JP2714984B2 - 鉛浴から蒼鉛その他の不純物を除去する方法 - Google Patents
鉛浴から蒼鉛その他の不純物を除去する方法Info
- Publication number
- JP2714984B2 JP2714984B2 JP1124657A JP12465789A JP2714984B2 JP 2714984 B2 JP2714984 B2 JP 2714984B2 JP 1124657 A JP1124657 A JP 1124657A JP 12465789 A JP12465789 A JP 12465789A JP 2714984 B2 JP2714984 B2 JP 2714984B2
- Authority
- JP
- Japan
- Prior art keywords
- lead
- calcium
- alloy
- magnesium
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000012535 impurity Substances 0.000 title claims description 5
- 239000011575 calcium Substances 0.000 claims abstract description 121
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 108
- 239000000956 alloy Substances 0.000 claims abstract description 108
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 93
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 90
- 239000011777 magnesium Substances 0.000 claims abstract description 84
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 54
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000007787 solid Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims 1
- 238000011084 recovery Methods 0.000 abstract description 17
- 238000007670 refining Methods 0.000 abstract description 3
- 239000011133 lead Substances 0.000 description 104
- 238000002844 melting Methods 0.000 description 27
- 230000008018 melting Effects 0.000 description 27
- 229910052751 metal Inorganic materials 0.000 description 21
- 239000002184 metal Substances 0.000 description 21
- 229910000882 Ca alloy Inorganic materials 0.000 description 19
- 238000004090 dissolution Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 17
- 239000000376 reactant Substances 0.000 description 16
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 15
- 239000008187 granular material Substances 0.000 description 15
- 230000003647 oxidation Effects 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 230000005496 eutectics Effects 0.000 description 12
- 238000012545 processing Methods 0.000 description 12
- 239000000155 melt Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 229910000765 intermetallic Inorganic materials 0.000 description 7
- 230000001681 protective effect Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000013019 agitation Methods 0.000 description 6
- 238000010587 phase diagram Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 5
- 150000001342 alkaline earth metals Chemical class 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 229910000861 Mg alloy Inorganic materials 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008241 heterogeneous mixture Substances 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- 239000002142 lead-calcium alloy Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- YTKTZYQDHXMUCC-UHFFFAOYSA-N [Ca].[Pb].[Mg] Chemical compound [Ca].[Pb].[Mg] YTKTZYQDHXMUCC-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000006023 eutectic alloy Substances 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000008202 granule composition Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000012994 industrial processing Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- -1 magnesium metals Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/06—Refining
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)
- Lead Frames For Integrated Circuits (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA567,408 | 1988-05-20 | ||
| CA567408 | 1988-05-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0270038A JPH0270038A (ja) | 1990-03-08 |
| JP2714984B2 true JP2714984B2 (ja) | 1998-02-16 |
Family
ID=4138064
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1124657A Expired - Fee Related JP2714984B2 (ja) | 1988-05-20 | 1989-05-19 | 鉛浴から蒼鉛その他の不純物を除去する方法 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0343012B2 (de) |
| JP (1) | JP2714984B2 (de) |
| AT (1) | ATE127859T1 (de) |
| AU (1) | AU620822B2 (de) |
| DE (1) | DE68924194T3 (de) |
| ES (1) | ES2076961T3 (de) |
| GR (1) | GR3018160T3 (de) |
| YU (1) | YU102489A (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5041160A (en) * | 1988-05-20 | 1991-08-20 | Timminco Limited | Magnesium-calcium alloys for debismuthizing lead |
| US5234492A (en) * | 1992-04-14 | 1993-08-10 | Asarco Incorporated | Refining of bismuth |
| FR2807768B1 (fr) * | 2000-04-13 | 2002-10-31 | Pechiney Electrometallurgie | Procede de debismuthage du plomb fondu par le calcium et le magnesium |
| CN114410982B (zh) * | 2021-12-23 | 2023-08-25 | 邢台松赫环保科技有限公司 | 一种铅火法精炼深度除铋方法 |
| JP7834323B2 (ja) * | 2022-02-28 | 2026-03-24 | 国立大学法人東北大学 | 水素発生合金、実験教材、マグネシウム電池用負極材、及び発電用水素発生剤 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1428041A (en) * | 1920-09-21 | 1922-09-05 | Kroll Guillaume Justine | Process for the separation and recovery of metals from metal alloys |
| US1853540A (en) * | 1930-03-29 | 1932-04-12 | American Smelting Refining | Process of debismuthizing lead |
| US2129445A (en) * | 1937-07-08 | 1938-09-06 | American Metal Co Ltd | Treating impure lead and/or tin metal |
| CA1079979A (en) * | 1975-08-19 | 1980-06-24 | Denby H. Ward | Debismuthising lead |
| NL7903764A (nl) * | 1979-05-14 | 1980-11-18 | Shell Int Research | Werkwijze ter bereiding van calcium-houdend lood, daarmee verkregen lood en daaruit verkregen accuplaten of -roosters. |
| FR2514786A1 (fr) * | 1981-10-20 | 1983-04-22 | Extramet Sa | Procede de debismuthage du plomb |
-
1988
- 1988-10-28 AU AU24515/88A patent/AU620822B2/en not_active Ceased
-
1989
- 1989-05-18 YU YU01024/89A patent/YU102489A/xx unknown
- 1989-05-19 JP JP1124657A patent/JP2714984B2/ja not_active Expired - Fee Related
- 1989-05-19 EP EP89305122A patent/EP0343012B2/de not_active Expired - Lifetime
- 1989-05-19 ES ES89305122T patent/ES2076961T3/es not_active Expired - Lifetime
- 1989-05-19 DE DE68924194T patent/DE68924194T3/de not_active Expired - Lifetime
- 1989-05-19 AT AT89305122T patent/ATE127859T1/de not_active IP Right Cessation
-
1995
- 1995-11-22 GR GR950403278T patent/GR3018160T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0343012B1 (de) | 1995-09-13 |
| EP0343012B2 (de) | 2002-09-18 |
| EP0343012A2 (de) | 1989-11-23 |
| YU102489A (en) | 1991-10-31 |
| ATE127859T1 (de) | 1995-09-15 |
| JPH0270038A (ja) | 1990-03-08 |
| AU620822B2 (en) | 1992-02-27 |
| DE68924194D1 (de) | 1995-10-19 |
| GR3018160T3 (en) | 1996-02-29 |
| DE68924194T3 (de) | 2003-01-30 |
| EP0343012A3 (de) | 1991-01-09 |
| ES2076961T3 (es) | 1995-11-16 |
| DE68924194T2 (de) | 1996-11-28 |
| AU2451588A (en) | 1989-11-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |