JP2011012353A - Fiber fabric having anti-pollen-adhesion and pollen allergen-inactivating ability - Google Patents
Fiber fabric having anti-pollen-adhesion and pollen allergen-inactivating ability Download PDFInfo
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- JP2011012353A JP2011012353A JP2009155022A JP2009155022A JP2011012353A JP 2011012353 A JP2011012353 A JP 2011012353A JP 2009155022 A JP2009155022 A JP 2009155022A JP 2009155022 A JP2009155022 A JP 2009155022A JP 2011012353 A JP2011012353 A JP 2011012353A
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- Prior art keywords
- pollen
- fiber
- layer
- silver
- fiber fabric
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- 239000000835 fiber Substances 0.000 title claims abstract description 146
- 239000004744 fabric Substances 0.000 title claims abstract description 93
- 239000010410 layer Substances 0.000 claims abstract description 136
- 125000000129 anionic group Chemical group 0.000 claims abstract description 50
- 239000010419 fine particle Substances 0.000 claims abstract description 42
- 150000001875 compounds Chemical class 0.000 claims abstract description 39
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 239000011347 resin Substances 0.000 claims abstract description 34
- 229910052709 silver Inorganic materials 0.000 claims abstract description 31
- 239000004332 silver Substances 0.000 claims abstract description 31
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 125000002091 cationic group Chemical group 0.000 claims abstract description 25
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 20
- 239000011247 coating layer Substances 0.000 claims abstract description 19
- 239000011230 binding agent Substances 0.000 claims abstract description 15
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 239000013573 pollen allergen Substances 0.000 claims description 36
- 230000024100 pollen adhesion Effects 0.000 claims description 31
- 229940100890 silver compound Drugs 0.000 claims description 16
- 150000003379 silver compounds Chemical class 0.000 claims description 16
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 14
- 229920001225 polyester resin Polymers 0.000 claims description 9
- 239000004645 polyester resin Substances 0.000 claims description 9
- 229910001923 silver oxide Inorganic materials 0.000 claims description 7
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 21
- 238000002845 discoloration Methods 0.000 abstract description 8
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- 238000012360 testing method Methods 0.000 description 14
- 230000002779 inactivation Effects 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 230000000415 inactivating effect Effects 0.000 description 10
- 208000035285 Allergic Seasonal Rhinitis Diseases 0.000 description 9
- 241000218645 Cedrus Species 0.000 description 9
- 239000013566 allergen Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- LOKCTEFSRHRXRJ-UHFFFAOYSA-I dipotassium trisodium dihydrogen phosphate hydrogen phosphate dichloride Chemical compound P(=O)(O)(O)[O-].[K+].P(=O)(O)([O-])[O-].[Na+].[Na+].[Cl-].[K+].[Cl-].[Na+] LOKCTEFSRHRXRJ-UHFFFAOYSA-I 0.000 description 8
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- 238000012545 processing Methods 0.000 description 7
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 239000002759 woven fabric Substances 0.000 description 6
- 108091003079 Bovine Serum Albumin Proteins 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
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- 229940098773 bovine serum albumin Drugs 0.000 description 5
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
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- 230000002265 prevention Effects 0.000 description 3
- 150000003378 silver Chemical class 0.000 description 3
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- 230000003068 static effect Effects 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920001213 Polysorbate 20 Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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- 238000010521 absorption reaction Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000006196 drop Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
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- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
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- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
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- 125000001302 tertiary amino group Chemical group 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
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- 239000004925 Acrylic resin Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
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- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
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- FEVWXNHNUKCNMX-UHFFFAOYSA-N amino(ethoxy)silicon Chemical compound CCO[Si]N FEVWXNHNUKCNMX-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
本発明は、花粉付着防止能と花粉アレルゲン不活化能を有する繊維布帛に関する。 The present invention relates to a fiber fabric having pollen adhesion preventing ability and pollen allergen inactivating ability.
近年、花粉アレルギーが大きな問題として取り上げられている。花粉症は一旦発症すると花粉の飛散する季節には毎年発症する場合が多く、日本においては５人に１人と多くの人が花粉症に悩んでいるといわれている。内服薬や目薬、点鼻薬などで症状を緩和することは可能であるが、花粉症はアレルギー疾患であるため、完治させることは難しいとされている。したがって、花粉または花粉アレルゲンに触れないようにすることが最も重要であり、花粉症患者は、外出時にはマスクや眼鏡、帽子などを使用して対策を講じているが、花粉は衣服に付着しやすく、そのまま屋内に持ち込まれて、屋内外を問わず花粉症に悩まされているのが現状である。そこで、花粉症に対応する衣服素材、具体的には、花粉が衣服に付着しにくく、また、付着しても落ちやすい性能を備えた衣服素材の開発が行われている。 In recent years, pollen allergy has been taken up as a major problem. Once hay fever develops, it often occurs every year in the season when pollen scatters, and it is said that as many as one in five people suffer from hay fever in Japan. Although it is possible to relieve symptoms with internal medicine, eye drops, nasal drops, etc., hay fever is an allergic disease, and it is considered difficult to cure completely. Therefore, it is most important to avoid contact with pollen or pollen allergens, and hay fever patients use masks, glasses, hats, etc. when they go out, but pollen tends to adhere to clothes. They are brought indoors and suffered from hay fever both indoors and outdoors. In view of this, development of garment materials that deal with hay fever, specifically, garment materials that have the performance that pollen is less likely to adhere to clothing and that easily fall off even if it adheres, is being carried out.
例えば、特許文献１には、繊維布帛、好ましくは織物の表面摩擦係数や表面粗さを規定して布帛表面の平滑性を高めることにより、花粉付着防止能を付与した繊維構造物が記載されている。また、特許文献２には、布帛表面の平滑性を高めるとともに、隣接する経糸同士および緯糸同士の間隙を花粉の大きさ（３０μｍ程度）よりも小さくすることにより、花粉が付着しにくく、また、繊維間や衣服内に入り込みにくくした織物が記載されている。しかしながら、これらの技術は、長繊維を用いた布帛や高密度織物に限定され、伸縮性が小さいため、スポーツウェアなどの用途には不向きであった。また、通気度が小さいため、衣服としての快適性という観点でも不十分であった。 For example, Patent Document 1 describes a fiber structure imparted with an ability to prevent pollen adhesion by regulating the surface friction coefficient and surface roughness of a fiber fabric, preferably a woven fabric, to increase the smoothness of the fabric surface. Yes. Patent Document 2 discloses that the surface of the fabric is increased in smoothness, and the gap between adjacent warps and wefts is made smaller than the size of pollen (about 30 μm), so that pollen is less likely to adhere, It describes fabrics that are less likely to enter between fibers or into clothing. However, these techniques are limited to fabrics using long fibers and high-density fabrics, and are not suitable for sportswear applications because of their low stretchability. Further, since the air permeability is small, it is insufficient from the viewpoint of comfort as clothes.
これに対し、特許文献３には、経方向と緯方向の編密度の積を規定することにより、花粉付着防止能を付与した編物が記載されている。しかしながら、その効果は、高密度織物と比較すると明らかに劣るものであった。経糸と緯糸の直線的な組み合わせからなる織物に対し、編物は、糸の屈曲によるループが連続して絡み合っているため、伸縮性、弾力性、嵩高性などには優れるものの、ゴミや埃、そして花粉などが捕捉されやすく、かつ、落ちにくいのである。なお、この傾向は、後述する他の方法により花粉付着防止能を付与する場合にも同様に認められる。 On the other hand, Patent Document 3 describes a knitted fabric imparted with pollen adhesion preventing ability by defining the product of the knitting density in the warp direction and the weft direction. However, the effect was clearly inferior compared to high density fabrics. In contrast to a woven fabric that consists of a linear combination of warp and weft, the knitted fabric has excellent loopability, elasticity, bulkiness, etc. because the loops caused by the bending of the yarn are continuously intertwined. Pollen and the like are easily captured and are difficult to fall off. In addition, this tendency is recognized similarly also when providing pollen adhesion prevention ability with the other method mentioned later.
花粉が付着する原因となり得る静電気の発生を抑えることにより、花粉を付着させないようにする試みも提案されている。例えば、前記特許文献２や前記特許文献３に記載の布帛でも、布帛組織の改良とともに、導電性繊維の使用や、帯電防止剤の処理により制電性が付与されている。また、特許文献４には、繊維表面に、ポリアルキレンオキサイドセグメントを主体とする主鎖の末端または側鎖にアクリル基および／またはメタクリル基を有する単量体を重合せしめてなる被膜を形成し、さらに、該被膜中に無機微粒子を含有させることにより、制電性や花粉付着防止能を付与した繊維構造物が記載されている。ここで、無機微粒子は、被膜の粘着性を抑えて花粉の離脱性を良くするために用いられる。しかしながら、今一つ良好な効果は得られなかった。 Attempts have been made to prevent pollen from adhering by suppressing the generation of static electricity that can cause pollen to adhere. For example, even in the fabrics described in Patent Document 2 and Patent Document 3, antistatic properties are imparted through the use of conductive fibers and the treatment with an antistatic agent as the fabric structure is improved. In Patent Document 4, a film is formed on the fiber surface by polymerizing a monomer having an acrylic group and / or a methacrylic group at the end or side chain of the main chain mainly composed of a polyalkylene oxide segment, Furthermore, a fiber structure having antistatic properties and ability to prevent pollen adhesion by containing inorganic fine particles in the coating is described. Here, the inorganic fine particles are used to suppress the adhesiveness of the coating and improve the pollen release. However, another good effect was not obtained.
