JP2008510035A - 脱硫化及びそれのための新規な工程 - Google Patents

脱硫化及びそれのための新規な工程 Download PDF

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Publication number
JP2008510035A
JP2008510035A JP2007525741A JP2007525741A JP2008510035A JP 2008510035 A JP2008510035 A JP 2008510035A JP 2007525741 A JP2007525741 A JP 2007525741A JP 2007525741 A JP2007525741 A JP 2007525741A JP 2008510035 A JP2008510035 A JP 2008510035A
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composition
mixture
sulfur
range
metal
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Japanese (ja)
Inventor
チョーダリー,トゥシャール,ヴイ
ドッドウェル,グレン,ダヴリュ
ジョンソン,マーヴィン,エム
ジャスト,デボラ,ケイ
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ConocoPhillips Co
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ConocoPhillips Co
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3078Thermal treatment, e.g. calcining or pyrolizing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/104Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/112Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/24Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/308Carbonoxysulfide COS
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42Materials comprising a mixture of inorganic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • C10G2300/104Light gasoline having a boiling range of about 20 - 100 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • C10G2300/1048Middle distillates
    • C10G2300/1055Diesel having a boiling range of about 230 - 330 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70Catalyst aspects
    • C10G2300/703Activation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Liquid Carbonaceous Fuels (AREA)
JP2007525741A 2004-08-10 2005-08-09 脱硫化及びそれのための新規な工程 Pending JP2008510035A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/914,798 US20050020446A1 (en) 2003-07-23 2004-08-10 Desulfurization and novel process for same
PCT/US2005/028277 WO2006020642A2 (fr) 2004-08-10 2005-08-09 Desulfuration et nouveau procede de desulfuration

Publications (1)

Publication Number Publication Date
JP2008510035A true JP2008510035A (ja) 2008-04-03

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JP2007525741A Pending JP2008510035A (ja) 2004-08-10 2005-08-09 脱硫化及びそれのための新規な工程

Country Status (7)

Country Link
US (1) US20050020446A1 (fr)
EP (1) EP1799794A4 (fr)
JP (1) JP2008510035A (fr)
CN (1) CN101432398B (fr)
BR (1) BRPI0514299B1 (fr)
RU (1) RU2393919C2 (fr)
WO (1) WO2006020642A2 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007254728A (ja) * 2006-02-24 2007-10-04 Cosmo Oil Co Ltd 炭化水素用脱硫剤
JP2010209154A (ja) * 2009-03-06 2010-09-24 Japan Energy Corp 炭化水素油の脱硫方法及び燃料電池システム
JP2013508527A (ja) * 2009-10-30 2013-03-07 コリア エレクトリック パワー コーポレイション 噴霧乾燥方法で成形された亜鉛系脱硫剤及びその製造方法
JP2020116488A (ja) * 2019-01-21 2020-08-06 日揮触媒化成株式会社 脱硫剤の製造方法および脱硫剤前駆体の製造方法、並びに脱硫剤前駆体
JP2022137269A (ja) * 2019-01-21 2022-09-21 日揮触媒化成株式会社 脱硫剤前駆体

