JP3149749B2 - Manufacturing method of embossed sheet - Google Patents
Manufacturing method of embossed sheetInfo
- Publication number
- JP3149749B2 JP3149749B2 JP29087795A JP29087795A JP3149749B2 JP 3149749 B2 JP3149749 B2 JP 3149749B2 JP 29087795 A JP29087795 A JP 29087795A JP 29087795 A JP29087795 A JP 29087795A JP 3149749 B2 JP3149749 B2 JP 3149749B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- sheet
- embossed
- ionizing radiation
- curable resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
- B29C59/046—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts for layered or coated substantially flat surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
- B29C43/222—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length characterised by the shape of the surface
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、エンボスシートの
製造方法に関し、特に表面に強固な樹脂層を持ち耐久性
を必要とする耐久消費財の表面材用途に好適に用いられ
るエンボスシートの製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing an embossed sheet, and more particularly, to a method for producing an embossed sheet which is preferably used for a surface material of a durable consumer product having a strong resin layer on its surface and requiring durability. About.
【０００２】[0002]
【従来の技術】従来、電子線や紫外線などいわゆる電離
放射線によって硬化する樹脂を用いたエンボスシートの
製造方法は、種々提案されている。例えば、基材シート
に必要に応じて絵柄インキ層を設け、透明保護層として
常温では液状である電子線又は紫外線硬化型樹脂を用
い、塗工後電子線又は紫外線を照射して硬化させるもの
が代表的なものである。2. Description of the Related Art Hitherto, various methods for producing an embossed sheet using a resin which is cured by so-called ionizing radiation such as an electron beam or ultraviolet rays have been proposed. For example, a pattern ink layer is provided on a base sheet as needed, and an electron beam or an ultraviolet curable resin which is liquid at room temperature is used as a transparent protective layer, and after application, an electron beam or an ultraviolet ray is used to cure the resin. It is typical.
【０００３】この透明保護層としての厚さは通常２０μ
ｍ以下であるが、この場合、例えば１００μｍ以上の凹
部を持つエンボスを透明保護層で形成することは当然な
がら不可能であった。The thickness of this transparent protective layer is usually 20 μm.
m, but in this case, it is naturally impossible to form an emboss having a concave portion of 100 μm or more with the transparent protective layer.
【０００４】また、透明保護層を２０μｍ以上塗工した
場合、基材のカールや透明保護層の柔軟性の問題から、
巻き取ることが困難であった。When the transparent protective layer is coated to a thickness of 20 μm or more, the curl of the substrate and the flexibility of the transparent protective layer may cause problems.
It was difficult to wind up.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、以上のよう
な問題を解決するためになされたもので、その課題とす
るところは、透明保護層として強固な硬度を保ち、場合
によっては深いエンボスを形成することができ、かつ、
良好な意匠性が得られるエンボスシートを安定的に製造
する方法を提供することにある。DISCLOSURE OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and an object of the present invention is to maintain a strong hardness as a transparent protective layer, and in some cases, to provide a deep emboss. Can be formed, and
An object of the present invention is to provide a method for stably producing an embossed sheet that can obtain good design properties.
【０００６】[0006]
【課題を解決するための手段】本発明に於いて上記目的
を達成するために、まず請求項１においては、任意の基
材シートと表面に所望の凹凸形状を形成したエンボス冷
却ロールとの間に、常温で固体の電離放射線硬化型樹脂
を押出機により加熱溶融させて押出し、該エンボス冷却
ロールによりエンボス付与を行いつつ冷却・積層した
後、エンボス冷却ロールから剥離してなる積層シート
に、電離放射線を照射してこの樹脂を完全硬化させたも
のである。In order to achieve the above-mentioned object in the present invention, first, according to the first aspect, an arbitrary base sheet and an embossed cooling roll having a desired uneven shape formed on the surface are provided. Then, an ionizing radiation-curable resin solid at room temperature is heated and melted by an extruder, extruded, cooled and laminated while embossing is performed by the embossed cooling roll, and then ionized into a laminated sheet peeled from the embossed cooling roll. The resin is completely cured by irradiation with radiation.
【０００７】また、請求項２においては、常温で固体の
電離放射線硬化型樹脂に熱可塑性樹脂を添加し、加熱溶
融させながら押出機で押出すものである。According to a second aspect of the present invention, a thermoplastic resin is added to an ionizing radiation-curable resin which is solid at room temperature, and extruded by an extruder while being heated and melted.