また、繊維表面に花粉よりも小さな微粒子を付着させ、繊維表面に微細な凹凸を形成することにより、繊維と花粉、厳密には微粒子と花粉との接触状態を点接触として、花粉を付着させないように、かつ、付着しても落ちやすいようにする試みも提案されている。例えば、特許文献５には、直径が数ｎｍ〜数１００ｎｍのコロイダルシリカ類の微粒子を繊維構造物の表面に均一に付着させることにより、繊維構造物に花粉付着防止能を付与する方法が記載されている。また、特許文献６には、粒子径が５００ｎｍ以下、好ましくは１００ｎｍ以下の微粒子を繊維表面に付着させることにより、繊維製品に花粉付着防止能を付与する方法が記載されている。しかしながら、これらの微粒子は、洗濯などにより脱落しやすく、また、耐久性を向上させるためにグリオキザール系樹脂などのバインダー樹脂を用いると、樹脂の粘着性により、一旦付着した花粉が落ちにくいという問題があった。さらに、無機系の微粒子を用いた場合には、風合いが硬くなるという問題があった。 Also, by attaching fine particles smaller than pollen to the fiber surface and forming fine irregularities on the fiber surface, the contact state between the fiber and pollen, strictly speaking, the fine particle and pollen is point contact, so that no pollen is attached. Attempts have also been made to make it easy to drop even if it adheres. For example, Patent Document 5 describes a method of imparting pollen adhesion preventing ability to a fiber structure by uniformly attaching fine particles of colloidal silica having a diameter of several nm to several hundred nm on the surface of the fiber structure. ing. Patent Document 6 describes a method of imparting pollen adhesion preventing ability to a fiber product by attaching fine particles having a particle diameter of 500 nm or less, preferably 100 nm or less, to the fiber surface. However, these fine particles are easy to fall off by washing or the like, and when a binder resin such as glyoxal resin is used to improve the durability, pollen once adhered is difficult to drop due to the adhesiveness of the resin. there were. Further, when inorganic fine particles are used, there is a problem that the texture becomes hard.
花粉症対応衣服素材に関する他の試みとして、花粉アレルゲンを不活化（低減化を含む）する性能を備えた衣服素材の開発が挙げられる。例えば、特許文献７には、銀系化合物を含有するハウスダスト処理剤が記載されており、これをカーペットや絨毯、カーテンなどに噴霧したり、不織布や織布などに含浸、塗布または吸着させたりすることにより、ハウスダストに含まれるダニ、花粉などに由来するアレルゲン全てを不活化することができる旨説明されている。また、特許文献８には、抗アレルゲン性金属成分、好ましくは銀および／または亜鉛を含有するアレルゲン不活性化剤が記載されており、前記特許文献７と同様の説明がなされている。しかしながら、これらは、一時的効果を狙ったものにすぎず、洗濯などにより金属が溶出または脱落し、効果が失われるという問題があった。 Another attempt related to hay fever-resistant clothing materials includes the development of clothing materials with the ability to inactivate (including reduction) pollen allergens. For example, Patent Document 7 describes a house dust treatment agent containing a silver-based compound, which is sprayed on carpets, carpets, curtains, or impregnated, applied, or adsorbed on nonwoven fabrics or woven fabrics. It is explained that all allergens derived from mites, pollen and the like contained in house dust can be inactivated. Patent Document 8 describes an allergen inactivating agent containing an anti-allergenic metal component, preferably silver and / or zinc, and has the same explanation as Patent Document 7. However, these are only intended for temporary effects, and there is a problem that the metal is eluted or dropped out by washing or the like, and the effect is lost.
これに対し、特許文献９には、アレルゲン低減化成分、好ましくは芳香族ヒドロキシ化合物を、グラフト化反応により繊維に化学的に結合させるか、または、バインダーを用いて繊維表面に固着させることにより、アレルゲン低減化能を持続的に付与した繊維が記載されている。しかしながら、芳香族ヒドロキシ化合物が有するフェノール系水酸基は酸化しやすく、これに伴いアレルゲン低減化能が失われたり、変色したりするという問題があった。 In contrast, Patent Document 9 discloses that an allergen-reducing component, preferably an aromatic hydroxy compound, is chemically bonded to a fiber by a grafting reaction, or is fixed to a fiber surface using a binder, A fiber that has been continuously imparted with allergen-reducing ability is described. However, the phenolic hydroxyl group contained in the aromatic hydroxy compound is easily oxidized, and there is a problem in that the allergen reducing ability is lost or discolored.
このように、消費者が十分に満足し得る花粉症対応衣服素材は、未だ達成されていない。 Thus, a hay fever garment material that can be fully satisfied by consumers has not yet been achieved.
本発明は、かかる現状に鑑みてなされたもので、花粉付着防止能と花粉アレルゲン不活化能の双方の性能を備え、変色を伴わず、風合いが良好で、しかも洗濯耐久性に優れ、スポーツウェアなどの各種衣服素材として好適に用いることができる繊維布帛を提供することを目的とする。 The present invention has been made in view of the current situation, and has both performances of preventing pollen adhesion and pollen allergen inactivation, is not accompanied by discoloration, has a good texture, and has excellent washing durability, sportswear It aims at providing the textile fabric which can be used suitably as various clothing materials, such as.
本発明は、繊維表面に少なくとも内層と外層の二層からなる複合層を有する繊維布帛であって、内層がアニオン性親水性樹脂からなる被膜層であり、外層がカチオン性シリコーン系化合物微粒子からなる被膜層であり、かつ、
（１）内層が銀系化合物を含有する、および／または、
（２）内層と外層との間に、銀系化合物を含有するノニオン性および／またはアニオン性バインダー樹脂からなる被膜層が中間層として配されてなる、
ことを特徴とする花粉付着防止能と花粉アレルゲン不活化能を有する繊維布帛である。
The present invention is a fiber fabric having a composite layer consisting of at least two layers of an inner layer and an outer layer on the fiber surface, the inner layer being a coating layer made of an anionic hydrophilic resin, and the outer layer being made of cationic silicone compound fine particles A coating layer, and
(1) The inner layer contains a silver compound and / or
(2) Between the inner layer and the outer layer, a coating layer made of a nonionic and / or anionic binder resin containing a silver compound is disposed as an intermediate layer.
This is a fiber fabric having the ability to prevent pollen adhesion and the ability to inactivate pollen allergens.
前記繊維布帛において、銀系化合物は、酸化銀、銀錯体および銀塩からなる群より選ばれる少なくとも１種であることが好ましい。
また、カチオン性シリコーン系化合物微粒子は、カチオン変性オルガノシリケート微粒子であることが好ましい。
また、アニオン性親水性樹脂は、アニオン性親水性ポリエステル系樹脂であることが好ましい。
In the fiber fabric, the silver-based compound is preferably at least one selected from the group consisting of silver oxide, a silver complex, and a silver salt.
The cationic silicone compound fine particles are preferably cation-modified organosilicate fine particles.
The anionic hydrophilic resin is preferably an anionic hydrophilic polyester resin.
本発明によれば、花粉付着防止能と花粉アレルゲン不活化能の双方の性能を備え、変色を伴わず、風合いが良好で、しかも洗濯耐久性に優れ、スポーツウェアなどの各種衣服素材として好適に用いることができる繊維布帛を提供することができる。 According to the present invention, it has both the ability to prevent pollen adhesion and the ability to inactivate pollen allergen, is not accompanied by discoloration, has a good texture, has excellent washing durability, and is suitable as various clothing materials such as sportswear. A fiber fabric that can be used can be provided.
以下、本発明の実施の形態について、詳細に説明する。 Hereinafter, embodiments of the present invention will be described in detail.
本発明に用いられる繊維布帛の形態としては、例えば、織物、編物、不織布などを挙げることができる。花粉付着防止能の点では織物が優れているが、編物や不織布であっても、実用上、問題なく用いることができる。
また、繊維素材としては、例えば、ポリエステル、ポリアミド、アクリル、ビニロン等の合成繊維；アセテート、トリアセテート等の半合成繊維；レーヨン、キュプラ等の再生繊維；綿、羊毛、絹等の天然繊維などを挙げることができ、これらが２種以上組み合わされていてもよい。なかでも、繊維物性、特には寸法安定性に優れた素材である合成繊維が好ましい。繊維の寸法変化が、繊維加工剤の脱落性、つまりは花粉付着防止能や花粉アレルゲン不活化能の洗濯耐久性に影響を及ぼし得るからである。
繊維布帛は、必要に応じて、染料や顔料により着色されたものであってもよい。
Examples of the form of the fiber fabric used in the present invention include a woven fabric, a knitted fabric, and a non-woven fabric. Woven fabrics are superior in terms of preventing pollen adhesion, but even knitted fabrics and non-woven fabrics can be used practically without problems.
Examples of the fiber material include synthetic fibers such as polyester, polyamide, acrylic, and vinylon; semi-synthetic fibers such as acetate and triacetate; regenerated fibers such as rayon and cupra; natural fibers such as cotton, wool, and silk. Two or more of these may be combined. Of these, synthetic fibers, which are materials excellent in fiber properties, particularly dimensional stability, are preferred. This is because the dimensional change of the fibers can affect the detachability of the fiber processing agent, that is, the washing durability of pollen adhesion prevention ability and pollen allergen inactivation ability.
The fiber fabric may be colored with a dye or a pigment as necessary.
本発明は、かかる繊維布帛を構成する繊維１本１本（すなわち単繊維）の表面に、少なくとも内層と外層の二層からなる複合層を有するものである。このうち、内層はアニオン性親水性樹脂からなる被膜層であり、外層はカチオン性シリコーン系化合物微粒子からなる被膜層である。なお、本明細書において内層とは、繊維と直に接して配される層をいい、外層とは、内層の外側に空気と接して配される層をいうものとする。 The present invention has a composite layer composed of at least two layers of an inner layer and an outer layer on the surface of each fiber (that is, a single fiber) constituting the fiber fabric. Among these, the inner layer is a coating layer made of an anionic hydrophilic resin, and the outer layer is a coating layer made of cationic silicone compound fine particles. In the present specification, the inner layer refers to a layer disposed in direct contact with the fiber, and the outer layer refers to a layer disposed in contact with air outside the inner layer.
親水性樹脂は、その親水性に起因して、制電性、吸水性、防汚性などの性能を発揮する。かかる親水性樹脂を用いて繊維表面を直に被覆する内層を形成することにより、静電気の発生を抑え、花粉が付着するのを防止することができる。また、花粉が付着したとしても、洗濯時には洗浄剤の花粉への接近を容易にし、洗浄力を高め、もって花粉の除去性を良くすることができる。さらに、着用時には発汗などによる水分を素早く吸収することができる。 The hydrophilic resin exhibits performance such as antistatic property, water absorption property, and antifouling property due to its hydrophilicity. By forming an inner layer that directly covers the fiber surface using such a hydrophilic resin, generation of static electricity can be suppressed and pollen can be prevented from adhering. Moreover, even if pollen adheres, it is possible to facilitate access to the pollen of the cleaning agent during washing, increase the cleaning power, and improve the pollen removability. Furthermore, moisture due to sweating can be quickly absorbed when worn.