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CA2531262A1 (fr) * 2005-12-21 2007-06-21 Imperial Oil Resources Limited Petrole brut lourd a tres faible teneur en soufre et procede pour sa production
CA2714575A1 (fr) * 2008-02-08 2009-08-13 Vale Inco Limited Procede de fabrication d'un oxyde metallique pre-fluxe a partir de precurseurs hydroxydes metalliques et carbonates metalliques
US8557019B2 (en) * 2008-02-08 2013-10-15 Vale Inco Limited Process for production of nickel and cobalt using metal hydroxide, metal oxide and/or metal carbonate
CA2721388A1 (fr) * 2008-04-16 2009-10-22 Vale Inco Limited Procede de production de nickel et de cobalt utilisant un hydroxyde metallique, un oxyde metallique et/ou un carbonate metallique
CN101618314B (zh) * 2008-05-20 2013-03-06 中国石油化工股份有限公司 一种脱硫吸附剂及其制备方法和应用
CN101618313B (zh) * 2008-06-30 2012-11-14 中国石油化工股份有限公司 一种脱硫吸附剂及其制备方法和应用
WO2010075672A1 (fr) * 2008-12-31 2010-07-08 中国石油化工股份有限公司 Adsorbant désulfurant, son procédé de préparation et son utilisation
CN103328973B (zh) 2011-07-20 2015-04-01 加利福尼亚大学董事会 双孔装置
FR2984762B1 (fr) * 2011-12-21 2014-04-25 IFP Energies Nouvelles Adsorbant catalytique pour la captation de l'arsenic et l'hydrodesulfuration selective des essences de craquage catalytique
CA2818272C (fr) * 2012-06-12 2017-11-14 China Petroleum & Chemical Corporation Catalyseur de recuperation de soufre a base d'alumine et son procede de preparation
DE102013015117A1 (de) 2013-09-12 2015-03-12 Johnson Matthey Catalysts (Germany) Gmbh Katalysator sowie Verfahren zur Stickoxidminderung in einem Abgas
CN104549489B (zh) * 2013-10-29 2017-07-25 中国石油化工股份有限公司 一种脱硫催化剂及其制备与烃油脱硫的方法
DE102013113660A1 (de) * 2013-12-06 2015-06-11 Thyssenkrupp Ag Verfahren und Koksgewinnungsanlage zur Behandlung von schwefelhaltigen Prozessrückständen aus der Erdölverarbeitung; Petrolkoks gebildet aus schwefelhaltigen Prozessrückständen
CN104148002B (zh) * 2014-07-30 2017-07-11 迪普沃科技(深圳)有限公司 一种Zr‑Ce‑O双功能催化吸附剂及其制备方法与其在燃油脱硫中的应用
CN105583001B (zh) * 2014-10-20 2018-05-18 中国石油化工股份有限公司 一种脱硫催化剂及其制备方法和烃油脱硫的方法
CN113603658A (zh) * 2015-08-28 2021-11-05 利安德化学技术有限公司 环氧化工艺及其使用的催化剂
CN106554832A (zh) * 2015-09-24 2017-04-05 刘从荡 一种凹凸棒沼气脱硫干燥剂的制备方法
CN105749863A (zh) * 2016-04-06 2016-07-13 山东成泰化工有限公司 一种复合脱硫剂及其制备方法
CN107474870B (zh) * 2016-06-07 2019-11-15 中国石油化工股份有限公司 一种吸附剂的硫化方法
CN108114756A (zh) * 2016-11-29 2018-06-05 中国石油化工股份有限公司 一种含硫有机废气催化氧化保护剂及其制备方法和应用
US12025435B2 (en) 2017-02-12 2024-07-02 Magēmã Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil
US12071592B2 (en) 2017-02-12 2024-08-27 Magēmā Technology LLC Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US12559689B2 (en) 2017-02-12 2026-02-24 Magēmā Technology LLC Multi-stage process and device for treatment heavy marine fuel and resultant composition and the removal of detrimental solids
US12281266B2 (en) 2017-02-12 2025-04-22 Magẽmã Technology LLC Heavy marine fuel oil composition
US20180230389A1 (en) 2017-02-12 2018-08-16 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
CN108686642A (zh) * 2018-05-09 2018-10-23 内蒙古包钢和发稀土有限公司 高岭土基稀土脱硫催化剂的制备方法
CN109433219B (zh) * 2018-10-31 2021-08-06 沈阳三聚凯特催化剂有限公司 一种有机硫加氢催化剂及其制备方法、应用
CN109529860A (zh) * 2018-12-04 2019-03-29 云南大学 一种X-Sn-Zr还原催化剂及其制备方法和用途
CN114570413B (zh) * 2020-12-02 2024-03-12 宁波中科远东催化工程技术有限公司 一种用于脱硫的物质、其制备方法及应用
CN117619393B (zh) * 2023-11-28 2026-03-13 安阳金辉环保科技有限公司 一种脱硫剂及其制备方法和应用

Citations (9)

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JP2001279260A (ja) * 2000-03-31 2001-10-10 Idemitsu Kosan Co Ltd Ni−Cu系脱硫剤及び燃料電池用水素の製造方法
JP2001279255A (ja) * 2000-03-31 2001-10-10 Idemitsu Kosan Co Ltd ニッケル系脱硫剤の製造方法
JP2001342466A (ja) * 2000-03-31 2001-12-14 Idemitsu Kosan Co Ltd ニッケル−銅系脱硫剤の製造方法
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WO2006020642A2 (fr) 2006-02-23
BRPI0514299B1 (pt) 2016-03-29
EP1799794A4 (fr) 2010-06-09
RU2007108545A (ru) 2008-09-20
EP1799794A2 (fr) 2007-06-27
BRPI0514299A (pt) 2008-06-10
WO2006020642A3 (fr) 2009-06-04
RU2393919C2 (ru) 2010-07-10
CN101432398B (zh) 2012-03-28
US20050020446A1 (en) 2005-01-27

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