JP2012144695A5 - - Google Patents
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- JP2012144695A5 JP2012144695A5 JP2011192997A JP2011192997A JP2012144695A5 JP 2012144695 A5 JP2012144695 A5 JP 2012144695A5 JP 2011192997 A JP2011192997 A JP 2011192997A JP 2011192997 A JP2011192997 A JP 2011192997A JP 2012144695 A5 JP2012144695 A5 JP 2012144695A5
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- JP
- Japan
- Prior art keywords
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- antifouling
- coating agent
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- article
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 230000003373 anti-fouling effect Effects 0.000 claims 21
- 239000011248 coating agent Substances 0.000 claims 16
- 238000004519 manufacturing process Methods 0.000 claims 5
- 239000000758 substrate Substances 0.000 claims 5
- 229910052731 fluorine Inorganic materials 0.000 claims 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 238000000576 coating method Methods 0.000 claims 3
- 239000011737 fluorine Substances 0.000 claims 3
- 238000005192 partition Methods 0.000 claims 3
- 239000010702 perfluoropolyether Substances 0.000 claims 3
- 229910000077 silane Inorganic materials 0.000 claims 3
- 239000002904 solvent Substances 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
Claims (10)
（式中、Ｗはフッ素原子又は下記式の構造で表される置換基を表し、
Ｘは、式：−（Ｏ）ｇ−（ＣＦ２）ｈ−（ＣＨ２）ｉ−（ここで、ｇ、ｈおよびｉはそれぞれ独立して、０〜５０の整数を表し、かつ、ｇとｈの和は１以上であり、括弧でくくられた各繰り返し単位の存在順序は、式中において任意である。）で示される基を表す。Ｙは水素原子又は炭素数１〜５の低級アルキル基を表し、Ｚはメトキシ基、エトキシ基、プロポキシ基、イソプロポキシ基、ブトキシ基等のアルコキシ基、クロロ基、及びイソシアネート基からなる群から選ばれる少なくとも１つの加水分解可能な官能基を表し、Ｒは炭素数が１〜１０のアルキル基を表す。ａは０〜５０の整数を表し、ｂは１〜２００の整数を表し、ｃは１〜３の整数を表し、ｄは１〜１０の整数を表し、ｅおよびｆはそれぞれ独立して、０〜５の整数を表し、ｍおよびｎはそれぞれ独立して、０〜５０の整数であり、かつ、ｍとｎの和は１以上である。）
（式中、Ｒｆ １ は炭素数が１〜１００の直鎖状のパーフルオロアルキル基を表し、ｐは１〜１００の整数、ｑは０〜２の整数を表す。Ｙ、Ｒ、ｄは一般式［１］と同じである。） An organic solvent having a surface tension of 20.0 mN / m or less and a boiling point of 95 to 200 ° C., a perfluoropolyether group-containing silane represented by the following general formula [1] , or the following general formula [2] A coating agent for forming an antifouling layer for an antifouling article to be used under steam, comprising dissolving the perfluoropolyether group-containing silane represented .
(Wherein, W represents a fluorine atom or a substituent represented by the structure of the following formula,
X represents the formula: — (O) g — (CF 2 ) h — (CH 2 ) i — (wherein g, h and i each independently represents an integer of 0 to 50; The sum of h is 1 or more, and the order of presence of each repeating unit enclosed in parentheses is arbitrary in the formula. Y represents a hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms, and Z is selected from the group consisting of an alkoxy group such as a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a chloro group, and an isocyanate group. Represents at least one hydrolyzable functional group, and R represents an alkyl group having 1 to 10 carbon atoms. a represents an integer of 0 to 50; b represents an integer of 1 to 200; c represents an integer of 1 to 3; d represents an integer of 1 to 10; and e and f are each independently 0 Represents an integer of ˜5, m and n are each independently an integer of 0 to 50, and the sum of m and n is 1 or more. )
(In the formula, Rf 1 represents a linear perfluoroalkyl group having 1 to 100 carbon atoms, p represents an integer of 1 to 100, and q represents an integer of 0 to 2. Y, R, and d are general. Same as equation [1].)
