有材料から製造されるポリマーポリオールおよびポリマー分散物 |
| JP2008518057A (ja) * | 2004-10-25 | 2008-05-29 | ダウ グローバル テクノロジーズ インコーポレイティド | ヒドロキシメチル含有脂肪酸またはそのような脂肪酸のアルキルエステルから作られるポリウレタン |
| JP2010037468A (ja) * | 2008-08-07 | 2010-02-18 | Bridgestone Corp | ポリウレタンスラブフォーム |
| WO2019176659A1 (ja) * | 2018-03-13 | 2019-09-19 | 株式会社クラレ | ウレタン組成物 |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007018129A1 (ja) * | 2005-08-05 | 2007-02-15 | Asahi Glass Company, Limited | 軟質ポリウレタンフォーム、その製造方法および自動車用シート |
| FR2911145A1 (fr) * | 2007-01-09 | 2008-07-11 | Cera | Resine polyol d'une mousse de polyurethanne souple pour matelassure de siege de vehicule automobile |
| US8063113B2 (en) * | 2008-04-23 | 2011-11-22 | Momentive Performance Materials Inc. | Polyurethane foam-forming compositions containing polysilsesquioxane cell opening agents |
| US8901187B1 (en) | 2008-12-19 | 2014-12-02 | Hickory Springs Manufacturing Company | High resilience flexible polyurethane foam using MDI |
| US8906975B1 (en) | 2009-02-09 | 2014-12-09 | Hickory Springs Manufacturing Company | Conventional flexible polyurethane foam using MDI |
| JP4920051B2 (ja) * | 2009-02-25 | 2012-04-18 | 株式会社日立製作所 | 酸素燃焼ボイラプラント及び酸素燃焼ボイラプラントの運転方法 |
| US8933139B1 (en) * | 2009-02-27 | 2015-01-13 | Peterson Chemical Technology, Inc. | In-situ gelatinous triblock copolymer elastomers in polyurethane flexible foams |
| US9080051B2 (en) | 2009-02-27 | 2015-07-14 | Peterson Chemical Technology, Inc. | Gelatinous triblock copolymer elastomer particles in polyurethane flexible foams |
| US9481759B2 (en) | 2009-08-14 | 2016-11-01 | Boral Ip Holdings Llc | Polyurethanes derived from highly reactive reactants and coal ash |
| US8846776B2 (en) | 2009-08-14 | 2014-09-30 | Boral Ip Holdings Llc | Filled polyurethane composites and methods of making same |
| US9534098B2 (en) | 2010-02-26 | 2017-01-03 | Peterson Chemical Technology, Llc. | Enhanced thermally conductive cushioning foams by addition of metal materials |
| CN102190775B (zh) * | 2010-03-08 | 2014-12-17 | 拜耳材料科技(中国)有限公司 | 具有改进耐磨性能的聚氨酯及其制备方法和用途 |
| US9163099B2 (en) * | 2013-03-08 | 2015-10-20 | Bayer Materialscience Llc | Polybutadiene modified polymer polyols, foams prepared from polybutadiene modified polymer polyols, and processes for the production thereof |
| DE102013204991A1 (de) | 2013-03-21 | 2014-09-25 | Evonik Industries Ag | Herstellung von Polyurethanschäumen, die Polyole auf Polyolefinbasis enthalten |
| WO2016018226A1 (en) | 2014-07-28 | 2016-02-04 | Crocco Guy | The use of evaporative coolants to manufacture filled polyurethane composites |
| RU2734761C2 (ru) * | 2015-12-21 | 2020-10-23 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения полиуретановых пен |
| US11814566B2 (en) | 2020-07-13 | 2023-11-14 | L&P Property Management Company | Thermally conductive nanomaterials in flexible foam |
| US11597862B2 (en) | 2021-03-10 | 2023-03-07 | L&P Property Management Company | Thermally conductive nanomaterial coatings on flexible foam or fabrics |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US28715A (en) * | 1860-06-12 | Improvement in soldering handles of cutlery | ||
| US29118A (en) * | 1860-07-10 | Improved signal-lantern | ||
