JP3745091B2 - 熱現像写真材料 - Google Patents

熱現像写真材料 Download PDF

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Publication number: JP3745091B2
Authority: JP; Japan
Prior art keywords: group; silver; general formula; compounds; carbon atoms
Prior art date: 1997-07-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP20241097A

Other languages

English (en)

Japanese (ja)

Other versions

JPH1130832A (ja

JPH1130832A5 (2

Inventor

克之渡辺

茂夫平野

稔酒井

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Fujifilm Holdings Corp

Original Assignee

Fuji Photo Film Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-07-11

Filing date

1997-07-11

Publication date

2006-02-15

1997-07-11 Application filed by Fuji Photo Film Co Ltd filed Critical Fuji Photo Film Co Ltd

1997-07-11 Priority to JP20241097A priority Critical patent/JP3745091B2/ja

1998-03-20 Priority to AT98105131T priority patent/ATE219842T1/de

1998-03-20 Priority to DE69806199T priority patent/DE69806199T2/de

1998-03-20 Priority to EP98105131A priority patent/EP0869391B1/en

1998-04-02 Priority to CNB981013112A priority patent/CN1163795C/zh

1998-04-02 Priority to US09/053,652 priority patent/US6025122A/en

1999-02-02 Publication of JPH1130832A publication Critical patent/JPH1130832A/ja

2004-10-07 Publication of JPH1130832A5 publication Critical patent/JPH1130832A5/ja