本発明において、内層を形成する親水性樹脂は、アニオン性であることが求められる。これは、電気的相互作用により、カチオン性を有する外層との密着性を高めるためである。本発明に用いられるアニオン性親水性樹脂としては、例えば、親水性ポリエステル系樹脂、親水性ポリアミド系樹脂、親水性ポリウレタン系樹脂、親水性ポリアクリル系樹脂などの一部が、カルボキシル基、スルホン酸基などによりアニオン化されたものを挙げることができる。なかでも、耐久性の点からアニオン性親水性ポリエステル系樹脂が好ましい。親水性ポリエステル系樹脂は、ポリエチレングリコール、ポリプロピレングリコール、ポリテトラメチレングリコール、エチレングリコール、プロピレングリコール、テトラメチレングリコールなどのジオール成分と、テレフタル酸、イソフタル酸などのジカルボン酸成分からなり、そのアニオン化物を用いることにより、前述の効果を、安定的かつ持続的に得ることができる。 In the present invention, the hydrophilic resin forming the inner layer is required to be anionic. This is to enhance the adhesion with the outer layer having a cationic property by electrical interaction. Examples of the anionic hydrophilic resin used in the present invention include, for example, a hydrophilic polyester resin, a hydrophilic polyamide resin, a hydrophilic polyurethane resin, a hydrophilic polyacrylic resin, a carboxyl group, a sulfonic acid, and the like. Examples thereof include anionized groups. Among these, an anionic hydrophilic polyester resin is preferable from the viewpoint of durability. The hydrophilic polyester resin consists of diol components such as polyethylene glycol, polypropylene glycol, polytetramethylene glycol, ethylene glycol, propylene glycol, and tetramethylene glycol, and dicarboxylic acid components such as terephthalic acid and isophthalic acid. By using it, the above-mentioned effects can be obtained stably and continuously.
アニオン性親水性樹脂の付着量は、繊維重量に対し０．０５〜１０重量％であることが好ましく、０．１〜５重量％であることがより好ましい。付着量が０．０５重量％未満であると、十分な花粉付着防止能が得られない虞がある。付着量が１０重量％を超えると、風合いが硬くなったり、染色堅牢度が悪くなったりする虞がある。付着量がこの範囲となるように、後述する処理液の濃度や、圧搾率などを調整する。 The adhesion amount of the anionic hydrophilic resin is preferably 0.05 to 10% by weight and more preferably 0.1 to 5% by weight with respect to the fiber weight. If the adhesion amount is less than 0.05% by weight, there is a possibility that sufficient pollen adhesion preventing ability cannot be obtained. When the adhesion amount exceeds 10% by weight, the texture may become hard or the color fastness may deteriorate. The concentration of the treatment liquid described later, the squeezing rate, and the like are adjusted so that the adhesion amount falls within this range.
アニオン性親水性樹脂からなる被膜層を、内層として、繊維表面に形成するには、繊維加工において一般的に行われている方法を用いればよく、例えば、（１）アニオン性親水性樹脂を含む処理液に繊維布帛を浸漬し、８０〜１５０℃の浴中で吸尽処理する方法、（２）前記処理液に繊維布帛を浸漬することにより、または、前記処理液を繊維布帛にスプレーもしくは塗布することにより、前記処理液を繊維布帛に含浸させた後、必要に応じて圧搾して余剰液を除去し、次いで１１０〜１８０℃で熱処理して乾燥する方法、を挙げることができる。なかでも、アニオン性親水性樹脂を繊維表面に均一に導入することが可能で、洗濯耐久性を容易に得ることができるという理由により、（１）の方法が好ましい。 In order to form a coating layer made of an anionic hydrophilic resin on the fiber surface as an inner layer, a method generally used in fiber processing may be used. For example, (1) including an anionic hydrophilic resin A method of immersing the fiber cloth in the treatment liquid and exhausting it in a bath at 80 to 150 ° C. (2) By immersing the fiber cloth in the treatment liquid, or spraying or applying the treatment liquid onto the fiber cloth By so doing, after impregnating the above-mentioned treatment liquid into the fiber fabric, the excess liquid can be removed by pressing as necessary, and then heat treated at 110 to 180 ° C. and dried. Among these, the method (1) is preferable because the anionic hydrophilic resin can be uniformly introduced onto the fiber surface and the washing durability can be easily obtained.
なお、処理液は、必要に応じて紫外線吸収剤、赤外線吸収剤、制電剤、抗菌剤、消臭剤、防虫剤、ｐＨ調整剤など、他の成分を含んでいてもよい。 The treatment liquid may contain other components such as an ultraviolet absorber, an infrared absorber, an antistatic agent, an antibacterial agent, a deodorant, an insect repellent, and a pH adjuster as necessary.
本発明の１つの態様においては、この、繊維表面に形成されるアニオン性の内層が、銀系化合物を含有する。このとき内層を形成するアニオン性親水性樹脂は、いわばバインダー樹脂として機能する。 In one embodiment of the present invention, the anionic inner layer formed on the fiber surface contains a silver-based compound. At this time, the anionic hydrophilic resin forming the inner layer functions as a binder resin.
以前より、銀が抗菌性や消臭性を有することは知られていたが、近年になって、アレルゲン不活化能をも有することが明らかとなってきた。イオン状態の銀にその性能が強く発現される。銀イオンが、アレルゲンとなるタンパク質を変性し、生物の受容体と合致しなくなることで、不活化されると考えられている。したがって、アレルゲンとの反応により銀が消費されることがなく、銀が繊維に付着している限り、その効果は持続する。本態様においては、アニオン性の内層に、銀を化合物として含有させ、さらにその周囲を、カチオン性の外層で被覆するため、洗濯耐久性に優れたアレルゲン不活化能、特には花粉アレルゲン不活化能を具備することができる。 Although silver has been known to have antibacterial and deodorizing properties, it has become clear in recent years that it also has allergen inactivation ability. Its performance is strongly expressed in ionic silver. It is believed that silver ions are inactivated by denaturing allergen proteins and becoming incompatible with biological receptors. Therefore, silver is not consumed by reaction with the allergen, and as long as the silver is attached to the fiber, the effect persists. In this embodiment, the anionic inner layer contains silver as a compound, and the periphery thereof is coated with a cationic outer layer, so that allergen inactivating ability excellent in washing durability, in particular pollen allergen inactivating ability Can be provided.
本態様に用いられる銀系化合物は、水溶性であっても非水溶性であってもよく、例えば、酸化銀；フィチン酸等との銀錯体；硝酸銀、硫酸銀、Ｎ−ステアリル−Ｌ−グルタミン酸銀等の銀塩などをあげることができる。銀系化合物は、担体に担持されていてもよく、こうすることにより、花粉アレルゲン不活化能をより向上させることができる。このような担体としては、例えば、ゼオライト（結晶性アルミノケイ酸塩）、シリカゲル、粘土鉱物等のケイ酸塩；リン酸ジルコニウム、リン酸カルシウム等のリン酸塩類；酸化チタン、酸化ケイ素、酸化アルミニウム、酸化ジルコニウム等の酸化物；溶解性ガラス、活性炭、金属担体、有機金属などを挙げることができる。銀系化合物（担持物を含む）は１種単独で、または２種以上組み合わせて用いることができる。なかでも、持続性、安全性、非着色性などの点から、酸化銀を酸化チタンに担持したものが好ましい。 The silver-based compound used in this embodiment may be water-soluble or water-insoluble. For example, silver oxide; silver complex with phytic acid or the like; silver nitrate, silver sulfate, N-stearyl-L-glutamic acid Silver salts such as silver can be listed. The silver-based compound may be supported on a carrier, and by doing so, the pollen allergen inactivation ability can be further improved. Examples of such carriers include silicates such as zeolite (crystalline aluminosilicate), silica gel, clay minerals; phosphates such as zirconium phosphate and calcium phosphate; titanium oxide, silicon oxide, aluminum oxide, zirconium oxide And the like; soluble glass, activated carbon, metal carrier, organic metal and the like. A silver type compound (a support is included) can be used individually by 1 type or in combination of 2 or more types. Of these, silver oxide supported on titanium oxide is preferable from the standpoints of durability, safety, and non-coloration.
銀系化合物（担持物を含む）の平均粒子径は、１μｍ以下であることが好ましく、５００ｎｍ以下であることがより好ましい。平均粒子径を小さくすることにより表面積が増大するため、花粉アレルゲン不活化能を高めることができる。また、アニオン性親水性樹脂の造膜性が損なわれることがない。 The average particle size of the silver-based compound (including the support) is preferably 1 μm or less, and more preferably 500 nm or less. Since the surface area is increased by reducing the average particle size, pollen allergen inactivation ability can be enhanced. Moreover, the film-forming property of an anionic hydrophilic resin is not impaired.
銀系化合物の付着量は、銀元素濃度換算で繊維重量に対し０．０００１〜１重量％であることが好ましく、０．００１〜０．５重量％であることがより好ましい。付着量が０．０００１重量％未満であると、十分な花粉アレルゲン不活化能が得られない虞がある。付着量が１重量％を超えると、コストが高くなったり、風合いが硬くなったりする虞がある。付着量がこの範囲となるように、前記のアニオン性親水性樹脂を含む処理液に添加すればよい。 The adhesion amount of the silver-based compound is preferably 0.0001 to 1% by weight and more preferably 0.001 to 0.5% by weight with respect to the fiber weight in terms of silver element concentration. If the adhesion amount is less than 0.0001% by weight, sufficient pollen allergen inactivation ability may not be obtained. If the adhesion amount exceeds 1% by weight, the cost may increase or the texture may become hard. What is necessary is just to add to the process liquid containing the said anionic hydrophilic resin so that the adhesion amount may become this range.
このように、銀系化合物は、少量でアレルゲン不活化能、特に花粉アレルゲン不活化能を発揮することができる。これに対し、他のアレルゲン不活化成分、例えば、タンニン類、ポリフェノール類などは、銀系化合物の２〜５倍量以上必要とされる。また、銀系化合物は安全性が高く、無色無臭であり、加工により変色をきたすことがなく、繊維加工剤として使い勝手がよい。 Thus, the silver-based compound can exhibit allergen inactivating ability, particularly pollen allergen inactivating ability, in a small amount. On the other hand, other allergen-inactivating components, such as tannins and polyphenols, are required in an amount of 2 to 5 times the silver compound. In addition, the silver-based compound has high safety, is colorless and odorless, does not cause discoloration by processing, and is easy to use as a fiber processing agent.
