JP5706973B2 - エチレン性不飽和モノマの重合阻害方法、および、多成分重合阻害組成物 - Google Patents
エチレン性不飽和モノマの重合阻害方法、および、多成分重合阻害組成物 Download PDFInfo
- Publication number
- JP5706973B2 JP5706973B2 JP2013552592A JP2013552592A JP5706973B2 JP 5706973 B2 JP5706973 B2 JP 5706973B2 JP 2013552592 A JP2013552592 A JP 2013552592A JP 2013552592 A JP2013552592 A JP 2013552592A JP 5706973 B2 JP5706973 B2 JP 5706973B2
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- JP
- Japan
- Prior art keywords
- nitroxide
- ethylenically unsaturated
- polymerization
- unsaturated monomer
- phenylenediamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/32—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/020,487 US8691994B2 (en) | 2011-02-03 | 2011-02-03 | Multi-component polymerization inhibitors for ethylenically unsaturated monomers |
| US13/020,487 | 2011-02-03 | ||
| PCT/US2012/023453 WO2012106410A2 (fr) | 2011-02-03 | 2012-02-01 | Inhibiteurs de polymérisation multi-composants pour monomères à insaturation éthylénique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014507533A JP2014507533A (ja) | 2014-03-27 |
| JP5706973B2 true JP5706973B2 (ja) | 2015-04-22 |
Family
ID=46601076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013552592A Active JP5706973B2 (ja) | 2011-02-03 | 2012-02-01 | エチレン性不飽和モノマの重合阻害方法、および、多成分重合阻害組成物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8691994B2 (fr) |
| EP (1) | EP2670800B1 (fr) |
| JP (1) | JP5706973B2 (fr) |
| KR (1) | KR101853649B1 (fr) |
| CN (1) | CN103339179B (fr) |
| ES (1) | ES2665976T3 (fr) |
| TW (1) | TWI537250B (fr) |
| WO (1) | WO2012106410A2 (fr) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2612507C2 (ru) * | 2011-11-29 | 2017-03-09 | Дорф Кетал Кемикалс (Индия) Прайвит Лимитэд | Композиция добавки на основе амина для контроля и ингибирования полимеризации стирола и способ ее использования |
| JP5697617B2 (ja) * | 2012-02-09 | 2015-04-08 | 富士フイルム株式会社 | インクジェット記録用インク組成物、インクジェット記録方法、及び、印刷物 |
| JP6043937B2 (ja) * | 2012-08-16 | 2016-12-14 | 株式会社片山化学工業研究所 | ビニル芳香族モノマーの重合を抑制するための組成物 |
| CN103553862A (zh) * | 2013-11-19 | 2014-02-05 | 北京斯伯乐科技发展有限公司 | 一种用于环戊烯装置的戊二烯阻聚剂的制备及其使用方法 |
| US9399622B2 (en) * | 2013-12-03 | 2016-07-26 | Ecolab Usa Inc. | Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes |
| CN104403059B (zh) * | 2014-11-06 | 2018-01-19 | 山纳合成橡胶有限责任公司 | 一种接枝型氯丁橡胶终止剂及其制备方法 |
| EP3026101A1 (fr) | 2014-11-26 | 2016-06-01 | Borealis AG | Huile de lavage destinée à être utilisée comme agent antisalissure dans des compresseurs de gaz |
| CA3034458C (fr) * | 2016-08-31 | 2023-09-26 | Ecolab Usa Inc. | Methode d'inhibition de la polymerisation dans une eau de procede |
| EP3585867A1 (fr) * | 2017-02-27 | 2020-01-01 | Ecolab USA, Inc. | Formulation anti-encrassement pour compresseurs |
| CN111100002B (zh) * | 2018-10-25 | 2024-04-02 | 中国石油化工股份有限公司 | 一种复配型乙酸乙烯酯精馏阻聚剂及其使用方法 |
| EP3947271A1 (fr) | 2019-04-02 | 2022-02-09 | Ecolab Usa Inc. | Système de génération de dioxyde de chlore pur à usage d'acide réduit |
