JP5450426B2 - プロパン及びイソブタンのアンモ酸化又は酸化方法 - Google Patents

プロパン及びイソブタンのアンモ酸化又は酸化方法 Download PDF

Info

Publication number: JP5450426B2
Authority: JP; Japan
Prior art keywords: catalyst; mixture; antimony; mixed metal; metal oxide
Prior art date: 2007-10-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP2010528872A

Other languages

English (en)

Japanese (ja)

Other versions

JP2011500564A (ja

Inventor

クリストスパパリゾス

マイケルジェイシーリ

ジェームズエフジュニアブラズディル

バギャチャンドラストラダー

Original Assignee

イネオスユーエスエイリミテッドライアビリティカンパニー

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2007-10-11

Filing date

2008-10-07

Publication date

2014-03-26

2008-10-07 Application filed by イネオスユーエスエイリミテッドライアビリティカンパニー filed Critical イネオスユーエスエイリミテッドライアビリティカンパニー

2011-01-06 Publication of JP2011500564A publication Critical patent/JP2011500564A/ja

2014-03-26 Application granted granted Critical

2014-03-26 Publication of JP5450426B2 publication Critical patent/JP5450426B2/ja

Status Expired - Fee Related legal-status Critical Current

2028-10-07 Anticipated expiration legal-status Critical

Links

238000000034 method Methods 0.000 title claims description 78
238000007254 oxidation reaction Methods 0.000 title claims description 37
230000003647 oxidation Effects 0.000 title claims description 36
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 title description 60
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 title description 42
239000001294 propane Substances 0.000 title description 30
239000001282 iso-butane Substances 0.000 title description 21
239000003054 catalyst Substances 0.000 claims description 279
239000000203 mixture Substances 0.000 claims description 202
229910003455 mixed metal oxide Inorganic materials 0.000 claims description 71
239000003607 modifier Substances 0.000 claims description 58
239000010955 niobium Substances 0.000 claims description 58
239000002131 composite material Substances 0.000 claims description 48
229930195734 saturated hydrocarbon Natural products 0.000 claims description 48
229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 48
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 42
229910052750 molybdenum Inorganic materials 0.000 claims description 42
239000011733 molybdenum Substances 0.000 claims description 42
229910052758 niobium Inorganic materials 0.000 claims description 40
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 40
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 38
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 36
239000007789 gas Substances 0.000 claims description 31
229910052787 antimony Inorganic materials 0.000 claims description 30
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 30
239000001301 oxygen Substances 0.000 claims description 30
229910052760 oxygen Inorganic materials 0.000 claims description 30
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 28
238000002156 mixing Methods 0.000 claims description 28
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 21
229920006395 saturated elastomer Polymers 0.000 claims description 20
229910021529 ammonia Inorganic materials 0.000 claims description 18
229910052721 tungsten Inorganic materials 0.000 claims description 18
229910052726 zirconium Inorganic materials 0.000 claims description 18
229910052684 Cerium Inorganic materials 0.000 claims description 17
238000001027 hydrothermal synthesis Methods 0.000 claims description 17
229910052714 tellurium Inorganic materials 0.000 claims description 17
229910052718 tin Inorganic materials 0.000 claims description 17
239000011135 tin Substances 0.000 claims description 17
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 17
229910052779 Neodymium Inorganic materials 0.000 claims description 16
229910052777 Praseodymium Inorganic materials 0.000 claims description 16
229910052735 hafnium Inorganic materials 0.000 claims description 16
229910052746 lanthanum Inorganic materials 0.000 claims description 16
229910052744 lithium Inorganic materials 0.000 claims description 16
229910052720 vanadium Inorganic materials 0.000 claims description 16
229910052692 Dysprosium Inorganic materials 0.000 claims description 15
229910052691 Erbium Inorganic materials 0.000 claims description 15
229910052693 Europium Inorganic materials 0.000 claims description 15
229910052688 Gadolinium Inorganic materials 0.000 claims description 15
229910052689 Holmium Inorganic materials 0.000 claims description 15
229910052765 Lutetium Inorganic materials 0.000 claims description 15
229910052772 Samarium Inorganic materials 0.000 claims description 15
229910052771 Terbium Inorganic materials 0.000 claims description 15
229910052775 Thulium Inorganic materials 0.000 claims description 15
