JP6126852B2 - ガスタービン部品のコーティング及びコーティング方法 - Google Patents

ガスタービン部品のコーティング及びコーティング方法 Download PDF

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Publication number: JP6126852B2
Authority: JP; Japan
Prior art keywords: region; coating; chromium; substrate; diffusion
Prior art date: 2012-02-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

JP2013018304A

Other languages

English (en)

Japanese (ja)

Other versions

JP2013216968A (ja

Inventor

エス．マーフィーケネス

シー．バスタウィリアム

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Howmet Corp

Original Assignee

Howmet Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2012-02-21

Filing date

2013-02-01

Publication date

2017-05-10

2013-02-01 Application filed by Howmet Corp filed Critical Howmet Corp

2013-10-24 Publication of JP2013216968A publication Critical patent/JP2013216968A/ja

2017-05-10 Application granted granted Critical

2017-05-10 Publication of JP6126852B2 publication Critical patent/JP6126852B2/ja

Status Active legal-status Critical Current

2033-02-01 Anticipated expiration legal-status Critical

Links

238000000576 coating method Methods 0.000 title claims description 141
239000011248 coating agent Substances 0.000 title claims description 122
239000011651 chromium Substances 0.000 claims description 155
238000009792 diffusion process Methods 0.000 claims description 80
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 75
229910052804 chromium Inorganic materials 0.000 claims description 71
238000000034 method Methods 0.000 claims description 47
239000000758 substrate Substances 0.000 claims description 43
229910000951 Aluminide Inorganic materials 0.000 claims description 25
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 25
238000009713 electroplating Methods 0.000 claims description 24
230000008569 process Effects 0.000 claims description 23
230000000873 masking effect Effects 0.000 claims description 22
229910052751 metal Inorganic materials 0.000 claims description 19
239000002184 metal Substances 0.000 claims description 19
238000010438 heat treatment Methods 0.000 claims description 17
238000000151 deposition Methods 0.000 claims description 12
239000007788 liquid Substances 0.000 claims description 12
229910052759 nickel Inorganic materials 0.000 claims description 11
229910000531 Co alloy Inorganic materials 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 4
239000000463 material Substances 0.000 claims description 3
238000001652 electrophoretic deposition Methods 0.000 claims description 2
RMXTYBQNQCQHEU-UHFFFAOYSA-N ac1lawpn Chemical compound [Cr]#[Cr] RMXTYBQNQCQHEU-UHFFFAOYSA-N 0.000 claims 1
238000007581 slurry coating method Methods 0.000 claims 1
238000005260 corrosion Methods 0.000 description 40
230000007797 corrosion Effects 0.000 description 40
238000007747 plating Methods 0.000 description 31
229910052782 aluminium Inorganic materials 0.000 description 28
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 25
229910045601 alloy Inorganic materials 0.000 description 23
239000000956 alloy Substances 0.000 description 23
229910001011 CMSX-4 Inorganic materials 0.000 description 17
238000012360 testing method Methods 0.000 description 15
238000005269 aluminizing Methods 0.000 description 14
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
229910000601 superalloy Inorganic materials 0.000 description 14
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
238000005254 chromizing Methods 0.000 description 7
230000008021 deposition Effects 0.000 description 7
230000003647 oxidation Effects 0.000 description 7
238000007254 oxidation reaction Methods 0.000 description 7
230000008859 change Effects 0.000 description 6
239000000843 powder Substances 0.000 description 6
239000011734 sodium Substances 0.000 description 6
239000012808 vapor phase Substances 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
239000002243 precursor Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
238000010586 diagram Methods 0.000 description 4
239000011253 protective coating Substances 0.000 description 4
230000001681 protective effect Effects 0.000 description 4
239000002002 slurry Substances 0.000 description 4
229910000599 Cr alloy Inorganic materials 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
238000013461 design Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000001000 micrograph Methods 0.000 description 3
238000012545 processing Methods 0.000 description 3
230000002829 reductive effect Effects 0.000 description 3
229910052938 sodium sulfate Inorganic materials 0.000 description 3
235000011152 sodium sulphate Nutrition 0.000 description 3
239000012720 thermal barrier coating Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000012190 activator Substances 0.000 description 2
239000011825 aerospace material Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
239000010432 diamond Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
238000007689 inspection Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000012071 phase Substances 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
239000006104 solid solution Substances 0.000 description 2
229910000990 Ni alloy Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
-1 and about 0.60 Mo) % Inorganic materials 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
238000005422 blasting Methods 0.000 description 1
238000005229 chemical vapour deposition Methods 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
239000000788 chromium alloy Substances 0.000 description 1
238000005253 cladding Methods 0.000 description 1
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
238000001962 electrophoresis Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000009413 insulation Methods 0.000 description 1
239000011344 liquid material Substances 0.000 description 1
238000003754 machining Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
238000010525 oxidative degradation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000003973 paint Substances 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
238000005240 physical vapour deposition Methods 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000004544 sputter deposition Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
238000007740 vapor deposition Methods 0.000 description 1
238000005019 vapor deposition process Methods 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 1