| CN111943869A (zh) * | 2019-05-17 | 2020-11-17 | 中国石油天然气股份有限公司 | 丙烯腈阻聚剂、其制备方法及应用 |
| JP2021004316A (ja) * | 2019-06-26 | 2021-01-14 | パナソニックIpマネジメント株式会社 | 樹脂組成物、プリプレグ、プリプレグの製造方法、積層板及びプリント配線板 |
| KR102400224B1 (ko) * | 2020-06-03 | 2022-05-23 | 주식회사 켐트로닉스 | 알킬 3-알콕시 프로피오네이트의 제조 방법 |
| CN113461864A (zh) * | 2021-08-12 | 2021-10-01 | 中化学科学技术研究有限公司 | 一种丙烯酸酯类接枝共聚物的制备方法及其树脂组合物 |
| TW202404930A (zh) | 2022-04-01 | 2024-02-01 | 美商藝康美國公司 | 在共軛二烯單體之萃取蒸餾期間減少非所要之乳化聚合 |
| TW202348786A (zh) | 2022-04-01 | 2023-12-16 | 美商藝康美國公司 | 用於蒸氣空間應用之防汙劑組成物 |
| TW202348787A (zh) | 2022-04-01 | 2023-12-16 | 美商藝康美國公司 | 用於乙烯系單體流之高苛刻度加工的防汙劑組成物 |
| CN114685854A (zh) * | 2022-04-25 | 2022-07-01 | 萧县新秀新材料有限公司 | 一种用于反式异戊橡胶的稳定剂及应用 |
| WO2024190862A1 (fr) * | 2023-03-16 | 2024-09-19 | デンカ株式会社 | Composition durcissable et produit durci associé |
| CN118546114A (zh) * | 2024-07-09 | 2024-08-27 | 岳阳兴长石化股份有限公司 | 一种连续性制备甲基四氢苯酐的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US3744988A (en) | 1971-12-23 | 1973-07-10 | Lilly Co Eli | Tobacco sucker control |
| US3959358A (en) | 1975-01-08 | 1976-05-25 | Nalco Chemical Company | Polymerization inhibition of acrylate esters |
| US4670131A (en) | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
| CN1010679B (zh) | 1986-06-05 | 1990-12-05 | 化学工业部锦西化工研究院 | 甲基丙烯酸及其酯类的复合阻聚剂 |
| US4720566A (en) | 1986-10-23 | 1988-01-19 | Betz Laboratories, Inc. | Method and composition for inhibiting acrylonitrile polymerization |
| US5290888A (en) | 1990-07-20 | 1994-03-01 | Ciba-Geigy Corporation | Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions |
| US5322960A (en) | 1993-04-15 | 1994-06-21 | Nippon Shokubai Co., Ltd. | Method for inhibiting polymerization of (meth) acrylic acid and esters thereof |
| US5728872A (en) | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
| US5489720A (en) | 1994-06-30 | 1996-02-06 | Betz Laboratories, Inc. | Methods for inhibiting vinyl aromatic monomer polymerization |
| US6608226B1 (en) | 1995-06-07 | 2003-08-19 | Baker Hughes Incorporated | Use of phenylenediamines and hindered phenols to inhibit polymer formation during the manufacture of acrylonitrile |
| WO1998014416A1 (fr) | 1996-10-04 | 1998-04-09 | Betzdearborn Inc. | Compositions et methodes inhibant la polymerisation de monomeres aromatiques vinyliques |
| JP3187345B2 (ja) * | 1997-07-29 | 2001-07-11 | 伯東株式会社 | オレフィン類製造あるいは精製工程の汚れ防止方法 |
| US5955643A (en) | 1997-10-17 | 1999-09-21 | Nalco/Exxon Energy Chemicals, L.P. | Composition and method for inhibiting polymerization during the anaerobic of styrene |
| JP2002524471A (ja) | 1998-09-09 | 2002-08-06 | ベイカー ヒューズ インコーポレイテッド | ヒンダードヒドロキシルアミンを使用したビニルモノマーの重合禁止剤 |
| US6337426B1 (en) | 1998-11-23 | 2002-01-08 | Nalco/Exxon Energy Chemicals, L.P. | Antifoulant compositions and processes |
| US20040019247A1 (en) * | 1999-02-26 | 2004-01-29 | Basf Aktiengesellschaft | Continuous recovery of styrene from a styrene-containing mixture |