229910052769 Ytterbium Inorganic materials 0.000 claims description 15
229910052732 germanium Inorganic materials 0.000 claims description 15
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 15
239000000377 silicon dioxide Substances 0.000 claims description 12
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 11
150000002825 nitriles Chemical class 0.000 claims description 11
125000004430 oxygen atom Chemical group O* 0.000 claims description 10
SZXAQBAUDGBVLT-UHFFFAOYSA-H antimony(3+);2,3-dihydroxybutanedioate Chemical compound [Sb+3].[Sb+3].[O-]C(=O)C(O)C(O)C([O-])=O.[O-]C(=O)C(O)C(O)C([O-])=O.[O-]C(=O)C(O)C(O)C([O-])=O SZXAQBAUDGBVLT-UHFFFAOYSA-H 0.000 claims description 9
BMYPOELGNTXHPU-UHFFFAOYSA-H bis(4,5-dioxo-1,3,2-dioxastibolan-2-yl) oxalate Chemical compound [Sb+3].[Sb+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O BMYPOELGNTXHPU-UHFFFAOYSA-H 0.000 claims description 9
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
150000007524 organic acids Chemical class 0.000 claims description 8
239000010936 titanium Substances 0.000 claims description 8
XUGISPSHIFXEHZ-GPJXBBLFSA-N [(3r,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C1C=C2C[C@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-GPJXBBLFSA-N 0.000 claims description 7
238000005470 impregnation Methods 0.000 claims description 7
229910052719 titanium Inorganic materials 0.000 claims description 7
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 5
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 5
230000001590 oxidative effect Effects 0.000 claims description 5
239000010937 tungsten Substances 0.000 claims description 5
AHBGXHAWSHTPOM-UHFFFAOYSA-N 1,3,2$l^{4},4$l^{4}-dioxadistibetane 2,4-dioxide Chemical compound O=[Sb]O[Sb](=O)=O AHBGXHAWSHTPOM-UHFFFAOYSA-N 0.000 claims description 4
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
229910000410 antimony oxide Inorganic materials 0.000 claims description 4
229910000411 antimony tetroxide Inorganic materials 0.000 claims description 4
KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 4
UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 4
OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 4
UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 4
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 4
KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 4
OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 4
QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 4
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 4
PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 4
KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 4
GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 4
NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 4
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
238000006243 chemical reaction Methods 0.000 description 53
150000001875 compounds Chemical class 0.000 description 49
150000002822 niobium compounds Chemical class 0.000 description 28
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 23
239000007864 aqueous solution Substances 0.000 description 23
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 19
230000000052 comparative effect Effects 0.000 description 19
239000002002 slurry Substances 0.000 description 17
239000007787 solid Substances 0.000 description 17
238000003756 stirring Methods 0.000 description 17
238000010438 heat treatment Methods 0.000 description 15
239000007788 liquid Substances 0.000 description 15
-1 aluminum compound Chemical class 0.000 description 14
150000001463 antimony compounds Chemical class 0.000 description 13
230000008569 process Effects 0.000 description 12
150000003498 tellurium compounds Chemical class 0.000 description 12
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 11
238000001035 drying Methods 0.000 description 11
239000002245 particle Substances 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 10
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 10
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 10
238000010304 firing Methods 0.000 description 10
238000002360 preparation method Methods 0.000 description 10
150000003609 titanium compounds Chemical class 0.000 description 10
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
150000001495 arsenic compounds Chemical class 0.000 description 9
150000001639 boron compounds Chemical class 0.000 description 9
150000001785 cerium compounds Chemical class 0.000 description 9
150000002291 germanium compounds Chemical class 0.000 description 9
150000002642 lithium compounds Chemical class 0.000 description 9
150000002798 neodymium compounds Chemical class 0.000 description 9