2006-02-15 Application granted granted Critical

2006-02-15 Publication of JP3745091B2 publication Critical patent/JP3745091B2/ja

2017-07-11 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000463 material Substances 0.000 title claims description 57
-1 silver halide Chemical class 0.000 claims description 228
150000001875 compounds Chemical class 0.000 claims description 100
239000004332 silver Substances 0.000 claims description 93
229910052709 silver Inorganic materials 0.000 claims description 93
125000003118 aryl group Chemical group 0.000 claims description 52
125000000623 heterocyclic group Chemical group 0.000 claims description 50
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 41
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 31
125000001931 aliphatic group Chemical group 0.000 claims description 15
239000011230 binding agent Substances 0.000 claims description 14
239000003638 chemical reducing agent Substances 0.000 claims description 12
239000002872 contrast media Substances 0.000 claims description 12
239000011941 photocatalyst Substances 0.000 claims description 5
150000001768 cations Chemical class 0.000 claims description 4
239000010410 layer Substances 0.000 description 79
125000004432 carbon atom Chemical group C* 0.000 description 67
238000000034 method Methods 0.000 description 67
239000000839 emulsion Substances 0.000 description 59
125000000217 alkyl group Chemical group 0.000 description 49
239000000975 dye Substances 0.000 description 46
229920000642 polymer Polymers 0.000 description 43
125000001424 substituent group Chemical group 0.000 description 38
239000000126 substance Substances 0.000 description 34
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
229920001577 copolymer Polymers 0.000 description 31
238000011161 development Methods 0.000 description 31
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 30
239000000243 solution Substances 0.000 description 30
125000003545 alkoxy group Chemical group 0.000 description 29
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 27
239000011248 coating agent Substances 0.000 description 25
238000000576 coating method Methods 0.000 description 25
239000002245 particle Substances 0.000 description 25
229920000126 latex Polymers 0.000 description 24
239000004816 latex Substances 0.000 description 24
125000003277 amino group Chemical group 0.000 description 22
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 20
150000002429 hydrazines Chemical class 0.000 description 20
125000004104 aryloxy group Chemical group 0.000 description 19
239000006185 dispersion Substances 0.000 description 19
150000003839 salts Chemical class 0.000 description 19
150000003378 silver Chemical class 0.000 description 19
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 18
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 17
230000001235 sensitizing effect Effects 0.000 description 17
206010070834 Sensitisation Diseases 0.000 description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 16
238000002360 preparation method Methods 0.000 description 16
230000008313 sensitization Effects 0.000 description 16
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
125000002252 acyl group Chemical group 0.000 description 15
125000004442 acylamino group Chemical group 0.000 description 15
125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 15
125000004435 hydrogen atom Chemical group [H]* 0.000 description 15
239000002253 acid Substances 0.000 description 14
125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 14
239000006224 matting agent Substances 0.000 description 14
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
108010010803 Gelatin Proteins 0.000 description 12
125000004453 alkoxycarbonyl group Chemical group 0.000 description 12
239000007864 aqueous solution Substances 0.000 description 12
229920000159 gelatin Polymers 0.000 description 12
239000008273 gelatin Substances 0.000 description 12
235000019322 gelatine Nutrition 0.000 description 12
235000011852 gelatine desserts Nutrition 0.000 description 12
239000000203 mixture Substances 0.000 description 12
239000011241 protective layer Substances 0.000 description 12
230000035945 sensitivity Effects 0.000 description 12
125000005843 halogen group Chemical group 0.000 description 11
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
229910052757 nitrogen Inorganic materials 0.000 description 11
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 10
125000003342 alkenyl group Chemical group 0.000 description 10
125000000304 alkynyl group Chemical group 0.000 description 10
125000004093 cyano group Chemical group *C#N 0.000 description 10
235000019441 ethanol Nutrition 0.000 description 10
229910052751 metal Chemical class 0.000 description 10
239000002184 metal Chemical class 0.000 description 10
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 10
238000003756 stirring Methods 0.000 description 10
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 9
125000004423 acyloxy group Chemical group 0.000 description 9
125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 9
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 9
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 9
125000006296 sulfonyl amino group Chemical group [H]N(*)S(*)(=O)=O 0.000 description 9
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 9
239000004094 surface-active agent Substances 0.000 description 9
ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 9
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
229910052799 carbon Inorganic materials 0.000 description 8
125000002950 monocyclic group Chemical group 0.000 description 8
150000007524 organic acids Chemical class 0.000 description 8
239000003960 organic solvent Substances 0.000 description 8
PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoric acid amide group Chemical group P(N)(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 8
238000007639 printing Methods 0.000 description 8
230000005070 ripening Effects 0.000 description 8
239000007787 solid Substances 0.000 description 8
239000002904 solvent Substances 0.000 description 8
125000004149 thio group Chemical group *S* 0.000 description 8
229920002554 vinyl polymer Polymers 0.000 description 8
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 7
