JP2005290186A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2005290186A5 JP2005290186A5 JP2004106778A JP2004106778A JP2005290186A5 JP 2005290186 A5 JP2005290186 A5 JP 2005290186A5 JP 2004106778 A JP2004106778 A JP 2004106778A JP 2004106778 A JP2004106778 A JP 2004106778A JP 2005290186 A5 JP2005290186 A5 JP 2005290186A5
- Authority
- JP
- Japan
- Prior art keywords
- less
- content
- volume
- mass ppm
- aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 claims description 8
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 4
- 239000003350 kerosene Substances 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000000779 smoke Substances 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Description
本発明者は、鋭意研究を重ねた結果、硫黄の低減により、燃焼排ガス中のＳＯｘを低減し得ること、極性物質（窒素分、硫黄分）の低減により、泡立ちを抑制し得ること、及び窒素分、不飽和分の低減により、貯蔵安定性が良好になること、そして、特にベンゾチオフェン含有量、ジベンゾチオフェン含有量及び窒素分を特定量以下に調整した灯油がその目的に十分に適合しうることを見出し、この知見に基づいて本発明をなすに到った。すなわち、本発明の要旨は下記のとおりである。
１．下記の（ａ）〜（ｎ）の要件を満足する低発泡性灯油。
（ａ）引火点が４０℃以上である。
（ｂ）９５容量％留出温度（Ｔ９５）が２７０℃以下である。
（ｃ）煙点が２３ｍｍ以上である。
（ｄ）銅板腐食が１以下である。
（ｅ）セイボルト色が＋２５以上である。
（ｆ）密度が０．７８０〜０．８０１ｇ／ｃｍ3である。
（ｇ）硫黄分が１０質量ｐｐｍ以下である。
（ｈ）ベンゾチオフェン含有量が１０質量ｐｐｍ以下で、ジベンゾチオフェン含有量が１０質量ｐｐｍ以下である。
（ｉ）窒素分が１質量ｐｐｍ以下で、複素環式化合物が１質量ｐｐｍ以下である。
（ｊ）飽和分が８０容量％以上、不飽和分が０．１容量％以下及び全芳香族分が２０容量％以下であり、かつ芳香族分のうちの２環以上の芳香族分が１容量％以下で、飽和分のうちのｎ−パラフィンが３０容量％以下である。
（ｋ）過酸化物価が２質量ｐｐｍ以下である。
（ｌ）３０℃における動粘度が１．００〜２．００ｍｍ2／ｓである。
（ｍ）ドクター試験が陰性である。
（ｎ）セタン指数が４０以上である。
２．ベンゾチオフェン含有量が５質量ｐｐｍ以下で、ジベンゾチオフェン含有量が５質量ｐｐｍ以下である上記１記載の低発泡性灯油。
As a result of extensive research, the inventor has been able to reduce SOx in combustion exhaust gas by reducing sulfur, to suppress foaming by reducing polar substances (nitrogen and sulfur), and nitrogen. The storage stability is improved by reducing the content and the unsaturated content, and in particular, kerosene with the benzothiophene content, dibenzothiophene content and nitrogen content adjusted to a specific amount or less can be adequately adapted to the purpose. Based on this finding, the present inventors have made the present invention. That is, the gist of the present invention is as follows.
1. A low-foaming kerosene that satisfies the following requirements (a) to (n):
(A) The flash point is 40 ° C. or higher.
(B) 95 volume% distillation temperature (T95) is 270 degrees C or less.
(C) The smoke point is 23 mm or more.
(D) Copper plate corrosion is 1 or less.
(E) Saybolt color is +25 or more.
(F) The density is 0.780 to 0.801 g / cm3.
(G) The sulfur content is 10 mass ppm or less.
(H) The benzothiophene content is 10 mass ppm or less and the dibenzothiophene content is 10 mass ppm or less.
(I) The nitrogen content is 1 mass ppm or less, and the heterocyclic compound is 1 mass ppm or less.
(J) The saturated content is 80% by volume or more, the unsaturated content is 0.1% by volume or less, the total aromatic content is 20% by volume or less, and the aromatic content of two or more rings in the aromatic content is 1 The volume is not more than volume%, and n-paraffin in the saturation is not more than 30 volume%.
(K) The peroxide value is 2 mass ppm or less.
(L) The kinematic viscosity at 30 ° C. is 1.00 to 2.00 mm 2 / s.
(M) Doctor test is negative.