239000000047 product Substances 0.000 description 9
239000012429 reaction media Substances 0.000 description 9
150000003482 tantalum compounds Chemical class 0.000 description 9
150000003658 tungsten compounds Chemical class 0.000 description 9
150000003682 vanadium compounds Chemical class 0.000 description 9
229910001868 water Inorganic materials 0.000 description 9
150000003755 zirconium compounds Chemical class 0.000 description 9
239000002253 acid Substances 0.000 description 8
229910052782 aluminium Inorganic materials 0.000 description 8
IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 8
229940065287 selenium compound Drugs 0.000 description 8
150000003343 selenium compounds Chemical class 0.000 description 8
VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 8
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
239000005078 molybdenum compound Substances 0.000 description 7
150000002752 molybdenum compounds Chemical class 0.000 description 7
238000001694 spray drying Methods 0.000 description 7
229910010413 TiO 2 Inorganic materials 0.000 description 6
IKWTVSLWAPBBKU-UHFFFAOYSA-N a1010_sial Chemical compound O=[As]O[As]=O IKWTVSLWAPBBKU-UHFFFAOYSA-N 0.000 description 6
229910000413 arsenic oxide Inorganic materials 0.000 description 6
229960002594 arsenic trioxide Drugs 0.000 description 6
239000012298 atmosphere Substances 0.000 description 6
XFHGGMBZPXFEOU-UHFFFAOYSA-I azanium;niobium(5+);oxalate Chemical compound [NH4+].[Nb+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O XFHGGMBZPXFEOU-UHFFFAOYSA-I 0.000 description 6
FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 6
229910001947 lithium oxide Inorganic materials 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 6
150000003018 phosphorus compounds Chemical class 0.000 description 6
JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 description 6
239000000243 solution Substances 0.000 description 6
ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 6
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 5
239000003570 air Substances 0.000 description 5
238000001354 calcination Methods 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
238000001816 cooling Methods 0.000 description 5
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 5
OLQSNYOQJMTVNH-UHFFFAOYSA-N germanium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Ge+4] OLQSNYOQJMTVNH-UHFFFAOYSA-N 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 4
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 4
VGBWDOLBWVJTRZ-UHFFFAOYSA-K cerium(3+);triacetate Chemical compound [Ce+3].CC([O-])=O.CC([O-])=O.CC([O-])=O VGBWDOLBWVJTRZ-UHFFFAOYSA-K 0.000 description 4
JCCYXJAEFHYHPP-OLXYHTOASA-L dilithium;(2r,3r)-2,3-dihydroxybutanedioate Chemical compound [Li+].[Li+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O JCCYXJAEFHYHPP-OLXYHTOASA-L 0.000 description 4
LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 4
239000011261 inert gas Substances 0.000 description 4
XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 4
UJVRJBAUJYZFIX-UHFFFAOYSA-N nitric acid;oxozirconium Chemical compound [Zr]=O.O[N+]([O-])=O.O[N+]([O-])=O UJVRJBAUJYZFIX-UHFFFAOYSA-N 0.000 description 4
FXADMRZICBQPQY-UHFFFAOYSA-N orthotelluric acid Chemical compound O[Te](O)(O)(O)(O)O FXADMRZICBQPQY-UHFFFAOYSA-N 0.000 description 4
239000000376 reactant Substances 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
229910001935 vanadium oxide Inorganic materials 0.000 description 4
238000010626 work up procedure Methods 0.000 description 4
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical group [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 3
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
239000004254 Ammonium phosphate Substances 0.000 description 3
DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 3
235000011114 ammonium hydroxide Nutrition 0.000 description 3
229910000148 ammonium phosphate Inorganic materials 0.000 description 3
235000019289 ammonium phosphates Nutrition 0.000 description 3
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 3
239000003125 aqueous solvent Substances 0.000 description 3
229940000488 arsenic acid Drugs 0.000 description 3
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
239000004327 boric acid Substances 0.000 description 3
229910052810 boron oxide Inorganic materials 0.000 description 3
238000005119 centrifugation Methods 0.000 description 3
XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 3
ZMZNLKYXLARXFY-UHFFFAOYSA-H cerium(3+);oxalate Chemical compound [Ce+3].[Ce+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O ZMZNLKYXLARXFY-UHFFFAOYSA-H 0.000 description 3