238000007792 addition Methods 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 7
230000008859 change Effects 0.000 description 7
238000009826 distribution Methods 0.000 description 7
239000010419 fine particle Substances 0.000 description 7
238000010438 heat treatment Methods 0.000 description 7
125000004433 nitrogen atom Chemical group N* 0.000 description 7
229920005989 resin Polymers 0.000 description 7
239000011347 resin Substances 0.000 description 7
230000003595 spectral effect Effects 0.000 description 7
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 7
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
150000001298 alcohols Chemical class 0.000 description 6
125000004414 alkyl thio group Chemical group 0.000 description 6
125000005110 aryl thio group Chemical group 0.000 description 6
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical group C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
239000000084 colloidal system Substances 0.000 description 6
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 6
229910052731 fluorine Inorganic materials 0.000 description 6
229910052736 halogen Inorganic materials 0.000 description 6
150000002367 halogens Chemical class 0.000 description 6
125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
125000002883 imidazolyl group Chemical group 0.000 description 6
238000002156 mixing Methods 0.000 description 6
238000010899 nucleation Methods 0.000 description 6
230000006911 nucleation Effects 0.000 description 6
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
238000012545 processing Methods 0.000 description 6
230000009467 reduction Effects 0.000 description 6
239000000377 silicon dioxide Substances 0.000 description 6
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 6
125000000565 sulfonamide group Chemical group 0.000 description 6
229910052717 sulfur Inorganic materials 0.000 description 6
150000004772 tellurides Chemical class 0.000 description 6
229910052714 tellurium Inorganic materials 0.000 description 6
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 6
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 5
229920002472 Starch Polymers 0.000 description 5
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
ISAKRJDGNUQOIC-UHFFFAOYSA-N Uracil Chemical compound O=C1C=CNC(=O)N1 ISAKRJDGNUQOIC-UHFFFAOYSA-N 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
125000005161 aryl oxy carbonyl group Chemical group 0.000 description 5
239000013078 crystal Substances 0.000 description 5
DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 5
150000002894 organic compounds Chemical class 0.000 description 5
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 5
229920002451 polyvinyl alcohol Polymers 0.000 description 5
230000008569 process Effects 0.000 description 5
125000003226 pyrazolyl group Chemical group 0.000 description 5
125000004076 pyridyl group Chemical group 0.000 description 5
229920006395 saturated elastomer Polymers 0.000 description 5
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 5
239000003381 stabilizer Substances 0.000 description 5
239000008107 starch Substances 0.000 description 5
239000011593 sulfur Substances 0.000 description 5
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
NVXLIZQNSVLKPO-UHFFFAOYSA-N Glucosereductone Chemical compound O=CC(O)C=O NVXLIZQNSVLKPO-UHFFFAOYSA-N 0.000 description 4
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
239000004372 Polyvinyl alcohol Substances 0.000 description 4
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
125000003282 alkyl amino group Chemical group 0.000 description 4
125000003710 aryl alkyl group Chemical group 0.000 description 4
125000001769 aryl amino group Chemical group 0.000 description 4
235000010323 ascorbic acid Nutrition 0.000 description 4
229960005070 ascorbic acid Drugs 0.000 description 4
239000011668 ascorbic acid Substances 0.000 description 4
239000011324 bead Substances 0.000 description 4
229920002301 cellulose acetate Polymers 0.000 description 4
125000001309 chloro group Chemical group Cl* 0.000 description 4
150000004696 coordination complex Chemical class 0.000 description 4
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
239000011737 fluorine Substances 0.000 description 4
125000005462 imide group Chemical group 0.000 description 4
150000002576 ketones Chemical class 0.000 description 4
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 4
125000001624 naphthyl group Chemical group 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
229920001228 polyisocyanate Polymers 0.000 description 4
239000005056 polyisocyanate Substances 0.000 description 4
229920002689 polyvinyl acetate Polymers 0.000 description 4
239000011118 polyvinyl acetate Substances 0.000 description 4
239000002243 precursor Substances 0.000 description 4
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
125000005493 quinolyl group Chemical group 0.000 description 4
229910052711 selenium Inorganic materials 0.000 description 4
229910001961 silver nitrate Inorganic materials 0.000 description 4
239000002002 slurry Substances 0.000 description 4
235000019698 starch Nutrition 0.000 description 4
238000003860 storage Methods 0.000 description 4
125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 3
125000001399 1,2,3-triazolyl group Chemical group N1N=NC(=C1)* 0.000 description 3
125000004520 1,3,4-thiadiazolyl group Chemical group 0.000 description 3
125000005955 1H-indazolyl group Chemical group 0.000 description 3
125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 3
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 3
WZHHYIOUKQNLQM-UHFFFAOYSA-N 3,4,5,6-tetrachlorophthalic acid Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(O)=O WZHHYIOUKQNLQM-UHFFFAOYSA-N 0.000 description 3
CWJJAFQCTXFSTA-UHFFFAOYSA-N 4-methylphthalic acid Chemical compound CC1=CC=C(C(O)=O)C(C(O)=O)=C1 CWJJAFQCTXFSTA-UHFFFAOYSA-N 0.000 description 3
229920002126 Acrylic acid copolymer Polymers 0.000 description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
241001061127 Thione Species 0.000 description 3
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 3
150000008360 acrylonitriles Chemical class 0.000 description 3
239000000654 additive Substances 0.000 description 3
125000004466 alkoxycarbonylamino group Chemical group 0.000 description 3