（１）前記塗布剤を保持した保持部材を基材表面に接触させて、該保持部材を基材表面上で特定の一方向に往復させて塗布剤を全面に塗布する塗布Ａ、次いで前記保持部材を再度基材表面に接触させて、該保持部材を基材表面上で前記塗布Ａでの塗布方向とは異なる一方向に往復させて塗布剤を全面になじませる塗布Ｂ、最後に基材の端部に沿って塗布する塗布Ｃを有する工程、
（２）前記塗布された塗布剤を乾燥する工程を含むことを特徴とする、蒸気下で使用される防汚性物品の製造方法。 A method for producing an antifouling article used under steam using the coating agent for forming an antifouling layer according to any one of claims 1 to 5 ,
(1) The holding member holding the coating agent is brought into contact with the substrate surface, and the holding member is reciprocated in a specific direction on the substrate surface to apply the coating agent over the entire surface, and then the holding. The member is brought into contact with the substrate surface again, and the holding member is reciprocated on the substrate surface in one direction different from the coating direction in the coating A to apply the coating agent over the entire surface. Finally, the substrate A process having a coating C applied along the edge of
(2) A method for producing an antifouling article to be used under steam, comprising a step of drying the applied coating agent.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011192997A JP2012144695A (en) | 2010-09-14 | 2011-09-05 | Antifouling article and production method therefor, and embrocation for forming antifouling layer |
| PCT/JP2011/070431 WO2012036053A1 (en) | 2010-09-14 | 2011-09-08 | Antifouling article and production method therefor, and embrocation for forming antifouling layer |
| CN2011800442073A CN103097475A (en) | 2010-09-14 | 2011-09-08 | Antifouling article and production method therefor, and embrocation for forming antifouling layer |
| KR1020137008949A KR101485719B1 (en) | 2010-09-14 | 2011-09-08 | Antifouling article and production method therefor, and embrocation for forming antifouling layer |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010206083 | 2010-09-14 | ||
| JP2010206083 | 2010-09-14 | ||
| JP2010283912 | 2010-12-21 | ||
| JP2010283912 | 2010-12-21 | ||
| JP2011192997A JP2012144695A (en) | 2010-09-14 | 2011-09-05 | Antifouling article and production method therefor, and embrocation for forming antifouling layer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012144695A JP2012144695A (en) | 2012-08-02 |
| JP2012144695A5 true JP2012144695A5 (en) | 2013-04-18 |
Family
ID=45831516
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011192997A Pending JP2012144695A (en) | 2010-09-14 | 2011-09-05 | Antifouling article and production method therefor, and embrocation for forming antifouling layer |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2012144695A (en) |
| KR (1) | KR101485719B1 (en) |
| CN (1) | CN103097475A (en) |
| WO (1) | WO2012036053A1 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012157856A (en) | 2011-01-13 | 2012-08-23 | Central Glass Co Ltd | Stainproof article and method for manufacturing this article |
| JP2013184856A (en) * | 2012-03-08 | 2013-09-19 | Asahi Glass Co Ltd | Water-repellent glass for bathroom |
| JP6044211B2 (en) * | 2012-09-13 | 2016-12-14 | ダイキン工業株式会社 | Method for producing fluorooxyalkylene group-containing silane compound |
| WO2014050798A1 (en) * | 2012-09-28 | 2014-04-03 | Hoya株式会社 | Cover glass for electronic instrument and method for manufacturing same |
| US20160168397A1 (en) * | 2013-07-17 | 2016-06-16 | Jun Liu | Substrate coating compositions and methods |