| ES2292487T3 (es) | 1999-12-03 | 2008-03-16 | Chemtura Corporation | Composicion y metodo para inhibir la polimerizacion y el crecimiento polimerico. |
| US6262323B1 (en) | 1999-12-14 | 2001-07-17 | Baker Hughes Incorporated | Polymerization inhibition of isoprene |
| JP3863694B2 (ja) | 1999-12-24 | 2006-12-27 | 株式会社日本触媒 | ビニル化合物中のn−オキシル化合物の安定化方法 |
| US6525146B1 (en) | 2000-04-03 | 2003-02-25 | Baker Hughes Incorporated | Inhibition of popcorn polymer growth |
| US6447649B1 (en) * | 2000-07-24 | 2002-09-10 | Ge Betz, Inc. | Polymerization inhibitor for vinyl-containing materials |
| JP2002234858A (ja) | 2001-02-08 | 2002-08-23 | Mitsubishi Rayon Co Ltd | α,β−不飽和カルボン酸及びそのエステルの重合防止方法 |
| FR2822832B1 (fr) * | 2001-04-02 | 2005-01-14 | Atofina | Polymerisation en suspension acqueuse du chlorure de vinyle seul ou en melange avec un autre monomere vinylique avec utilisation d'un radical stable de type nitroxyde comme agent d'arret de polymerisation |
| US6579442B2 (en) | 2001-05-22 | 2003-06-17 | Ge Betz, Inc. | Methods and compositions for inhibiting polymerization of vinyl monomers |
| JP4993831B2 (ja) * | 2001-09-19 | 2012-08-08 | 日本合成化学工業株式会社 | エチレン−酢酸ビニル共重合体及びそのケン化物の製造法 |
| JP4679144B2 (ja) * | 2004-12-28 | 2011-04-27 | 伯東株式会社 | ジビニルベンゼンと、スチレン又はスチレン誘導体を含む共重合体の重合抑制方法 |
| US7651635B1 (en) | 2009-02-05 | 2010-01-26 | Nalco Company | Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination |
| DE102009001577A1 (de) * | 2009-03-16 | 2010-09-23 | Evonik Röhm Gmbh | Für eine Aufreinigung stabilisierte Zusammensetzung und Verfahren zur Aufreinigung und zur Herstellung von Hydroxyalkyl(meth)acrylaten |
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2011
- 2011-02-03 US US13/020,487 patent/US8691994B2/en active Active
-
2012
- 2012-01-12 TW TW101101217A patent/TWI537250B/zh active
- 2012-02-01 JP JP2013552592A patent/JP5706973B2/ja active Active
- 2012-02-01 WO PCT/US2012/023453 patent/WO2012106410A2/fr not_active Ceased
- 2012-02-01 ES ES12741845.7T patent/ES2665976T3/es active Active
- 2012-02-01 KR KR1020137020525A patent/KR101853649B1/ko active Active
- 2012-02-01 CN CN201280007432.4A patent/CN103339179B/zh active Active
- 2012-02-01 EP EP12741845.7A patent/EP2670800B1/fr active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2670800A4 (fr) | 2016-03-02 |
| CN103339179B (zh) | 2015-06-17 |
| JP2014507533A (ja) | 2014-03-27 |
| ES2665976T3 (es) | 2018-04-30 |
| EP2670800A2 (fr) | 2013-12-11 |
| US20120203020A1 (en) | 2012-08-09 |
| TWI537250B (zh) | 2016-06-11 |
| EP2670800B1 (fr) | 2018-01-17 |
| KR20130119969A (ko) | 2013-11-01 |
| WO2012106410A2 (fr) | 2012-08-09 |
| US8691994B2 (en) | 2014-04-08 |
| TW201249794A (en) | 2012-12-16 |
| KR101853649B1 (ko) | 2018-05-02 |
| WO2012106410A3 (fr) | 2012-11-08 |
| CN103339179A (zh) | 2013-10-02 |
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