125000005162 aryl oxy carbonyl amino group Chemical group 0.000 description 3
125000000656 azaniumyl group Chemical group [H][N+]([H])([H])[*] 0.000 description 3
125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 3
239000012964 benzotriazole Substances 0.000 description 3
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 3
230000000903 blocking effect Effects 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
229920006217 cellulose acetate butyrate Polymers 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
125000000259 cinnolinyl group Chemical group N1=NC(=CC2=CC=CC=C12)* 0.000 description 3
229910017052 cobalt Inorganic materials 0.000 description 3
239000010941 cobalt Substances 0.000 description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
238000011033 desalting Methods 0.000 description 3
239000002612 dispersion medium Substances 0.000 description 3
238000004945 emulsification Methods 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
238000011156 evaluation Methods 0.000 description 3
238000007765 extrusion coating Methods 0.000 description 3
239000001087 glyceryl triacetate Substances 0.000 description 3
235000013773 glyceryl triacetate Nutrition 0.000 description 3
125000005842 heteroatom Chemical group 0.000 description 3
FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 3
238000003384 imaging method Methods 0.000 description 3
125000001041 indolyl group Chemical group 0.000 description 3
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
239000007788 liquid Substances 0.000 description 3
229920003145 methacrylic acid copolymer Polymers 0.000 description 3
229940117841 methacrylic acid copolymer Drugs 0.000 description 3
239000000178 monomer Substances 0.000 description 3
125000004593 naphthyridinyl group Chemical group N1=C(C=CC2=CC=CN=C12)* 0.000 description 3
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125000003072 pyrazolidinyl group Chemical group 0.000 description 1
125000002755 pyrazolinyl group Chemical group 0.000 description 1
PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
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125000001422 pyrrolinyl group Chemical group 0.000 description 1
QEIQICVPDMCDHG-UHFFFAOYSA-N pyrrolo[2,3-d]triazole Chemical class N1=NC2=CC=NC2=N1 QEIQICVPDMCDHG-UHFFFAOYSA-N 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
JWVCLYRUEFBMGU-UHFFFAOYSA-N quinazoline Chemical compound N1=CN=CC2=CC=CC=C21 JWVCLYRUEFBMGU-UHFFFAOYSA-N 0.000 description 1
125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 description 1
125000004621 quinuclidinyl group Chemical group N12C(CC(CC1)CC2)* 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
150000003283 rhodium Chemical class 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
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VXNYVYJABGOSBX-UHFFFAOYSA-N rhodium(3+);trinitrate Chemical compound [Rh+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VXNYVYJABGOSBX-UHFFFAOYSA-N 0.000 description 1
238000007363 ring formation reaction Methods 0.000 description 1
238000007761 roller coating Methods 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000003346 selenoethers Chemical class 0.000 description 1
239000010420 shell particle Substances 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
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IZXSLAZMYLIILP-ODZAUARKSA-M silver (Z)-4-hydroxy-4-oxobut-2-enoate Chemical compound [Ag+].OC(=O)\C=C/C([O-])=O IZXSLAZMYLIILP-ODZAUARKSA-M 0.000 description 1
YRSQDSCQMOUOKO-KVVVOXFISA-M silver;(z)-octadec-9-enoate Chemical compound [Ag+].CCCCCCCC\C=C/CCCCCCCC([O-])=O YRSQDSCQMOUOKO-KVVVOXFISA-M 0.000 description 1
JKOCEVIXVMBKJA-UHFFFAOYSA-M silver;butanoate Chemical compound [Ag+].CCCC([O-])=O JKOCEVIXVMBKJA-UHFFFAOYSA-M 0.000 description 1
MNMYRUHURLPFQW-UHFFFAOYSA-M silver;dodecanoate Chemical compound [Ag+].CCCCCCCCCCCC([O-])=O MNMYRUHURLPFQW-UHFFFAOYSA-M 0.000 description 1
LTYHQUJGIQUHMS-UHFFFAOYSA-M silver;hexadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCC([O-])=O LTYHQUJGIQUHMS-UHFFFAOYSA-M 0.000 description 1
ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
OHGHHPYRRURLHR-UHFFFAOYSA-M silver;tetradecanoate Chemical compound [Ag+].CCCCCCCCCCCCCC([O-])=O OHGHHPYRRURLHR-UHFFFAOYSA-M 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
238000010129 solution processing Methods 0.000 description 1
241000894007 species Species 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
239000001119 stannous chloride Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
229960002317 succinimide Drugs 0.000 description 1
238000000967 suction filtration Methods 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
125000000213 sulfino group Chemical group [H]OS(*)=O 0.000 description 1
229940124530 sulfonamide Drugs 0.000 description 1
150000003456 sulfonamides Chemical class 0.000 description 1
150000003461 sulfonyl halides Chemical class 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
150000003498 tellurium compounds Chemical class 0.000 description 1
230000002123 temporal effect Effects 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
238000004154 testing of material Methods 0.000 description 1
150000003536 tetrazoles Chemical class 0.000 description 1
VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
150000003557 thiazoles Chemical class 0.000 description 1
150000003549 thiazolines Chemical class 0.000 description 1
125000001544 thienyl group Chemical group 0.000 description 1
125000001391 thioamide group Chemical group 0.000 description 1
BRWIZMBXBAOCCF-UHFFFAOYSA-N thiosemicarbazide group Chemical group NNC(=S)N BRWIZMBXBAOCCF-UHFFFAOYSA-N 0.000 description 1
ZEMGGZBWXRYJHK-UHFFFAOYSA-N thiouracil Chemical compound O=C1C=CNC(=S)N1 ZEMGGZBWXRYJHK-UHFFFAOYSA-N 0.000 description 1
229950000329 thiouracil Drugs 0.000 description 1
FYOWZTWVYZOZSI-UHFFFAOYSA-N thiourea dioxide Chemical class NC(=N)S(O)=O FYOWZTWVYZOZSI-UHFFFAOYSA-N 0.000 description 1
UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 description 1
DWWMSEANWMWMCB-UHFFFAOYSA-N tribromomethylsulfonylbenzene Chemical compound BrC(Br)(Br)S(=O)(=O)C1=CC=CC=C1 DWWMSEANWMWMCB-UHFFFAOYSA-N 0.000 description 1
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
239000001018 xanthene dye Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

