JP5037112B2 - Casting structure - Google Patents

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JP5037112B2
JP5037112B2 JP2006347428A JP2006347428A JP5037112B2 JP 5037112 B2 JP5037112 B2 JP 5037112B2 JP 2006347428 A JP2006347428 A JP 2006347428A JP 2006347428 A JP2006347428 A JP 2006347428A JP 5037112 B2 JP5037112 B2 JP 5037112B2
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thermoplastic resin
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春樹 池永
俊樹 松尾
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Kao Corp
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Description

本発明は、鋳物の製造時に用いられる鋳型等の構造体、及びその製造方法、並びに該構造体を用いた鋳物の製造方法に関する。   The present invention relates to a structure such as a mold used in manufacturing a casting, a method for manufacturing the structure, and a method for manufacturing a casting using the structure.

鋳物は、一般に、木型や金型などをもとに鋳物砂で内部にキャビティを有する鋳型を形成するとともに、必要に応じて該キャビティ内に中子を配した後、該キャビティに溶湯を供給して製造されている。   For castings, in general, a mold having a cavity is formed with casting sand based on a wooden mold or a mold, and a core is disposed in the cavity as needed, and then a molten metal is supplied to the cavity. Manufactured.

木型、金型の製造は、加工に熟練を要し高価な設備も必要で、高価で重い等の欠点と共に廃棄処理の問題も生じ、量産の鋳物のほかには使用が困難である。また、鋳物砂を用いた砂型は、通常の砂にバインダーを添加し、硬化させて形状を保持させているため、砂の再利用には再生処理工程が必須となる。また、再生処理の際にダストなどの廃棄物が発生するなどの問題も生じている。加えて、中子を砂型で製造する場合、上記課題に加え中子自身の重量のため取り扱いに難があり、さらには、鋳込み時の強度保持と鋳込み後の中子除去性という相反する性能が要求される。   The manufacture of wooden molds and molds requires skill in processing and expensive equipment, and there are disadvantages such as expensive and heavy disposal, as well as disposal problems, making it difficult to use in addition to mass-produced castings. Moreover, since the sand mold | die using casting sand has added the binder to normal sand, it is made to harden | cure and the shape is hold | maintained, a recycling process process becomes essential for reuse of sand. There is also a problem that waste such as dust is generated during the regeneration process. In addition, when the core is manufactured in a sand mold, it is difficult to handle due to the weight of the core itself in addition to the above problems, and furthermore, there are conflicting performances of strength maintenance during casting and core removal after casting. Required.

このような課題を解決する技術として、鋳型に用いる部材を例えば、粉状黒鉛と粉状黒鉛同士を接着するプラスチック材料で成形する技術(下記特許文献1参照)が知られている。また、有機繊維、無機繊維、無機粒子及び熱硬化性樹脂を含有する鋳物製造用構造体を得る技術(下記特許文献2参照)が知られているが、実質、熱可塑性樹脂は用いられていない。   As a technique for solving such a problem, a technique for molding a member used for a mold with, for example, a plastic material that adheres powdered graphite and powdered graphite (see Patent Document 1 below) is known. Moreover, although the technique (refer patent document 2 below) which obtains the structure for casting manufacture containing an organic fiber, an inorganic fiber, an inorganic particle, and a thermosetting resin is known, a thermoplastic resin is not used substantially. .

特開平8−90145号公報JP-A-8-90145 特開2005−349428号公報JP 2005-349428 A

従来の熱可塑性樹脂を使用した構造体においては、鋳込み時の熱間強度が低いため、鋳込み時に鋳物製造用構造体が変形する等して、意図した鋳物の形状を保持できない、つまり寸法精度が悪いという課題を有していた。   In a structure using a conventional thermoplastic resin, the hot strength at the time of casting is low, so the structure for casting production is deformed at the time of casting, so the intended shape of the casting cannot be maintained. Had the problem of being bad.

本発明の目的は、鋳物製造用構造体の成形性が良く、軽量で、鋳込み時においても十分な熱間強度を有する為、鋳込み時の形状保持性に優れ、寸法精度の良い鋳物が得られる鋳物製造用構造体並びにその製造方法、並びにこれらを用いた鋳物の製造方法を提供することにある。   The object of the present invention is to provide a casting with a good moldability, light weight, and sufficient hot strength even during casting. An object of the present invention is to provide a casting manufacturing structure, a manufacturing method thereof, and a casting manufacturing method using these.

本発明は、無機繊維、無機粒子、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂及び熱可塑性樹脂を含有する鋳物製造用構造体に関する。   The present invention relates to a structure for producing castings containing inorganic fibers, inorganic particles, a resol-based phenol resin having a gel time at 150 ° C. of 1.5 minutes or more, and a thermoplastic resin.

また、本発明は、無機繊維、無機粒子、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂及び熱可塑性樹脂を、溶融混練後、成形する鋳物製造用構造体の製造方法に関する。   The present invention also relates to a method for producing a casting manufacturing structure in which inorganic fibers, inorganic particles, a resol-based phenol resin and a thermoplastic resin having a gel time at 150 ° C. of 1.5 minutes or more are melt-kneaded and then molded.

また、本発明は、上記本発明の鋳物製造用構造体を用いる鋳物の製造方法に関する。   Moreover, this invention relates to the manufacturing method of the casting which uses the structure for casting manufacture of the said invention.

本発明によれば、鋳込み時に十分な熱間強度を有するので鋳込み時の形状保持性に優れ、意図した形状の鋳物が精度良く得られる鋳物製造用構造体が提供される。   ADVANTAGE OF THE INVENTION According to this invention, since it has sufficient hot strength at the time of casting, it is excellent in the shape retainability at the time of casting, and the structure for casting manufacture from which the casting of the intended shape is obtained accurately is provided.

本発明の鋳物製造用構造体は、無機繊維、無機粒子、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂及び熱可塑性樹脂をを含有する。   The structure for producing a casting of the present invention contains inorganic fibers, inorganic particles, a resol-based phenol resin and a thermoplastic resin having a gel time at 150 ° C. of 1.5 minutes or more.