【０００８】また、請求項３においては、基材シートが
少なくとも片面に絵柄が施された化粧シートであり、溶
融押出しする樹脂が、電離放射線硬化型樹脂又は電離放
射線硬化型樹脂と熱可塑性樹脂の混合樹脂からなり、い
ずれも透明樹脂とするものである。According to a third aspect of the present invention, the base sheet is a decorative sheet having a pattern on at least one surface, and the resin to be melt-extruded is an ionizing radiation-curable resin or a mixture of an ionizing radiation-curable resin and a thermoplastic resin. It is made of a mixed resin, and all are made of a transparent resin.
【０００９】以下、本発明を詳細に説明する。図１に本
発明によるエンボスシートの一例を示す。原紙（基材）
１の表面に印刷インキ層２を施し、エンボスシート部３
をラミネートしたものである。Hereinafter, the present invention will be described in detail. FIG. 1 shows an example of an embossed sheet according to the present invention. Base paper (base material)
1, a printing ink layer 2 is applied to the surface of
Are laminated.
【００１０】本発明における基材シートとしては、紙、
各種樹脂フィルムが使用できる。また、印刷インキ層を
設ける方法としては、グラビア印刷法、グラビアオフセ
ット法等のいずれかでよい。In the present invention, the base sheet may be paper,
Various resin films can be used. Further, as a method of providing the printing ink layer, any of a gravure printing method, a gravure offset method, and the like may be used.
【００１１】電離放射線硬化型樹脂としては、常温で固
体であるような分子量の大きい高粘度のウレタンアクリ
レート、ポリエステルアクリレート、エポキシアクリレ
ート等が用いられる。必要に応じて、エポキシ樹脂、ア
クリル樹脂等の熱可塑性樹脂を添加混合することが可能
である。As the ionizing radiation-curable resin, a high-viscosity urethane acrylate, polyester acrylate, epoxy acrylate or the like having a large molecular weight and being solid at normal temperature is used. If necessary, a thermoplastic resin such as an epoxy resin or an acrylic resin can be added and mixed.
【００１２】[0012]
【発明の実施の形態】以下に本発明の実施の形態につ説
明する。図２は、本発明によるエンボスシートの製造方
法の一例である。Ｔダイ４から、常温で固体の電離放射
線硬化型樹脂又は電離放射線硬化型樹脂と熱可塑性樹脂
の混合樹脂を押出し、凹凸形状が形成された冷却ロール
５で、溶融樹脂６を加圧ロール７で圧縮しながら冷却硬
化する方法が用いられている。その後、剥離ロール８に
よって冷却ロール５から剥離した表面の樹脂層に、電子
線又は紫外線の照射装置９で電離放射線を照射すること
で、電離放射線硬化型樹脂が完全に硬化され、耐摩耗
性、硬度に優れたエンボスシートを能率的に製造するこ
とができる。なお、電離放射線としては、電子線または
紫外線が用いられる。電子線は樹脂層の色調、厚さなど
の点で自由度が高い。Embodiments of the present invention will be described below. FIG. 2 is an example of a method for producing an embossed sheet according to the present invention. From the T-die 4, an ionizing radiation-curable resin or a mixed resin of an ionizing radiation-curable resin and a thermoplastic resin which is solid at room temperature is extruded. A method of cooling and hardening while compressing is used. Thereafter, the resin layer on the surface peeled off from the cooling roll 5 by the peeling roll 8 is irradiated with ionizing radiation by an electron beam or ultraviolet irradiation device 9, whereby the ionizing radiation-curable resin is completely cured and has abrasion resistance, An embossed sheet having excellent hardness can be efficiently manufactured. Note that an electron beam or an ultraviolet ray is used as the ionizing radiation. The electron beam has a high degree of freedom in terms of the color tone and thickness of the resin layer.
【００１３】[0013]
【実施例】以下実施例により本発明を詳細に説明する。The present invention will be described in detail with reference to the following examples.