(N) The cetane index is 40 or more.
2. 2. The low foaming kerosene according to 1 above, having a benzothiophene content of 5 mass ppm or less and a dibenzothiophene content of 5 mass ppm or less.
Claims (1)
（ａ）引火点が４０℃以上である。
（ｂ）９５容量％留出温度（Ｔ９５）が２７０℃以下である。
（ｃ）煙点が２３ｍｍ以上である。
（ｄ）銅板腐食が１以下である。
（ｅ）セイボルト色が＋２５以上である。
（ｆ）密度が０．７８０〜０．８０１ｇ／ｃｍ3である。
（ｇ）硫黄分が１０質量ｐｐｍ以下である。
（ｈ）ベンゾチオフェン含有量が１０質量ｐｐｍ以下で、ジベンゾチオフェン含有量が１０質量ｐｐｍ以下である。
（ｉ）窒素分が１質量ｐｐｍ以下で、複素環式化合物が１質量ｐｐｍ以下である。
（ｊ）飽和分が８０容量％以上、不飽和分が０．１容量％以下及び全芳香族分が２０容量％以下であり、かつ芳香族分のうちの２環以上の芳香族分が１容量％以下で、飽和分のうちのｎ−パラフィンが３０容量％以下である。
（ｋ）過酸化物価が２質量ｐｐｍ以下である。
（ｌ）３０℃における動粘度が１．００〜２．００ｍｍ2／ｓである。
（ｍ）ドクター試験が陰性である。
（ｎ）セタン指数が４０以上である。 A low-foaming kerosene that satisfies the following requirements (a) to (n):
(A) The flash point is 40 ° C. or higher.
(B) 95 volume% distillation temperature (T95) is 270 degrees C or less.
(C) The smoke point is 23 mm or more.
(D) Copper plate corrosion is 1 or less.
(E) Saybolt color is +25 or more.
(F) The density is 0.780 to 0.801 g / cm3.
(G) The sulfur content is 10 mass ppm or less.
(H) The benzothiophene content is 10 mass ppm or less and the dibenzothiophene content is 10 mass ppm or less.
(I) The nitrogen content is 1 mass ppm or less, and the heterocyclic compound is 1 mass ppm or less.
(J) The saturated content is 80% by volume or more, the unsaturated content is 0.1% by volume or less, the total aromatic content is 20% by volume or less, and the aromatic content of two or more rings in the aromatic content is 1 The volume is not more than volume%, and n-paraffin in the saturation is not more than 30 volume%.
(K) The peroxide value is 2 mass ppm or less.
(L) The kinematic viscosity at 30 ° C. is 1.00 to 2.00 mm 2 / s.
(M) Doctor test is negative.
(N) The cetane index is 40 or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004106778A JP4568008B2 (en) | 2004-03-31 | 2004-03-31 | Low foaming kerosene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004106778A JP4568008B2 (en) | 2004-03-31 | 2004-03-31 | Low foaming kerosene |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005290186A JP2005290186A (en) | 2005-10-20 |
| JP2005290186A5 true JP2005290186A5 (en) | 2007-03-29 |
| JP4568008B2 JP4568008B2 (en) | 2010-10-27 |
Family
ID=35323491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004106778A Expired - Fee Related JP4568008B2 (en) | 2004-03-31 | 2004-03-31 | Low foaming kerosene |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4568008B2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5348821B2 (en) * | 2005-05-26 | 2013-11-20 | Ｊｘ日鉱日石エネルギー株式会社 | Kerosene composition |
| JP4881663B2 (en) * | 2006-06-20 | 2012-02-22 | コスモ石油株式会社 | Kerosene composition and method for producing kerosene composition |
| JP5144316B2 (en) * | 2007-03-15 | 2013-02-13 | コスモ石油株式会社 | Kerosene composition |
| JP2008239811A (en) * | 2007-03-27 | 2008-10-09 | Nippon Oil Corp | Fuel oil composition |
| JP5138307B2 (en) * | 2007-08-10 | 2013-02-06 | Ｊｘ日鉱日石エネルギー株式会社 | High performance fuel composition |
| JP2009132900A (en) * | 2007-11-01 | 2009-06-18 | Japan Energy Corp | Low sulfur fuel oil composition with good defoaming properties |
| JP5758083B2 (en) * | 2010-03-25 | 2015-08-05 | 太平洋セメント株式会社 | How to use waste oil solid fuel |