238000007796 conventional method Methods 0.000 description 3
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 3
YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 3
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 3
238000001914 filtration Methods 0.000 description 3
229940093920 gynecological arsenic compound Drugs 0.000 description 3
230000006872 improvement Effects 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
230000004048 modification Effects 0.000 description 3
238000012986 modification Methods 0.000 description 3
GMQPBTKWMZBSCT-UHFFFAOYSA-K neodymium(3+);triacetate;hydrate Chemical compound O.[Nd+3].CC([O-])=O.CC([O-])=O.CC([O-])=O GMQPBTKWMZBSCT-UHFFFAOYSA-K 0.000 description 3
ATINCSYRHURBSP-UHFFFAOYSA-K neodymium(iii) chloride Chemical compound Cl[Nd](Cl)Cl ATINCSYRHURBSP-UHFFFAOYSA-K 0.000 description 3
229910000484 niobium oxide Inorganic materials 0.000 description 3
XNHGKSMNCCTMFO-UHFFFAOYSA-D niobium(5+);oxalate Chemical compound [Nb+5].[Nb+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O XNHGKSMNCCTMFO-UHFFFAOYSA-D 0.000 description 3
URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 3
235000005985 organic acids Nutrition 0.000 description 3
OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 3
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 3
229910052698 phosphorus Inorganic materials 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 3
239000006069 physical mixture Substances 0.000 description 3
ILVGAIQLOCKNQA-UHFFFAOYSA-N propyl 2-hydroxypropanoate Chemical compound CCCOC(=O)C(C)O ILVGAIQLOCKNQA-UHFFFAOYSA-N 0.000 description 3
238000010992 reflux Methods 0.000 description 3
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
229910001936 tantalum oxide Inorganic materials 0.000 description 3
LAJZODKXOMJMPK-UHFFFAOYSA-N tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 description 3
IIXQANVWKBCLEB-UHFFFAOYSA-N tellurium trioxide Chemical compound O=[Te](=O)=O IIXQANVWKBCLEB-UHFFFAOYSA-N 0.000 description 3
239000004408 titanium dioxide Substances 0.000 description 3
AXIFGFAGYFPNFC-UHFFFAOYSA-I 2-hydroxy-2-oxoacetate;niobium(5+) Chemical compound [Nb+5].OC(=O)C([O-])=O.OC(=O)C([O-])=O.OC(=O)C([O-])=O.OC(=O)C([O-])=O.OC(=O)C([O-])=O AXIFGFAGYFPNFC-UHFFFAOYSA-I 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
229910021541 Vanadium(III) oxide Inorganic materials 0.000 description 2
229910021542 Vanadium(IV) oxide Inorganic materials 0.000 description 2
239000012190 activator Substances 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
239000012018 catalyst precursor Substances 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
229960001759 cerium oxalate Drugs 0.000 description 2
229910000420 cerium oxide Inorganic materials 0.000 description 2
VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 2
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
239000013078 crystal Substances 0.000 description 2
238000010908 decantation Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000013461 design Methods 0.000 description 2
NLQFUUYNQFMIJW-UHFFFAOYSA-N dysprosium(iii) oxide Chemical compound O=[Dy]O[Dy]=O NLQFUUYNQFMIJW-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 description 2
RSEIMSPAXMNYFJ-UHFFFAOYSA-N europium(iii) oxide Chemical compound O=[Eu]O[Eu]=O RSEIMSPAXMNYFJ-UHFFFAOYSA-N 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 2
PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 2
JYTUFVYWTIKZGR-UHFFFAOYSA-N holmium(iii) oxide Chemical compound [O][Ho]O[Ho][O] JYTUFVYWTIKZGR-UHFFFAOYSA-N 0.000 description 2
MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
239000002609 medium Substances 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
235000006408 oxalic acid Nutrition 0.000 description 2
KFAFTZQGYMGWLU-UHFFFAOYSA-N oxo(oxovanadiooxy)vanadium Chemical compound O=[V]O[V]=O KFAFTZQGYMGWLU-UHFFFAOYSA-N 0.000 description 2
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 2
DUSYNUCUMASASA-UHFFFAOYSA-N oxygen(2-);vanadium(4+) Chemical compound [O-2].[O-2].[V+4] DUSYNUCUMASASA-UHFFFAOYSA-N 0.000 description 2
239000013618 particulate matter Substances 0.000 description 2
238000010298 pulverizing process Methods 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 description 2
238000000926 separation method Methods 0.000 description 2
238000007873 sieving Methods 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
ZIKATJAYWZUJPY-UHFFFAOYSA-N thulium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Tm+3].[Tm+3] ZIKATJAYWZUJPY-UHFFFAOYSA-N 0.000 description 2
CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 2
238000005406 washing Methods 0.000 description 2
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
