JP2877880B2 - 改良型着色コンタクトレンズ及びその製造方法 - Google Patents

改良型着色コンタクトレンズ及びその製造方法

Info

Publication number: JP2877880B2
Authority: JP; Japan
Prior art keywords: contact lens; chloride; coloring; group; dye
Prior art date: 1989-03-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP2060160A

Other languages

English (en)

Japanese (ja)

Other versions

JPH03200922A (ja

Inventor

ウィリアム・エム・ハン

カイ・シー・スー

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Novartis AG

Original Assignee

Novartis AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-03-14

Filing date

1990-03-13

Publication date

1999-04-05

1990-03-13 Application filed by Novartis AG filed Critical Novartis AG

1991-09-02 Publication of JPH03200922A publication Critical patent/JPH03200922A/ja

1999-04-05 Application granted granted Critical

1999-04-05 Publication of JP2877880B2 publication Critical patent/JP2877880B2/ja

2014-04-05 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000004519 manufacturing process Methods 0.000 title claims abstract description 8
239000000463 material Substances 0.000 claims abstract description 19
239000000975 dye Substances 0.000 claims abstract description 17
239000000017 hydrogel Substances 0.000 claims abstract description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract 2
238000004040 coloring Methods 0.000 claims description 39
239000007788 liquid Substances 0.000 claims description 26
238000000034 method Methods 0.000 claims description 21
SHFJWMWCIHQNCP-UHFFFAOYSA-M hydron;tetrabutylazanium;sulfate Chemical compound OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC SHFJWMWCIHQNCP-UHFFFAOYSA-M 0.000 claims description 18
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 15
239000000985 reactive dye Substances 0.000 claims description 14
125000000217 alkyl group Chemical group 0.000 claims description 10
125000005210 alkyl ammonium group Chemical group 0.000 claims description 8
229910052801 chlorine Inorganic materials 0.000 claims description 6
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
229910052794 bromium Inorganic materials 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 claims description 4
229910052731 fluorine Inorganic materials 0.000 claims description 4
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
235000019270 ammonium chloride Nutrition 0.000 claims description 3
VJGNLOIQCWLBJR-UHFFFAOYSA-M benzyl(tributyl)azanium;chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CC1=CC=CC=C1 VJGNLOIQCWLBJR-UHFFFAOYSA-M 0.000 claims description 3
HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical group [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 claims description 3
125000005843 halogen group Chemical group 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
229920000642 polymer Polymers 0.000 claims description 3
MQAYPFVXSPHGJM-UHFFFAOYSA-M trimethyl(phenyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC=C1 MQAYPFVXSPHGJM-UHFFFAOYSA-M 0.000 claims description 3
230000003213 activating effect Effects 0.000 claims description 2
125000006575 electron-withdrawing group Chemical group 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
239000000203 mixture Substances 0.000 claims description 2
YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 claims description 2
NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 claims 2
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims 1
UACSZOWTRIJIFU-UHFFFAOYSA-N hydroxymethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCO UACSZOWTRIJIFU-UHFFFAOYSA-N 0.000 claims 1
150000003839 salts Chemical group 0.000 abstract 1
239000000243 solution Substances 0.000 description 22
239000007864 aqueous solution Substances 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
239000003054 catalyst Substances 0.000 description 10
239000003086 colorant Substances 0.000 description 9
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 8
238000000605 extraction Methods 0.000 description 8
JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 8
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 8
239000000460 chlorine Substances 0.000 description 7
239000008367 deionised water Substances 0.000 description 7
229910021641 deionized water Inorganic materials 0.000 description 7
238000002834 transmittance Methods 0.000 description 7
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 6
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 6
239000000178 monomer Substances 0.000 description 6
239000002253 acid Substances 0.000 description 5
150000007513 acids Chemical class 0.000 description 5
235000011187 glycerol Nutrition 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
229910020335 Na3 PO4.12H2 O Inorganic materials 0.000 description 4
238000002835 absorbance Methods 0.000 description 4