【００１４】＜実施例１＞坪量５０ｇ／ｍ2 の建材用紙
に水性インキにより木目模様をグラビア印刷した後、常
温で固体の透明な電子線硬化型樹脂としてエポキシアク
リレート樹脂（VR-60 ，昭和高分子（株）製）をＴダイ
から押出し、導管に相当する凹凸形状が形成されたエン
ボス冷却ロールで、エンボスシート厚４０μｍ以下とな
るようシート成形し、エンボス冷却ロールからシートを
剥離後、電子線照射装置で２００ｋｖ、５Ｍｒａｄの電
子線を照射した後、シートを巻き取った。一連の加工に
おいては紙切れ、樹脂の取られもなく極めて安定的に行
うことができた。<Example 1> Gravure-printing a wood grain pattern on a building material paper having a basis weight of 50 g / m 2 with an aqueous ink, and then using an epoxy acrylate resin (VR-60, Showa) as a solid transparent electron beam-curable resin at room temperature Polymer Co., Ltd.) is extruded from a T-die, formed into a sheet with an embossed cooling roll having an irregular shape corresponding to a conduit so as to have an embossed sheet thickness of 40 μm or less. After irradiation with an electron beam of 200 kv and 5 Mrad by a beam irradiation device, the sheet was wound up. In a series of processing, it was possible to carry out extremely stably without paper breakage or resin removal.
【００１５】成形エンボスシートを尿素・酢酸ビニル系
の接着剤にてパーティクルボードと貼り合わせたとこ
ろ、非常に優れた表面強度および耐久性を有する化粧板
が得られた。When the molded embossed sheet was bonded to the particle board with a urea / vinyl acetate adhesive, a decorative board having extremely excellent surface strength and durability was obtained.
【００１６】熱可塑性エポキシ樹脂（エピクロン3010,
大日本インキ化学工業（株) 製）を、実施例１で使用し
たエポキシアクリレート樹脂１００部に対し、２０部ブ
レンドしたものをＴダイから押出し、冷却ロールでエン
ボスシート厚１００μｍ、エンボス深さ８０μｍ以下と
なるようシート成形し、エンボス冷却ロールからシート
を剥離後、電子線照射装置で２５０ｋｖ、５Ｍｒａｄの
電子線を照射した後、シートを巻き取った。A thermoplastic epoxy resin (Epiclon 3010,
100 parts of the epoxy acrylate resin used in Example 1 was extruded from a T-die and blended with 20 parts of the epoxy acrylate resin used in Example 1, and the embossed sheet thickness was 100 μm and the emboss depth was 80 μm or less with a cooling roll. After the sheet was formed from the embossed cooling roll, the sheet was irradiated with an electron beam of 250 kv and 5 Mrad by an electron beam irradiation device, and then wound up.
【００１７】成形エンボスシートは熱可塑性樹脂のため
に、透明保護層を厚くすることが可能となり、より深い
エンボス表現ができるシートであった。Since the molded embossed sheet is a thermoplastic resin, the thickness of the transparent protective layer can be increased, so that a deeper embossed expression can be obtained.
【００１８】成形エンボスシートを尿素・酢酸ビニル系
の接着剤にてパーティクルボードと貼り合わせたとこ
ろ、実施例１で得られた化粧板に劣らない、優れた表面
強度および耐久性を有する化粧板が得られた。When the molded embossed sheet was bonded to the particle board with a urea / vinyl acetate adhesive, a decorative board having excellent surface strength and durability not inferior to the decorative board obtained in Example 1 was obtained. Obtained.
【００１９】[0019]
【発明の効果】本発明は以上の構成であるから、下記に
示す如き効果がある。すなわち、本発明は常温で固体の
電離放射線硬化型樹脂を押出成形法によって基材シート
上に押し出して、同時にエンボスを付与するから、エン
ボスの成形が安定して行われる。次いで電離放射線照射
を行うことにより樹脂層が完全に硬化するから、表面強
度、耐久性に優れたエンボスシートが得られた。As described above, the present invention has the following effects. That is, in the present invention, since the ionizing radiation-curable resin which is solid at normal temperature is extruded onto the base sheet by the extrusion molding method, and at the same time, the embossing is applied, the embossing is performed stably. Then, the resin layer was completely cured by performing ionizing radiation irradiation, so that an embossed sheet having excellent surface strength and durability was obtained.
【００２０】また、電離放射線硬化型樹脂を適切に選ぶ
ことで、耐久性、硬度に優れたエンボスシートを製造す
ることが可能となった。Further, by appropriately selecting an ionizing radiation-curable resin, it has become possible to produce an embossed sheet having excellent durability and hardness.
【００２１】さらに熱可塑性樹脂を電離放射線硬化型樹
脂にブレンドして押出成形することで、より深いエンボ
ス形状をもったエンボスシートを製造することが可能と
なった。Furthermore, by blending a thermoplastic resin with an ionizing radiation-curable resin and extruding it, it has become possible to produce an embossed sheet having a deeper embossed shape.