無機繊維の含有量は、構造体中、1〜50重量%、更に2〜40重量%、特に3〜30重量%が好ましい。なお、この含有量の数値は、構造体中の配合量の数値であってもよい(以下も同様)。更に、この含有量の数値は、無機繊維、無機粒子、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂及び熱可塑性樹脂の合計を100重量%とした場合の数値であってもよい(以下も同様)。   The content of the inorganic fiber in the structure is preferably 1 to 50% by weight, more preferably 2 to 40% by weight, and particularly preferably 3 to 30% by weight. In addition, the numerical value of this content may be a numerical value of the blending amount in the structure (the same applies hereinafter). Furthermore, the numerical value of this content may be a numerical value when the total of inorganic fibers, inorganic particles, a resol phenol resin having a gel time at 150 ° C. of 1.5 minutes or more, and a thermoplastic resin is 100% by weight. Good (and so on).

この無機繊維の含有量が1重量%以上であることは構造体の耐熱性の低下に伴う熱収縮を抑制して構造体の形状を精度よく鋳物に転写する観点、ガスの発生量を抑制する観点から好ましく、この含有量が50重量%以下であることは構造体の成形性が良好で鋳込み後の構造体の除去性も良好となるという観点から好ましい。   The content of the inorganic fiber of 1% by weight or more suppresses heat shrinkage due to a decrease in the heat resistance of the structure and suppresses the amount of gas generated from the viewpoint of accurately transferring the shape of the structure to the casting. From the viewpoint, the content is preferably 50% by weight or less from the viewpoint that the moldability of the structure is good and the removability of the structure after casting is also good.

また、無機粒子の含有量は、構造体中、5〜70重量%、更に10〜60重量%、特に20〜50重量%が好ましい。   The content of the inorganic particles is preferably 5 to 70% by weight, more preferably 10 to 60% by weight, and particularly preferably 20 to 50% by weight in the structure.

この無機粒子の含有量が5重量%以上であることは後述する無機粒子の添加効果がより発現しやすいという観点から好ましく、この含有量が70重量%以下であることは構造体の成形性、鋳物への形状転写性に優れる観点から好ましい。   The content of the inorganic particles is preferably 5% by weight or more from the viewpoint that the effect of adding the inorganic particles described later is more easily expressed, and the content of 70% by weight or less is the moldability of the structure, It is preferable from the viewpoint of excellent shape transferability to a casting.

また、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂の含有量は、構造体中、1〜70重量%、更に10〜60重量%、特に15〜50重量%が好ましい。   In addition, the content of the resol phenol resin having a gel time at 150 ° C. of 1.5 minutes or more is preferably 1 to 70% by weight, more preferably 10 to 60% by weight, and particularly preferably 15 to 50% by weight in the structure.

この150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂の含有量が1重量%以上であることは鋳物の表面の平滑性が良好で、構造体の強度や形状保持性も良好となるという観点から好ましく、この含有量が70重量%以下であることは構造体の成形性が良くなるほか、ガス発生量が低減されて鋳物の表面欠陥を抑制できるという観点から好ましい。   When the content of the resol phenol resin having a gel time at 150 ° C. of 1.5 minutes or more is 1% by weight or more, the smoothness of the casting surface is good, and the strength and shape retention of the structure are also good. This content is preferably 70% by weight or less from the viewpoint of improving the moldability of the structure and reducing the amount of gas generated to suppress surface defects of the casting.

また、熱可塑性樹脂の含有量は、構造体中、5〜60重量%、更に8〜40重量%、特に10〜35重量%が好ましい。   Further, the content of the thermoplastic resin in the structure is preferably 5 to 60% by weight, more preferably 8 to 40% by weight, and particularly preferably 10 to 35% by weight.

この熱可塑性樹脂の含有量が5重量%以上であることは溶融混練が可能であり、鋳物製造用構造体の成形性を向上する観点から好ましく、この含有量が60重量%以下であることは、ガス発生量を低減して鋳物の表面欠陥を抑制する観点から好ましい。   The thermoplastic resin content of 5% by weight or more is preferable from the viewpoint of melt kneading and improving the moldability of the structure for producing castings, and the content is 60% by weight or less. From the viewpoint of reducing the amount of gas generated and suppressing surface defects of the casting.

前記無機繊維は、主として鋳物製造用構造体において鋳造に用いられる前の状態ではその骨格をなし、鋳造に用いられたときには溶融金属の熱によって燃焼せずにその形状を維持する成分である。特に、鋳物製造用構造体が溶融金属の熱によって熱分解して生じる熱収縮を抑える成分である。   The inorganic fiber is a component that mainly forms a skeleton in a state before being used for casting in a structure for producing castings, and maintains its shape without being burned by the heat of molten metal when used for casting. In particular, it is a component that suppresses thermal shrinkage caused by thermal decomposition of the casting production structure by the heat of the molten metal.

前記無機繊維としては、炭素繊維、ロックウール等の人造鉱物繊維、セラミック繊維、アルミナ繊維、天然鉱物繊維が挙げられる。無機繊維は、これらを単独で又は二以上を選択して用いることができる。そして、これらの中でも、鋳物製造用構造体の熱分解に伴う収縮を効果的に抑える点から高温でも高強度を有する炭素繊維が好ましく、ピッチ系やポリアクリロニトリル(PAN)系炭素繊維を用いることがより好ましく、特にPAN系の炭素繊維が好ましい。これら炭素繊維は、ロックウール等の人造鉱物繊維、セラミック繊維、アルミナ繊維、天然鉱物繊維等の無機繊維と組み合わせて使用することができる。   Examples of the inorganic fibers include artificial mineral fibers such as carbon fibers and rock wool, ceramic fibers, alumina fibers, and natural mineral fibers. These inorganic fibers can be used alone or in combination of two or more. Among these, carbon fibers having high strength even at high temperatures are preferable from the viewpoint of effectively suppressing shrinkage associated with thermal decomposition of the structure for casting production, and pitch-based or polyacrylonitrile (PAN) -based carbon fibers are preferably used. More preferably, PAN-based carbon fiber is particularly preferable. These carbon fibers can be used in combination with artificial mineral fibers such as rock wool, inorganic fibers such as ceramic fibers, alumina fibers, and natural mineral fibers.