| US3523093A (en) | 1961-11-28 | 1970-08-04 | Paul Stamberger | Method of producing polyurethanes by reacting polyisocyanate with a preformed polymer resulting from polymerization of ethylenically unsaturated monomers |
| GB1022434A (en) | 1961-11-28 | 1966-03-16 | Union Carbide Corp | Improvements in and relating to polymers |
| US3304273A (en) | 1963-02-06 | 1967-02-14 | Stamberger Paul | Method of preparing polyurethanes from liquid, stable, reactive, filmforming polymer/polyol mixtures formed by polymerizing an ethylenically unsaturated monomer in a polyol |
| USRE29118E (en) | 1963-02-06 | 1977-01-18 | Method of preparing polyurethanes from liquid, stable, reactive, film-forming polymer/polyol mixtures formed by polymerizing an ethylenically unsaturated monomer in a polyol | |
| USRE28715E (en) | 1964-08-12 | 1976-02-17 | Polyurethanes, reactive solutions and methods and their production | |
| US3823101A (en) | 1968-12-06 | 1974-07-09 | Aluminum Co Of America | Opaque white coating composition comprising essentially cellulose ester/cross-linking agent/catalyst/solvent and organic liquid |
| BE759006A (fr) | 1969-11-20 | 1971-05-17 | Marles Kuhlmann Wyandotte | Copolymeres greffes et preparation de polyurethanes |
| JPS50149794A (2) | 1974-05-23 | 1975-12-01 | ||
| US4104236A (en) | 1974-08-28 | 1978-08-01 | Union Carbide Corporation | Liquid polymer/polyols and polyurethane elastomers based thereon |
| CA1074049A (en) | 1974-11-13 | 1980-03-18 | Russell Van Cleve | Polymer/polyols and polyurethane derivatives thereof |
| US4089835A (en) | 1975-03-27 | 1978-05-16 | Bayer Aktiengesellschaft | Stable polyurethane dispersions and process for production thereof |
| US4172825A (en) | 1975-07-10 | 1979-10-30 | Union Carbide Corporation | Polymer/polyols and process for production thereof |
| US4119586A (en) | 1976-06-24 | 1978-10-10 | Union Carbide Corporation | Polymer/polyol compositions, processes for making same and processes for making polyurethane products therefrom |
| US4125505A (en) | 1976-07-06 | 1978-11-14 | Union Carbide Corporation | Polymer/polyols from high ethylene oxide content polyols |
| DE2639254A1 (de) | 1976-09-01 | 1978-03-02 | Bayer Ag | Verfahren zur herstellung von stabilen dispersionen |
| US4148840A (en) | 1978-03-29 | 1979-04-10 | Union Carbide Corporation | Polymer/polyol compositions made from preformed polymer/polyols, processes for making same and processes for making polyurethane products therefrom |
| US4524157A (en) | 1981-07-01 | 1985-06-18 | Union Carbide Corporation | Adducts and polymer-polyols useful in the preparation of improved plastics, including polyurethane foams, elastomers and the like |
| US4690956A (en) | 1982-04-01 | 1987-09-01 | Basf Corporation | Process for the preparation of graft polymer dispersions and flame-retardant polyurethane foams |
| US4579700A (en) | 1983-11-07 | 1986-04-01 | Union Carbide Corporation | Novel process for making flexible polyurethane cellular products including a novel cell opening technique |
| US5011908A (en) | 1988-07-12 | 1991-04-30 | Arco Chemical Technology, Inc. | Polymer polyol compositions and their use in the preparation of polyurethane foams |
| US5171759A (en) | 1988-07-12 | 1992-12-15 | Arco Chemical Technology, L.P. | Polymer polyol compositions and their use in the preparation of polyurethane foams |