【００２２】したがって、本発明は耐久性を必要とする
耐久消費財の表面材用途において、意匠性および表面硬
度、耐久性に優れたエンボスシートを安価に能率良く提
供できる効果を奏する。Therefore, the present invention has the effect of efficiently and inexpensively providing an embossed sheet having excellent designability, surface hardness and durability in the surface material application of durable consumer goods requiring durability.
【図１】本発明の製造方法により得られるエンボスシー
トの一例を示す断面図である。FIG. 1 is a cross-sectional view illustrating an example of an embossed sheet obtained by a manufacturing method of the present invention.
【図２】本発明のエンボスシートの製造方法の一例を示
す説明図である。FIG. 2 is an explanatory view showing an example of a method for producing an embossed sheet of the present invention.
１…基材シート ２…印刷インキ層 ３…透明保護層 ４…Ｔダイ ５…エンボス冷却ロール ６…溶融樹脂 ７…加圧ロール ８…剥離ロール ９…電離放射線照射装置 DESCRIPTION OF SYMBOLS 1 ... Base sheet 2 ... Printing ink layer 3 ... Transparent protective layer 4 ... T die 5 ... Emboss cooling roll 6 ... Molten resin 7 ... Pressure roll 8 ... Peeling roll 9 ... Ionizing radiation irradiation device
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｂ２９Ｋ 101:12 105:24 105:32 Ｂ２９Ｌ 9:00 (56)参考文献 特開 平２−310023（ＪＰ，Ａ) 特開 平５−24158（ＪＰ，Ａ) 特開 平５−115833（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) B32B 1/00 - 35/00 B29C 35/08 B29C 47/02 B29C 59/04 ────────────────────────────────────────────────── ─── Continued on the front page (51) Int.Cl. 7 Identification symbol FI B29K 101: 12 105: 24 105: 32 B29L 9:00 (56) References JP-A-2-310023 (JP, A) JP JP-A-5-24158 (JP, A) JP-A-5-115833 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) B32B 1/00-35/00 B29C 35/08 B29C 47 / 02 B29C 59/04
Claims (3)
を形成したエンボス冷却ロールとの間に、常温で固体の
電離放射線硬化型樹脂を押出機により加熱溶融させて押
出し、該エンボス冷却ロールによりエンボス付与を行い
つつ冷却・積層した後、エンボス冷却ロールから剥離し
てなる積層シートに、電離放射線を照射して前記樹脂を
硬化させることを特徴とするエンボスシートの製造方
法。An extruder heats and melts a solid ionizing radiation-curable resin at room temperature between an arbitrary substrate sheet and an embossed cooling roll having a desired unevenness formed on the surface thereof. A method for manufacturing an embossed sheet, comprising cooling and laminating while embossing with a roll, and then irradiating the laminated sheet formed by peeling from the embossed cooling roll with ionizing radiation to cure the resin.
熱可塑性樹脂を添加し、加熱溶融させながら押出機で押
出すことを特徴とする請求項１に記載のエンボスシート
の製造方法。2. The method for producing an embossed sheet according to claim 1, wherein a thermoplastic resin is added to the ionizing radiation-curable resin solid at room temperature, and extruded by an extruder while heating and melting.
が施された化粧シートであり、溶融押出しする樹脂が、
電離放射線硬化型樹脂又は電離放射線硬化型樹脂と熱可
塑性樹脂の混合樹脂で、いずれも透明樹脂からなること
を特徴とする請求項１及び請求項２に記載のエンボスシ
ートの製造方法。3. The base sheet is a decorative sheet having a pattern on at least one surface, and the resin to be melt-extruded is:
3. The method for producing an embossed sheet according to claim 1, wherein the resin is an ionizing radiation-curable resin or a mixed resin of an ionizing radiation-curable resin and a thermoplastic resin, each of which is made of a transparent resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29087795A JP3149749B2 (en) | 1995-11-09 | 1995-11-09 | Manufacturing method of embossed sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29087795A JP3149749B2 (en) | 1995-11-09 | 1995-11-09 | Manufacturing method of embossed sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09131846A JPH09131846A (en) | 1997-05-20 |
| JP3149749B2 true JP3149749B2 (en) | 2001-03-26 |
Family
ID=17761669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29087795A Expired - Fee Related JP3149749B2 (en) | 1995-11-09 | 1995-11-09 | Manufacturing method of embossed sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3149749B2 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100275620B1 (en) * | 1998-05-27 | 2000-12-15 | 김만석 | Emboss coating method using embossing master roll |
| ITTO20010150A1 (en) * | 2001-02-20 | 2002-08-20 | Propack S P A | ANTI-SHOCK AND / OR SCRATCH FLEXIBLE SHEET. |
| MXPA03007545A (en) | 2001-02-21 | 2004-10-15 | Tilia Int Inc | Method for preparing air channel-equipped film for use in vacuum package. |
| WO2002066227A1 (en) * | 2001-02-21 | 2002-08-29 | Gul-Joo Lee | Method of manufacturing film for vacuum packaging bag, and vacuum packaging bag manufactured using the film |