前記無機粒子は、該構造体の耐熱性を向上させる成分である。前記無機粒子としては、シリカ、アルミナ、ムライト、マグネシア、ジルコニア、雲母、黒鉛、黒曜石、タングステン、ルテニウム、酸化トリウム、酸化ハフニウム、酸化ジルコニウム、酸化ベリリウム、石灰、酸化イットリウム、酸化セリウム、酸化タリウム、酸化ランタン、炭酸カルシウム、炭酸カリウム、炭酸ナトリウム、炭酸水素ナトリウム、水酸化マグネシウム、水酸化アルミニウム、ケイ酸、ジルコン、シリマナイト、スピネル、クロマイト、ホルステライト、エンスタタイト、炭化チタニウム、炭化ジルコニウム、炭化ハフニウム、炭化バナジウム、炭化ニオビウム、炭化タンタル、炭化クロミウム、炭化モリブデン、炭化タングステン、窒化チタニウム、窒化ジルコニウム、窒化ハフニウム、窒化タンタル、ホウ化ジルコニウム、ホウ化ハフニウム、ホウ化タングステンなどの無機粒子が挙げれ、耐火度800〜4000℃、好ましくは1000〜4000℃の無機粒子が好ましく、耐熱性、構造体成型時の離型性の点から黒鉛がより好ましい。また、ガス欠陥低減、構造体成形時の離型性の観点から、炭酸カルシウムがより好ましい。なお、これらの無機粒子は単独で又は二種以上を併用しても良い。該無機粒子は、粒子径が200μm以下のものを用いることが好ましい。特に、鋳造する溶融金属の鋳込温度に対し±300℃、特に±200℃の耐火度を有する無機粒子が好ましい。ここで、無機粒子の耐火度は、ゼーゲルコーンを用いた測定方法(JIS R2204)で測定される。市販されている好ましい無機粒子としては、例えば、Bogala Graphite Lanka Limited製の黒鉛(平均粒径56μm)、三共精粉(株)製、商品名「エスカロン#800」の炭酸カルシウム、白石カルシウム(株)製、商品名「ホワイトンB」の炭酸カルシウム等が挙げられる。   The inorganic particles are components that improve the heat resistance of the structure. Examples of the inorganic particles include silica, alumina, mullite, magnesia, zirconia, mica, graphite, obsidian, tungsten, ruthenium, thorium oxide, hafnium oxide, zirconium oxide, beryllium oxide, lime, yttrium oxide, cerium oxide, thallium oxide, and oxide. Lanthanum, calcium carbonate, potassium carbonate, sodium carbonate, sodium bicarbonate, magnesium hydroxide, aluminum hydroxide, silicic acid, zircon, sillimanite, spinel, chromite, holsterite, enstatite, titanium carbide, zirconium carbide, hafnium carbide, carbonized Vanadium, Niobium carbide, Tantalum carbide, Chromium carbide, Molybdenum carbide, Tungsten carbide, Titanium nitride, Zirconium nitride, Hafnium nitride, Tantalum nitride, Zirconium boride Inorganic particles such as copper, hafnium boride, tungsten boride and the like, inorganic particles having a fire resistance of 800 to 4000 ° C., preferably 1000 to 4000 ° C. are preferred, and graphite is preferable from the viewpoint of heat resistance and releasability at the time of molding a structure. Is more preferable. In addition, calcium carbonate is more preferable from the viewpoint of gas defect reduction and releasability at the time of forming a structure. These inorganic particles may be used alone or in combination of two or more. The inorganic particles preferably have a particle size of 200 μm or less. In particular, inorganic particles having a fire resistance of ± 300 ° C., particularly ± 200 ° C. with respect to the casting temperature of the molten metal to be cast are preferable. Here, the fire resistance of the inorganic particles is measured by a measuring method (JIS R2204) using a Zeger cone. Preferred inorganic particles that are commercially available include, for example, graphite (average particle size 56 μm) manufactured by Bogala Graphite Lanka Limited, calcium carbonate manufactured by Sankyo Seimitsu Co., Ltd., trade name “Escalon # 800”, calcium shiraishi Co., Ltd. For example, calcium carbonate having a trade name of “Whiteon B” may be used.

本発明に用いられる150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂(以下、単にレゾール系フェノール樹脂ということもある)は、熱硬化性樹脂の一種である。本発明のレゾール系フェノール樹脂は、150℃におけるゲルタイムが1.5分以上であれば、構造体の強度や形状保持性に優れ、好ましくは2分以上であり、好ましくは10分以下、より好ましくは6分以下である。従って、かかるゲルタイムはまた、より好ましくは2分〜10分であり、更に好ましくは2分〜6分である。   The resol-type phenol resin (hereinafter also referred to simply as “resol-type phenol resin”) having a gel time at 150 ° C. of 1.5 minutes or more used in the present invention is a kind of thermosetting resin. If the gel time at 150 ° C. is 1.5 minutes or more, the resol phenolic resin of the present invention is excellent in structure strength and shape retention, preferably 2 minutes or more, preferably 10 minutes or less, more preferably Is less than 6 minutes. Therefore, such gel time is also more preferably 2 minutes to 10 minutes, and further preferably 2 minutes to 6 minutes.

また、定かではないが、本発明のレゾール系フェノール樹脂は、150℃におけるゲルタイムが1.5分以上であるので溶融混練時におけるレゾール系フェノール樹脂の硬化がゆっくり進行するため、分散状態が良好な結果、十分な熱間強度を有する鋳物製造用構造体が得られる為、当該構造体は、鋳込み時の形状保持性に優れ、意図した形状の鋳物が得られるという本発明の効果が発現するものと考えられる。   Moreover, although it is not certain, the resol phenolic resin of the present invention has a good dispersion state because the gel time at 150 ° C. is 1.5 minutes or more and the curing of the resol phenolic resin at the time of melt kneading proceeds slowly. As a result, a structure for producing castings having sufficient hot strength can be obtained. Therefore, the structure has excellent shape retention at the time of casting, and the effect of the present invention that a casting having the intended shape can be obtained. it is conceivable that.

尚、ゲルタイムは、キュラストメーターを用いた測定方法(JIS K6300)に従って求めることができる。   The gel time can be determined according to a measurement method (JIS K6300) using a curast meter.