| DE3837351C1 (2) | 1988-11-03 | 1989-11-23 | Th. Goldschmidt Ag, 4300 Essen, De | |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| JP3155809B2 (ja) | 1992-03-16 | 2001-04-16 | 三井化学株式会社 | 硬質ポリウレタンフォームおよびその製造方法 |
| US5614566A (en) | 1993-02-10 | 1997-03-25 | Th. Goldschmidt Ag. | Method for the preparation of rigid foams having urethane and/or isocyanurate groups and being extensively open celled |
| US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| GB9325043D0 (en) * | 1993-12-07 | 1994-02-02 | Polyol Int Bv | Polyol compositions and their use in the preparation of high resilience polyurethane foams |
| US5690855A (en) | 1994-01-11 | 1997-11-25 | Sealed Air Corporation | Polyol blend, cellular polyurethane foam product made therefrom, and halogenated hydrocarbon-free process therefor |
| US5605939A (en) | 1996-01-26 | 1997-02-25 | Arco Chemical Technology, L.P. | Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and foam prepared therewith |
| DE19746807A1 (de) | 1997-10-23 | 1999-04-29 | Basf Ag | Verfahren zur Herstellung von Polyurethanschaumstoffen |
| US6034197A (en) | 1998-07-27 | 2000-03-07 | Sealed Air Corporation | Polyol blend, multi-component system for producing polyurethane foam, and foam produced thereby |
| US6136876A (en) | 1998-11-17 | 2000-10-24 | Air Products And Chemicals | Weak bronsted acid derivatives for improving dimensional stability of polyurethane flexible foams |
-
2003
- 2003-01-28 US US10/352,614 patent/US6855742B2/en not_active Expired - Lifetime
-
2004
- 2004-01-21 CN CNB2004100029858A patent/CN1320016C/zh not_active Expired - Fee Related
- 2004-01-21 CA CA2455513A patent/CA2455513C/en not_active Expired - Fee Related
- 2004-01-26 MX MXPA04000795A patent/MXPA04000795A/es active IP Right Grant
- 2004-01-27 KR KR1020040004942A patent/KR20040069274A/ko not_active Ceased
- 2004-01-28 JP JP2004019509A patent/JP2004231963A/ja not_active Withdrawn
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008514742A (ja) * | 2004-09-28 | 2008-05-08 | ビーエーエスエフ ソシエタス・ヨーロピア | 軟質ポリウレタンフォームの製造方法 |
| JP2008514741A (ja) * | 2004-09-28 | 2008-05-08 | ビーエーエスエフ ソシエタス・ヨーロピア | 軟質ポリウレタンフォームの製造方法 |
| JP2008518055A (ja) * | 2004-10-25 | 2008-05-29 | ダウ グローバル テクノロジーズ インコーポレイティド | 植物油ベースのヒドロキシル含有材料から製造されるポリマーポリオールおよびポリマー分散物 |
| JP2008518057A (ja) * | 2004-10-25 | 2008-05-29 | ダウ グローバル テクノロジーズ インコーポレイティド | ヒドロキシメチル含有脂肪酸またはそのような脂肪酸のアルキルエステルから作られるポリウレタン |
| KR101298387B1 (ko) * | 2004-10-25 | 2013-08-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 히드록시메틸 함유 지방산 또는 상기 지방산의 알킬에스테르로부터 제조된 폴리우레탄 |
| JP2008050487A (ja) * | 2006-08-25 | 2008-03-06 | Bridgestone Corp | ポリウレタンフォーム成形品及びその製造方法 |
| JP2010037468A (ja) * | 2008-08-07 | 2010-02-18 | Bridgestone Corp | ポリウレタンスラブフォーム |
| WO2019176659A1 (ja) * | 2018-03-13 | 2019-09-19 | 株式会社クラレ | ウレタン組成物 |
| JPWO2019176659A1 (ja) * | 2018-03-13 | 2021-02-25 | 株式会社クラレ | ウレタン組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20040069274A (ko) | 2004-08-05 |
| CN1320016C (zh) | 2007-06-06 |
| MXPA04000795A (es) | 2004-06-22 |
| CN1517375A (zh) | 2004-08-04 |
| US20040147627A1 (en) | 2004-07-29 |
| CA2455513A1 (en) | 2004-07-28 |
| US6855742B2 (en) | 2005-02-15 |
| CA2455513C (en) | 2011-10-18 |
| HK1068637A1 (en) | 2005-04-29 |
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