| JP2015183030A (en) * | 2014-03-20 | 2015-10-22 | Ｊｘ日鉱日石エネルギー株式会社 | kerosene composition |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07103384B2 (en) * | 1988-10-20 | 1995-11-08 | 日本石油株式会社 | High performance kerosene |
| JP2519191B2 (en) * | 1990-04-10 | 1996-07-31 | 触媒化成工業株式会社 | Kerosene oil hydrotreating method |
| JPH0649463A (en) * | 1992-07-27 | 1994-02-22 | Showa Shell Sekiyu Kk | Manufacturing method of modified kerosene |
| JP3544603B2 (en) * | 1996-09-10 | 2004-07-21 | 株式会社ジャパンエナジー | Hydrorefining method of hydrocarbon oil |
| JP4583666B2 (en) * | 2000-06-29 | 2010-11-17 | Ｊｘ日鉱日石エネルギー株式会社 | Fuel for fuel cell system |
| JP4375646B2 (en) * | 2001-09-28 | 2009-12-02 | 新日本石油株式会社 | Kerosene manufacturing method |
| JP2004182745A (en) * | 2002-11-29 | 2004-07-02 | Idemitsu Kosan Co Ltd | Low sulfur kerosene having improved oxidation stability and method for producing the same |
| JP3891569B2 (en) * | 2003-02-18 | 2007-03-14 | 株式会社ジョモテクニカルリサーチセンター | Low sulfur kerosene and method for producing the same |
| JP4537666B2 (en) * | 2003-04-18 | 2010-09-01 | 新日本石油株式会社 | Fuel for fuel cell system and fuel cell system |
-
2004
- 2004-03-31 JP JP2004106778A patent/JP4568008B2/en not_active Expired - Fee Related
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EA201071063A1 (en) | DESULPHURIZATION MATERIALS | |
| RU2016136673A (en) | COMPOSITION FOR REMOVING SULFUR CONTAINING COMPOUNDS | |
| BR112013004469A2 (en) | sorbent activated carbon to remove mercury from emissions produced during fuel combustion, non-halogenated additive and process to increase thermal stability of activated carbon | |
| RU2007129119A (en) | FULLY BURNING DIESEL FUEL | |
| JP2005290186A5 (en) | ||
| RU2008152365A (en) | GASOIL COMPOSITION | |
| EA200900736A1 (en) | NEW SINGLE-PHASE WATER FUEL ON HYDROCARBON BASED, HOW TO OBTAIN ITEM AND COMPOSITIONS FOR USE IN THIS METHOD | |
| JP2007177245A5 (en) | ||
| EA201592043A1 (en) | ADDITIVE TO INCREASE THE STABILITY TO OXIDATION AND / OR STABILITY DURING THE STORAGE OF MOTOR FUEL OR LIQUID CONTAINING HYDROCARBON FUEL | |
| JP6654286B2 (en) | Fuel oil A composition | |
| Choi | Experimental study on emission characteristics and analysis by various oxygenated fuels in a DI diesel engine | |
| MY154597A (en) | Gas oil composition | |
| RU2008143025A (en) | DIESEL FUEL COMPOSITION | |
| RU2008143249A (en) | COMPOSITIONS OF LIGHT OIL FRACTIONS | |
| JP4568008B2 (en) | Low foaming kerosene | |
| RU2013134482A (en) | IMPROVEMENTS CONCERNING COMPOSITION OF FUEL MIXTURES | |
| JP2004526011A5 (en) | ||
| JP2004051964A5 (en) | ||
| EA023027B9 (en) | COMPOSITION FOR CONDITIONING HAIR | |
| RU2014102231A (en) | THE COMPOSITION IMPAIRED WITH A SIMPLE AMINO ETHERIC ADDITIVE USED IN THE CATALYTIC HYDROPROCESSING OF HYDROCARBONS AND THE METHOD FOR PRODUCING SUCH A COMPOSITION | |
| CN103627456B (en) | A kind of Environment-friendlycomposite composite fuel oil additive and preparation method thereof | |
| WO2001081511A3 (en) | Low sulfur/low aromatics distillate fuels | |
| EA200600804A1 (en) | MIXTURE OF ADDITIVE AS A COMPONENT OF COMPOSITION BASED ON MINERAL OIL FUEL | |
| CN108686484B (en) | Phase Change Absorber with Antioxidative Degradation and Viscosity Reduction for Acid Gas Separation | |
| RU2008143233A (en) | DIESEL FUEL COMPOSITION |