本発明のレゾール系フェノール系樹脂の重量平均分子量は、構造体の強度や形状保持性の観点から、好ましくは、3000〜20000であり、より好ましくは5000〜15000である。尚、重量平均分子量は、ゲルパーミエーションクロマトグラフィー(GPC)を用い、溶媒にクロロホルム、カラムにGM HHR−H×2(東ソー製)、流量1.0mL/min、カラム温度40℃、検出器に示差屈折率検出器(RI)、リファレンスとして既知の分子量を有するスチレンを換算して求めることができる。   The weight average molecular weight of the resol-based phenolic resin of the present invention is preferably 3000 to 20000, more preferably 5000 to 15000, from the viewpoint of the strength and shape retention of the structure. The weight average molecular weight was determined by using gel permeation chromatography (GPC), chloroform as a solvent, GM HHR-H × 2 (manufactured by Tosoh), a flow rate of 1.0 mL / min, a column temperature of 40 ° C., and a detector. A differential refractive index detector (RI) can be obtained by converting styrene having a known molecular weight as a reference.

本発明においては、市販されている150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂を用いることができる。このようなレゾール系フェノール樹脂としては、例えば、エア・ウォーター(株)製、商品名ベルパールS890(150℃におけるゲルタイム:3分、重量平均分子量:10000)等が挙げられる。   In the present invention, a commercially available resol phenol resin having a gel time at 150 ° C. of 1.5 minutes or more can be used. Examples of such a resol-based phenol resin include a product name Belpearl S890 (gel time at 150 ° C .: 3 minutes, weight average molecular weight: 10,000) manufactured by Air Water Co., Ltd.

本発明で用いる熱可塑性樹脂は、溶融・流動化することにより、様々な形状の構造体を成形するために必要な成分である。   The thermoplastic resin used in the present invention is a component necessary for forming structures of various shapes by melting and fluidizing.

本発明で用いる熱可塑性樹脂は、低温での溶融混練が本発明のレゾール系フェノール樹脂の分散性に寄与すると考えられる為、低融点の熱可塑性樹脂が好ましい。本発明で用いる好ましい熱可塑性樹脂としては、170℃以下で溶融混練・流動化することにより、様々な形状の構造体を成形できるような熱可塑性樹脂を用いることが好ましく、例えば、好ましくは融点が160℃以下、より好ましくは150℃以下の熱可塑性樹脂であり、下限は特に限定されないが好ましくは融点が80℃以上、より好ましくは90℃以上の熱可塑性樹脂である。熱可塑性樹脂としては、例えば、ポリエチレン、ポリ塩化ビニル、ポリ乳酸、ポリブチレンサクシネート、ポリビニルアルコール、エチレン−ビニルアルコール共重合体などが挙げられる。好ましくはポリエチレン及びポリ乳酸から選ばれる熱可塑性樹脂である。   The thermoplastic resin used in the present invention is preferably a thermoplastic resin having a low melting point because melt kneading at a low temperature contributes to the dispersibility of the resol phenolic resin of the present invention. As a preferable thermoplastic resin used in the present invention, it is preferable to use a thermoplastic resin that can form structures of various shapes by melt-kneading and fluidizing at 170 ° C. or lower. It is a thermoplastic resin having a temperature of 160 ° C. or lower, more preferably 150 ° C. or lower. The lower limit is not particularly limited, but a thermoplastic resin having a melting point of 80 ° C. or higher, more preferably 90 ° C. or higher is preferable. Examples of the thermoplastic resin include polyethylene, polyvinyl chloride, polylactic acid, polybutylene succinate, polyvinyl alcohol, and ethylene-vinyl alcohol copolymer. A thermoplastic resin selected from polyethylene and polylactic acid is preferred.

尚、熱可塑性樹脂の融点は、JIS−K7121に基づく示差走査熱量測定(DSC)の昇温法による結晶融解吸熱ピーク温度より求められる値である。   In addition, melting | fusing point of a thermoplastic resin is a value calculated | required from the crystal melting endothermic peak temperature by the temperature rising method of differential scanning calorimetry (DSC) based on JIS-K7121.

前記熱可塑性樹脂は、単独で又は二以上を選択して用いることもできる。また、高融点の熱可塑性樹脂を使用する場合は、可塑剤等の併用により、低温(例えば170℃以下)で溶融混練できる処方にして使用することが好ましい。   The thermoplastic resins may be used alone or in combination of two or more. Moreover, when using a high-melting-point thermoplastic resin, it is preferable to use it by prescription which can be melt-kneaded at low temperature (for example, 170 degrees C or less) by combined use with a plasticizer.

本発明では、鋳物製造用構造体の製造原料に、本発明の目的を損なわない範囲で、安定剤(酸化防止剤、紫外線吸収剤など)、離型剤(脂肪酸、脂肪酸金属塩、オキシ脂肪酸、脂肪酸エステル、脂肪族部分鹸化エステル、パラフィン、低分子量ポリオレフィン、脂肪酸アミド、アルキレンビス脂肪酸アミド、脂肪族ケトン、脂肪酸低級アルコールエステル、脂肪酸多価アルコールエステル、脂肪酸ポリグリコールエステル、変成シリコーン)などを添加することもできる。   In the present invention, as a raw material for producing a structure for producing castings, a stabilizer (antioxidant, ultraviolet absorber, etc.), mold release agent (fatty acid, fatty acid metal salt, oxyfatty acid, Fatty acid ester, aliphatic partially saponified ester, paraffin, low molecular weight polyolefin, fatty acid amide, alkylene bis fatty acid amide, aliphatic ketone, fatty acid lower alcohol ester, fatty acid polyhydric alcohol ester, fatty acid polyglycol ester, modified silicone), etc. You can also.

本発明により得られた鋳物製造用構造体は、内面に鋳物製品形状のキャビティを有する主型、その主型に入れて使用する中子、或いは湯道などの注湯系部材等に適用することができるが、本発明の鋳物製造用構造体が表面平滑性に優れており、良好な鋳肌の鋳物を得ることができるため、主型や中子への適用が好ましい。   The casting manufacturing structure obtained by the present invention is applied to a main mold having a cast product-shaped cavity on the inner surface, a core used in the main mold, or a pouring member such as a runner. However, since the structure for producing a casting according to the present invention is excellent in surface smoothness and a casting having a good casting surface can be obtained, application to a main mold and a core is preferable.