本発明の別の態様においては、前記の、繊維表面に形成されるアニオン性の内層の外側に、後述するカチオン性の外層と挟み込まれるような状態で、すなわち中間層として、銀系化合物を含有するノニオン性および／またはアニオン性バインダー樹脂からなる被膜層を配する。このように銀系化合物を含有する層を別途設けることにより、バインダー樹脂が銀系化合物を強固に固着させ、洗濯耐久性を向上させる利点がある。なお、アニオン性の内層は、銀系化合物の含有を要さないが、銀系化合物を含有していても何ら差し支えない。以下、アニオン性の内層が銀系化合物を含有しないことを前提に説明する。 In another aspect of the present invention, a silver-based compound is contained in the state of being sandwiched between a cationic outer layer described later on the outside of the anionic inner layer formed on the fiber surface, that is, as an intermediate layer. A coating layer made of nonionic and / or anionic binder resin is disposed. Thus, by separately providing a layer containing a silver compound, there is an advantage that the binder resin firmly fixes the silver compound and improves the washing durability. The anionic inner layer does not need to contain a silver compound, but may contain a silver compound. The following description is based on the assumption that the anionic inner layer does not contain a silver compound.
本態様に用いられる銀系化合物の種類や、その付着量については、前記した態様（内層に銀系化合物を含有させる態様）の場合と同様である。 About the kind of silver-type compound used for this aspect, and the adhesion amount, it is the same as that of the case of an above described aspect (mode which makes a inner layer contain a silver-type compound).
本態様に用いられるバインダー樹脂は、ノニオン性またはアニオン性であることが求められる。これは、アニオン性を有する内層と、カチオン性を有する外層との電気的相互作用を阻害することなく、かつ、中間層自身と外層との電気的相互作用により、複合層全体の密着性を高めるためである。 The binder resin used in this embodiment is required to be nonionic or anionic. This enhances the adhesion of the entire composite layer without hindering the electrical interaction between the anionic inner layer and the cationic outer layer and by the electrical interaction between the intermediate layer itself and the outer layer. Because.
本態様に用いられるノニオン性バインダー樹脂としては、例えば、アクリル酸エステルモノマーの重合体、オレフィンの重合体、イソシアネートとポリオールの重合体、アミノ基とアルデヒド基の重合体、シロキサン結合を有する重合体、アクリロニトリルの重合体、グリシジル基の重合体、単糖の重合体、アミノ酸の重合体、およびこれらの共重合体などを挙げることができる。これらは前もってポリマー化したものを用いてもよいし、モノマーあるいはプレポリマーを用いて繊維上で重合させポリマー化してもよい。また、反応性の高い官能基が保護されたものであってもよい。 Examples of the nonionic binder resin used in this embodiment include a polymer of an acrylate ester monomer, a polymer of an olefin, a polymer of an isocyanate and a polyol, a polymer of an amino group and an aldehyde group, a polymer having a siloxane bond, Examples include acrylonitrile polymers, glycidyl group polymers, monosaccharide polymers, amino acid polymers, and copolymers thereof. These may be polymerized in advance, or may be polymerized on a fiber using a monomer or a prepolymer. Moreover, the functional group with high reactivity may be protected.
また、本態様に用いられるアニオン性バインダー樹脂としては、前記化合物の一部が、カルボキシル基、水酸基、スルホン酸基、リン酸基などによりアニオン化されたものを挙げることができる。 In addition, examples of the anionic binder resin used in this embodiment include those in which a part of the compound is anionized with a carboxyl group, a hydroxyl group, a sulfonic acid group, a phosphoric acid group, or the like.
これらは１種単独で、または２種以上組み合わせて用いることができ、イオン性の異なるものを組み合わせることもできる。なかでも、風合いの柔らかさの点で、アクリル酸エステルモノマーの重合体、イソシアネートとポリオールの重合体、イソシアネートとポリオールの重合体であって両末端、片末端または側鎖にブロックイソシアネートを有するもの、およびこれらの共重合体が好ましく、さらにこれらがアニオン化されたものであると、付着力に優れより好ましい。 These can be used individually by 1 type or in combination of 2 or more types, The thing from which ionicity differs can also be combined. Among them, in terms of softness, a polymer of an acrylate monomer, a polymer of an isocyanate and a polyol, a polymer of an isocyanate and a polyol having a blocked isocyanate at both ends, one end or a side chain, These copolymers are also preferred, and those anionized are more preferred because of their excellent adhesion.
ノニオン性および／またはアニオン性バインダー樹脂の付着量は、繊維重量に対し０.０１〜１０重量％であることが好ましく、０.０５〜５重量％であることがより好ましい。付着量が０.０１重量％未満であると、目的量の銀系化合物を付与することができない虞がある。付着量が１０重量％を超えると、風合いが硬くなったり、染色堅牢度が悪くなったりする虞がある。付着量がこの範囲となるように、後述する処理液の濃度や、圧搾率などを調整する。 The adhesion amount of the nonionic and / or anionic binder resin is preferably from 0.01 to 10% by weight, more preferably from 0.05 to 5% by weight, based on the fiber weight. If the adhesion amount is less than 0.01% by weight, there is a possibility that the target amount of the silver compound cannot be applied. When the adhesion amount exceeds 10% by weight, the texture may become hard or the color fastness may deteriorate. The concentration of the treatment liquid, which will be described later, the squeezing rate, and the like are adjusted so that the adhesion amount falls within this range.
銀系化合物を含有するノニオン性および／またはアニオン性バインダー樹脂からなる被膜層を、中間層として、繊維表面に形成されたアニオン性の内層の外側に形成するには、繊維加工において一般的に行われている方法を用いればよく、例えば、（１）銀系化合物と、ノニオン性および／またはアニオン性バインダー樹脂とを含む処理液に、内層が形成された繊維布帛を浸漬し、８０〜１５０℃の浴中で吸尽処理する方法、（２）前記処理液に前記繊維布帛を浸漬することにより、または、前記処理液を前記繊維布帛にスプレーもしくは塗布することにより、前記処理液を前記繊維布帛に含浸させた後、必要に応じて圧搾して余剰液を除去し、次いで１１０〜１８０℃で熱処理して乾燥する方法、を挙げることができる。なかでも、操作が簡便で、かつ、付着量の調整が容易であるという理由により、（２）の方法、特に前記処理液に前記繊維布帛を浸漬後、圧搾し、乾燥する方法が好ましい。 In order to form a coating layer made of a nonionic and / or anionic binder resin containing a silver-based compound as an intermediate layer outside the anionic inner layer formed on the fiber surface, it is a common practice in fiber processing. For example, (1) a fiber fabric having an inner layer formed is immersed in a treatment liquid containing a silver compound and a nonionic and / or anionic binder resin, and the temperature is 80 to 150 ° C. And (2) immersing the fiber cloth in the treatment liquid, or spraying or coating the treatment liquid onto the fiber cloth, thereby treating the fiber cloth with the treatment liquid. After impregnating, a method may be mentioned in which the excess liquid is removed by pressing as necessary, followed by heat treatment at 110 to 180 ° C. and drying. Among these, the method (2), particularly the method of squeezing and drying the fiber fabric in the treatment liquid, is preferable because the operation is simple and the adjustment of the adhesion amount is easy.
なお、処理液は、必要に応じて触媒、重合開始剤、紫外線遮蔽剤、赤外線吸収剤、制電剤、抗菌剤、消臭剤、防虫剤、ｐＨ調整剤など、他の成分を含んでいてもよい。 The treatment liquid contains other components such as a catalyst, a polymerization initiator, an ultraviolet shielding agent, an infrared absorber, an antistatic agent, an antibacterial agent, a deodorant, an insect repellent, and a pH adjuster as necessary. Also good.
本発明による花粉付着防止能と花粉アレルゲン不活化能を有する繊維布帛は、以上説明した、繊維表面に形成された銀系化合物を含有するアニオン性の内層の外側に、または、繊維表面に形成された銀系化合物を含有しないアニオン性の内層と銀系化合物を含有するノニオン性またはアニオン性の中間層の外側に、外層として、カチオン性シリコーン系化合物微粒子からなる被膜層を配したものである。 The fiber fabric having the ability to prevent pollen adhesion and the ability to inactivate pollen allergens according to the present invention is formed on the outside of the anionic inner layer containing the silver-based compound formed on the fiber surface described above or on the fiber surface. In addition, a coating layer composed of cationic silicone compound fine particles is disposed as an outer layer on the outer side of an anionic inner layer containing no silver compound and a nonionic or anionic intermediate layer containing a silver compound.
カチオン性シリコーン系化合物とは、ＳｉＯ結合を有し、かつ、１〜３級アミノ基や４級アンモニウム基などのカチオン性基を導入した有機基を有する化合物である。カチオン性シリコーン系化合物は有機基を有するため、適度な弾性があり、繊維表面を被覆する複合層の外層に配しても、繊維布帛の風合いを損なうことがない。 The cationic silicone compound is a compound having an SiO group and an organic group into which a cationic group such as a primary to tertiary amino group or a quaternary ammonium group is introduced. Since the cationic silicone compound has an organic group, it has moderate elasticity, and even if it is arranged in the outer layer of the composite layer covering the fiber surface, the texture of the fiber fabric is not impaired.
なお、カチオン性シリコーン系化合物が、エラストマーのように粘弾性を有するものであると、花粉の付着により被膜が圧着変形し、さらには、花粉が被膜内部に潜り込む状態となって、離脱性が悪くなるため、好ましくない。また、水などに溶解した花粉アレルゲンに対しても、粘弾性が花粉アレルゲンの離脱を阻害するため、好ましくない。 When the cationic silicone compound has viscoelasticity like an elastomer, the coating is deformed by the adhesion of pollen, and further, the pollen is in a state of being embedded in the coating, resulting in poor release properties. Therefore, it is not preferable. Also, it is not preferable for pollen allergens dissolved in water or the like because viscoelasticity inhibits the release of pollen allergens.