OHVLMTFVQDZYHP-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CN1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O OHVLMTFVQDZYHP-UHFFFAOYSA-N 0.000 description 1
HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
LDXJRKWFNNFDSA-UHFFFAOYSA-N 2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound C1CN(CC2=NNN=C21)CC(=O)N3CCN(CC3)C4=CN=C(N=C4)NCC5=CC(=CC=C5)OC(F)(F)F LDXJRKWFNNFDSA-UHFFFAOYSA-N 0.000 description 1
WZFUQSJFWNHZHM-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 WZFUQSJFWNHZHM-UHFFFAOYSA-N 0.000 description 1
YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
GAPRPFRDVCCCHR-UHFFFAOYSA-N 3-bromoprop-1-ynyl(trimethyl)silane Chemical compound C[Si](C)(C)C#CCBr GAPRPFRDVCCCHR-UHFFFAOYSA-N 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229910004664 Cerium(III) chloride Inorganic materials 0.000 description 1
229910003317 GdCl3 Inorganic materials 0.000 description 1
229910005793 GeO 2 Inorganic materials 0.000 description 1
BHZNSIWFNMFWJE-UHFFFAOYSA-L [O-2].[Nb+5].C(C(=O)[O-])(=O)[O-].[Nb+5] Chemical compound [O-2].[Nb+5].C(C(=O)[O-])(=O)[O-].[Nb+5] BHZNSIWFNMFWJE-UHFFFAOYSA-L 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
QPBWWHHFCKKZJQ-UHFFFAOYSA-N acetic acid;praseodymium;hydrate Chemical compound O.[Pr].CC(O)=O.CC(O)=O.CC(O)=O QPBWWHHFCKKZJQ-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000012080 ambient air Substances 0.000 description 1
229910000379 antimony sulfate Inorganic materials 0.000 description 1
MVMLTMBYNXHXFI-UHFFFAOYSA-H antimony(3+);trisulfate Chemical compound [Sb+3].[Sb+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O MVMLTMBYNXHXFI-UHFFFAOYSA-H 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
JITPFBSJZPOLGT-UHFFFAOYSA-N cerium(3+);propan-2-olate Chemical compound [Ce+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] JITPFBSJZPOLGT-UHFFFAOYSA-N 0.000 description 1
AERUOEZHIAYQQL-UHFFFAOYSA-K cerium(3+);triacetate;hydrate Chemical compound O.[Ce+3].CC([O-])=O.CC([O-])=O.CC([O-])=O AERUOEZHIAYQQL-UHFFFAOYSA-K 0.000 description 1
229910000421 cerium(III) oxide Inorganic materials 0.000 description 1
230000008859 change Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000001447 compensatory effect Effects 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000000151 deposition Methods 0.000 description 1
JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 1
PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
238000007599 discharging Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
XPEKDHWAGKXPST-UHFFFAOYSA-N dysprosium(3+);propan-2-olate Chemical compound [Dy+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] XPEKDHWAGKXPST-UHFFFAOYSA-N 0.000 description 1
AAGMOWMTSATFBV-UHFFFAOYSA-K dysprosium(3+);triacetate;hydrate Chemical compound O.[Dy+3].CC([O-])=O.CC([O-])=O.CC([O-])=O AAGMOWMTSATFBV-UHFFFAOYSA-K 0.000 description 1
BOXVSFHSLKQLNZ-UHFFFAOYSA-K dysprosium(iii) chloride Chemical compound Cl[Dy](Cl)Cl BOXVSFHSLKQLNZ-UHFFFAOYSA-K 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
VOCNVTAXVORJBI-UHFFFAOYSA-N erbium(3+);propan-2-olate Chemical compound [Er+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] VOCNVTAXVORJBI-UHFFFAOYSA-N 0.000 description 1
DBUHPIKTDUMWTR-UHFFFAOYSA-K erbium(3+);triacetate Chemical compound [Er+3].CC([O-])=O.CC([O-])=O.CC([O-])=O DBUHPIKTDUMWTR-UHFFFAOYSA-K 0.000 description 1
HDGGAKOVUDZYES-UHFFFAOYSA-K erbium(iii) chloride Chemical compound Cl[Er](Cl)Cl HDGGAKOVUDZYES-UHFFFAOYSA-K 0.000 description 1
JGJIXMFWDPQYRL-UHFFFAOYSA-K europium(3+);triacetate;hydrate Chemical compound O.[Eu+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JGJIXMFWDPQYRL-UHFFFAOYSA-K 0.000 description 1
NNMXSTWQJRPBJZ-UHFFFAOYSA-K europium(iii) chloride Chemical compound Cl[Eu](Cl)Cl NNMXSTWQJRPBJZ-UHFFFAOYSA-K 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000004108 freeze drying Methods 0.000 description 1
229910021485 fumed silica Inorganic materials 0.000 description 1
MEANOSLIBWSCIT-UHFFFAOYSA-K gadolinium trichloride Chemical compound Cl[Gd](Cl)Cl MEANOSLIBWSCIT-UHFFFAOYSA-K 0.000 description 1
GXCUBNRUECGTSC-UHFFFAOYSA-K gadolinium(3+);triacetate;hydrate Chemical compound O.[Gd+3].CC([O-])=O.CC([O-])=O.CC([O-])=O GXCUBNRUECGTSC-UHFFFAOYSA-K 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
238000000227 grinding Methods 0.000 description 1
JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
229910000449 hafnium oxide Inorganic materials 0.000 description 1
WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
LCCGYXRQAXROOW-UHFFFAOYSA-K holmium(3+);triacetate;hydrate Chemical compound O.[Ho+3].CC([O-])=O.CC([O-])=O.CC([O-])=O LCCGYXRQAXROOW-UHFFFAOYSA-K 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