本発明の鋳物製造用構造体の製造方法では、無機繊維、無機粒子、レゾール系フェノール樹脂及び熱可塑性樹脂を、溶融混練後、成形するが、熱可塑性樹脂の成形において用いられている公知の方法を採用することができる。例えば、無機繊維、無機粒子、レゾール系フェノール樹脂及び熱可塑性樹脂を、高速攪拌機または低速撹拌機などを用いて均一混合した後、充分な混練能力のある一軸あるいは多軸の押出機で溶融混練する方法を採用することができる。また、例えば、無機繊維、無機粒子及び熱可塑性樹脂を混合した後に、レゾール系フェノール樹脂を混合し、溶融混練してもよく、熱可塑性樹脂、無機粒子及び無機繊維を混合ペレット化した後に、レゾール系フェノール樹脂を混合し、溶融混練してもよく、その混合方法、溶融混練する方法に何ら制限はない。   In the method for producing a structure for producing a casting according to the present invention, inorganic fibers, inorganic particles, a resol phenol resin and a thermoplastic resin are molded after melt-kneading, and a known method used in molding a thermoplastic resin. Can be adopted. For example, inorganic fibers, inorganic particles, resole phenolic resin, and thermoplastic resin are uniformly mixed using a high-speed stirrer or low-speed stirrer, and then melt-kneaded with a single-screw or multi-screw extruder having sufficient kneading ability. The method can be adopted. Further, for example, after mixing inorganic fibers, inorganic particles and thermoplastic resin, the resol phenol resin may be mixed and melt-kneaded. After the thermoplastic resin, inorganic particles and inorganic fiber are mixed and pelletized, the resole The phenolic resin may be mixed and melt-kneaded, and the mixing method and melt-kneading method are not limited.

本発明の効果が発現する理由は定かではないが、低温で溶融混練することにより、レゾール系フェノール樹脂がより良く分散した状態の構造体が得られると考えられ、その結果、鋳込み時において、構造体中でより良く分散したレゾール系フェノール樹脂が、硬化して架橋する為、鋳込み時においての十分な熱間強度を有するので形状保持性に優れる鋳物製造用構造体を得るという本発明の効果が発現するものと考えられる。従って、溶融混練の温度は、好ましくは170℃以下であり、より好ましくは160℃以下、更に好ましくは155℃以下である。また、無機繊維、無機粒子、レゾール系フェノール樹脂及び熱可塑性樹脂を溶融混練温度の下限は、溶融混練できる温度であれば特に限定されるものではないが、好ましくは90℃以上であり、より好ましくは100℃以上であり、更に好ましくは110℃以上であある。かかる観点から溶融混練の温度は、好ましくは90〜170℃であり、より好ましくは100〜165℃であり、更に好ましくは110〜155℃である。   The reason why the effect of the present invention is manifest is not clear, but it is considered that a structure in which the resol phenolic resin is better dispersed can be obtained by melting and kneading at a low temperature. Since the resole phenolic resin that is better dispersed in the body is cured and cross-linked, it has sufficient hot strength at the time of casting, so that the effect of the present invention is obtained to obtain a structure for producing castings that is excellent in shape retention. It is considered to be expressed. Accordingly, the temperature for melt kneading is preferably 170 ° C. or lower, more preferably 160 ° C. or lower, and further preferably 155 ° C. or lower. Further, the lower limit of the melt kneading temperature of the inorganic fibers, inorganic particles, resol phenol resin and thermoplastic resin is not particularly limited as long as the temperature can be melt kneaded, but is preferably 90 ° C. or more, more preferably Is 100 ° C. or higher, more preferably 110 ° C. or higher. From this viewpoint, the temperature for melt kneading is preferably 90 to 170 ° C, more preferably 100 to 165 ° C, and still more preferably 110 to 155 ° C.

溶融混練温度は、熱可塑性樹脂の融点に対して5〜30℃高い温度が好ましい。また、目的に応じて、各種安定剤、紫外線吸収剤、難燃剤、内部離型剤、滑剤、可塑剤などを添加することもできる。本発明において、鋳物製造用構造体の製造は、公知の混練技術、例えば、ヘンシェルミキサー、リボンブレンダー等で各原料を固体状で混合させたり、さらに押出機等を用いてポリマーを溶融させながら混練させる方法を用いることもできる。溶融混練した混合物は、通常、ペレット、棒状、粉末等の形状にして成形に供することが好ましい。かかる混合物を混合機で均一にして、通常の成形条件で射出成形、押出し成形、圧縮成形等に供することができる。   The melt kneading temperature is preferably 5 to 30 ° C. higher than the melting point of the thermoplastic resin. Depending on the purpose, various stabilizers, ultraviolet absorbers, flame retardants, internal mold release agents, lubricants, plasticizers, and the like can also be added. In the present invention, the structure for casting production is produced by mixing each raw material in a solid state using a known kneading technique, for example, a Henschel mixer, a ribbon blender or the like, and further kneading while melting the polymer using an extruder or the like. It is also possible to use a method of In general, the melt-kneaded mixture is preferably used for molding in the form of pellets, rods, powders or the like. Such a mixture can be made uniform by a mixer and used for injection molding, extrusion molding, compression molding and the like under normal molding conditions.

本発明において、溶融混練により得られた混合物は、射出成形、ブロー成形、押出成形、インフレーション成形、およびシート加工後の真空成形、圧空成形、真空圧空成形等の成形方法により成形して鋳物製造用構造体を得ることができる。とりわけ、射出成形法が好ましく、一般的な射出成形法のほか、ガス射出成形、射出プレス成形等も採用できる。本発明の鋳物製造用構造体に適した射出成形条件の一例を挙げれば、シリンダ温度を、鋳物製造用構造体の流動開始温度以上、好ましくは90〜170℃、より好ましくは100〜165℃の範囲とし、また、金型温度は、溶融混練により得られた混合物の流動開始温度の−20℃以下とするのが適当である。成形温度が低すぎると成形品にショートが発生するなど操業性が不安定になったり、過負荷に陥りやすく、逆に成形温度が高すぎると溶融混練により得られた混合物、特に樹脂成分が分解し、得られる成形体の強度が低下したり、着色する等の問題が発生しやすい。   In the present invention, the mixture obtained by melt-kneading is molded by a molding method such as injection molding, blow molding, extrusion molding, inflation molding, vacuum forming after sheet processing, pressure forming, vacuum pressure forming, etc. A structure can be obtained. In particular, an injection molding method is preferable, and in addition to a general injection molding method, gas injection molding, injection press molding, or the like can be employed. If an example of the injection molding conditions suitable for the structure for casting manufacture of this invention is given, cylinder temperature will be more than the flow start temperature of the structure for casting manufacture, Preferably it is 90-170 degreeC, More preferably, it is 100-165 degreeC. The mold temperature is suitably set to −20 ° C. or less of the flow start temperature of the mixture obtained by melt kneading. If the molding temperature is too low, the operability becomes unstable or overloading occurs, such as a short circuit in the molded product. Conversely, if the molding temperature is too high, the mixture obtained by melt-kneading, particularly the resin components, will decompose. In addition, the strength of the resulting molded product is likely to decrease, or problems such as coloring may occur.

