JP2012178224A - 表面炭素被覆ケイ素含有炭素系複合材料の製造方法 - Google Patents
表面炭素被覆ケイ素含有炭素系複合材料の製造方法 Download PDFInfo
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- JP2012178224A JP2012178224A JP2011032462A JP2011032462A JP2012178224A JP 2012178224 A JP2012178224 A JP 2012178224A JP 2011032462 A JP2011032462 A JP 2011032462A JP 2011032462 A JP2011032462 A JP 2011032462A JP 2012178224 A JP2012178224 A JP 2012178224A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 122
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 113
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 112
- 239000010703 silicon Substances 0.000 title claims abstract description 105
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 91
- 239000002131 composite material Substances 0.000 title claims abstract description 76
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 239000011248 coating agent Substances 0.000 title abstract description 3
- 238000000576 coating method Methods 0.000 title abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 41
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 34
- 239000007772 electrode material Substances 0.000 claims abstract description 29
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 25
- 238000004132 cross linking Methods 0.000 claims abstract description 24
- 238000003860 storage Methods 0.000 claims abstract description 21
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 17
- 230000005611 electricity Effects 0.000 claims abstract description 15
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- 239000002245 particle Substances 0.000 claims description 59
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 36
- 125000001931 aliphatic group Chemical group 0.000 claims description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 21
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- 125000000217 alkyl group Chemical group 0.000 claims description 20
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 10
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 10
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- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 7
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
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- 125000001424 substituent group Chemical group 0.000 description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
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- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 3
- CEBKHWWANWSNTI-UHFFFAOYSA-N 2-methylbut-3-yn-2-ol Chemical compound CC(C)(O)C#C CEBKHWWANWSNTI-UHFFFAOYSA-N 0.000 description 3
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- YIQKFUFJMGYQFK-UHFFFAOYSA-N (2,6-dimethylbenzoyl) 2,6-dimethylbenzenecarboperoxoate Chemical compound CC1=CC=CC(C)=C1C(=O)OOC(=O)C1=C(C)C=CC=C1C YIQKFUFJMGYQFK-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62802—Powder coating materials
- C04B35/62828—Non-oxide ceramics
- C04B35/62839—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62892—Coating the powders or the macroscopic reinforcing agents with a coating layer consisting of particles
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62897—Coatings characterised by their thickness
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
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Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011032462A JP2012178224A (ja) | 2011-01-31 | 2011-02-17 | 表面炭素被覆ケイ素含有炭素系複合材料の製造方法 |
| PCT/JP2012/052440 WO2012105669A1 (fr) | 2011-01-31 | 2012-01-27 | Procédé pour la fabrication d'un matériau composite à base de carbone contenant du silicium revêtu de carbone en surface |
| TW101103136A TW201235296A (en) | 2011-01-31 | 2012-01-31 | Method for manufacturing a carbon surface-coated silicon-containing carbon-based composite material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011018235 | 2011-01-31 | ||
| JP2011018235 | 2011-01-31 | ||
| JP2011032462A JP2012178224A (ja) | 2011-01-31 | 2011-02-17 | 表面炭素被覆ケイ素含有炭素系複合材料の製造方法 |
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| JP2012178224A true JP2012178224A (ja) | 2012-09-13 |
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| JP2011032462A Withdrawn JP2012178224A (ja) | 2011-01-31 | 2011-02-17 | 表面炭素被覆ケイ素含有炭素系複合材料の製造方法 |
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| WO (1) | WO2012105669A1 (fr) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014098070A1 (fr) * | 2012-12-19 | 2014-06-26 | Dic株式会社 | Matériau actif pour électrodes négatives de batteries rechargeables non aqueuses et batterie rechargeable non aqueuse |
| JP2015062168A (ja) * | 2013-08-19 | 2015-04-02 | Jsr株式会社 | 電極材料の製造方法、電極及び蓄電デバイス |
| JP2015162295A (ja) * | 2014-02-26 | 2015-09-07 | 東海カーボン株式会社 | シリコンオキシカーバイドセラミックス、その製造方法、シリコンオキシカーバイド複合材料および非水電解質二次電池 |
| JPWO2014091962A1 (ja) * | 2012-12-12 | 2017-01-05 | 日本電気硝子株式会社 | 蓄電デバイス用負極活物質およびその製造方法 |
| JP2018502029A (ja) * | 2014-11-06 | 2018-01-25 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | SiOC複合電極材料 |
| WO2023218765A1 (fr) * | 2022-05-11 | 2023-11-16 | Dic株式会社 | Matière active d'électrode négative ainsi que procédé de fabrication de celle-ci, et batterie secondaire |
| US12046755B2 (en) | 2018-11-19 | 2024-07-23 | Lg Energy Solution, Ltd. | Negative electrode active material including active material core particle linked to conductive material with organic linker and elastomer covering active material core particle and conductive material, and lithium secondary battery including the same |
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| US20110319252A1 (en) * | 2010-06-28 | 2011-12-29 | Schmidt Wayde R | Composite powders |
| JP2013157221A (ja) * | 2012-01-30 | 2013-08-15 | Dow Corning Toray Co Ltd | ケイ素含有炭素系複合材料 |
| KR101708363B1 (ko) * | 2013-02-15 | 2017-02-20 | 삼성에스디아이 주식회사 | 음극 활물질, 및 이를 채용한 음극과 리튬 전지 |
| US9006355B1 (en) | 2013-10-04 | 2015-04-14 | Burning Bush Group, Llc | High performance silicon-based compositions |
| JP6268049B2 (ja) * | 2014-06-23 | 2018-01-24 | 信越化学工業株式会社 | 非水電解質二次電池用負極材及び非水電解質二次電池並びに負極活物質粒子の製造方法 |
| CN110649234A (zh) * | 2019-08-21 | 2020-01-03 | 合肥国轩高科动力能源有限公司 | 一种高库伦效率硅基负极材料的制备方法 |
| US12351462B1 (en) | 2024-10-25 | 2025-07-08 | Urbix, Inc. | Graphite shaping and coating devices, systems, and methods |
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| GB1023797A (en) | 1964-02-14 | 1966-03-23 | Ici Ltd | New and improved process of preparing organosilicon polymers |
| US4404153A (en) | 1981-01-15 | 1983-09-13 | Dow Corning Corporation | Process for the preparation of poly(disilyl)silazane polymers and the polymers therefrom |
| US4340619A (en) | 1981-01-15 | 1982-07-20 | Dow Corning Corporation | Process for the preparation of poly(disilyl)silazane polymers and the polymers therefrom |
| US4312970A (en) | 1981-02-20 | 1982-01-26 | Dow Corning Corporation | Silazane polymers from {R'3 Si}2 NH and organochlorosilanes |
| US4395460A (en) | 1981-09-21 | 1983-07-26 | Dow Corning Corporation | Preparation of polysilazane polymers and the polymers therefrom |
| US4397828A (en) | 1981-11-16 | 1983-08-09 | Massachusetts Institute Of Technology | Stable liquid polymeric precursor to silicon nitride and process |
| US4540803A (en) | 1983-11-28 | 1985-09-10 | Dow Corning Corporation | Hydrosilazane polymers from [R3 Si]2 NH and HSiCl3 |
| US4543344A (en) | 1983-11-28 | 1985-09-24 | Dow Corning Corporation | Silicon nitride-containing ceramic material prepared by pyrolysis of hydrosilazane polymers from (R3 Si)2 NH and HSiCl3 |