本発明に用いられるカチオン性シリコーン系化合物は、微粒子状であることが求められる。これは、繊維表面に微細な凹凸を形成することにより、花粉付着防止能を付与するためである。微粒子の形成性、形状および硬さの点から、カチオン性シリコーン系化合物微粒子は、カチオン変性オルガノシリケート微粒子であることが好ましい。 The cationic silicone compound used in the present invention is required to be in the form of fine particles. This is to provide pollen adhesion preventing ability by forming fine irregularities on the fiber surface. From the viewpoint of the formability, shape and hardness of the fine particles, the cationic silicone compound fine particles are preferably cation-modified organosilicate fine particles.
カチオン変性オルガノシリケート微粒子は、通常、１〜３級アミノ基や４級アンモニウム基などのカチオン性基と、シリカ表面のシラノール基に対して反応性を有する官能基との双方を有する有機化合物により、シリカ微粒子を表面処理することによって製造される。前記有機化合物としては、例えば、アミノエトキシシランやアミノアルキルジグリシジルエーテルなどを挙げることができる。 The cation-modified organosilicate fine particles are usually an organic compound having both a cationic group such as a primary to tertiary amino group or a quaternary ammonium group and a functional group having reactivity with a silanol group on the silica surface. Manufactured by surface-treating silica fine particles. Examples of the organic compound include aminoethoxysilane and aminoalkyldiglycidyl ether.
カチオン性シリコーン系化合物微粒子の平均粒子径は、１μｍ以下であることが好ましく、０．００５μｍ〜１μｍであることがより好ましい。平均粒子径がこの範囲にある微粒子を用いることにより、糸条同士の間隙や繊維同士の間隙はもちろん、繊維表面に存在し得る微細な窪み（花粉がひっかかりやすい）にまで微粒子が入り込み、繊維表面を均一に斑なく被覆する被膜層が形成される。こうして、繊維表面には微粒子による微細な凹凸が形成されるため、花粉付着防止能を具備することができる。平均粒子径が１μｍを超えると、十分な花粉付着防止能が得られなかったり、洗濯耐久性が低下したり、風合いが硬くなったりする虞がある。 The average particle size of the cationic silicone compound fine particles is preferably 1 μm or less, and more preferably 0.005 μm to 1 μm. By using fine particles with an average particle diameter in this range, fine particles can enter not only the gaps between the yarns and the gaps between the fibers, but also into the fine dents that are likely to be present on the fiber surface (pollen catches easily). A coating layer that uniformly coats the film is formed. In this way, fine irregularities due to fine particles are formed on the fiber surface, and thus can have pollen adhesion preventing ability. If the average particle diameter exceeds 1 μm, sufficient pollen adhesion preventing ability may not be obtained, washing durability may be reduced, and the texture may be hardened.
カチオン性シリコーン系化合物微粒子の付着量は、繊維重量に対し０．０１〜１０重量％であることが好ましく、０.０５〜５重量％であることがより好ましい。付着量が０．０１重量％未満であると、十分な花粉付着防止能が得られない虞がある。付着量が１０重量％を超えても、性能の向上が見られないばかりか、風合いが硬くなる虞がある。付着量がこの範囲となるように、後述する処理液の濃度や、圧搾率などを調整する。 The adhesion amount of the cationic silicone compound fine particles is preferably 0.01 to 10% by weight, more preferably 0.05 to 5% by weight, based on the fiber weight. If the adhesion amount is less than 0.01% by weight, there is a possibility that sufficient pollen adhesion preventing ability cannot be obtained. Even if the adhesion amount exceeds 10% by weight, not only the performance is not improved, but also the texture may become hard. The concentration of the treatment liquid described later, the squeezing rate, and the like are adjusted so that the adhesion amount falls within this range.
カチオン性シリコーン系化合物微粒子からなる被膜層を、外層として、繊維表面に形成された銀系化合物を含有するアニオン性の内層の外側に、または、繊維表面に形成された銀系化合物を含有しないアニオン性の内層と銀系化合物を含有するノニオン性および／またはアニオン性の中間層の外側に形成するには、繊維加工において一般的に行われている方法を用いればよく、例えば、（１）カチオン性シリコーン系化合物微粒子を含む処理液に、内層または内層と中間層が形成された繊維布帛を浸漬し、２０〜５０℃の浴中で吸尽処理する方法、（２）前記処理液に前記繊維布帛を浸漬することにより、または、前記処理液を前記繊維布帛にスプレーもしくは塗布することにより、前記処理液を前記繊維布帛に含浸させた後、必要に応じて圧搾して余剰液を除去し、次いで１１０〜１８０℃で熱処理して乾燥する方法、を挙げることができる。なかでも、操作が簡便であるという理由により、（２）の方法、特に前記処理液に前記繊維布帛を浸漬後、圧搾し、乾燥する方法が好ましい。 An anion that does not contain a silver compound formed on the fiber surface or on the outside of the anionic inner layer containing the silver compound formed on the fiber surface, with the coating layer comprising cationic silicone compound fine particles as the outer layer In order to form on the outer side of the nonionic and / or anionic intermediate layer containing a silver-based compound and a conductive inner layer, a method generally used in fiber processing may be used. For example, (1) a cation A method of immersing a fiber fabric having an inner layer or an inner layer and an intermediate layer in a treatment liquid containing fine conductive silicone compound fine particles, and exhausting the fiber fabric in a bath at 20 to 50 ° C., (2) the fibers in the treatment liquid After impregnating the fiber fabric with the treatment liquid by immersing the fabric or spraying or applying the treatment liquid to the fiber fabric, if necessary. To remove the excess liquid and exploitation, then followed by drying and heat-treated at 110 to 180 ° C., can be mentioned. Especially, the method of (2), especially the method of squeezing after drying the said fiber fabric in the said process liquid, and drying for the reason that operation is simple is preferable.
なお、処理液は、必要に応じて他の成分を含んでいてもよい。特に、平均粒子径が１μｍ以下の水不溶性微粒子を併用すると、花粉付着防止能を向上させることができ好ましい。このような水不溶性微粒子としては、例えば、二酸化ケイ素、酸化アルミニウム、珪酸マグネシウム、珪酸カルシウム、炭酸マグネシウム、炭酸カルシウムなどを挙げることができる。 In addition, the processing liquid may contain other components as necessary. In particular, when water-insoluble fine particles having an average particle diameter of 1 μm or less are used in combination, the ability to prevent pollen adhesion can be improved. Examples of such water-insoluble fine particles include silicon dioxide, aluminum oxide, magnesium silicate, calcium silicate, magnesium carbonate, and calcium carbonate.
かくして、本発明による花粉付着防止能と花粉アレルゲン不活化能を有する繊維布帛を得ることができる。 Thus, a fiber fabric having the ability to prevent pollen adhesion and the ability to inactivate pollen allergens according to the present invention can be obtained.
本発明による繊維布帛は、繊維表面に内層と外層、さらにその間に配されることのある中間層からなる複合層を有する。外層がカチオン性シリコーン系微粒子からなることにより、繊維表面に微細な凹凸を形成し、繊維と花粉との接触状態を点接触として、花粉付着防止能を発揮することができる。また、内層がアニオン性親水性樹脂からなることにより、静電気の発生を抑え、花粉付着防止能を高めるとともに、洗濯時には洗浄力を高め、花粉の除去性を良くすることができる。そして、前記内層、またはノニオン性および／またはアニオン性バインダー樹脂からなる中間層に銀系化合物を含有させることにより、変色を伴うことなく、花粉アレルゲン不活化能を具備することができる。このように、本発明による繊維布帛は、花粉付着防止能と花粉アレルゲン不活化能の双方の性能を備えるため、織物はもちろん、これまで困難とされていた編物においても、花粉症対応衣服素材として十分に機能することができる。 The fiber fabric according to the present invention has a composite layer comprising an inner layer and an outer layer on the fiber surface, and an intermediate layer that may be disposed therebetween. When the outer layer is made of cationic silicone-based fine particles, fine irregularities can be formed on the fiber surface, and the contact state between the fiber and pollen can be point-contacted to exhibit pollen adhesion preventing ability. In addition, since the inner layer is made of an anionic hydrophilic resin, it is possible to suppress the generation of static electricity and enhance the ability to prevent pollen adhesion, increase the detergency during washing, and improve pollen removability. And the pollen allergen inactivation ability can be comprised without accompanying discoloration by containing a silver-type compound in the intermediate | middle layer which consists of said inner layer or nonionic and / or anionic binder resin. As described above, since the fiber fabric according to the present invention has both the ability to prevent pollen adhesion and the ability to inactivate pollen allergens, it can be used not only for woven fabrics but also for knitted fabrics that have been difficult so far. Can function well.
本発明による繊維布帛は、繊維表面に形成されたアニオン性の内層とカチオン性の外層、さらにその間に配されることのあるノニオン性またはアニオン性の中間層が、電気的相互作用により強固に結合する構造を有するため、洗濯耐久性に優れている。しかも、外層に配されたカチオン性シリコーン系化合物微粒子の弾性により、風合いの良好な繊維布帛となる。
したがって、本発明による繊維布帛は、スポーツウェアなどの各種衣服素材として、好適に用いることができる。
In the fiber fabric according to the present invention, the anionic inner layer and the cationic outer layer formed on the fiber surface, and the nonionic or anionic intermediate layer that may be disposed between them are firmly bonded by electrical interaction. Since it has a structure to do, it is excellent in washing durability. In addition, the elasticity of the cationic silicone compound fine particles arranged in the outer layer provides a fiber fabric with a good texture.
Therefore, the fiber fabric according to the present invention can be suitably used as various clothing materials such as sportswear.
以上、内層または中間層のいずれかに銀系化合物を含有させる態様について説明したが、内層および中間層の双方に銀系化合物を含有させた場合にも、目的とする効果が得られることは容易に理解できよう。 As mentioned above, although the aspect which contains a silver type compound in either an inner layer or an intermediate | middle layer was demonstrated, when a silver type compound is contained in both an inner layer and an intermediate | middle layer, it is easy to obtain the target effect. To understand.
以下、実施例により本発明をさらに詳しく説明するが、本発明は以下の実施例に限定されるものではない。なお、性能の評価は以下の方法に従った。 EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to a following example. The performance was evaluated according to the following method.