239000007975 buffered saline Substances 0.000 description 4
229910052736 halogen Inorganic materials 0.000 description 4
150000002367 halogens Chemical group 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
238000010561 standard procedure Methods 0.000 description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
YKCWQPZFAFZLBI-UHFFFAOYSA-N cibacron blue Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=C1S(O)(=O)=O)=CC=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC=C1S(O)(=O)=O YKCWQPZFAFZLBI-UHFFFAOYSA-N 0.000 description 3
239000000284 extract Substances 0.000 description 3
239000001530 fumaric acid Substances 0.000 description 3
-1 hydroxy, phenoxy, nitro, carboxy, acetamido, phenyl Chemical group 0.000 description 3
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
239000011976 maleic acid Substances 0.000 description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
125000002877 alkyl aryl group Chemical group 0.000 description 2
125000003710 aryl alkyl group Chemical group 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
239000001045 blue dye Substances 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
150000001721 carbon Chemical group 0.000 description 2
239000011737 fluorine Substances 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
125000002768 hydroxyalkyl group Chemical group 0.000 description 2
229940049920 malate Drugs 0.000 description 2
BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
238000001429 visible spectrum Methods 0.000 description 2
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
UGIJCMNGQCUTPI-UHFFFAOYSA-N 2-aminoethyl prop-2-enoate Chemical compound NCCOC(=O)C=C UGIJCMNGQCUTPI-UHFFFAOYSA-N 0.000 description 1
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
ABZJDNLKVWSLPM-UHFFFAOYSA-N 2-sulfanylethyl prop-2-enoate Chemical compound SCCOC(=O)C=C ABZJDNLKVWSLPM-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920013683 Celanese Polymers 0.000 description 1
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
241000255777 Lepidoptera Species 0.000 description 1
OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
125000006177 alkyl benzyl group Chemical group 0.000 description 1
FTWHFXMUJQRNBK-UHFFFAOYSA-N alpha-Methylen-gamma-aminobuttersaeure Natural products NCCC(=C)C(O)=O FTWHFXMUJQRNBK-UHFFFAOYSA-N 0.000 description 1
125000004103 aminoalkyl group Chemical group 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
239000001000 anthraquinone dye Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
239000012267 brine Substances 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000000835 fiber Substances 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
230000000968 intestinal effect Effects 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
125000005647 linker group Chemical group 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
239000001005 nitro dye Substances 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000002243 precursor Substances 0.000 description 1
CMDGQTVYVAKDNA-UHFFFAOYSA-N propane-1,2,3-triol;hydrate Chemical compound O.OCC(O)CO CMDGQTVYVAKDNA-UHFFFAOYSA-N 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
239000012088 reference solution Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/008—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using reactive dyes
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0056—Dyeing with polymeric dyes involving building the polymeric dyes on the fibres
- D06P1/006—Dyeing with polymeric dyes involving building the polymeric dyes on the fibres by using dyes with polymerisable groups, e.g. dye ---CH=CH2
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/021—Lenses; Lens systems ; Methods of designing lenses with pattern for identification or with cosmetic or therapeutic effects

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Physics & Mathematics (AREA)
Health & Medical Sciences (AREA)
Ophthalmology & Optometry (AREA)
General Health & Medical Sciences (AREA)
Structural Engineering (AREA)
General Physics & Mathematics (AREA)
Optics & Photonics (AREA)
Eyeglasses (AREA)
Coloring (AREA)
Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Treatments Of Macromolecular Shaped Articles (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Compositions Of Macromolecular Compounds (AREA)

JP2060160A 1989-03-14 1990-03-13 改良型着色コンタクトレンズ及びその製造方法 Expired - Fee Related JP2877880B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/323,355 US4954132A (en)	1989-03-14	1989-03-14	Tinted contact lens and method of tinting with reactive dye and quaternary ammonium salt
US323355		1989-03-14

Publications (2)

Publication Number	Publication Date
JPH03200922A JPH03200922A (ja)	1991-09-02
JP2877880B2 true JP2877880B2 (ja)	1999-04-05