| WO2016136817A1 (en) * | 2015-02-25 | 2016-09-01 | 株式会社ニコン | Fluorine-containing composition, substrate for patterning, photo-degradable coupling agent, method for patterning, and manufacturing method for transistor |
| JP6640593B2 (en) * | 2015-02-25 | 2020-02-05 | 学校法人神奈川大学 | Fluorine-containing composition, pattern forming substrate, photodegradable coupling agent, pattern forming method, and transistor manufacturing method |
| US20190300717A1 (en) * | 2016-07-15 | 2019-10-03 | Nissan Motor Co., Ltd. | Antifouling structure precursor, antifouling structure, surface modification composition and surface modification method |
| JP6711489B2 (en) * | 2017-05-26 | 2020-06-17 | 株式会社フロロテクノロジー | Coating agent |
| CN110691822B (en) * | 2017-06-02 | 2021-06-15 | 三菱电机株式会社 | Coating film, coating composition, and article having the coating film |
| JP6529654B1 (en) | 2018-10-24 | 2019-06-12 | デクセリアルズ株式会社 | Active energy ray curable resin composition, antifogging antifouling laminate, method for producing the same, article, and antifogging method |
| TWI820451B (en) * | 2020-07-13 | 2023-11-01 | 日商日東電工股份有限公司 | Optical film with antifouling layer |
| WO2023026876A1 (en) * | 2021-08-26 | 2023-03-02 | ダイキン工業株式会社 | Surface treatment agent |
| JP7743843B2 (en) * | 2022-01-17 | 2025-09-25 | Toto株式会社 | Sanitary ware |
| JP7743842B2 (en) * | 2022-01-17 | 2025-09-25 | Toto株式会社 | Sanitary ware |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01175922A (en) * | 1987-12-28 | 1989-07-12 | Kobayashi Kose Co Ltd | Production of solid powdery cosmetic |
| JP3601062B2 (en) * | 1993-02-24 | 2004-12-15 | 旭硝子株式会社 | Solvent type surface treatment composition |
| JPH10111401A (en) * | 1996-08-14 | 1998-04-28 | Daikin Ind Ltd | Anti-reflective treatment article |
| JP2000234071A (en) * | 1999-02-16 | 2000-08-29 | Tomoegawa Paper Co Ltd | Antifouling composition |
| JP4412450B2 (en) * | 2001-10-05 | 2010-02-10 | 信越化学工業株式会社 | Anti-reflective filter |
| TWI302549B (en) * | 2001-10-05 | 2008-11-01 | Shinetsu Chemical Co | Perfluoropolyether-modified silane, surface treating agent, and antireflection filter |
| JP2003138213A (en) * | 2001-11-07 | 2003-05-14 | Sony Corp | Composition for surface modified film, surface modified film, filter for display device and display device |
| JP2005255740A (en) * | 2004-03-09 | 2005-09-22 | Sony Corp | Hard coat composition, surface protective film and optical disk |
| JP2006028256A (en) * | 2004-07-13 | 2006-02-02 | Fuji Photo Film Co Ltd | Black ink composition, inkjet ink and inkjet ink set |
| US8158264B2 (en) * | 2006-10-20 | 2012-04-17 | 3M Innovative Properties Company | Method for easy-to-clean substrates and articles therefrom |
| JP5131840B2 (en) * | 2007-07-03 | 2013-01-30 | 信越化学工業株式会社 | COATING COMPOSITION AND HIGH DRILLING FILM USING THE COMPOSITION |
| JP2010043251A (en) * | 2008-07-17 | 2010-02-25 | Shin-Etsu Chemical Co Ltd | Perfluoropolyether-modified polysilazane and surface treatment agent using the same |
-
2011
- 2011-09-05 JP JP2011192997A patent/JP2012144695A/en active Pending
- 2011-09-08 CN CN2011800442073A patent/CN103097475A/en active Pending
- 2011-09-08 KR KR1020137008949A patent/KR101485719B1/en not_active Expired - Fee Related
- 2011-09-08 WO PCT/JP2011/070431 patent/WO2012036053A1/en not_active Ceased
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