本発明の鋳物製造用構造体の製造方法の好ましい態様の一例を挙げれば、(1)無機繊維5〜30重量%、(2)無機粒子20〜40重量%、(3)150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂20〜50重量%、及び(4)融点が160℃以下の熱可塑性樹脂、好ましくはポリエチレン及びポリ乳酸から選ばれる熱可塑性樹脂10〜30重量%を、170℃以下で溶融混練後、成形する方法が挙げられる。ここで、各成分の重量%は、(1)〜(4)の合計を100重量%とした場合の数値である。   If an example of the preferable aspect of the manufacturing method of the structure for casting manufacture of this invention is given, (1) Inorganic fiber 5-30 weight%, (2) Inorganic particle 20-40 weight%, (3) Gel time in 150 degreeC 20 to 50% by weight of a resole phenolic resin that is 1.5 minutes or longer, and (4) a thermoplastic resin having a melting point of 160 ° C. or lower, preferably 10 to 30% by weight selected from polyethylene and polylactic acid, Examples of the method include molding after melt-kneading at 170 ° C. or lower. Here, the weight% of each component is a numerical value when the total of (1) to (4) is 100% by weight.

次に、本発明により得られた鋳物製造用構造体を用いた鋳物の製造方法を、その好ましい実施形態に基づいて説明する。本実施形態の鋳物の製造方法では、上述のようにして得られた所定の鋳物製造用構造体を鋳物砂内の所定位置に埋設して造型する。鋳物砂には、従来からこの種の鋳物の製造に用いられている通常のものを特に制限なく用いることができる。なお、鋳物砂はバインダーで硬化させなくてもよいが、必要に応じて硬化させてもよい。鋳物製造用構造体が中空中子の場合には中子内に鋳物砂の充填は不要であるが、充填することもできる。   Next, a casting manufacturing method using the casting manufacturing structure obtained according to the present invention will be described based on preferred embodiments thereof. In the casting manufacturing method of the present embodiment, the predetermined casting manufacturing structure obtained as described above is embedded in a predetermined position in the casting sand to form a mold. As the foundry sand, a conventional one that has been conventionally used for producing this type of casting can be used without any particular limitation. The foundry sand need not be cured with a binder, but may be cured as necessary. When the structure for casting production is a hollow core, the core does not need to be filled with foundry sand, but can be filled.

そして、注湯口から溶融金属を注ぎ入れ、鋳込みを行う。このとき、本発明の構造体は、熱間強度が維持され、鋳物製造用構造体の熱分解に伴う熱収縮が抑えられるため、各鋳物製造用構造体にひび割れが生じたり、鋳物製造用構造体自体が破損したりすることもほとんどなく、溶融金属の鋳物用構造体への差込みや鋳物砂などの付着もほとんど生じることがない。   Then, the molten metal is poured from the pouring gate and cast. At this time, in the structure of the present invention, the hot strength is maintained and the thermal shrinkage accompanying the thermal decomposition of the structure for casting production is suppressed. The body itself is hardly damaged, and there is hardly any insertion of molten metal into the casting structure or adhesion of foundry sand.

鋳込みを終えた後、所定の温度まで冷却し、鋳枠を解体して鋳物砂を取り除き、さらにブラスト処理によって鋳物製造用構造体を取り除いて鋳物を露呈させる。この時、前記熱可塑性樹脂が熱分解しているため、鋳物製造用構造体の除去処理は容易である。その後必要に応じて鋳物にトリミング処理等の後処理を施して鋳物の製造を完了する。   After the casting is finished, the casting is cooled to a predetermined temperature, the casting frame is disassembled to remove the casting sand, and the casting manufacturing structure is removed by blasting to expose the casting. At this time, since the thermoplastic resin is thermally decomposed, it is easy to remove the casting manufacturing structure. Thereafter, post-processing such as trimming is performed on the casting as necessary to complete the manufacturing of the casting.

本実施形態の鋳物の製造方法は、十分な熱間強度を有した形状保持性に優れる鋳物製造用構造体を用いるので、寸法精度や表面の平滑性に優れる鋳物を製造することができる。また、前記熱可塑性樹脂などの熱分解によって鋳物構造体の内部に空隙を形成して鋳込み後の当該鋳物製造溶構造体の除去を容易に行うことができるので、従来に比べて廃棄物処理を簡便に行うことができるほか、その廃棄物の発生量も大幅に抑えることができる。また、鋳物砂をバインダーで硬化させる必要がないため、鋳物砂の再生処理も簡便なものとなる。   Since the casting manufacturing method of the present embodiment uses a casting manufacturing structure having sufficient hot strength and excellent shape retention, it is possible to manufacture a casting having excellent dimensional accuracy and surface smoothness. Moreover, since the voids can be formed inside the cast structure by thermal decomposition of the thermoplastic resin or the like, and the cast manufacturing melted structure after casting can be easily removed, the waste treatment can be performed as compared with the conventional case. In addition to simple operation, the amount of waste generated can be greatly reduced. In addition, since it is not necessary to harden the foundry sand with a binder, the reclaiming treatment of the foundry sand becomes simple.