Family

ID=23258863

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2060160A Expired - Fee Related JP2877880B2 (ja)	1989-03-14	1990-03-13	改良型着色コンタクトレンズ及びその製造方法

Country Status (11)

Country	Link
US (1)	US4954132A (da)
EP (1)	EP0388357B1 (da)
JP (1)	JP2877880B2 (da)
AT (1)	ATE96861T1 (da)
AU (1)	AU625745B2 (da)
CA (1)	CA2011946A1 (da)
DE (1)	DE69004305T2 (da)
DK (1)	DK0388357T3 (da)
ES (1)	ES2060121T3 (da)
IE (1)	IE64398B1 (da)
PT (1)	PT93418B (da)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5298033A (en) *	1989-03-14	1994-03-29	Ciba-Geigy Corporation	Ultraviolet absorbing lenses and methods of manufacturing thereof
US5021068A (en) *	1989-03-14	1991-06-04	Ciba-Geigy Corporation	Tinted contact lens and method of manufacture thereof: reactive dye and quaternary phosphonium salt
US4963160A (en) *	1989-03-14	1990-10-16	Ciba-Geigy Corporation	Reactive uv absorbing compositions and method of preparing lenses therefrom
US5151106A (en) *	1990-12-21	1992-09-29	Allergan, Inc.	Method for tinting a hydrophilic polymer by incorporating a reactive dye into the polymer prior to polymerization
JP2982988B2 (ja) *	1992-01-28	1999-11-29	日本化薬株式会社	アニオン染料組成物およびそれを用いる繊維材料の染色法
US5944853A (en) *	1992-10-26	1999-08-31	Johnson & Johnson Vision Products, Inc.	Method for preparing halotriazine dye- and vinyl sulfone dye-monomer compounds
NZ248969A (en) *	1992-10-26	1995-08-28	Johnson & Johnson Vision Prod	Tinted contact lens; method of preparation using reactive monomer-halotriazine dye adjunct
US5352245A (en) *	1992-11-20	1994-10-04	Ciba-Geigy Corporation	Process for tinting contact lens
US5846457A (en) *	1994-10-28	1998-12-08	Hoffman; William C.	Light filtering contact lens method
US5665420A (en) *	1994-12-05	1997-09-09	Ciba Vision Corporation	Impulse-jet method and apparatus for uniformly dispersing articles in a treatment solution
TW425410B (en) *	1995-02-03	2001-03-11	Novartis Ag	Preparation of the crosslinked tinted polymers and their moldings
US7278736B2 (en) *	2004-02-25	2007-10-09	Novartis Ag	Contact lenses imparting a vivacious appearance to the eye
DE602005006996D1 (de) *	2004-03-24	2008-07-03	Novartis Ag	Verfahren zur herstellung von kontaktlinsen
US8147728B2 (en)	2004-04-01	2012-04-03	Novartis Ag	Pad transfer printing of silicone hydrogel lenses using colored ink
MXPA06012125A (es)	2004-04-21	2007-01-17	Novartis Ag	Tintas de color curables para fabricar lentes de hidrogel de silicona coloreados.
CA2574143A1 (en) *	2004-07-28	2006-02-02	Novartis Ag	Water-based inks for hydrogel lenses
TW200613391A (en) *	2004-09-01	2006-05-01	Novartis Ag	Method for making colored silicone hydrogel contact lenses
US20060065138A1 (en) *	2004-09-30	2006-03-30	Tucker Robert C	Pad printing method for making colored contact lenses
US7255438B2 (en) *	2004-09-30	2007-08-14	Novartis Ag	Pad transfer printing method for making colored contact lenses
EP2268230B1 (en)	2008-04-04	2016-03-30	Battelle Memorial Institute	Adjustable intraocular lens
US10018853B2 (en)	2008-04-04	2018-07-10	Battelle Memorial Institute	Methods of altering the refractive index of materials
WO2015038614A1 (en)	2013-09-12	2015-03-19	Battelle Memorial Institute	Methods of altering the refractive index of materials
US10254562B2 (en)	2008-04-04	2019-04-09	Battelle Memorial Institute	Methods for tailoring the refractive index of lenses
SG190327A1 (en)	2010-12-14	2013-07-31	Novartis Ag	Colored contact lens
TWI844878B (zh) *	2022-06-29	2024-06-11	晶碩光學股份有限公司	用於隱形眼鏡的固色組合物、其隱形眼鏡及其製備方法
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1989
- 1989-03-14 US US07/323,355 patent/US4954132A/en not_active Expired - Lifetime
1990
- 1990-03-07 DE DE90810175T patent/DE69004305T2/de not_active Expired - Fee Related
- 1990-03-07 DK DK90810175.1T patent/DK0388357T3/da active
- 1990-03-07 EP EP90810175A patent/EP0388357B1/en not_active Expired - Lifetime
- 1990-03-07 ES ES90810175T patent/ES2060121T3/es not_active Expired - Lifetime
- 1990-03-07 AT AT90810175T patent/ATE96861T1/de not_active IP Right Cessation
- 1990-03-12 AU AU51255/90A patent/AU625745B2/en not_active Ceased
- 1990-03-12 CA CA002011946A patent/CA2011946A1/en not_active Abandoned
- 1990-03-13 JP JP2060160A patent/JP2877880B2/ja not_active Expired - Fee Related
- 1990-03-13 PT PT93418A patent/PT93418B/pt not_active IP Right Cessation
- 1990-03-13 IE IE89490A patent/IE64398B1/en not_active IP Right Cessation