| US4482689A (en) | 1984-03-12 | 1984-11-13 | Dow Corning Corporation | Process for the preparation of polymetallo(disily)silazane polymers and the polymers therefrom |
| US4544803A (en) | 1984-06-11 | 1985-10-01 | Ceramic Magnetics, Inc. | Positional transducer |
| US4916200A (en) | 1987-06-08 | 1990-04-10 | Dow Corning Corporation | Silane modified polysilacyclobutasilazanes |
| US4835238A (en) | 1987-06-08 | 1989-05-30 | Dow Corning Corporation | Polysilacyclobutasilazanes |
| US4774312A (en) | 1987-06-08 | 1988-09-27 | Dow Corning Corporation | Polydisilacyclobutasilazanes |
| US4929742A (en) | 1988-11-28 | 1990-05-29 | Dow Corning Corporation | Silane modified polysilacyclobutasilazanes |
| JPH04334551A (ja) | 1991-05-10 | 1992-11-20 | Tonen Corp | ヒドロシランの重合触媒 |
| US6306541B1 (en) | 1996-06-11 | 2001-10-23 | Dow Corning Corporation | Electrodes for lithium ion batteries using polysilanes |
| US5824280A (en) | 1996-06-11 | 1998-10-20 | Dow Corning Corporation | Electrodes for lithium ion batteries using polysiloxanes |
| US6174982B1 (en) | 1996-12-27 | 2001-01-16 | Osaka Gas Company Limited | Process for the preparation of polysilanes |
| CA2231665A1 (fr) | 1997-03-25 | 1998-09-25 | Dow Corning Corporation | Procede pour la production d'un materiau destine a la fabrication d'electrodes de batteries au lithium |
| JP2004273377A (ja) | 2003-03-12 | 2004-09-30 | Mitsubishi Materials Corp | 充放電可能な無機化合物及びその製造方法並びにこれを用いた非水電解液二次電池 |
| US7618678B2 (en) * | 2003-12-19 | 2009-11-17 | Conocophillips Company | Carbon-coated silicon particle powders as the anode material for lithium ion batteries and the method of making the same |
| US7785661B2 (en) * | 2003-12-19 | 2010-08-31 | Conocophillips Company | Methods of preparing composite carbon-graphite-silicon particles and using same |
-
2011
- 2011-02-17 JP JP2011032462A patent/JP2012178224A/ja not_active Withdrawn
-
2012
- 2012-01-27 WO PCT/JP2012/052440 patent/WO2012105669A1/fr not_active Ceased
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2014091962A1 (ja) * | 2012-12-12 | 2017-01-05 | 日本電気硝子株式会社 | 蓄電デバイス用負極活物質およびその製造方法 |
| WO2014098070A1 (fr) * | 2012-12-19 | 2014-06-26 | Dic株式会社 | Matériau actif pour électrodes négatives de batteries rechargeables non aqueuses et batterie rechargeable non aqueuse |
| JPWO2014098070A1 (ja) * | 2012-12-19 | 2017-01-12 | Dic株式会社 | 非水性二次電池負極用活物質、及び非水性二次電池 |
| US10950363B2 (en) | 2012-12-19 | 2021-03-16 | Dic Corporation | Active material for negative electrodes of nonaqueous secondary batteries, and nonaqueous secondary battery |
| JP2015062168A (ja) * | 2013-08-19 | 2015-04-02 | Jsr株式会社 | 電極材料の製造方法、電極及び蓄電デバイス |
| JP2015162295A (ja) * | 2014-02-26 | 2015-09-07 | 東海カーボン株式会社 | シリコンオキシカーバイドセラミックス、その製造方法、シリコンオキシカーバイド複合材料および非水電解質二次電池 |
| JP2018502029A (ja) * | 2014-11-06 | 2018-01-25 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | SiOC複合電極材料 |
| US12046755B2 (en) | 2018-11-19 | 2024-07-23 | Lg Energy Solution, Ltd. | Negative electrode active material including active material core particle linked to conductive material with organic linker and elastomer covering active material core particle and conductive material, and lithium secondary battery including the same |
| WO2023218765A1 (fr) * | 2022-05-11 | 2023-11-16 | Dic株式会社 | Matière active d'électrode négative ainsi que procédé de fabrication de celle-ci, et batterie secondaire |
| JP7435916B1 (ja) * | 2022-05-11 | 2024-02-21 | Dic株式会社 | 負極活物質の製造方法、負極活物質および二次電池 |
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| Publication number | Publication date |
|---|---|
| WO2012105669A1 (fr) | 2012-08-09 |
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