JLRJWBUSTKIQQH-UHFFFAOYSA-K lanthanum(3+);triacetate Chemical compound [La+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JLRJWBUSTKIQQH-UHFFFAOYSA-K 0.000 description 1
ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 1
230000007774 longterm Effects 0.000 description 1
229950010610 lutetium chloride Drugs 0.000 description 1
229910003443 lutetium oxide Inorganic materials 0.000 description 1
AEDROEGYZIARPU-UHFFFAOYSA-K lutetium(iii) chloride Chemical compound Cl[Lu](Cl)Cl AEDROEGYZIARPU-UHFFFAOYSA-K 0.000 description 1
239000000463 material Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910001960 metal nitrate Inorganic materials 0.000 description 1
229910000476 molybdenum oxide Inorganic materials 0.000 description 1
VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
238000000465 moulding Methods 0.000 description 1
238000003541 multi-stage reaction Methods 0.000 description 1
ZTILUDNICMILKJ-UHFFFAOYSA-N niobium(v) ethoxide Chemical compound CCO[Nb](OCC)(OCC)(OCC)OCC ZTILUDNICMILKJ-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
MPARYNQUYZOBJM-UHFFFAOYSA-N oxo(oxolutetiooxy)lutetium Chemical compound O=[Lu]O[Lu]=O MPARYNQUYZOBJM-UHFFFAOYSA-N 0.000 description 1
MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 description 1
UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229910003447 praseodymium oxide Inorganic materials 0.000 description 1
UMIVUKFKISBKQB-UHFFFAOYSA-N praseodymium(3+);propan-2-olate Chemical compound [Pr+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] UMIVUKFKISBKQB-UHFFFAOYSA-N 0.000 description 1
LHBNLZDGIPPZLL-UHFFFAOYSA-K praseodymium(iii) chloride Chemical compound Cl[Pr](Cl)Cl LHBNLZDGIPPZLL-UHFFFAOYSA-K 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 1
HJCRVWSKQNDSPZ-UHFFFAOYSA-N propan-2-olate;samarium(3+) Chemical compound [Sm+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] HJCRVWSKQNDSPZ-UHFFFAOYSA-N 0.000 description 1
RAKJHSBPOPJWKI-UHFFFAOYSA-N propan-2-olate;ytterbium(3+) Chemical compound [Yb+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] RAKJHSBPOPJWKI-UHFFFAOYSA-N 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000004064 recycling Methods 0.000 description 1
238000002390 rotary evaporation Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
LKSVMAKMHXTSQX-UHFFFAOYSA-K samarium(3+);triacetate;hydrate Chemical compound O.[Sm+3].CC([O-])=O.CC([O-])=O.CC([O-])=O LKSVMAKMHXTSQX-UHFFFAOYSA-K 0.000 description 1
BHXBZLPMVFUQBQ-UHFFFAOYSA-K samarium(iii) chloride Chemical compound Cl[Sm](Cl)Cl BHXBZLPMVFUQBQ-UHFFFAOYSA-K 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
JQBILSNVGUAPMM-UHFFFAOYSA-K terbium(3+);triacetate Chemical compound [Tb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JQBILSNVGUAPMM-UHFFFAOYSA-K 0.000 description 1
GFISHBQNVWAVFU-UHFFFAOYSA-K terbium(iii) chloride Chemical compound Cl[Tb](Cl)Cl GFISHBQNVWAVFU-UHFFFAOYSA-K 0.000 description 1
SCRZPWWVSXWCMC-UHFFFAOYSA-N terbium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Tb+3].[Tb+3] SCRZPWWVSXWCMC-UHFFFAOYSA-N 0.000 description 1
FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 description 1
SNMVVAHJCCXTQR-UHFFFAOYSA-K thulium(3+);triacetate Chemical compound [Tm+3].CC([O-])=O.CC([O-])=O.CC([O-])=O SNMVVAHJCCXTQR-UHFFFAOYSA-K 0.000 description 1
ILOTUXNTERMOJL-UHFFFAOYSA-K thulium(iii) chloride Chemical compound Cl[Tm](Cl)Cl ILOTUXNTERMOJL-UHFFFAOYSA-K 0.000 description 1
PYOOBRULIYNHJR-UHFFFAOYSA-K trichloroholmium Chemical compound Cl[Ho](Cl)Cl PYOOBRULIYNHJR-UHFFFAOYSA-K 0.000 description 1
230000005514 two-phase flow Effects 0.000 description 1
UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 1
229940041260 vanadyl sulfate Drugs 0.000 description 1
229910000352 vanadyl sulfate Inorganic materials 0.000 description 1
229910003454 ytterbium oxide Inorganic materials 0.000 description 1
229940075624 ytterbium oxide Drugs 0.000 description 1
OSCVBYCJUSOYPN-UHFFFAOYSA-K ytterbium(3+);triacetate Chemical compound [Yb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OSCVBYCJUSOYPN-UHFFFAOYSA-K 0.000 description 1
CKLHRQNQYIJFFX-UHFFFAOYSA-K ytterbium(III) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Yb+3] CKLHRQNQYIJFFX-UHFFFAOYSA-K 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP2010528872A 2007-10-11 2008-10-07 プロパン及びイソブタンのアンモ酸化又は酸化方法 Expired - Fee Related JP5450426B2 (ja)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US97928507P	2007-10-11	2007-10-11
US97927607P	2007-10-11	2007-10-11
US60/979,285		2007-10-11
US60/979,276		2007-10-11
PCT/US2008/011551 WO2009048553A2 (en)	2007-10-11	2008-10-07	Process for the ammoxidation or oxidation of propane and isobutane