Also Published As

Publication number	Publication date
JPH03200922A (ja)	1991-09-02
US4954132A (en)	1990-09-04
ES2060121T3 (es)	1994-11-16
DE69004305T2 (de)	1994-03-24
ATE96861T1 (de)	1993-11-15
PT93418B (pt)	1996-02-29
AU5125590A (en)	1990-09-20
DK0388357T3 (da)	1993-12-06
IE900894L (en)	1990-09-14
EP0388357B1 (en)	1993-11-03
AU625745B2 (en)	1992-07-16
DE69004305D1 (de)	1993-12-09
CA2011946A1 (en)	1990-09-14
IE64398B1 (en)	1995-08-09
PT93418A (pt)	1990-11-07
EP0388357A1 (en)	1990-09-19

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Publication	Publication Date	Title
JP2877880B2 (ja)	1999-04-05	改良型着色コンタクトレンズ及びその製造方法
US4553975A (en)	1985-11-19	Tinted contact lenses and a method for their preparation
US4559059A (en)	1985-12-17	Tinted contact lenses and a method for their preparation
US4468229A (en)	1984-08-28	Tinted contact lenses and a method for their preparation with reactive dyes
EP0072353B1 (de)	1987-04-15	Getönte Kontaktlinsen und Verfahren zu deren Herstellung
US4891046A (en)	1990-01-02	Tinted contact lens and method for preparation with dichlorotriazine reactive dye
JP3483601B2 (ja)	2004-01-06	色付きコンタクトレンズの製造方法
JP3267969B2 (ja)	2002-03-25	親水性の重合体を色味付けする方法
JP3625097B2 (ja)	2005-03-02	着色コンタクトレンズおよびその製造法
JPH03107121A (ja)	1991-05-07	含水性コンタクトレンズの染色方法
JPH0733808A (ja)	1995-02-03	着色されたコンタクトレンズの製法
JP3040207B2 (ja)	2000-05-15	改良型着色コンタクトレンズ及びその製造方法
JP3980667B2 (ja)	2007-09-26	高分子染料およびその製法、ならびに該高分子染料を用いてなる着色コンタクトレンズおよびその製法
JPH03102314A (ja)	1991-04-26	ソフトコンタクトレンズの染色方法
HUT70585A (en)	1995-10-30	Method for preparing dye useful for tinting contact lenses
JPS5982477A (ja)	1984-05-12	染色方法