JP2017014473A5 - - Google Patents

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Publication number: JP2017014473A5
Authority: JP; Japan
Prior art keywords: lubricant; fine particles; oil; lubricating oil; sliding surface
Prior art date: 2015-07-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP2015143425A

Other languages

English (en)

Japanese (ja)

Other versions

JP6598002B2 (ja

JP2017014473A (ja

Filing date

2015-07-01

Publication date

2018-03-29

2015-07-01 Application filed filed Critical

2015-07-01 Priority to JP2015143425A priority Critical patent/JP6598002B2/ja

2015-07-01 Priority claimed from JP2015143425A external-priority patent/JP6598002B2/ja

2017-01-19 Publication of JP2017014473A publication Critical patent/JP2017014473A/ja

2018-03-29 Publication of JP2017014473A5 publication Critical patent/JP2017014473A5/ja

2019-10-30 Application granted granted Critical

2019-10-30 Publication of JP6598002B2 publication Critical patent/JP6598002B2/ja

Status Expired - Fee Related legal-status Critical Current

2035-07-01 Anticipated expiration legal-status Critical

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239000000314 lubricant Substances 0.000 claims description 120
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 110
239000010687 lubricating oil Substances 0.000 claims description 98
150000002894 organic compounds Chemical class 0.000 claims description 60
SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 48
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 41
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 33
239000002245 particle Substances 0.000 claims description 33
238000009835 boiling Methods 0.000 claims description 23
150000001733 carboxylic acid esters Chemical class 0.000 claims description 21
238000004519 manufacturing process Methods 0.000 claims description 21
239000007788 liquid Substances 0.000 claims description 20
229910052751 metal Inorganic materials 0.000 claims description 19
239000002184 metal Substances 0.000 claims description 19
239000000203 mixture Substances 0.000 claims description 16
238000002844 melting Methods 0.000 claims description 14
230000008018 melting Effects 0.000 claims description 14
239000000725 suspension Substances 0.000 claims description 14
239000012298 atmosphere Substances 0.000 claims description 10
239000002199 base oil Substances 0.000 claims description 10
239000006185 dispersion Substances 0.000 claims description 10
239000011259 mixed solution Substances 0.000 claims description 10
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
239000000463 material Substances 0.000 claims description 6
238000005979 thermal decomposition reaction Methods 0.000 claims description 6
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
238000000034 method Methods 0.000 claims description 3
238000002156 mixing Methods 0.000 claims description 3
239000002244 precipitate Substances 0.000 claims description 3
238000003756 stirring Methods 0.000 claims description 3
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
239000011361 granulated particle Substances 0.000 claims description 2
125000005609 naphthenate group Chemical group 0.000 claims 1
239000010419 fine particle Substances 0.000 description 152
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 68
238000005461 lubrication Methods 0.000 description 46
239000012530 fluid Substances 0.000 description 38
239000003921 oil Substances 0.000 description 29
229910052742 iron Inorganic materials 0.000 description 28
-1 iron ion Chemical class 0.000 description 27
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 22
239000011148 porous material Substances 0.000 description 15
150000002148 esters Chemical class 0.000 description 14
230000005291 magnetic effect Effects 0.000 description 12
230000000694 effects Effects 0.000 description 11
229910044991 metal oxide Inorganic materials 0.000 description 11
150000004706 metal oxides Chemical class 0.000 description 11
239000013078 crystal Substances 0.000 description 10
238000005096 rolling process Methods 0.000 description 10
HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 9
230000009471 action Effects 0.000 description 9
239000002994 raw material Substances 0.000 description 8
238000012360 testing method Methods 0.000 description 8
229910000831 Steel Inorganic materials 0.000 description 7
229910001566 austenite Inorganic materials 0.000 description 7
238000010894 electron beam technology Methods 0.000 description 7
239000010690 paraffinic oil Substances 0.000 description 7
239000007787 solid Substances 0.000 description 7
239000010959 steel Substances 0.000 description 7
239000000696 magnetic material Substances 0.000 description 6
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 6
230000003068 static effect Effects 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
239000011248 coating agent Substances 0.000 description 5
238000000576 coating method Methods 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
239000001301 oxygen Substances 0.000 description 5
229910052760 oxygen Inorganic materials 0.000 description 5
230000035699 permeability Effects 0.000 description 5
239000000047 product Substances 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
230000001133 acceleration Effects 0.000 description 4
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 4
239000003317 industrial substance Substances 0.000 description 4
238000012545 processing Methods 0.000 description 4
238000001179 sorption measurement Methods 0.000 description 4
229910000975 Carbon steel Inorganic materials 0.000 description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000010962 carbon steel Substances 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
230000007423 decrease Effects 0.000 description 3
229910052595 hematite Inorganic materials 0.000 description 3
239000011019 hematite Substances 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
235000013980 iron oxide Nutrition 0.000 description 3
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 3
230000005415 magnetization Effects 0.000 description 3
150000002888 oleic acid derivatives Chemical class 0.000 description 3
238000000197 pyrolysis Methods 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
231100000241 scar Toxicity 0.000 description 3
230000035939 shock Effects 0.000 description 3
230000002269 spontaneous effect Effects 0.000 description 3
230000008016 vaporization Effects 0.000 description 3
229910000859 α-Fe Inorganic materials 0.000 description 3
QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 2
LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
238000013459 approach Methods 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
230000008859 change Effects 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
230000002542 deteriorative effect Effects 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 description 2
229940093471 ethyl oleate Drugs 0.000 description 2
229910052598 goethite Inorganic materials 0.000 description 2
AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
230000001050 lubricating effect Effects 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
239000011859 microparticle Substances 0.000 description 2
229910052750 molybdenum Inorganic materials 0.000 description 2
239000011733 molybdenum Substances 0.000 description 2
125000000896 monocarboxylic acid group Chemical group 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
150000007524 organic acids Chemical class 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
230000008569 process Effects 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
150000003329 sebacic acid derivatives Chemical class 0.000 description 2
239000000126 substance Substances 0.000 description 2
230000003746 surface roughness Effects 0.000 description 2
230000007704 transition Effects 0.000 description 2
238000009834 vaporization Methods 0.000 description 2
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
229910000851 Alloy steel Inorganic materials 0.000 description 1
229910000669 Chrome steel Inorganic materials 0.000 description 1
208000032544 Cicatrix Diseases 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
125000005396 acrylic acid ester group Chemical group 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
150000001558 benzoic acid derivatives Chemical class 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
150000001656 butanoic acid esters Chemical class 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical class C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
150000001954 decanoic acid esters Chemical class 0.000 description 1
230000006837 decompression Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000000994 depressogenic effect Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
230000005489 elastic deformation Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002168 ethanoic acid esters Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
229960004887 ferric hydroxide Drugs 0.000 description 1
230000005293 ferrimagnetic effect Effects 0.000 description 1
235000003891 ferrous sulphate Nutrition 0.000 description 1
239000011790 ferrous sulphate Substances 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
150000002400 hexanoic acid esters Chemical class 0.000 description 1
230000002706 hydrostatic effect Effects 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
150000002506 iron compounds Chemical class 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
239000003446 ligand Substances 0.000 description 1
230000005389 magnetism Effects 0.000 description 1
239000012528 membrane Substances 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical class CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
IIGMITQLXAGZTL-UHFFFAOYSA-N octyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC IIGMITQLXAGZTL-UHFFFAOYSA-N 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000003973 paint Substances 0.000 description 1
150000002942 palmitic acid derivatives Chemical class 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
150000003021 phthalic acid derivatives Chemical class 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
150000003151 propanoic acid esters Chemical class 0.000 description 1
238000010298 pulverizing process Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
102200082816 rs34868397 Human genes 0.000 description 1
102220342298 rs777367316 Human genes 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
230000037387 scars Effects 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
238000003466 welding Methods 0.000 description 1