（１）花粉付着防止能
３０ｃｍ×３０ｃｍ×３０ｃｍの発泡スチロール製箱型容器の内壁の一面に、１０ｃｍ×１０ｃｍにカットした試験布を取り付けた。次いで、容器に１．４ｇの擬似花粉（ヒカゲノカズラ胞子）を入れ、均一に拡散するように３０秒間振とうした。次いで、試験布を取り付けてある一面を上にして置き、高さ２０ｃｍの位置から１００ｇの錘を落として衝撃を与えた。衝撃の前後の試験布の状態を、マイクロスコープにより２００倍に拡大して撮影し、付着している花粉の個数をカウントし、以下の式により花粉リリース率を算出した。
花粉リリース率（％）＝［（衝撃前の花粉数−衝撃後の花粉数）／衝撃前の花粉数］×１００
(1) Pollen adhesion preventing ability A test cloth cut to 10 cm x 10 cm was attached to one surface of an inner wall of a 30 cm x 30 cm x 30 cm polystyrene foam box-type container. Next, 1.4 g of artificial pollen (L. genus spores) was placed in the container, and shaken for 30 seconds so as to diffuse evenly. Next, one surface on which the test cloth was attached was placed on top, and a 100 g weight was dropped from a position of 20 cm in height to give an impact. The state of the test cloth before and after the impact was photographed with a microscope at a magnification of 200 times, the number of adhering pollen was counted, and the pollen release rate was calculated by the following equation.
Pollen release rate (%) = [(number of pollen before impact−number of pollen after impact) / number of pollen before impact] × 100
（２）花粉アレルゲン不活化能
＜検液の調製＞
試験管に、２０ｎｇ／ｍｌのスギ花粉アレルゲン溶液（商品名「スギ花粉抗原ＳＢＰ」、生化学工業株式会社製）を１０ｍｌ入れ、５ｃｍ×５ｃｍにカットした試験布を浸漬した。室温で一晩静置後、試験布を取り出して得られる抽出液を検液とした。また、ブランクとして、２０ｎｇ／ｍｌのスギ花粉アレルゲン溶液を用いた。
(2) Pollen allergen inactivation ability <Preparation of test solution>
10 ml of a 20 ng / ml cedar pollen allergen solution (trade name “Sugi Pollen Antigen SBP”, manufactured by Seikagaku Corporation) was placed in a test tube, and a test cloth cut into 5 cm × 5 cm was immersed therein. After leaving still at room temperature overnight, the extract obtained by taking out the test cloth was used as a test solution. Moreover, a 20 ng / ml cedar pollen allergen solution was used as a blank.
＜検量線用標準溶液の調製＞
スギ花粉アレルゲン（商品名「精製Ｃｒｙｊ１」、生化学工業株式会社製）を０．１重量％ウシ血清アルブミン（ＢＳＡ）含有リン酸緩衝生理食塩水（ＰＢＳ）で希釈し、２０ｎｇ／ｍｌ、１０ｎｇ／ｍｌ、２ｎｇ／ｍｌ、０．５ｎｇ／ｍｌ、０．２５ｎｇ／ｍｌ、０ｎｇ／ｍｌの検量線用標準溶液を調製した。
<Preparation of standard solution for calibration curve>
Sugi pollen allergen (trade name “purified Cryj1”, manufactured by Seikagaku Corporation) was diluted with phosphate buffered saline (PBS) containing 0.1% by weight bovine serum albumin (BSA), and 20 ng / ml, 10 ng / Standard solutions for calibration curves of ml, 2 ng / ml, 0.5 ng / ml, 0.25 ng / ml, and 0 ng / ml were prepared.
＜測定手順＞
固相用抗体（商品名「ａｎｔｉ−Ｃｒｙｊ１」、生化学工業株式会社製）をＰＢＳで１０μｇ／ｍｌとなるように希釈したものを、マイクロプレートの各穴に１００μｌずつ加え、室温で２．５時間静置した。次いで、固相用抗体溶液を除去し、０．１重量％ＢＳＡ含有ＰＢＳを２５０μｌずつ加え、４℃で一晩静置した。
<Measurement procedure>
An antibody for solid phase (trade name “anti-Cryj1”, manufactured by Seikagaku Corporation) diluted with PBS to 10 μg / ml was added to each well of the microplate in a volume of 100 μl, and 2.5 ml at room temperature. Let stand for hours. Subsequently, the antibody solution for solid phase was removed, 250 μl of 0.1 wt% BSA-containing PBS was added, and allowed to stand at 4 ° C. overnight.
次いで、０．１重量％ＢＳＡ含有ＰＢＳを除去し、前記の検量線用標準溶液または検液を１００μｌずつ加え、室温で１．５時間静置した。次いで、検量線用標準溶液または検液を除去し、０．０５重量％Ｔｗｅｅｎ２０含有ＰＢＳを２５０μｌずつ加えて洗浄した。洗浄操作は３回繰り返した。 Next, 0.1 wt% BSA-containing PBS was removed, 100 μl of the standard curve standard solution or test solution was added, and allowed to stand at room temperature for 1.5 hours. Subsequently, the standard curve standard solution or the test solution was removed, and washed by adding 250 μl each of PBS containing 0.05 wt% Tween20. The washing operation was repeated 3 times.
次いで、スギ花粉アレルゲンモノクローナル抗体（商品名「Ｐｅｒｏｘｉｄａｓｅ ｃｏｎｊｕｇａｔｅｄ ａｎｔｉ−Ｃｒｙｊ１ ｍＡｂ０５３（西洋ワサビペルオキシダーゼ標識抗Ｃｒｙｊ１モノクローナル抗体０５３）」、生化学工業株式会社製）を０．１重量％ＢＳＡ含有ＰＢＳで１０００倍に希釈したものを１００μｌずつ加え、室温で２時間静置した。次いで、スギ花粉アレルゲンモノクローナル抗体溶液を除去し、０．０５重量％Ｔｗｅｅｎ２０含有ＰＢＳ２５０μｌで３回洗浄した。 Next, a cedar pollen allergen monoclonal antibody (trade name “Peroxidase conjugated anti-Cryj1 mAb053 (horseradish peroxidase-labeled anti-Cryj1 monoclonal antibody 053)”, manufactured by Seikagaku Corporation) was added 1000 times with PBS containing 0.1 wt% BSA. 100 μl of the diluted product was added and allowed to stand at room temperature for 2 hours. Subsequently, the cedar pollen allergen monoclonal antibody solution was removed, and washed with 250 μl of PBS containing 0.05 wt% Tween 20 three times.
次いで、基質溶液（０．１ｍｏｌ／ｌクエン酸・リン酸緩衝液１００ｍｌ、オルト−フェニレンジアミン５０ｍｇ、３０重量％過酸化水素水１００μｌで調製）を１００μｌずつ加え、室温で３分間発色させた後、マイクロプレートリーダー用分光光度計で４９０〜６５０ｎｍの吸光度を測定した。 Next, a substrate solution (100 ml of 0.1 mol / l citrate / phosphate buffer solution, 50 mg of ortho-phenylenediamine, 100 μl of 30 wt% hydrogen peroxide solution) was added 100 μl at a time, and color was allowed to develop for 3 minutes at room temperature. Absorbance at 490 to 650 nm was measured with a spectrophotometer for a microplate reader.
検量線用標準溶液の吸光度から得られる検量線を用いて、検液中のスギ花粉アレルゲン濃度を定量し、以下の式によりスギ花粉アレルゲン不活化率を算出した。
スギ花粉アレルゲン不活化率（％）＝［（ブランクのスギ花粉アレルゲン濃度−試験布のスギ花粉アレルゲン濃度）／ブランクのスギ花粉アレルゲン濃度］×１００
Using the calibration curve obtained from the absorbance of the standard curve standard solution, the cedar pollen allergen concentration in the test solution was quantified, and the cedar pollen allergen inactivation rate was calculated according to the following formula.
Cedar pollen allergen inactivation rate (%) = [(blank cedar pollen allergen concentration−cedar pollen allergen concentration of test cloth) / blank cedar pollen allergen concentration] × 100
（３）洗濯耐久性
ＪＩＳ Ｌ−０２１７ １０３法に従い、繰り返し洗濯を２０回行った。その後、よく乾燥させた試験布を用いて、前記の（１）および（２）の評価を行った。
(3) Washing durability According to JIS L-0217 103 method, repeated washing was performed 20 times. Thereafter, the above-mentioned (1) and (2) were evaluated using a well-dried test cloth.
（４）風合い
官能評価により、下記の基準に従って判定した。
○：良い
△：やや硬い
×：硬い
(4) Texture It was determined according to the following criteria by sensory evaluation.
○: Good △: Slightly hard ×: Hard
（５）変色性
官能評価により、下記の基準に従って判定した。
○：変色なし
△：やや変色あり
×：変色あり
(5) Discoloration property It was determined according to the following criteria by sensory evaluation.
○: No color change △: Some color change ×: Color change
また、試験用繊維布帛として、以下のものを用いた。
（７）試験用繊維布帛
１１０ｄｔｅｘ／３６フィラメントのポリエステルマルチフィラメント糸と、８４ｄｔｅｘ／３６フィラメントのポリエステルマルチフィラメント糸を、交編率（重量比）５０：５０で用いて、天竺組織の丸編地を編成した。得られた編地の重量は１５０ｇ／ｍ２であった。この編地を、常法により精練、プレセットしたものを、試験用繊維布帛とした。
Moreover, the following were used as the test fiber fabric.
(7) Fiber fabric for test Using a polyester multifilament yarn of 110 dtex / 36 filament and a polyester multifilament yarn of 84 dtex / 36 filament at a knitting ratio (weight ratio) of 50:50, Organized. The weight of the obtained knitted fabric was 150 g / m 2 . What kneaded and preset this knitted fabric by a conventional method was used as a test fiber fabric.
［実施例１］
内層の形成
アニオン性親水性ポリエステル系樹脂の乳濁液（商品名「ＳＲ−１０００」、固形分：１０重量％、高松油脂株式会社製）を繊維重量に対し２重量％の濃度で含み、かつ、酢酸にてｐＨを４．５に調整した処理液に、浴比が１：２０となるように試験用繊維布帛を浸漬し、１３０℃の浴中で３０分間吸尽処理を行った。水洗後、１２０℃で２分間熱処理して乾燥した。かくして、繊維表面に内層を形成した。
[Example 1]
Formation of inner layer An anionic hydrophilic polyester resin emulsion (trade name “SR-1000”, solid content: 10% by weight, manufactured by Takamatsu Yushi Co., Ltd.) is contained at a concentration of 2% by weight with respect to the fiber weight, and The test fiber fabric was immersed in a treatment solution adjusted to pH 4.5 with acetic acid so that the bath ratio was 1:20, and exhausted in a bath at 130 ° C. for 30 minutes. After washing with water, it was dried by heat treatment at 120 ° C. for 2 minutes. Thus, an inner layer was formed on the fiber surface.