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Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

JP20241097A 1997-04-02 1997-07-11 熱現像写真材料 Expired - Fee Related JP3745091B2 (ja)

Priority Applications (6)

Application Number	Priority Date	Filing Date	Title
JP20241097A JP3745091B2 (ja)	1997-07-11	1997-07-11	熱現像写真材料
DE69806199T DE69806199T2 (de)	1997-04-02	1998-03-20	Wärmeentwickelbare photographische Materialien
EP98105131A EP0869391B1 (en)	1997-04-02	1998-03-20	Heat-developable photographic materials
AT98105131T ATE219842T1 (de)	1997-04-02	1998-03-20	Wärmeentwickelbare photographische materialien
CNB981013112A CN1163795C (zh)	1997-04-02	1998-04-02	可热显影的感光材料
US09/053,652 US6025122A (en)	1997-04-02	1998-04-02	Heat-developable photographic materials

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP20241097A JP3745091B2 (ja)	1997-07-11	1997-07-11	熱現像写真材料

Publications (3)

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JPH1130832A JPH1130832A (ja)	1999-02-02
JPH1130832A5 JPH1130832A5 (2)	2004-10-07
JP3745091B2 true JP3745091B2 (ja)	2006-02-15

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JP4369876B2 (ja)	2004-03-23	2009-11-25	富士フイルム株式会社	ハロゲン化銀感光材料および熱現像感光材料
US20060057512A1 (en)	2004-09-14	2006-03-16	Fuji Photo Film Co., Ltd.	Photothermographic material

1997
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