| US7138025B2 (en) | 2003-03-05 | 2006-11-21 | Tilia International, Inc. | Method for manufacturing a sealable bag having an integrated tray for use in vacuum packaging |
| US20050034806A1 (en) | 2003-03-05 | 2005-02-17 | Tilia International, Inc. | Method for manufacturing liquid-trapping bag for use in vacuum packaging |
| US7087130B2 (en) | 2003-03-05 | 2006-08-08 | Tilia International, Inc. | Method for manufacturing a sealable bag having an integrated zipper for use in vacuum packaging |
| US7517484B2 (en) | 2003-03-24 | 2009-04-14 | Sunbeam Products, Inc. | Forming evacuation channels during single and multi-layer extrusion process |
| US7220053B2 (en) | 2003-12-16 | 2007-05-22 | Sunbeam Products, Inc. | Flexible composite bag for vacuum sealing |
| US7534039B2 (en) | 2004-07-22 | 2009-05-19 | Sunbeam Products, Inc. | Vacuum packaging films patterned with protruding cavernous structures |
| US7398953B2 (en) | 2004-12-22 | 2008-07-15 | Cti Industries, Inc. | One way valve for fluid evacuation from a container |
| US7972064B2 (en) * | 2004-12-22 | 2011-07-05 | Cti Industries Corporation | One way valve and container |
| KR101424403B1 (en) * | 2013-08-21 | 2014-07-28 | 김인수 | Equipments for manufacturing interlayer noise preventing floor material |
| JP6791615B2 (en) | 2015-03-06 | 2020-11-25 | スリーエム イノベイティブ プロパティズ カンパニー | UV crosslinkable composition |
| JP2022132010A (en) * | 2021-02-26 | 2022-09-07 | 東洋インキＳｃホールディングス株式会社 | Electron beam curable composition and electron beam curable overcoat varnish |
-
1995
- 1995-11-09 JP JP29087795A patent/JP3149749B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09131846A (en) | 1997-05-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3149749B2 (en) | Manufacturing method of embossed sheet | |
| JP3117032B2 (en) | Molded body with uneven surface | |
| JP5223221B2 (en) | Transfer decorative sheet, method for producing decorative molded product, and decorative molded product | |
| JP4121488B2 (en) | Cosmetic material and method for producing the same | |
| JP3117031B2 (en) | Molded article having gloss-matte pattern | |
| JP3153349B2 (en) | Decorative sheet and method for producing the decorative sheet | |
| JP2015193246A (en) | Surface processed film and manufacturing method thereof | |
| JPH0732548A (en) | Inner embossed plastic molding | |
| JP2003103743A (en) | Method of manufacturing decorative sheet and uneven decorative sheet, method of manufacturing uneven decorative molded article | |
| JP2814074B2 (en) | Transfer sheet | |
| JPH0825789A (en) | Transfer sheet | |
| JP3341222B2 (en) | Mirror glossy makeup sheet | |
| JPH0414500A (en) | makeup sheet | |
| JPH068254A (en) | Shaping film and production thereof | |
| JP2874774B2 (en) | Manufacturing method of decorative sheet | |
| JP3089957B2 (en) | Decorative sheet and method for producing the same | |
| JP2868565B2 (en) | Manufacturing method of cosmetic materials | |
| JP3173168B2 (en) | Method and apparatus for manufacturing decorative paper | |
| JPH03174279A (en) | Production of decorative sheet | |
| JP2001062979A (en) | Decorative sheet and method for producing the same | |
| JPH1199597A (en) | Polyolefin resin decorative sheet and method for producing the same | |
| JPH04294141A (en) | Manufacture of decorative sheet having thick coating appearance | |
| JP3546485B2 (en) | Manufacturing method of decorative sheet | |
| JP3328862B2 (en) | Curable resin decorative sheet molding sheet | |
| JPH1034780A (en) | A decorative sheet with an uneven pattern inside |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080119 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090119 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100119 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100119 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110119 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120119 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130119 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130119 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140119 Year of fee payment: 13 |
|
| LAPS | Cancellation because of no payment of annual fees |