Publications (2)

Publication Number	Publication Date
JP2011500564A JP2011500564A (ja)	2011-01-06
JP5450426B2 true JP5450426B2 (ja)	2014-03-26

Family

ID=40342454

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2010528872A Expired - Fee Related JP5450426B2 (ja)	2007-10-11	2008-10-07	プロパン及びイソブタンのアンモ酸化又は酸化方法

Country Status (10)

Country	Link
EP (1)	EP2205554A2 (pt)
JP (1)	JP5450426B2 (pt)
KR (1)	KR20100090252A (pt)
CN (1)	CN101878194A (pt)
BR (1)	BRPI0817877A2 (pt)
EG (1)	EG26218A (pt)
MX (1)	MX2010003907A (pt)
MY (1)	MY154935A (pt)
RU (1)	RU2495024C2 (pt)
WO (1)	WO2009048553A2 (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
TR201810575T4 (tr)	2010-05-13	2018-08-27	Asahi Chemical Ind	Karışık katalizör.
JP5694727B2 (ja) *	2010-10-04	2015-04-01	旭化成ケミカルズ株式会社	不飽和酸又は不飽和ニトリルの製造方法
JP5866292B2 (ja) *	2010-11-05	2016-02-17	旭化成ケミカルズ株式会社	酸化物触媒、酸化物触媒の製造方法、不飽和酸の製造方法及び不飽和ニトリルの製造方法
JP5879029B2 (ja) *	2010-11-09	2016-03-08	日立造船株式会社	アンモニア酸化・分解触媒
CN103402976B (zh)	2011-03-02	2016-03-30	旭化成化学株式会社	不饱和腈的制造方法
DE102013202048A1 (de) *	2013-02-07	2013-04-18	Basf Se	Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist
CN104645984B (zh) *	2013-11-20	2017-09-19	正大能源材料(大连)有限公司	一种饱和烷烃氨氧化制取不饱和腈的催化剂及其应用
CN105771959B (zh) *	2014-12-22	2018-12-18	中触媒有限公司	一种复合金属氧化物催化剂及其制备方法和应用
CN107282060B (zh) *	2016-04-13	2020-01-03	中国石油化工股份有限公司	氨氧化工艺丙烯腈催化剂
CN107282061B (zh) *	2016-04-13	2020-01-03	中国石油化工股份有限公司	氨氧化制丙烯腈的催化剂
CN107282064B (zh) *	2016-04-13	2020-05-05	中国石油化工股份有限公司	用于生产丙烯腈的催化剂
CN107282062A (zh) *	2016-04-13	2017-10-24	中国石油化工股份有限公司	丙烯氨氧化制丙烯腈的催化剂及其制备方法
CN107282063B (zh) *	2016-04-13	2020-01-03	中国石油化工股份有限公司	丙烯氨氧化法丙烯腈催化剂
CN107282065B (zh) *	2016-04-13	2020-01-03	中国石油化工股份有限公司	丙烯腈催化剂及其制备方法
CN107282092B (zh) *	2016-04-13	2020-03-31	中国石油化工股份有限公司	用于烯烃氨氧化合成丙烯腈的催化剂
CN107282093A (zh) *	2016-04-13	2017-10-24	中国石油化工股份有限公司	丙烯氨氧化制丙烯腈的催化剂
CN106076413A (zh) *	2016-06-05	2016-11-09	王金明	一种异丁烷生产甲基丙烯酸催化剂的制备方法
WO2026004428A1 (ja) *	2024-06-28	2026-01-02	旭化成株式会社	気相接触酸化反応触媒の製造方法、不飽和ニトリルの製造方法、及びアルケンの製造方法
WO2026004414A1 (ja) *	2024-06-28	2026-01-02	旭化成株式会社	触媒及びその製造方法並びに不飽和ニトリル又はアルケンの製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0529853B1 (en) *	1991-08-08	1996-02-28	Mitsubishi Chemical Corporation	Catalyst and process for producing nitriles
JP3168716B2 (ja) *	1992-02-04	2001-05-21	三菱化学株式会社	ニトリルの製造法
JP3217794B2 (ja) *	1996-03-12	2001-10-15	旭化成株式会社	不飽和ニトリルを製造する方法
US5994580A (en) *	1996-10-21	1999-11-30	Toagosei Co., Ltd.	Process for producing acrylic acid
JP4179675B2 (ja) *	1997-08-11	2008-11-12	旭化成ケミカルズ株式会社	不飽和ニトリルを製造する方法
JP4484995B2 (ja) *	2000-01-31	2010-06-16	旭化成ケミカルズ株式会社	不飽和ニトリルを製造する方法
WO2001096016A1 (en) *	2000-06-15	2001-12-20	Asahi Kasei Kabushiki Kaisha	Catalyst for vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation of propane or isobutane
JP2003048870A (ja) *	2001-05-30	2003-02-21	Mitsubishi Chemicals Corp	アクリロニトリルおよび／またはアクリル酸の製造方法
JP4688499B2 (ja) *	2002-12-02	2011-05-25	イネオス・ユーエスエイ・エルエルシー	オレフィンのアクリロニトリル及びメタクリロニトリルへの転化用の触媒組成物およびその転化方法
DE60336348D1 (de) *	2003-06-09	2011-04-21	Asahi Kasei Chemicals Corp	Katalysator zur oxidation oder ammoxidation
JP2005193172A (ja) *	2004-01-08	2005-07-21	Daiyanitorikkusu Kk	流動反応方法およびアクリロニトリルの製造方法