〔実施例1〕
<原料の配合>
・無機繊維:PAN炭素繊維(三菱レイヨン(株)製、商品名「パイロフィルチョップドファイバーTR03CMTR12CM」、繊維長:3mm)
・無機粒子:BP8083(Bogala Graphite Lanka Limited、平均粒径56μmの黒鉛)
・レゾール系フェノール樹脂:エア・ウォーター(株)製、商品名ベルパールS890(150℃におけるゲルタイム:3分、重量平均分子量:10000)、表中「ベルパール」と表記する。
・熱可塑性樹脂:ポリエチレン(日本ポリエチレン(株)製「ノバテックHD HS490P」)
・構造体の組成(重量%):無機繊維/無機粒子/レゾール系フェノール樹脂/熱可塑性樹脂=10/34/36/20
[Example 1]
<Combination of raw materials>
Inorganic fiber: PAN carbon fiber (Mitsubishi Rayon Co., Ltd., trade name “Pyrofil chopped fiber TR03CMTR12CM”, fiber length: 3 mm)
Inorganic particles: BP8083 (Bogala Graphite Lanka Limited, graphite having an average particle size of 56 μm)
Resole phenolic resin: manufactured by Air Water Co., Ltd., trade name Belpearl S890 (gel time at 150 ° C .: 3 minutes, weight average molecular weight: 10,000), represented as “Bellpearl” in the table.
-Thermoplastic resin: Polyethylene ("Novatec HD HS490P" manufactured by Nippon Polyethylene Co., Ltd.)
Structure composition (% by weight): inorganic fiber / inorganic particles / resole phenol resin / thermoplastic resin = 10/34/36/20

<鋳物製造用構造体の製造>
上記原料を、テストニーダー(ラボプラストミル40C、東洋精機(株)製)を用い、140℃で溶融混練した。得られた鋳物製造用構造体用の混合物を、厚さ1.0mmの型枠とともに金属板2枚に挟み、溶融混練温度と同様の温度にて3分間5kg/cm2で予圧した後、200kg/cm2でさらに1分間プレスし1.0mm厚のシートを作成した。得られたシートを、シートの軟化温度まで加熱し、外径30mmの円柱状の紙筒に巻きつけて、内径30mm(外径32mm)×高さ100mmの図1に示す円柱状の鋳物製造用構造体を得た。
<Manufacture of casting structures>
The above raw materials were melt-kneaded at 140 ° C. using a test kneader (Labo Plast Mill 40C, manufactured by Toyo Seiki Co., Ltd.). The obtained mixture for a structure for producing castings was sandwiched between two metal plates together with a mold having a thickness of 1.0 mm, pre-pressurized at 5 kg / cm 2 for 3 minutes at a temperature similar to the melt kneading temperature, and then 200 kg The sheet was further pressed for 1 minute at / cm 2 to produce a 1.0 mm thick sheet. The obtained sheet is heated to the softening temperature of the sheet, wound around a cylindrical paper tube having an outer diameter of 30 mm, and used for manufacturing a cylindrical casting shown in FIG. 1 having an inner diameter of 30 mm (outer diameter of 32 mm) × height of 100 mm. A structure was obtained.

<鋳物の鋳造>
得られたφ32mm×100mmの鋳物製造用構造体(図1に示す)を、図2のように陶管とつなぎ合わせ、バインダーで硬化させた鋳物砂内に埋設し、鋳物材質FC−200、鋳込温度1380℃で鋳物を製造した。得られた鋳物の形状保持性を以下のように評価し、それらの結果を表1に示した。
<Casting of castings>
The obtained structure for casting production of φ32 mm × 100 mm (shown in FIG. 1) is embedded in a molding sand joined with a ceramic pipe and cured with a binder as shown in FIG. Castings were produced at a filling temperature of 1380 ° C. The shape retention of the obtained casting was evaluated as follows, and the results are shown in Table 1.

〔鋳物の形状保持性〕
鋳造前の鋳物製造用構造体の体積と鋳造後の鋳物の体積とから体積変形率を求め、鋳物の形状保持性の指標とした。鋳造前の鋳物製造用構造体と鋳造後の鋳物の体積は、構造体の内径と鋳物の直径を、それぞれノギスで10点測定し、下記の式で求めた。得られた体積から、下記の式で体積変形率を求め、下記の基準で寸法精度を評価した。この体積変形率が小さいほど、形状保持性が良好であり、設計された形状に近い鋳物が得られていることを意味し、0%のものは設計形状と同一の形状の鋳物であることを意味する。
体積=(測定した内径もしくは直径の平均値/2)2×π×100
体積変形率(%)=〔1−(鋳造後の鋳物の体積/鋳造前の鋳物製造用構造体の体積)〕×100
○:体積変形率が0〜0.5%
△:体積変形率が0.5%超〜10%以下
×:体積変形率が10%超
[Casting shape retention]
The volume deformation rate was obtained from the volume of the casting manufacturing structure before casting and the volume of the casting after casting, and used as an index of the shape retention of the casting. The volume of the casting production structure before casting and the casting volume after casting were determined by the following formula by measuring the inner diameter of the structure and the diameter of the casting with 10 calipers. From the obtained volume, the volume deformation rate was determined by the following formula, and the dimensional accuracy was evaluated according to the following criteria. The smaller the volume deformation rate, the better the shape retention, which means that a casting close to the designed shape is obtained, and 0% is a casting having the same shape as the designed shape. means.
Volume = (average value of measured inner diameter or diameter / 2) 2 × π × 100
Volume deformation rate (%) = [1- (volume of casting after casting / volume of structure for casting production before casting)] × 100
○: Volume deformation rate is 0 to 0.5%
Δ: Volume deformation rate is more than 0.5% to 10% or less ×: Volume deformation rate is more than 10%

〔実施例2〕
無機粒子を炭酸カルシウム(三共精粉(株)製「エスカロン#800」)、成形時の原料混練温度を160℃に変更した以外は、実施例1と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。
[Example 2]
A structure for casting production was obtained in the same manner as in Example 1 except that the inorganic particles were calcium carbonate (“ESCALON # 800” manufactured by Sankyo Seimitsu Co., Ltd.) and the raw material kneading temperature at the time of molding was changed to 160 ° C. . Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.

〔実施例3〕
熱可塑性樹脂をポリ乳酸(三井化学(株)製「LACEA H−280」)、成形時の原料混練温度を150℃に変更した以外は、実施例1と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。
Example 3
A structure for casting production was obtained in the same manner as in Example 1 except that the thermoplastic resin was polylactic acid (“LACEA H-280” manufactured by Mitsui Chemicals, Inc.) and the raw material kneading temperature at the time of molding was changed to 150 ° C. It was. Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.