中間層の形成
次いで、酸化チタンに担持させた酸化銀のアニオン性水分散液（商品名「ＡＴＯＭＹ−ＢＡＬＬ（Ｓ）」、平均粒子径：５ｎｍ、固形分：１．５重量％、日揮触媒化成株式会社製）を５重量％、アニオン性アクリルシリコーンの乳濁液（商品名「ファイコート３０Ｇ」、固形分：３０重量％、大和化学株式会社製）を１重量％含む処理液に浸漬後、圧搾機にて圧搾率が繊維重量に対して１００重量％となるように圧搾し、次いで１２０℃で２分間熱処理して乾燥した。かくして、繊維表面に形成された内層の外側に中間層を形成した。このとき、銀元素の付着量は繊維重量に対して０．０７重量％であった。なお、銀元素の付着量は、繊維を硝酸、硫酸、過塩素酸の混合液（濃度は分解状態に応じて調整する）で湿式分解した後、原子吸光光度法によって測定された値により求めた。
Formation of intermediate layer Next, an anionic aqueous dispersion of silver oxide supported on titanium oxide (trade name “ATOMY-BALL (S)”, average particle size: 5 nm, solid content: 1.5% by weight, JGC catalyst conversion After immersion in a treatment liquid containing 5% by weight of an anionic acrylic silicone emulsion (trade name “Phicoat 30G”, solid content: 30% by weight, manufactured by Daiwa Chemical Co., Ltd.) The squeezing was performed with a squeezing machine so that the squeezing rate was 100% by weight with respect to the fiber weight. Thus, an intermediate layer was formed outside the inner layer formed on the fiber surface. At this time, the adhesion amount of elemental silver was 0.07% by weight with respect to the fiber weight. In addition, the adhesion amount of silver element was calculated | required by the value measured by the atomic absorption photometry after wet-decomposing the fiber with the liquid mixture of nitric acid, a sulfuric acid, and perchloric acid (concentration is adjusted according to a decomposition state). .
外層の形成
次いで、カチオン変性オルガノシリケート微粒子の水分散液（商品名「ＢＡＹＧＡＲＤ ＡＳ」、平均粒子径：０．０３μｍ、固形分：１０重量％、ランクセス株式会社製）を５重量％含む処理液に浸漬後、圧搾機にて圧搾率が繊維重量に対して１００重量％となるように圧搾し、次いで１２０℃で２分間熱処理して乾燥した。かくして、繊維表面に形成された内層と中間層の外側に外層を形成した。このとき、カチオン変性オルガノシリケート微粒子の付着量は繊維重量に対して０．５重量％であった。なお、カチオン性オルガノシリケート微粒子の付着量は、処理液中に占める含有率、および処理液の圧搾率により求めた。
かくして、実施例１の繊維布帛を得た。
Formation of outer layer Next, a treatment liquid containing 5% by weight of an aqueous dispersion of cation-modified organosilicate fine particles (trade name “BAYGARD AS”, average particle size: 0.03 μm, solid content: 10% by weight, manufactured by LANXESS Inc.) After the immersion, the mixture was pressed with a press so that the pressing rate was 100% by weight with respect to the fiber weight, and then heat treated at 120 ° C. for 2 minutes and dried. Thus, an outer layer was formed outside the inner layer and the intermediate layer formed on the fiber surface. At this time, the adhesion amount of the cation-modified organosilicate fine particles was 0.5% by weight with respect to the fiber weight. In addition, the adhesion amount of cationic organosilicate fine particles was calculated | required by the content rate which occupies in a process liquid, and the pressing rate of a process liquid.
Thus, the fiber fabric of Example 1 was obtained.
［実施例２］
内層の形成
アニオン性親水性ポリエステル系樹脂の乳濁液（商品名「ＳＲ−１０００」、固形分：１０重量％、高松油脂株式会社製）を繊維重量に対し２重量％、ゼオライトに担持させた酸化銀のアニオン性水分散液（商品名「バイオデンＤＹＮＥ」、平均粒子径：５００ｎｍ、固形分：２０重量％、大和化学株式会社製）を繊維重量に対し５重量％の濃度で含み、かつ、酢酸にてｐＨを４．５に調整した処理液に、浴比が１：２０となるように試験用繊維布帛を浸漬し、１３０℃の浴中で３０分間吸尽処理を行った。水洗後、１２０℃で２分間熱処理して乾燥した。かくして、繊維表面に内層を形成した。このとき、銀元素の付着量は繊維重量に対して０．０５重量％であった。
[Example 2]
Formation of inner layer An anionic hydrophilic polyester resin emulsion (trade name “SR-1000”, solid content: 10 wt%, manufactured by Takamatsu Yushi Co., Ltd.) was supported on zeolite by 2 wt% with respect to the fiber weight. An anionic aqueous dispersion of silver oxide (trade name “Bioden DYNE”, average particle size: 500 nm, solid content: 20% by weight, manufactured by Daiwa Chemical Co., Ltd.) at a concentration of 5% by weight with respect to the fiber weight; The test fiber fabric was immersed in a treatment solution adjusted to pH 4.5 with acetic acid so that the bath ratio was 1:20, and exhausted in a bath at 130 ° C. for 30 minutes. After washing with water, it was dried by heat treatment at 120 ° C. for 2 minutes. Thus, an inner layer was formed on the fiber surface. At this time, the adhesion amount of silver element was 0.05% by weight with respect to the fiber weight.
外層の形成
次いで、実施例１と同様に処理して、繊維布帛の表面に形成された内層の外側に外層を形成した。
かくして、実施例２の繊維布帛を得た。
Formation of outer layer Next, the outer layer was formed outside the inner layer formed on the surface of the fiber fabric in the same manner as in Example 1.
Thus, the fiber fabric of Example 2 was obtained.
［比較例１］
内層の形成
実施例１と同様に処理して、繊維布帛の表面に内層を形成した。
[Comparative Example 1]
Formation of inner layer The inner layer was formed on the surface of the fiber fabric in the same manner as in Example 1.
中間層の形成
次いで、フェノール樹脂の粉体（商品名「マルカリンカーＭ」、丸善石油工業株式会社製）を５重量％、アニオン性アクリルシリコーンの乳濁液（商品名「ファイコート３０Ｇ」、固形分：３０重量％、大和化学株式会社製）を１重量％含む処理液に浸漬後、圧搾機にて圧搾率が繊維重量に対して１００重量％となるように圧搾し、次いで１２０℃で２分間熱処理して乾燥した。かくして、繊維表面に形成された内層の外側に中間層を形成した。このとき、フェノール樹脂の付着量は繊維重量に対して５重量％であった。なお、フェノール樹脂の付着量は、処理液中に占める含有率、および処理液の圧搾率により求めた。
Formation of Intermediate Layer Next, 5% by weight of a phenol resin powder (trade name “Marcalinker M”, manufactured by Maruzen Petroleum Industries, Ltd.), an anionic acrylic silicone emulsion (trade name “Phicoat 30G”, solid Min: 30% by weight, manufactured by Daiwa Chemical Co., Ltd.) 1% by weight, and then squeezed with a squeezing machine so that the pressing rate is 100% by weight with respect to the fiber weight. Heat treated for minutes and dried. Thus, an intermediate layer was formed outside the inner layer formed on the fiber surface. At this time, the adhesion amount of the phenol resin was 5% by weight with respect to the fiber weight. In addition, the adhesion amount of the phenol resin was calculated | required by the content rate which occupies in a process liquid, and the pressing rate of a process liquid.
外層の形成
次いで、実施例１と同様に処理して、繊維布帛の表面に形成された内層と中間層の外側に外層を形成した。
かくして、比較例１の繊維布帛を得た。
Formation of outer layer Subsequently, the same treatment as in Example 1 was carried out to form an outer layer on the outer side of the inner layer and the intermediate layer formed on the surface of the fiber fabric.
Thus, the fiber fabric of Comparative Example 1 was obtained.
［比較例２］
内層の形成
実施例１と同様に処理して、繊維布帛の表面に内層を形成した。
[Comparative Example 2]
Formation of inner layer The inner layer was formed on the surface of the fiber fabric in the same manner as in Example 1.
中間層の形成
次いで、実施例１と同様に処理して、繊維表面に形成された内層の外側に中間層を形成した。
Formation of Intermediate Layer Next, the same treatment as in Example 1 was performed to form an intermediate layer outside the inner layer formed on the fiber surface.
外層の形成
次いで、コロイダルシリカ微粒子のアニオン性水分散液（商品名「ニコソルト２０９」、平均粒子径：０．０１５μｍ、固形分：２１重量％、日華化学株式会社製）を５重量％含む処理液に浸漬後、圧搾機にて圧搾率が繊維重量に対して１００重量％となるように圧搾し、次いで１２０℃で２分間熱処理して乾燥した。かくして、繊維表面に形成された内層と中間層の外側に外層を形成した。このとき、シリカ微粒子の付着量は繊維重量に対して１．１重量％であった。なお、シリカ微粒子の付着量は、処理液中に占める含有率、および処理液の圧搾率により求めた。
かくして、比較例２の繊維布帛を得た。
Formation of outer layer Next, a treatment containing 5% by weight of an anionic aqueous dispersion of colloidal silica fine particles (trade name “Nico Salt 209”, average particle size: 0.015 μm, solid content: 21% by weight, manufactured by Nikka Chemical Co., Ltd.) After being immersed in the liquid, the mixture was pressed with a press so that the pressing rate was 100% by weight with respect to the fiber weight, and then heat treated at 120 ° C. for 2 minutes and dried. Thus, an outer layer was formed outside the inner layer and the intermediate layer formed on the fiber surface. At this time, the adhesion amount of silica fine particles was 1.1% by weight with respect to the fiber weight. In addition, the adhesion amount of silica fine particles was calculated | required by the content rate which occupies in a process liquid, and the pressing rate of a process liquid.
Thus, the fiber fabric of Comparative Example 2 was obtained.