2008
- 2008-10-07 JP JP2010528872A patent/JP5450426B2/ja not_active Expired - Fee Related
- 2008-10-07 MX MX2010003907A patent/MX2010003907A/es not_active Application Discontinuation
- 2008-10-07 EP EP08837190A patent/EP2205554A2/en not_active Withdrawn
- 2008-10-07 WO PCT/US2008/011551 patent/WO2009048553A2/en not_active Ceased
- 2008-10-07 BR BRPI0817877-1A patent/BRPI0817877A2/pt not_active IP Right Cessation
- 2008-10-07 MY MYPI2010001637A patent/MY154935A/en unknown
- 2008-10-07 KR KR1020107010308A patent/KR20100090252A/ko not_active Abandoned
- 2008-10-07 CN CN2008801183712A patent/CN101878194A/zh active Pending
- 2008-10-07 RU RU2010118525/04A patent/RU2495024C2/ru not_active IP Right Cessation
2010
- 2010-04-11 EG EG2010040582A patent/EG26218A/en active

Also Published As

Publication number	Publication date
CN101878194A (zh)	2010-11-03
BRPI0817877A2 (pt)	2015-03-31
EP2205554A2 (en)	2010-07-14
JP2011500564A (ja)	2011-01-06
MX2010003907A (es)	2010-09-14
EG26218A (en)	2013-04-29
MY154935A (en)	2015-08-28
KR20100090252A (ko)	2010-08-13
RU2495024C2 (ru)	2013-10-10
RU2010118525A (ru)	2011-11-20
WO2009048553A3 (en)	2009-06-11
WO2009048553A2 (en)	2009-04-16

Legal Events

Date	Code	Title	Description
2011-08-26	A621	Written request for application examination	Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110825
2013-05-01	A977	Report on retrieval	Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130430
2013-05-30	A131	Notification of reasons for refusal	Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130529
2013-08-29	A521	Request for written amendment filed	Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130828
2013-11-21	TRDD	Decision of grant or rejection written
2013-11-26	A01	Written decision to grant a patent or to grant a registration (utility model)	Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20131125
2014-01-09	A61	First payment of annual fees (during grant procedure)	Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20131225
2014-01-10	R150	Certificate of patent or registration of utility model	Free format text: JAPANESE INTERMEDIATE CODE: R150
2017-01-10	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2018-01-10	LAPS	Cancellation because of no payment of annual fees

Publication	Publication Date	Title
JP5450426B2 (ja)	2014-03-26	プロパン及びイソブタンのアンモ酸化又は酸化方法
JP5547057B2 (ja)	2014-07-09	混合金属酸化物触媒および低級アルカン系炭化水素の接触転化
JP5596979B2 (ja)	2014-10-01	混合金属酸化物触媒を用いたプロパン及びイソブタンのアンモ酸化方法
US8658817B2 (en)	2014-02-25	Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons
JP5011176B2 (ja)	2012-08-29	アクリロニトリル合成用触媒およびアクリロニトリルの製造方法
JP2009142815A (ja)	2009-07-02	アルカン及びオレフィンのアンモ酸化のための触媒組成物、その製造方法、及び使用方法
WO2009073171A2 (en)	2009-06-11	Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons
US7754910B2 (en)	2010-07-13	Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
US20080103325A1 (en)	2008-05-01	Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
RU2455064C1 (ru)	2012-07-10	Катализатор для окисления углеводородов при газофазном контакте, способ получения этого катализатора и способ газофазного окисления углеводородов с использованием этого катализатора
JP3500680B2 (ja)	2004-02-23	ニトリル製造用触媒の製造方法
US20090198081A1 (en)	2009-08-06	Process for the ammoxidation of propane and isobutane
US7531681B2 (en)	2009-05-12	Process for the ammoxidation of propane and isobutane
RU2451548C2 (ru)	2012-05-27	Способ окислительного аммонолиза пропана и изобутана в присутствии смешанных металлоксидных катализаторов
US20070123730A1 (en)	2007-05-31	Catalyst composition without antimony or molybdenum for ammoxidation of alkanes, a process of making and a process of using thereof
US20080103326A1 (en)	2008-05-01	Lithium containing mixed metal oxide catalysts for ammoxidation of propane and isobutane
US20090005586A1 (en)	2009-01-01	Mixed metal oxide catalysts for the ammoxidation of propane and isobutane