JP2005294011A5 - - Google Patents

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Publication number
JP2005294011A5
JP2005294011A5 JP2004106876A JP2004106876A JP2005294011A5 JP 2005294011 A5 JP2005294011 A5 JP 2005294011A5 JP 2004106876 A JP2004106876 A JP 2004106876A JP 2004106876 A JP2004106876 A JP 2004106876A JP 2005294011 A5 JP2005294011 A5 JP 2005294011A5
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JP
Japan
Prior art keywords
graphite particles
secondary battery
electrolyte secondary
aqueous electrolyte
coated
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Application number
JP2004106876A
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Japanese (ja)
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JP4748949B2 (en
JP2005294011A (en
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Priority to JP2004106876A priority Critical patent/JP4748949B2/en
Priority claimed from JP2004106876A external-priority patent/JP4748949B2/en
Publication of JP2005294011A publication Critical patent/JP2005294011A/en
Publication of JP2005294011A5 publication Critical patent/JP2005294011A5/ja
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Publication of JP4748949B2 publication Critical patent/JP4748949B2/en
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Expired - Fee Related legal-status Critical Current

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Claims (5)

正極と、黒鉛粒子を活物質として含む負極と、非水電解質と、を有する非水電解質二次電池において、
前記黒鉛粒子は、その表面が非晶質炭素で被覆された被覆黒鉛粒子と、表面が非晶質炭素で被覆されていない
非被覆黒鉛粒子とが混合されてなるものであり、
前記黒鉛粒子のLc値が15nm以上であり、
前記黒鉛粒子のd 002 値が0.338nm以下であり、
前記黒鉛粒子の比表面積が2m 2 /g以上5m 2 /g以下であり、
前記黒鉛粒子の平均粒径が15μm以上であり、
前記黒鉛粒子のX線回折法による002面と110面とのピーク強度比I h002 /I h110 が200以下である、
ことを特徴とする非水電解質二次電池。
In a non-aqueous electrolyte secondary battery having a positive electrode, a negative electrode containing graphite particles as an active material, and a non-aqueous electrolyte,
The graphite particles are coated graphite particles whose surfaces are coated with amorphous carbon, and the surfaces are not coated with amorphous carbon.
All SANYO that the uncoated graphite particles, which are mixed,
Lc value of the graphite particles is 15 nm or more,
The d 002 value of the graphite particles is 0.338 nm or less,
The specific surface area of the graphite particles is 2 m 2 / g or more and 5 m 2 / g or less,
The average particle diameter of the graphite particles is 15 μm or more,
The peak intensity ratio I h002 / I h110 between the 002 plane and the 110 plane according to the X-ray diffraction method of the graphite particles is 200 or less.
A non-aqueous electrolyte secondary battery.
請求項1に記載の非水電解質二次電池において、
前記被覆黒鉛粒子と、前記非被覆黒鉛粒子との質量比が3:7〜7:3である、
ことを特徴とする非水電解質二次電池。
The nonaqueous electrolyte secondary battery according to claim 1,
The mass ratio of the coated graphite particles to the uncoated graphite particles is 3: 7 to 7: 3.
A non-aqueous electrolyte secondary battery.
請求項1または2に記載の非水電解質二次電池において、
前記被覆黒鉛粒子100質量部中に占める非晶質炭素の質量が、0.1〜10質量部である、
ことを特徴とする非水電解質二次電池。
The nonaqueous electrolyte secondary battery according to claim 1 or 2,
The mass of amorphous carbon in 100 parts by mass of the coated graphite particles is 0.1 to 10 parts by mass.
A non-aqueous electrolyte secondary battery.
請求項1、2または3に記載の非水電解質二次電池において、
前記被覆黒鉛粒子の核となる黒鉛粒子と、前記非被覆黒鉛粒子とが、同種の黒鉛粒子である、
ことを特徴とする非水電解質二次電池。
The nonaqueous electrolyte secondary battery according to claim 1, 2 or 3,
The graphite particles as the core of the coated graphite particles and the uncoated graphite particles are the same kind of graphite particles.
A non-aqueous electrolyte secondary battery.
請求項1、2、3、または4に記載の非水電解質二次電池において、
放電状態の前記負極の活物質充填密度が1.40g/ml以上であり、かつ前記負極のX線回折法による00
2面と110面とのピーク強度比Ih002/Ih110が300以下である、ことを特徴とする非水電解質二次電池。


The nonaqueous electrolyte secondary battery according to claim 1, 2, 3, or 4 ,
The active material filling density of the negative electrode in a discharged state is 1.40 g / ml or more, and 00 according to the X-ray diffraction method of the negative electrode.
A non-aqueous electrolyte secondary battery, wherein the peak intensity ratio I h002 / I h110 between the two surfaces and the 110 surface is 300 or less.


JP2004106876A 2004-03-31 2004-03-31 Nonaqueous electrolyte secondary battery Expired - Fee Related JP4748949B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004106876A JP4748949B2 (en) 2004-03-31 2004-03-31 Nonaqueous electrolyte secondary battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004106876A JP4748949B2 (en) 2004-03-31 2004-03-31 Nonaqueous electrolyte secondary battery

Publications (3)

Publication Number Publication Date
JP2005294011A JP2005294011A (en) 2005-10-20
JP2005294011A5 true JP2005294011A5 (en) 2007-04-12
JP4748949B2 JP4748949B2 (en) 2011-08-17

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JP2004106876A Expired - Fee Related JP4748949B2 (en) 2004-03-31 2004-03-31 Nonaqueous electrolyte secondary battery

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EP2306560A4 (en) * 2008-07-17 2014-05-07 Chuo Denki Kogyo Co Ltd MIXED CARBON MATERIAL AND NEGATIVE ELECTRODE FOR NONAQUEOUS RECHARGEABLE BATTERY
CN102362380B (en) 2009-03-27 2015-05-13 三菱化学株式会社 Negative electrode material for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery using the same
CN102362381B (en) 2009-03-27 2015-06-03 三菱化学株式会社 Negative electrode material for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery using the same
JP5375953B2 (en) 2009-03-30 2013-12-25 新日鐵住金株式会社 Mixed carbon material and negative electrode for non-aqueous secondary battery
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