〔実施例4〕
原料の配合を表1の通りに変更した以外は、実施例1と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。
Example 4
A casting manufacturing structure was obtained in the same manner as in Example 1 except that the composition of the raw materials was changed as shown in Table 1. Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.

〔実施例5〕
原料の配合及び混練温度を表1の通りに変更した以外は、実施例2と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。
Example 5
A structure for producing castings was obtained in the same manner as in Example 2 except that the blending of raw materials and the kneading temperature were changed as shown in Table 1. Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.

〔比較例1〕
レゾール系フェノール樹脂をAVライトレジンSP400(旭有機材工業(株)製、150℃でのゲルタイムが1.3分、表中「AVライトレジン」と表記する。)に変更した以外は、実施例1と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。
[Comparative Example 1]
Except that the resole phenolic resin was changed to AV Light Resin SP400 (Asahi Organic Materials Co., Ltd., gel time at 150 ° C. was 1.3 minutes, indicated as “AV Light Resin” in the table). In the same manner as in No. 1, a casting production structure was obtained. Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.

〔比較例2〕
熱可塑性樹脂をポリスチレン(PSジャパン(株)製「ポリスチレンH−9152」)、成形時の原料混練温度を220℃に変更した以外は、比較例1と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。
[Comparative Example 2]
A casting production structure was obtained in the same manner as in Comparative Example 1 except that the thermoplastic resin was polystyrene (“Polystyrene H-9152” manufactured by PS Japan Co., Ltd.) and the raw material kneading temperature at the time of molding was changed to 220 ° C. . Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.

〔比較例3〕
無機粒子を炭酸カルシウム(三共製粉(株)製「エスカロン#800」)、原料の配合を表1の通りに変更した以外は、実施例1と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。
[Comparative Example 3]
A structure for producing castings was obtained in the same manner as in Example 1 except that the inorganic particles were calcium carbonate (“Escalon # 800” manufactured by Sankyo Flour Milling Co., Ltd.) and the raw material composition was changed as shown in Table 1. Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.

〔比較例4〕
原料の配合を表1の通りに変更した以外は、実施例1と同様にして鋳物製造用構造体を得た。この構造体を用いて実施例1と同様に鋳物を製造し、体積変形率を実施例1と同様に評価した。結果を表1に示す。

Figure 0005037112
[Comparative Example 4]
A casting manufacturing structure was obtained in the same manner as in Example 1 except that the composition of the raw materials was changed as shown in Table 1. Using this structure, a casting was produced in the same manner as in Example 1, and the volume deformation rate was evaluated in the same manner as in Example 1. The results are shown in Table 1.
Figure 0005037112

表1に示すように、実施例1〜5は、体積変形率が小さく、形状保持性が良好であり、寸法精度よく設計通りの形状の鋳物が得られていることがわかる。これに対し、比較例1〜4では、鋳込み時の構造体の形状保持性が悪く、得られた鋳物の寸法精度が悪いことがわかる。   As shown in Table 1, it can be seen that in Examples 1 to 5, the volume deformation rate is small, the shape retention is good, and a casting having a shape as designed is obtained with high dimensional accuracy. On the other hand, in Comparative Examples 1-4, it turns out that the shape maintenance property of the structure at the time of casting is bad, and the dimensional accuracy of the obtained casting is bad.

実施例、比較例で製造した鋳物製造用構造体を模式的に示す斜視図である。It is a perspective view which shows typically the structure for casting manufacture manufactured by the Example and the comparative example. 実施例、比較例で、鋳造用に鋳物製造用構造体を陶管に接続した状態を模式的に示す図である。In an Example and a comparative example, it is a figure which shows typically the state which connected the structure for casting manufacture to the ceramic pipe for casting.

Claims (6)

無機繊維、無機粒子、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂及び熱可塑性樹脂を含有する鋳物製造用構造体であって、
無機繊維を1〜50重量%、無機粒子を5〜70重量%、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂を1〜70重量%、熱可塑性樹脂を5〜60重量%含有する、
鋳物製造用構造体
A structure for producing a casting containing inorganic fibers, inorganic particles, a resole phenolic resin having a gel time at 150 ° C. of 1.5 minutes or more, and a thermoplastic resin ,
1 to 50% by weight of inorganic fibers, 5 to 70% by weight of inorganic particles, 1 to 70% by weight of a resol-based phenol resin having a gel time at 150 ° C. of 1.5 minutes or more, and 5 to 60% by weight of a thermoplastic resin contains,
Casting manufacturing structure .
無機粒子を10〜60重量%含有する請求項1記載の鋳物製造用構造体。 The structure for producing a casting according to claim 1, comprising 10 to 60% by weight of inorganic particles . 無機繊維が炭素繊維である請求項1又は2記載の鋳物製造用構造体。 The structure for casting production according to claim 1 or 2, wherein the inorganic fibers are carbon fibers. 無機繊維、無機粒子、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂及び熱可塑性樹脂を、溶融混練後、成形する鋳物製造用構造体の製造方法であって、
前記鋳物製造用構造体が、無機繊維を1〜50重量%、無機粒子を5〜70重量%、150℃におけるゲルタイムが1.5分以上であるレゾール系フェノール樹脂を1〜70重量%、熱可塑性樹脂を5〜60重量%含有する、
鋳物製造用構造体の製造方法
Inorganic fiber, inorganic particles, resol phenolic resin having a gel time at 150 ° C. of 1.5 minutes or more, and a thermoplastic resin, a method for producing a structure for casting production that is molded after melt-kneading ,
The structure for producing castings is 1 to 50% by weight of inorganic fibers, 5 to 70% by weight of inorganic particles, 1 to 70% by weight of a resole phenolic resin having a gel time at 150 ° C. of 1.5 minutes or more, heat Containing 5 to 60% by weight of a plastic resin,
A method for manufacturing a casting manufacturing structure .
溶融混練温度が170℃以下である請求項4記載の鋳物製造用構造体の製造方法。 The method for producing a structure for producing a casting according to claim 4, wherein the melt kneading temperature is 170 ° C or lower. 請求項1〜3の何れか1項記載の鋳物製造用構造体を用いる鋳物の製造方法。 The manufacturing method of the casting using the structure for casting manufacture of any one of Claims 1-3.
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