［比較例３］
内層を形成しなかった以外は、実施例１と同様に処理して、比較例３の繊維布帛を得た。すなわち、比較例３においては、実施例１において中間層に相当する層が、繊維布帛の表面に直に形成されている。
[Comparative Example 3]
A fiber fabric of Comparative Example 3 was obtained in the same manner as in Example 1 except that the inner layer was not formed. That is, in Comparative Example 3, the layer corresponding to the intermediate layer in Example 1 is formed directly on the surface of the fiber fabric.
［比較例４］
外層を形成しなかった以外は、実施例１と同様に処理して、比較例４の繊維布帛を得た。すなわち、比較例４においては、実施例１において中間層に相当する層が、空気と接するように形成されている。
[Comparative Example 4]
A fiber fabric of Comparative Example 4 was obtained in the same manner as in Example 1 except that the outer layer was not formed. That is, in Comparative Example 4, the layer corresponding to the intermediate layer in Example 1 is formed in contact with air.
［比較例５］
中間層を形成しなかった以外は、実施例１と同様に処理して、比較例５の繊維布帛を得た。
[Comparative Example 5]
A fiber fabric of Comparative Example 5 was obtained in the same manner as in Example 1 except that no intermediate layer was formed.
［比較例６］
実施例１において内層に相当する層のみ繊維布帛の表面に形成して、比較例６の繊維布帛を得た。
[Comparative Example 6]
Only the layer corresponding to the inner layer in Example 1 was formed on the surface of the fiber fabric, and the fiber fabric of Comparative Example 6 was obtained.
実施例および比較例で得られた繊維布帛、ならび未処理の試験用繊維布帛について、評価した結果を表１に示した。 Table 1 shows the evaluation results of the fiber fabrics obtained in Examples and Comparative Examples and the untreated test fiber fabrics.
表１から明らかなように、実施例１および２の繊維布帛は、十分な花粉付着防止能および花粉アレルゲン不活化能を有し、洗濯耐久性にも優れていた。また、風合いが良好で、変色も認められなかった。 As is clear from Table 1, the fiber fabrics of Examples 1 and 2 had sufficient pollen adhesion preventing ability and pollen allergen inactivating ability, and were excellent in washing durability. Further, the texture was good and no discoloration was observed.
これに対し、中間層において、花粉アレルゲン不活化成分としてフェノール樹脂を付与した比較例１の繊維布帛は、初期段階では花粉アレルゲン不活化能を有するものの、洗濯耐久性に欠けていた。また、変色が認められた。
外層において、シリカ微粒子を付着させた比較例２の繊維布帛は、初期段階では十分な花粉付着防止能を有するものの、洗濯耐久性に欠けていた。また、風合いが硬くなった。
アニオン性親水性ポリエステル系樹脂かるなる被膜層を形成しなかった比較例３の繊維布帛は、初期段階で花粉付着防止能が劣っていた。
カチオン変性オルガノシリケート微粒子からなる被膜層を形成しなかった比較例４の繊維布帛は、初期段階で花粉付着防止能が著しく劣っていた。
酸化銀を含有する被膜層を形成しなかった比較例５の繊維布帛は、花粉アレルゲン不活化能を有さなかった。
アニオン性親水性ポリエステル系樹脂かるなる被膜層のみを形成した比較例６の繊維布帛は、初期段階で花粉付着防止能が著しく劣り、アレルゲン不活化能は有さなかった。
未処理の繊維布帛は、花粉付着防止能、花粉アレルゲン不活化能ともに有さなかった。
On the other hand, the fiber fabric of Comparative Example 1 to which a phenol resin was added as a pollen allergen inactivating component in the intermediate layer had pollen allergen inactivating ability at the initial stage, but lacked washing durability. Moreover, discoloration was recognized.
In the outer layer, the fiber fabric of Comparative Example 2 to which silica fine particles were adhered had sufficient pollen adhesion preventing ability at the initial stage, but lacked washing durability. Moreover, the texture became hard.
The fiber fabric of Comparative Example 3 that did not form a coating layer made of an anionic hydrophilic polyester resin had poor pollen adhesion preventing ability at the initial stage.
The fiber fabric of Comparative Example 4 in which a coating layer composed of cation-modified organosilicate fine particles was not formed was extremely inferior in the ability to prevent pollen adhesion at the initial stage.
The fiber fabric of Comparative Example 5 in which the coating layer containing silver oxide was not formed did not have pollen allergen inactivation ability.
The fiber fabric of Comparative Example 6 in which only the coating layer made of an anionic hydrophilic polyester resin was formed was extremely inferior in the ability to prevent pollen adhesion at the initial stage and did not have the allergen inactivating ability.
The untreated fiber fabric had neither pollen adhesion prevention ability nor pollen allergen inactivation ability.
Claims (4)
（１）内層が銀系化合物を含有する、および／または、
（２）内層と外層との間に、銀系化合物を含有するノニオン性および／またはアニオン性バインダー樹脂からなる被膜層が中間層として配されてなる、
ことを特徴とする花粉付着防止能と花粉アレルゲン不活化能を有する繊維布帛。 A fiber fabric having a composite layer comprising at least two layers of an inner layer and an outer layer on the fiber surface, the inner layer being a coating layer made of an anionic hydrophilic resin, and the outer layer being a coating layer made of cationic silicone compound fine particles ,And,
(1) The inner layer contains a silver compound and / or
(2) Between the inner layer and the outer layer, a coating layer made of a nonionic and / or anionic binder resin containing a silver compound is disposed as an intermediate layer.
A fiber fabric having the ability to prevent pollen adhesion and the ability to inactivate pollen allergens.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102353605A (en) * | 2011-06-30 | 2012-02-15 | 上海出入境检验检疫局工业品与原材料检测技术中心 | Airflow extracting apparatus and method for testing pollen proof function of textile utilizing the same |
| CN102719981A (en) * | 2012-03-28 | 2012-10-10 | 上海嘉乐股份有限公司 | Light and thin pollen resisting finished fabric and processing method thereof |
| JP2014188762A (en) * | 2013-03-26 | 2014-10-06 | Dainippon Printing Co Ltd | Laminate sheet and foamed laminated sheet |
| JP2015034366A (en) * | 2013-08-09 | 2015-02-19 | セーレン株式会社 | Deodorant fiber fabric |
| CN112301447A (en) * | 2020-11-03 | 2021-02-02 | 青岛大学 | Anti-pollen allergy fabric and preparation method thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004238788A (en) * | 2003-01-14 | 2004-08-26 | Ohara Palladium Kagaku Kk | Method for modifying textile product and modifying agent used for the same |
| JP2004346467A (en) * | 2003-05-26 | 2004-12-09 | Sakai Ovex Co Ltd | Pollen prevention fabric |
| JP2005089947A (en) * | 2003-08-11 | 2005-04-07 | Sekisui Chem Co Ltd | Allergen-reduced fiber product and method for producing the same |
| JP2005350779A (en) * | 2004-06-08 | 2005-12-22 | Toray Ind Inc | Fiber structure |
| JP2006057212A (en) * | 2004-08-23 | 2006-03-02 | Ohara Palladium Kagaku Kk | Fiber-finishing agent and fiber product finished by the same |
| JP2006083495A (en) * | 2004-09-17 | 2006-03-30 | Seiren Co Ltd | Antifouling fiber fabric and method for producing the same |
| JP2006183045A (en) * | 2004-11-30 | 2006-07-13 | Lion Corp | Silver compound containing house dust treatment agent |
| JP2006241432A (en) * | 2004-10-29 | 2006-09-14 | Toyobo Co Ltd | Agent for deactivating allergen |
| JP2006241431A (en) * | 2004-10-29 | 2006-09-14 | Toyobo Co Ltd | Agent for deactivating allergen and filter using the same |
| JP2006291031A (en) * | 2005-04-11 | 2006-10-26 | Rengo Co Ltd | Microprotein inactivating material |
| JP2008285777A (en) * | 2007-05-16 | 2008-11-27 | Soft99 Corporation | Functional fiber treatment agent |
-
2009
- 2009-06-30 JP JP2009155022A patent/JP5300625B2/en not_active Expired - Fee Related
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004238788A (en) * | 2003-01-14 | 2004-08-26 | Ohara Palladium Kagaku Kk | Method for modifying textile product and modifying agent used for the same |
| JP2004346467A (en) * | 2003-05-26 | 2004-12-09 | Sakai Ovex Co Ltd | Pollen prevention fabric |
| JP2005089947A (en) * | 2003-08-11 | 2005-04-07 | Sekisui Chem Co Ltd | Allergen-reduced fiber product and method for producing the same |
| JP2005350779A (en) * | 2004-06-08 | 2005-12-22 | Toray Ind Inc | Fiber structure |
| JP2006057212A (en) * | 2004-08-23 | 2006-03-02 | Ohara Palladium Kagaku Kk | Fiber-finishing agent and fiber product finished by the same |
| JP2006083495A (en) * | 2004-09-17 | 2006-03-30 | Seiren Co Ltd | Antifouling fiber fabric and method for producing the same |
| JP2006241432A (en) * | 2004-10-29 | 2006-09-14 | Toyobo Co Ltd | Agent for deactivating allergen |
| JP2006241431A (en) * | 2004-10-29 | 2006-09-14 | Toyobo Co Ltd | Agent for deactivating allergen and filter using the same |
| JP2006183045A (en) * | 2004-11-30 | 2006-07-13 | Lion Corp | Silver compound containing house dust treatment agent |
| JP2006291031A (en) * | 2005-04-11 | 2006-10-26 | Rengo Co Ltd | Microprotein inactivating material |
| JP2008285777A (en) * | 2007-05-16 | 2008-11-27 | Soft99 Corporation | Functional fiber treatment agent |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102353605A (en) * | 2011-06-30 | 2012-02-15 | 上海出入境检验检疫局工业品与原材料检测技术中心 | Airflow extracting apparatus and method for testing pollen proof function of textile utilizing the same |
| CN102719981A (en) * | 2012-03-28 | 2012-10-10 | 上海嘉乐股份有限公司 | Light and thin pollen resisting finished fabric and processing method thereof |
| JP2014188762A (en) * | 2013-03-26 | 2014-10-06 | Dainippon Printing Co Ltd | Laminate sheet and foamed laminated sheet |
| JP2015034366A (en) * | 2013-08-09 | 2015-02-19 | セーレン株式会社 | Deodorant fiber fabric |
| CN112301447A (en) * | 2020-11-03 | 2021-02-02 | 青岛大学 | Anti-pollen allergy fabric and preparation method thereof |
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|---|---|
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