Images

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/02—Pretreatment of the material to be coated
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/58—Embedding in a powder mixture, i.e. pack cementation more than one element being diffused in more than one step
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/02—Electrophoretic coating characterised by the process with inorganic material
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
- C25D13/16—Wires; Strips; Foils
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
- C25D5/022—Electroplating of selected surface areas using masking means
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C25D5/42—Pretreatment of metallic surfaces to be electroplated of light metals
- C25D5/44—Aluminium
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
- C25D5/50—After-treatment of electroplated surfaces by heat-treatment
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/30—Fixing blades to rotors; Blade roots ; Blade spacers
- F01D5/3007—Fixing blades to rotors; Blade roots ; Blade spacers of axial insertion type
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/30—Manufacture with deposition of material
- F05D2230/31—Layer deposition
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/10—Metals, alloys or intermetallic compounds
- F05D2300/12—Light metals
- F05D2300/121—Aluminium
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/10—Metals, alloys or intermetallic compounds
- F05D2300/13—Refractory metals, i.e. Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W
- F05D2300/132—Chromium

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Electrochemistry (AREA)
Mechanical Engineering (AREA)
General Engineering & Computer Science (AREA)
Inorganic Chemistry (AREA)
Turbine Rotor Nozzle Sealing (AREA)
Other Surface Treatments For Metallic Materials (AREA)
Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Electroplating Methods And Accessories (AREA)

JP2013018304A 2012-02-21 2013-02-01 ガスタービン部品のコーティング及びコーティング方法 Active JP6126852B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US201261633935P	2012-02-21	2012-02-21
US61/633935		2012-02-21

Publications (2)

Publication Number	Publication Date
JP2013216968A JP2013216968A (ja)	2013-10-24
JP6126852B2 true JP6126852B2 (ja)	2017-05-10

Family

ID=47747471

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2013018304A Active JP6126852B2 (ja)	2012-02-21	2013-02-01	ガスタービン部品のコーティング及びコーティング方法

Country Status (3)

Country	Link
US (1)	US20160010472A1 (fr)
EP (1)	EP2631325A3 (fr)
JP (1)	JP6126852B2 (fr)

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GB2421032A (en) *	2004-12-11	2006-06-14	Siemens Ind Turbomachinery Ltd	A method of protecting a component against hot corrosion
US9133718B2 (en) *	2004-12-13	2015-09-15	Mt Coatings, Llc	Turbine engine components with non-aluminide silicon-containing and chromium-containing protective coatings and methods of forming such non-aluminide protective coatings
US7371428B2 (en) *	2005-11-28	2008-05-13	Howmet Corporation	Duplex gas phase coating
DE102005060243A1 (de) *	2005-12-14	2007-06-21	Man Turbo Ag	Verfahren zum Beschichten einer Schaufel und Schaufel einer Gasturbine

2013
- 2013-02-01 JP JP2013018304A patent/JP6126852B2/ja active Active
- 2013-02-04 US US13/815,152 patent/US20160010472A1/en not_active Abandoned
- 2013-02-20 EP EP13155956.9A patent/EP2631325A3/fr not_active Withdrawn

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JP2013216968A (ja)	2013-10-24
EP2631325A2 (fr)	2013-08-28
US20160010472A1 (en)	2016-01-14

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