JP2015143425A 2015-07-01 2015-07-01 焼結金属からなる多孔質体に真空含浸する潤滑剤の製造方法 Expired - Fee Related JP6598002B2 (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP2015143425A JP6598002B2 (ja)	2015-07-01	2015-07-01	焼結金属からなる多孔質体に真空含浸する潤滑剤の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP2015143425A JP6598002B2 (ja)	2015-07-01	2015-07-01	焼結金属からなる多孔質体に真空含浸する潤滑剤の製造方法

Publications (3)

Publication Number	Publication Date
JP2017014473A JP2017014473A (ja)	2017-01-19
JP2017014473A5 true JP2017014473A5 (de)	2018-03-29
JP6598002B2 JP6598002B2 (ja)	2019-10-30

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JP (1)	JP6598002B2 (de)

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CN112509776B (zh) *	2020-11-24	2023-08-22	福建省长汀卓尔科技股份有限公司	一种钐钴合金粉用内添加剂、及钐钴烧结永磁体的制备方法
CN118271763B (zh) *	2024-04-29	2024-10-29	南京工业大学	一种石蜡低析出的pvc板材的生产方法

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JPS5919950A (ja) *	1982-07-24	1984-02-01	Konishiroku Photo Ind Co Ltd	マイクロカプセルトナ−の製造方法
JP2006322052A (ja) *	2005-05-19	2006-11-30	Noritake Co Ltd	金属粉末の製造方法
WO2007125603A1 (ja) *	2006-04-28	2007-11-08	Aisin Seiki Kabushiki Kaisha	メタル軸受
JP6283458B2 (ja) *	2012-09-20	2018-02-21	小林　博	軸部材の製造方法
JP2014201831A (ja) *	2013-04-08	2014-10-27	小林　博	部品ないしは基材ないしは素材の性質の改質
JP6228765B2 (ja) *	2013-06-19	2017-11-08	小林　博	ナノ粒子の製造方法
JP6283459B2 (ja) *	2013-07-04	2018-02-21	小林　博	転がり軸受装置及び転動体に磁気吸着させる方法

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